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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Aquatic geochemistry 4 (1998), S. 403-427 
    ISSN: 1573-1421
    Keywords: methane ; trace gases ; North Sea ; air-sea exchange
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The methane concentration in the atmosphere andsurface water was surveyed along 58° N acrossthe North Sea. In addition, the vertical methanedistribution in the water column was determined at sixstations along the transect. The methane contents ofthe surface water as well as in the water column wereextremely inhomogeneous. Input by freshwater fromriver discharge and injection of methane from thesediment were both observed. The survey continued fromthe western side of the North Sea to the Elbe Riverestuary. The Elbe River appears to have low methaneconcentrations compared to other European rivers, itsaverage input into the North Sea is estimated to be70 nmol s-1 of methane. Near 58° N,1°40' E, an abandoned drill site releases about 25 % ofthe North Sea's emission of methane to the atmosphere.The advective methane transport induced by watercirculation was assessed for May 16, 1994, using a 3-DNorth Sea circulation model. For the period of thissurvey, the North Sea's source strength foratmospheric methane is estimated using in situwind velocities. In comparison to the advectivetransport by the water circulation, the gas flux tothe atmosphere appears to be the dominant sink ofNorth Sea methane. This flux is estimated to bebetween 1500 · 106 mol a-1 and 3100 ·106mol a-1, depending on the relationbetween wind speed and gas transfer velocity.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2017-06-29
    Description: Hydrothermal activity in the Central Bransfield Basin revealed an active low-temperature vent field on top of a submarine volcanic structure. A temperature anomaly was detected and the sea floor showed various patches of white silica (opal-A) precipitate exposures and some yellow–brown Fe-oxyhydroxide crusts. Enriched dissolved methane concentrations were encountered. Sediment was near 24°C just after the grab came on deck. No dense population of chemosynthetically based macrofauna known from other hydrothermal venting areas was present, except for pogonophora. The observations suggest that the sedimented hydrothermal field at Hook Ridge is a low-temperature end-member branch from a deeper hydrothermal source.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2017-05-24
    Description: The scientific community is engaged in a lively debate over whether and how venting from the gas-hydrate reservoir and the Earth’s climate is connected. The various scenarios which have been proposed are based on the following assumptions: the inventory of methane gas-hydrate deposits is locally enormous, the stability of marine gas-hydrate deposits can easily be perturbed by temperature and pressure changes, enough methane can be released from these deposits to contribute adequate volumes of this isotopically distinct greenhouse gas to alter the composition of oceanic or atmospheric methane reservoirs, and the mechanisms exist for the transfer of methane from deeper geologic reservoirs to the ocean and/or atmosphere. However, some potential transfer mechanisms have been difficult to evaluate. Here, we consider the possibility of marine slumping as a mechanism to transfer methane carbon from gas hydrates within the seafloor into the ocean and atmosphere. Our analyses and field experiments indicate that large slumps could release volumetrically significant quantities of solid gas hydrates which would float upwards in the water column. Large pieces of gas hydrate would reach the upper layers of the ocean before decomposing, and some of the methane would be directly injected into the atmosphere.
    Type: Article , PeerReviewed
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  • 4
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    Springer
    In:  International Journal of Earth Sciences, 103 (7). pp. 1801-1815.
    Publication Date: 2019-09-23
    Description: Methane (CH4) concentrations and CH4 stable carbon isotopic composition (d13CCH4 ) were investigated in the water column within Jaco Scar. It is one of several scars formed by massive slides resulting from the subduction of seamounts offshore Costa Rica, a process that can open up structural and stratigraphical pathways for migrating CH4. The release of large amounts of CH4 into the adjacent water column was discovered at the outcropping lowermost sedimentary sequence of the hanging wall in the northwest corner of Jaco Scar, where concentrations reached up to 1,500 nmol L-1. There CH4-rich fluids seeping from the sedimentary sequence stimulate both growth and activity of a dense chemosynthetic community. Additional point sources supplying CH4 at lower concentrations were identified in density layers above and below the main plume from light carbon isotope ratios. The injected CH4 is most likely a mixture of microbial and thermogenic CH4 as suggested by d13CCH4 values between -50 and -62 % Vienna Pee Dee Belemnite. This CH4 spreads along isopycnal surfaces throughout the whole area of the scar, and the concentrations decrease due to mixing with ocean water and microbial oxidation. The supply of CH4 appears to be persistent as repeatedly high CH4 concentrations were found within the scar over 6 years. The maximum CH4 concentration and average excess CH4 concentration at Jaco Scar indicate that CH4 seepage from scars might be as significant as seepage from other tectonic structures in the marine realm. Hence, taking into account the global abundance of scars, such structures might constitute a substantial, hitherto unconsidered contribution to natural CH4 sources at the seafloor.
    Type: Article , PeerReviewed
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  • 5
    Publication Date: 2024-05-13
    Description: Es werden mögliche Beiträge geologischer und mariner Kohlenstoffspeicher für die Vermeidung von CO2-Emissionen in die Atmosphäre oder für die Entnahme von bereits emittiertem CO2 aus der Atmosphäre vorgestellt. Neben der Einlagerung von CO2 in geologischen Speichern unter Land und unter dem Meeresboden werden eine forcierte CO2-Entnahme aus der Atmosphäre und Abgabe in den Ozean durch Erhöhung der Alkalinität, durch Ozeandüngung und durch das Management vegetationsreicher Küstenökosysteme untersucht. Alle Optionen können sowohl global als auch aus deutscher Perspektive eine Rolle für das Erreichen der Klimaziele spielen. Umweltverträglichkeit, Permanenz der Speicherung sowie infrastrukturelle und rechtliche Voraussetzungen, gesellschaftliche Akzeptanz und wirtschaftliche Realisierbarkeit bedürfen für alle Ansätze weiterer Klärung, bevor hieraus realisierbare Optionen werden können.
