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  • 1
    Electronic Resource
    Electronic Resource
    Anthropogenic ocean acidification over the twenty-first century and its impact on calcifying organisms (2005)
    [s.l.] : Nature Publishing Group
    Nature 437 (2005), S. 681-686 
    Details
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Today's surface ocean is saturated with respect to calcium carbonate, but increasing atmospheric carbon dioxide concentrations are reducing ocean pH and carbonate ion concentrations, and thus the level of calcium carbonate saturation. Experimental evidence suggests that if these trends ...
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1038/nature04095
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    Paper (German National Licenses)
    Fulltext
  • 2
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    Biogeochemical protocols and diagnostics for the CMIP6 Ocean Model Intercomparison Project (OMIP) (2017)
    Copernicus Publications (EGU)
    In:  Geoscientific Model Development, 10 (6). pp. 2169-2199.
    Details
    Publication Date: 2020-02-06
    Description: The Ocean Model Intercomparison Project (OMIP) focuses on the physics and biogeochemistry of the ocean component of Earth system models participating in the sixth phase of the Coupled Model Intercomparison Project (CMIP6). OMIP aims to provide standard protocols and diagnostics for ocean models, while offering a forum to promote their common assessment and improvement. It also offers to compare solutions of the same ocean models when forced with reanalysis data (OMIP simulations) vs. when integrated within fully coupled Earth system models (CMIP6). Here we detail simulation protocols and diagnostics for OMIP's biogeochemical and inert chemical tracers. These passive-tracer simulations will be coupled to ocean circulation models, initialized with observational data or output from a model spin-up, and forced by repeating the 1948–2009 surface fluxes of heat, fresh water, and momentum. These so-called OMIP-BGC simulations include three inert chemical tracers (CFC-11, CFC-12, SF6) and biogeochemical tracers (e.g., dissolved inorganic carbon, carbon isotopes, alkalinity, nutrients, and oxygen). Modelers will use their preferred prognostic BGC model but should follow common guidelines for gas exchange and carbonate chemistry. Simulations include both natural and total carbon tracers. The required forced simulation (omip1) will be initialized with gridded observational climatologies. An optional forced simulation (omip1-spunup) will be initialized instead with BGC fields from a long model spin-up, preferably for 2000 years or more, and forced by repeating the same 62-year meteorological forcing. That optional run will also include abiotic tracers of total dissolved inorganic carbon and radiocarbon, CTabio and 14CTabio, to assess deep-ocean ventilation and distinguish the role of physics vs. biology. These simulations will be forced by observed atmospheric histories of the three inert gases and CO2 as well as carbon isotope ratios of CO2. OMIP-BGC simulation protocols are founded on those from previous phases of the Ocean Carbon-Cycle Model Intercomparison Project. They have been merged and updated to reflect improvements concerning gas exchange, carbonate chemistry, and new data for initial conditions and atmospheric gas histories. Code is provided to facilitate their implementation.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Format: text
    DOI: 10.5194/gmd-10-2169-2017
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 3
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    Coastal vegetation and estuaries are collectively a greenhouse gas sink (2023)
    Nature Research
    Details
    Publication Date: 2024-02-07
    Description: Coastal ecosystems release or absorb carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O), but the net effects of these ecosystems on the radiative balance remain unknown. We compiled a dataset of observations from 738 sites from studies published between 1975 and 2020 to quantify CO2, CH4 and N2O fluxes in estuaries and coastal vegetation in ten global regions. We show that the CO2-equivalent (CO(2)e) uptake by coastal vegetation is decreased by 23-27% due to estuarine CO(2)e outgassing, resulting in a global median net sink of 391 or 444 TgCO(2)e yr(-1) using the 20- or 100-year global warming potentials, respectively. Globally, total coastal CH4 and N2O emissions decrease the coastal CO2 sink by 9-20%. Southeast Asia, North America and Africa are critical regional hotspots of GHG sinks. Understanding these hotspots can guide our efforts to strengthen coastal CO2 uptake while effectively reducing CH4 and N2O emissions. The authors show that estuarine and coastal vegetation are collectively a greenhouse gas (GHG) sink for the atmosphere, but methane and nitrous oxide emissions counteract the carbon dioxide uptake. Critical coastal GHG sink hotspots are identified in Southeast Asia, North America and Africa.
