Description: The climactic Los Chocoyos (LCY) eruption from Atitlán caldera (Guatemala) is a key chronostratigraphic marker for the Quaternary period given the extensive distribution of its deposits that reached both the Pacific and Atlantic Oceans. Despite LCY tephra being an important marker horizon, a radioisotopic age for this eruption has remained elusive. Using zircon (U–Th)/He geochronology, we present the first radioisotopically determined eruption age for the LCY of 75 ± 2 ka. Additionally, the youngest zircon crystallization 238U–230Th rim ages in their respective samples constrain eruption age maxima for two other tephra units that erupted from Atitlán caldera, W‐Fall (130 +16/−14 ka) and I‐Fall eruptions (56 +8.2/−7.7 ka), which under‐ and overlie LCY tephra, respectively. Moreover, rim and interior zircon dating and glass chemistry suggest that before eruption silicic magma was stored for 〉80 kyr, with magma accumulation peaking within ca. 35 kyr before the LCY eruption during which the system may have developed into a vertically zoned magma chamber. Based on an updated distribution of LCY pyroclastic deposits, a new conservatively estimated volume of ~1220 ± 150 km3 is obtained (volcanic explosivity index VEI 〉 8), which confirms the LCY eruption as the first‐ever recognized supereruption in Central America.

Description: Deutsche Forschungsgemeinschaft SCH 2521/6‐1

Description: Geological histories of volcanic ocean islands can be revealed by the sediments shed by them. Hence there is an interest in studying cores of volcaniclastic sediments that are particularly preserved in the many flat-floored basins lying close to the Azores islands. We analyse four gravity cores collected around the central group of the islands. Three sedimentary facies (F1-F2a, F2b) are recognized based on visual core logging, particle morphometric and geochemical analyses. F1 is clay-rich hemipelagite comprising homogeneous mud with mottled structures from bioturbation. F2a and F2b are both clay-poor volcaniclastic deposits, which are carbonate-rich and carbonate-poor, respectively. More biogenic carbonate in F2a reflects the incorporation of unconsolidated calcareous material from island shelves or bioturbation. Within F2a and F2b we identify deposits emplaced by pyroclastic fallout, primary or secondary turbidity currents by combining multiple information from lithological composition, sedimentary structures, chemical composition of volcanic glass shards and morphometric characteristics of volcanic particles. Primary volcaniclastic sediments were found in all four cores, echoing activity known to have occurred up to historical times on the adjacent islands. These preliminary results suggest that greater details of geological events could be inferred for other volcanic islands by adopting a similar approach to core analysis.

Description: This review focuses on the recognition of volcanic ash occurrences in marine sediment cores and on using their appearance and properties to deduce their origin. Widespread marine tephra layers are important marker horizons for both volcanological as well as general geological investigations. We describe ash detection by visual inspection and logging of sediment cores. Ash layer structure and texture, particle morphologies and lithological compositions of primary volcanic deposits are summarized and processes modifying them are discussed, both natural processes acting on and in the seafloor, i.e. erosion and bioturbation, and anthropogenic modifications during drilling/coring and core preparation. We discuss primary emplacement processes of marine fall and flow tephra deposits derived from either subaerial or submarine sources in order to identify distinguishing properties. We also elaborate on processes generating secondary, resedimented volcaniclastic layers such as submarine landslides and shelf erosion as well as fluvial input and ice-rafting, and how they can be distinguished from primary volcaniclastic deposits, which is essential in tephrostratigraphy. Finally, methods of tephra correlation between cores and on-land deposits/volcanoes are illustrated because they allow us to extend the 1D information from single cores to 3D distribution and facies changes of tephras and to bridge the land–sea gap.