    Type: Book chapter , NonPeerReviewed
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  • 6
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Biogeosciences 15 (2018): 5891-5907, doi:10.5194/bg-15-5891-2018.
    Description: Large-scale climatic forcing is impacting oceanic biogeochemical cycles and is expected to influence the water-column distribution of trace gases, including methane and nitrous oxide. Our ability as a scientific community to evaluate changes in the water-column inventories of methane and nitrous oxide depends largely on our capacity to obtain robust and accurate concentration measurements that can be validated across different laboratory groups. This study represents the first formal international intercomparison of oceanic methane and nitrous oxide measurements whereby participating laboratories received batches of seawater samples from the subtropical Pacific Ocean and the Baltic Sea. Additionally, compressed gas standards from the same calibration scale were distributed to the majority of participating laboratories to improve the analytical accuracy of the gas measurements. The computations used by each laboratory to derive the dissolved gas concentrations were also evaluated for inconsistencies (e.g., pressure and temperature corrections, solubility constants). The results from the intercomparison and intercalibration provided invaluable insights into methane and nitrous oxide measurements. It was observed that analyses of seawater samples with the lowest concentrations of methane and nitrous oxide had the lowest precisions. In comparison, while the analytical precision for samples with the highest concentrations of trace gases was better, the variability between the different laboratories was higher: 36% for methane and 27% for nitrous oxide. In addition, the comparison of different batches of seawater samples with methane and nitrous oxide concentrations that ranged over an order of magnitude revealed the ramifications of different calibration procedures for each trace gas. Finally, this study builds upon the intercomparison results to develop recommendations for improving oceanic methane and nitrous oxide measurements, with the aim of precluding future analytical discrepancies between laboratories.
    Description: U.S. National Science Foundation (OCE-1546580); Funding for the gas standards was provided by the Center for Microbial Oceanography: Research and Education (C-MORE; EF0424599 to David M. Karl), SCOR, the EU FP7 funded Integrated non-CO2 Greenhouse gas Observation System (InGOS) (grant agreement no. 284274), and NOAA’s Climate Program Office, Climate Observations Division. Additional support was provided by the Gordon and Betty Moore Foundation no. 3794 (David M. Karl), the Simons Collaboration on Ocean Processes and Ecology (SCOPE; no. 329108 to David M. Karl), and the Global Research Laboratory Program (no. 2013K1A1A2A02078278 to David M. Karl) through the National Research Foundation of Korea (NRF); Alyson E. Santoro would like to acknowledge NSF OCE-1437310. Mercedes de la Paz would like to acknowledge the support of the Spanish Ministry of Economy and Competitiveness (CTM2015-74510-JIN). Laura Farías received financial support from FONDAP 1511009 and FONDECYT no. 1161138
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 7
    Publication Date: 2022-05-26
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Earth System Science Data 10 (2018): 405-448, doi:10.5194/essd-10-405-2018.
    Description: Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere – the "global carbon budget" – is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and methodology to quantify the five major components of the global carbon budget and their uncertainties. CO2 emissions from fossil fuels and industry (EFF) are based on energy statistics and cement production data, respectively, while emissions from land-use change (ELUC), mainly deforestation, are based on land-cover change data and bookkeeping models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. The ocean CO2 sink (SOCEAN) and terrestrial CO2 sink (SLAND) are estimated with global process models constrained by observations. The resulting carbon budget imbalance (BIM), the difference between the estimated total emissions and the estimated changes in the atmosphere, ocean, and terrestrial biosphere, is a measure of imperfect data and understanding of the contemporary carbon cycle. All uncertainties are reported as ±1σ. For the last decade available (2007–2016), EFF was 9.4 ± 0.5 GtC yr−1, ELUC 1.3 ± 0.7 GtC yr−1, GATM 4.7 ± 0.1 GtC yr−1, SOCEAN 2.4 ± 0.5 GtC yr−1, and SLAND 3.0 ± 0.8 GtC yr−1, with a budget imbalance BIM of 0.6 GtC yr−1 indicating overestimated emissions and/or underestimated sinks. For year 2016 alone, the growth in EFF was approximately zero and emissions remained at 9.9 ± 0.5 GtC yr−1. Also for 2016, ELUC was 1.3 ± 0.7 GtC yr−1, GATM was 6.1 ± 0.2 GtC yr−1, SOCEAN was 2.6 ± 0.5 GtC yr−1, and SLAND was 2.7 ± 1.0 GtC yr−1, with a small BIM of −0.3 GtC. GATM continued to be higher in 2016 compared to the past decade (2007–2016), reflecting in part the high fossil emissions and the small SLAND consistent with El Niño conditions. The global atmospheric CO2 concentration reached 402.8 ± 0.1 ppm averaged over 2016. For 2017, preliminary data for the first 6–9 months indicate a renewed growth in EFF of +2.0 % (range of 0.8 to 3.0 %) based on national emissions projections for China, USA, and India, and projections of gross domestic product (GDP) corrected for recent changes in the carbon intensity of the economy for the rest of the world. This living data update documents changes in the methods and data sets used in this new global carbon budget compared with previous publications of this data set (Le Quéré et al., 2016, 2015b, a, 2014, 2013). All results presented here can be downloaded from https://doi.org/10.18160/GCP-2017 (GCP, 2017).
    Repository Name: Woods Hole Open Access Server
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