    Type: Article , PeerReviewed
    Format: text
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 4
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    Quantifying the ocean carbon sink for 1994-2007: Combined evidence from multiple methods (2020)
    In:  EPIC3AGU Fall Meeting, online everywhere, 2020-12-07-2020-12-07
    Details
    Publication Date: 2021-03-31
    Description: By means of a variety of international observing and modeling efforts, the ocean carbon community has developed several independent estimates for ocean carbon uptake. In this presentation, we report on the synthesis effort we are undertaking under the auspices of an Ocean Carbon and Biogeochemistry Working Group. Our initial goal for this working group is to determine the best estimate for the net and anthropogenic carbon sink from 1994-2007, and then to infer the total magnitude of the poorly quantified fluxes that constitute their difference. Estimates for the net, or contemporary, ocean carbon uptake are derived from surface ocean pCO2 data interpolated to global coverage. From 4 of these products, we find Fnet = -1.7 PgC/yr for 1994-2007. Estimates for uptake of anthropogenic carbon comes from (1) interior observations of dissolved inorganic carbon and other tracers, (2) an ocean model constrained with observations, and (3) a suite of nine free-running ocean hindcast models in which the natural carbon cycle is assumed to be in a long-term steady state. Fant = -2.3 PgC/yr from the mean of these approaches. The difference between these two estimates is -0.6 PgC/yr, and acts as a quantitative constraint on the sum of the additional fluxes. As coastal zones and the Arctic are additional net carbon sinks, the sum of outgassed river-derived carbon, skin temperature effects on air-sea CO2 exchange, and non-steady state natural carbon fluxes in the open ocean can be no larger than a few tenths of PgC/yr. Our presentation details the uncertainties and assumptions made in deriving these estimates, and suggests paths forward to further reduce uncertainties.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 5
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    Biogeochemical protocols and diagnostics for the CMIP6 Ocean Model Intercomparison Project (OMIP) (2016)
    In:  EPIC3Geoscientific Model Development Discussions, pp. 1-45, ISSN: 1991-962X
    Details
    Publication Date: 2016-11-14
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 6
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    Biogeochemical protocols and diagnostics for the CMIP6 Ocean Model Intercomparison Project (OMIP) (2017)
    In:  EPIC3Geoscientific Model Development, 10(6), pp. 2169-2199, ISSN: 1991-9603
    Details
    Publication Date: 2017-06-13
    Description: The Ocean Model Intercomparison Project (OMIP) focuses on the physics and biogeochemistry of the ocean component of Earth system models participating in the sixth phase of the Coupled Model Intercomparison Project (CMIP6). OMIP aims to provide standard protocols and diagnostics for ocean models, while offering a forum to promote their common assessment and improvement. It also offers to compare solutions of the same ocean models when forced with reanalysis data (OMIP simulations) vs. when integrated within fully coupled Earth system models (CMIP6). Here we detail simulation protocols and diagnostics for OMIP’s biogeochemical and inert chemical tracers. These passive-tracer simulations will be coupled to ocean circulation models, initialized with observational data or output from a model spin-up, and forced by repeating the 1948– 2009 surface fluxes of heat, fresh water, and momentum. These so-called OMIP-BGC simulations include three inert chemical tracers (CFC-11, CFC-12, SF6) and biogeochemical tracers (e.g., dissolved inorganic carbon, carbon isotopes, alkalinity, nutrients, and oxygen). Modelers will use their preferred prognostic BGC model but should follow common guidelines for gas exchange and carbonate chemistry. Simulations include both natural and total carbon tracers. The required forced simulation (omip1) will be initialized with gridded observational climatologies. An optional forced simulation (omip1-spunup) will be initialized instead with BGC fields from a long model spin-up, preferably for 2000 years or more, and forced by repeating the same 62-year meteorological forcing. That optional run will also include abiotic tracers of total dissolved inorganic carbon and radiocarbon, Cabio T and 14Cabio T , to assess deep-ocean ventilation and distinguish the role of physics vs. biology. These simulations will be forced by observed atmospheric histories of the three inert gases and CO2 as well as carbon isotope ratios of CO2. OMIP-BGC simulation protocols are founded on those from previous phases of the Ocean Carbon-Cycle Model Intercomparison Project. They have been merged and updated to reflect improvements concerning gas exchange, carbonate chemistry, and new data for initial conditions and atmospheric gas histories. Code is provided to facilitate their implementation.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 7
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    A modeling study of the seasonal oxygen budget of the global ocean (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 112 (2007): C05017, doi:10.1029/2006JC003731.