Description: Highlights • Five Pleistocene and Holocene explosive eruptions of Mt. Erciyes dated. • Holocene Dikkartın and Perikartın pumices chemically equal Mediterranean S1 tephra. • Karagüllü dome eruption identified as the source of a Black Sea cryptotephra. • Eastward dispersal of Dikkartın fall-out consistent with probabilistic modeling. • Southerly S1 tephra occurrence suggests low altitude ash dispersal from Mt. Ericyes. Abstract Deposition of early Holocene Eastern Mediterranean S1 tephra and a Black Sea cryptotephra coincides with cultural transitions in the Fertile Crescent termed the Neolithic Revolution as well as sapropel formation during climate variability of the African humid period, classifying them as paramount regional marker horizons for archaeology as well as paleoclimatology. Their correlations with specific eruptions of the Mt. Erciyes stratovolcanic complex (Central Anatolia) remained inconclusive though. Here, we use zircon double-dating by (U–Th)/He and U–Th disequilibrium methods, major and trace element tephra glass geochemistry, and probabilistic modeling of tephra dispersal in an attempt to characterize all major late Quaternary proximal tephras of Mt. Erciyes, and to correlate them with distal deposits. Furthermore, we discuss contrasting proximal and distal tephra dispersal. Three nearly-coeval rhyolitic satellite domes (Dikkartın, Perikartın, and Karagüllü) erupted at Mt. Erciyes in the early Holocene, and their dome extrusions were all preceded by explosive phases producing pyroclastic material that formed tephra fall and pyroclastic flow deposits. The new eruption age of 9.03 ± 0.55 ka (1σ uncertainty here and elsewhere) for proximal Dikkartın pumice is consistent with 14C-based S1 tephra chronologies in distal locations averaging 8.92 ± 0.03 cal ka BP. Perikartın pyroclastic flow deposits predate S1 tephra by ca. 0.8 ka according to a pair of published 14C ages, and stratigraphically overlie Karagüllü fall-out, here dated to 8.2 ± 1.8 ka. Previously undated proximal tephras of Mt. Erciyes erupted in the Late (85.2 ± 4.9 ka) and Middle Pleistocene (154.5 ± 5.3 ka). S1 tephra glass is chemically similar to that of Dikkartın fall-out, but also indistinguishable from that of Perikartın fall-out. Karagüllü pumice is characterized by a distinct glass chemical composition, which correlates with that of unnamed cryptotephra reported for the southeastern Black Sea instead, where these results call for a re-evaluation of existing age models. Maximum lithic clast size isopleths for proximal Dikkartın fall-out indicate eastward dispersal of a 20 ± 5 km high eruption plume by stratospheric winds, in agreement with results of probabilistic tephra dispersal modeling. This azimuth contrasts with the known distribution of S1 tephra at distal locations that are all south of Mt. Erciyes. Significant tephra occurrences at up to 1300 km distance and orthogonal to prevalent stratospheric wind directions either result from very atypical wind conditions (probability ≪10 %), or are caused by tephra transport by prevailing low altitude winds. Two scenarios are proposed for low altitude transport: eolian reworking of primary fall-out (more likely from the more widespread Dikkartın deposits), or co-ignimbrite ash cloud dispersal (more likely from the Perikartın eruption which predominantly produced pyroclastic flows). Because S1 tephra is chemically indistinguishable from both Dikkartın and Perikartın by major and trace element glass compositions, its exact source and dispersal mechanism remain ambiguous, although existing 14C ages for Perikartın predating those for S1 tephra favor Dikkartın as its source.

Description: Highlights • Temporally close-spaced double eruption within a couple of hundreds of years. • Magmas are variably tapped from zoned magma chambers during eruptions due to changing magma discharge rates and/or vent migration. • Eruptions started with a series of fallouts featuring stable eruption columns followed by fluctuating and partially collapsing eruption columns. • Eruptive volumes sum up to a total of 25.6 km3 and 40.5 km3 tephra volume, eruption column heights have been between 20–33 km. • Potential hazards from similar sized eruptions around Coatepeque Caldera are indicated even in the distal regions around San Salvador. Abstract The Coatepeque volcanic complex in El Salvador produced at least four Plinian eruptions within the last 80 kyr. The eruption of the 72 ka old Arce Tephra formed the Coatepeque Caldera and was one of the most powerful explosive eruptions in El Salvador. Hitherto it was thought that the Arce tephra had been emplaced only by one, mostly Plinian, eruptive event that ended with the deposition of a thick ignimbrite. However, our stratigraphic, geochemical, and zircon data reveal a temporally closely- spaced double eruption separated by a gap of only a couple of hundred years, and we therefore distinguish Lower and Upper Arce Tephras. Both eruptions produced in the beginning a series of fallout units generated from fluctuating eruption columns and turning wind directions. The final phase of the Upper Arce eruption produced surge deposits by several eruption column collapses before the terminal phase of catastrophic ignimbrite eruption and caldera collapse. Mapping of the individual tephra units including the occurrences of distal marine and lacustrine ash layers in the Pacific Ocean, the Guatemalan lowlands and the Caribbean Sea, result in 25.6 km3 tephra volume, areal distribution of 4 × 105 km2 and eruption column heights between 20–33 km for the Lower Arce eruption, and 40.5 km3 tephra volume, including 10 km3 for the ignimbrite, distributed across 6 × 105 km2 and eruption column heights of 23–28 km for the Upper Arce eruption. These values and the detailed eruptive sequence emphasize the great hazard potential of possible future highly explosive eruptions at Coatepeque Caldera, especially for this kind of double eruption.

Description: The climactic Los Chocoyos (LCY) eruption from Atitlán caldera (Guatemala) is a key chronostratigraphic marker for the Quaternary period given the extensive distribution of its deposits that reached both the Pacific and Atlantic Oceans. Despite LCY tephra being an important marker horizon, a radioisotopic age for this eruption has remained elusive. Using zircon (U–Th)/He geochronology, we present the first radioisotopically determined eruption age for the LCY of 75 ± 2 ka. Additionally, the youngest zircon crystallization 238U–230Th rim ages in their respective samples constrain eruption age maxima for two other tephra units that erupted from Atitlán caldera, W-Fall (130 +16/−14 ka) and I-Fall eruptions (56 +8.2/−7.7 ka), which under- and overlie LCY tephra, respectively. Moreover, rim and interior zircon dating and glass chemistry suggest that before eruption silicic magma was stored for 〉80 kyr, with magma accumulation peaking within ca. 35 kyr before the LCY eruption during which the system may have developed into a vertically zoned magma chamber. Based on an updated distribution of LCY pyroclastic deposits, a new conservatively estimated volume of ~1220 ± 150 km3 is obtained (volcanic explosivity index VEI 〉 8), which confirms the LCY eruption as the first-ever recognized supereruption in Central America.

Description: Provenance studies of widely distributed tephra deposits are important to deduce systematic changes in the source, size, distribution, and temporal variation of regional explosive volcanism. Long-term deep ocean drilling sedimentary records are particularly useful for these kind of studies. In this study, we establish a robust tephrochronostratigraphy for 235 primary marine tephra layers collected during International Ocean Discovery Program Expeditions 353, 354, and 362, complemented by older drill cores from Deep Sea Drilling Program and Ocean Drilling Program Legs 22, 119, 120, 121, and 183. We infer at least two major phases of highly explosive arc volcanism during the Early Miocene to Pleistocene, as well as three episodes related to explosive ocean island volcanism located in the Kerguelen plateau, the Broken Ridge, and close to Réunion reaching back to the Paleogene. Twenty-two widespread arc-derived tephra layers from individual eruptions can be correlated by geochemical fingerprinting between multiple holes. These provide nine Quaternary and 13 Neogene temporal tie points in the sedimentary sequence including four new Usingle bondPb zircon ages. Provenance analysis of the marine tephra layers, which is based on glass composition, assign eleven of these layers to a Toba-like source, ranging from 24 Ma to 75 ka, with the youngest correlative being Young Toba Tuff. Based on distribution pattern, thickness decay, and compositional evidence another eleven tephra layers can be assigned to a northern Sumatran Arc or to an Andaman Arc provenance. First-order minimum eruptive volume estimates for the Neogene tephra layers imply eruptive magnitudes ranging from M = 6.5 to M = 7.5, proving a continuous history of large explosive eruptions from the Sumatran/Andaman Arc since the Neogene, as previously known from the Quaternary.

Description: The Toba Caldera on Sumatra, Indonesia is the host of the Young Toba eruption (~74 ka), globally one of the largest and most recognized eruptions during the Quaternary and regionally concentrated in the eastern Indian Ocean. Three older deposits (Middle, and Old Toba Tuff as well as Haranggaol Dacite Tuff) are also attributed to Toba caldera, with their eruption products distributed over the Indian Ocean. We present the Quaternary marine tephra record from an array of 14 sites and 28 holes from deep ocean drilling programs, complementing earlier work on distal to ultra-distal Indian Ocean sediment cores and terrestrial distribution data of Toba deposits. A unique set of major and trace element glass-shard compositions on 115 primary ash layers together with glass shard morphologies, core pictures and statistical analysis support geochemical fingerprinting between marine tephra layers and known deposits from Toba and five so far unidentified medium to large eruptions assigned to northern Sumatra. Additionally, zircon crystallization ages have been determined for the Haranggaol Dacite Tuff resulting in a new maximum eruption age of 1.42 ± 0.034 Ma. Tephra volumes and magma masses for the (co-ignimbrite) fallout are estimated based on the compiled marine tephra distribution that are complemented by published proximal ignimbrite volumes. For YTT the resulting tephra and DRE volumes of 5600 km3 and 3600 km3, respectively, are in between the previous estimates. For MTT (253 km3 DRE), ODT (1550 km3 DRE), HDT (129 km3 DRE), and the five additionally identified eruptions from Northern-Sumatran volcanoes, new magma volumes have been determined. Overall, the Indian Ocean tephra record reveals in one large eruption every 200 kyr in the Quaternary that is derived from northern Sumatra.