    Description: An ecosystem model embedded in a global ocean general circulation model is used to quantify roles of biological and physical processes on seasonal oxygen variations. We find that the thermally induced seasonal net outgassing (SNO) of oxygen is overestimated by about 30% if gas phase equilibrium is assumed, and we find that seasonal variations in thermocline oxygen due to biology are approximated well using the oxygen anomaly. Outside the tropics and the north Indian Ocean, biological SNO is, on average, 56% of net community production (defined as net oxygen production above 76 m) during the outgassing period and 35% of annual net community production. In the same region the seasonal drawdown of the oxygen anomaly within the upper thermocline (76–500 m) is 76% of the remineralization during the drawdown and 48% of annual remineralization. Applying model-derived relationships to observed O2 climatologies and using independent estimates for tropical and monsoonal systems, we estimate global net community production to be 14.9 ± 2.5 Pg C yr−1.
    Description: R.N., X.J., and F.L. were supported from the following grants: NOAA NA16GP2987, NASA NAG5-6451, and NSF OCE-9711937.
    Keywords: New production ; Remineralization ; Dissolved oxygen
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 8
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    Surface ocean pCO2 seasonality and sea-air CO2 flux estimates for the North American east coast (2014)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-25
    Description: © The Author(s), 2013. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 118 (2013): 5439–5460, doi:10.1002/jgrc.20369.
    Description: Underway and in situ observations of surface ocean pCO2, combined with satellite data, were used to develop pCO2 regional algorithms to analyze the seasonal and interannual variability of surface ocean pCO2 and sea-air CO2 flux for five physically and biologically distinct regions of the eastern North American continental shelf: the South Atlantic Bight (SAB), the Mid-Atlantic Bight (MAB), the Gulf of Maine (GoM), Nantucket Shoals and Georges Bank (NS+GB), and the Scotian Shelf (SS). Temperature and dissolved inorganic carbon variability are the most influential factors driving the seasonality of pCO2. Estimates of the sea-air CO2 flux were derived from the available pCO2 data, as well as from the pCO2 reconstructed by the algorithm. Two different gas exchange parameterizations were used. The SS, GB+NS, MAB, and SAB regions are net sinks of atmospheric CO2 while the GoM is a weak source. The estimates vary depending on the use of surface ocean pCO2 from the data or algorithm, as well as with the use of the two different gas exchange parameterizations. Most of the regional estimates are in general agreement with previous studies when the range of uncertainty and interannual variability are taken into account. According to the algorithm, the average annual uptake of atmospheric CO2 by eastern North American continental shelf waters is found to be between −3.4 and −5.4 Tg C yr−1 (areal average of −0.7 to −1.0 mol CO2 m−2 yr−1) over the period 2003–2010.
    Description: We wish to acknowledge the NASA Ocean Biology and Biogeochemistry program for providing funds for this project.
    Keywords: Coastal carbon ; Sea-air CO2 fluxes ; North American east coast
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 9
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    Impact of circulation on export production, dissolved organic matter, and dissolved oxygen in the ocean : results from Phase II of the Ocean Carbon-cycle Model Intercomparison Project (OCMIP-2) (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 21 (2007): GB3007, doi:10.1029/2006GB002857.
    Description: Results are presented of export production, dissolved organic matter (DOM) and dissolved oxygen simulated by 12 global ocean models participating in the second phase of the Ocean Carbon-cycle Model Intercomparison Project. A common, simple biogeochemical model is utilized in different coarse-resolution ocean circulation models. The model mean (±1σ) downward flux of organic matter across 75 m depth is 17 ± 6 Pg C yr−1. Model means of globally averaged particle export, the fraction of total export in dissolved form, surface semilabile dissolved organic carbon (DOC), and seasonal net outgassing (SNO) of oxygen are in good agreement with observation-based estimates, but particle export and surface DOC are too high in the tropics. There is a high sensitivity of the results to circulation, as evidenced by (1) the correlation of surface DOC and export with circulation metrics, including chlorofluorocarbon inventory and deep-ocean radiocarbon, (2) very large intermodel differences in Southern Ocean export, and (3) greater export production, fraction of export as DOM, and SNO in models with explicit mixed layer physics. However, deep-ocean oxygen, which varies widely among the models, is poorly correlated with other model indices. Cross-model means of several biogeochemical metrics show better agreement with observation-based estimates when restricted to those models that best simulate deep-ocean radiocarbon. Overall, the results emphasize the importance of physical processes in marine biogeochemical modeling and suggest that the development of circulation models can be accelerated by evaluating them with marine biogeochemical metrics.
    Description: R. G. N. and J. L. S. acknowledge the support of NASA grants NAG5-6451 and NAG5-6591, respectively, as part of the JGOFS Synthesis and Modeling Program. G. K. P. and F. J. acknowledge support by the Swiss National Science Foundation. European contributions were supported by the EU GOSAC Project (ENV4-CT97- 0495).
    Keywords: Export production ; Numerical modeling ; Ocean circulation
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 10
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    Carbon budget of tidal wetlands, estuaries, and shelf waters of eastern North America (2018)
    John Wiley & Sons
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 32 (2018): 389-416, doi:10.1002/2017GB005790.
    Description: Carbon cycling in the coastal zone affects global carbon budgets and is critical for understanding the urgent issues of hypoxia, acidification, and tidal wetland loss. However, there are no regional carbon budgets spanning the three main ecosystems in coastal waters: tidal wetlands, estuaries, and shelf waters. Here we construct such a budget for eastern North America using historical data, empirical models, remote sensing algorithms, and process‐based models. Considering the net fluxes of total carbon at the domain boundaries, 59 ± 12% (± 2 standard errors) of the carbon entering is from rivers and 41 ± 12% is from the atmosphere, while 80 ± 9% of the carbon leaving is exported to the open ocean and 20 ± 9% is buried. Net lateral carbon transfers between the three main ecosystem types are comparable to fluxes at the domain boundaries. Each ecosystem type contributes substantially to exchange with the atmosphere, with CO2 uptake split evenly between tidal wetlands and shelf waters, and estuarine CO2 outgassing offsetting half of the uptake. Similarly, burial is about equal in tidal wetlands and shelf waters, while estuaries play a smaller but still substantial role. The importance of tidal wetlands and estuaries in the overall budget is remarkable given that they, respectively, make up only 2.4 and 8.9% of the study domain area. This study shows that coastal carbon budgets should explicitly include tidal wetlands, estuaries, shelf waters, and the linkages between them; ignoring any of them may produce a biased picture of coastal carbon cycling.
    Description: NASA Interdisciplinary Science program Grant Number: NNX14AF93G; NASA Carbon Cycle Science Program Grant Number: NNX14AM37G; NASA Ocean Biology and Biogeochemistry Program Grant Number: NNX11AD47G; National Science Foundation's Chemical Oceanography Program Grant Number: OCE‐1260574
    Description: 2018-10-04
    Keywords: Carbon cycle ; Coastal zone ; Tidal wetlands ; Estuaries ; Shelf waters
    Repository Name: Woods Hole Open Access Server
    Type: Article
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