Description: Highlights • Syn-rift sediments in the northern South China Sea are from the East Cathaysia block. • Rivers delivered sediments migrated from eastern to western region. • Tributaries catchment of the Pearl River started to migrate since the late Eocene. • The migration of the river catchment is related to the west-east topographic swap. • Topographic change was possibly related to the local tectonic uplift and exhumation. We examined an International Ocean Discovery Program (IODP) drilling core from Site U1501, located on the distal margin of the northern South China Sea (SCS) basin to unravel the sediment provenance evolution in the Paleogene and the evolution of river catchments during basin opening. We attempt to understand the major factors driving river development in a rift basin by utilizing provenance tools to constrain sediment transport pathways and compare these with the regional tectonics during the Paleogene in order to resolve competing models for drainage evolution and test their relationships with the evolving topography of SW China and the SE Tibetan Plateau. For this purpose, ten samples were collected from a 200-m-thick, syn-rift Eocene/pre-Eocene interval. Detrital zircon U-Pb data were collected by LA-ICP-MS to identify the sediment provenance and differentiate fluvial sources. Bulk rock geochemistry data was utilized to shed light on chemical weathering conditions and compositional maturity to further decipher sediment transportation patterns. We compare our data with adjacent IODP Site U1435 and several industrial boreholes located in the Pearl River Mouth Basin (PRMB). We applied multiple statistical tests, including K-S, Monte Carlo mixing and multidimensional scaling testing, to evaluate U-Pb age spectra similarities and to estimate endmember contributions from a variety of source areas. Our results from Site U1501 show that sediments deposited as fluvial sands during the rifting stage, were predominantly derived from the East Cathaysia block, probably from local sources. A progressive increase in older detrital zircon U-Pb ages peaks (〉200 Ma) was observed at Site U1435 and in PRMB strata, signaling a spatial shift in sediment provenance from east to west occurring between the late Eocene and the early Oligocene. This trend reflects a transition in sediment delivery from local small-catchment streams to a more regional drainage eroding the east and north of the South China Block. Westward drainage expansion is likely impacted by the uplift of the Tibetan Plateau.

Description: We use the tephrostratigraphic framework along the Aegean Volcanic Arc established in part 1 of this contribution to determine hemipelagic sedimentation rates, calculate new tephra ages, and constrain the minimum magnitudes of (sub)plinian eruptions of the last 200 kyrs. Hemipelagic sedimentation rates range from ∼0.5 cm/kyr up to ∼40 cm/kyr and vary laterally as well as over time. Interpolation between dated tephras yields an eruption age of ∼37 ka for the Firiplaka tephra, showing that explosive volcanism on Milos is ∼24 kyrs younger than previously thought. The four marine Nisyros tephras (N1 to N4) identified in part 1 (including the Upper (N1) and Lower (N4) Pumice) have ages of ∼57 ka, ∼63 ka, ∼69 ka, and ∼76 ka, respectively. Eruption ages for the Yali-1 and Yali-2 tephras are ∼55 ka and ∼34 ka, respectively. The Yali-2 tephra comprises two geochemically and laterally distinct marine facies. The southern facies is identical to the Yali-2 fall deposit on land but the western facies has slightly less evolved glass compositions. Overall, erupted plinian and co-ignimbrite fall tephra volumes range from 〈1 to 56 km3 (excluding possible caldera fillings and ignimbite volumes), and 80% of the eruptions had magnitude 5.5〈M≤7.2 (M=log(m)-7; m = erupted magma mass in kg). Twenty percent of the tephras represent 3.2〈M〈5.5 eruptions. The long-term average tephra magma mass flux through highly explosive eruptions of Santorini is estimated at ∼40 kg/s. The analogous data for the Kos-Yali-Nisyros volcanic complex is less-well constrained but similar to Santorini.