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  • 1
    In: International journal of earth sciences, Berlin : Springer, 1999, (2009), 1437-3262
    In: year:2009
    In: extent:18
    Type of Medium: Online Resource
    Pages: 18 , Ill., graph. Darst
    ISSN: 1437-3262
    Language: English
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  • 2
    In: Sedimentary geology, Amsterdam [u.a.] : Elsevier, 1967, 203(2008), 3/4, Seite 246-266, 0037-0738
    In: volume:203
    In: year:2008
    In: number:3/4
    In: pages:246-266
    Type of Medium: Online Resource
    ISSN: 0037-0738
    Language: English
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  • 3
    In: Bulletin of volcanology, Berlin : Springer, 1986, 71(2009), 5, Seite 479-493, 1432-0819
    In: volume:71
    In: year:2009
    In: number:5
    In: pages:479-493
    Description / Table of Contents: We present the stratigraphy, lithology, volcanology, and age of the Acahualinca section in Managua, including a famous footprint layer exposed in two museum pits. The ca. 4-m-high walls of the main northern pit (Pit I) expose excellent cross sections of Late Holocene volcaniclastic deposits in northern Managua. We have subdivided the section into six lithostratigraphic units, some of which we correlate to Late Holocene eruptions. Unit I (1.2 m thick), chiefly of hydroclastic origin, begins with the footprint layer. The bulk is dominated by mostly massive basaltic-andesitic tephra layers, interpreted to represent separate pulses of a basically phreatomagmatic eruptive episode. We correlate these deposits based on compositional and stratigraphic evidence to the Masaya Triple Layer erupted at Masaya volcano ca. 2,120 ± 120 a B.P.. The eruption occurred during the dry season. A major erosional channel unconformity up to 1 m deep in the western half of Pit I separates Units II and I. Unit II begins with basal dacitic pumice lapilli up to 10 cm thick overlain by a massive to bedded fine-grained dacitic tuff including a layer of accretionary lapilli and pockets of well-rounded pumice lapilli. Angular nonvesicular glass shards are interpreted to represent hydroclastic fragmentation. The dacitic tephra is correlated unequivocally with the ca. 1.9-ka-Plinian dacitic Chiltepe eruption. Unit III, a lithified basaltic-andesitic deposit up to 50 cm thick and extremely rich in branch molds and excellent leaf impressions, is correlated with the Masaya Tuff erupted ca. 1.8 ka ago. Unit IV, a reworked massive basaltic-andesitic deposit, rich in brown tuff clasts and well bedded and cross bedded in the northwestern corner of Pit I, cuts erosionally down as far as Unit I. A poorly defined, pale brown mass flow deposit up to 1 m thick (Unit V) is overlain by 1-1.5 m of dominantly reworked, chiefly basaltic tephra topped by soil (Unit VI). A major erosional channel carved chiefly between deposition of Units II and I may have existed as a shallow drainage channel even prior to deposition of the footprint layer. The swath of the footprints is oriented NNW, roughly parallel to, and just east of, the axis of the channel. The interpretation of the footprint layer as the initial product of a powerful eruption at Masaya volcano followed without erosional breaks by additional layers of the same eruptive phase is strong evidence that the group of 15 or 16 people tried to escape from an eruption.
    Type of Medium: Online Resource
    Pages: Ill., graph. Darst
    ISSN: 1432-0819
    Language: English
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  • 4
    In: Chemical geology, Amsterdam [u.a.] : Elsevier, 1966, 249(2008), 3/4, Seite 321-338, 0009-2541
    In: volume:249
    In: year:2008
    In: number:3/4
    In: pages:321-338
    Description / Table of Contents: Four volcanic ash-bearing marine sediment cores and one ash-free reference core were examined during research cruise RV Meteor 54/2 offshore Nicaragua and Costa Rica to investigate the chemical composition of pore waters related to volcanic ash alteration. Sediments were composed of terrigenous matter derived from the adjacent continent and contained several distinct ash layers. Biogenic opal and carbonate were only minor components. The terrigenous fraction was mainly composed of smectite and other clay minerals while the pore water composition was strongly affected by the anaerobic degradation of particulate organic matter via microbial sulphate reduction. The alteration of volcanic matter showed only a minor effect on major element concentrations in pore waters. This is in contrast to prior studies based on long sediment cores taken during the DSDP, where deep sediments always showed distinct signs of volcanic ash alteration. The missing signal of ash alteration is probably caused by low reaction rates and the high background concentration of major dissolved ions in the seawater-derived pore fluids. Dissolved silica concentrations were, however, significantly enriched in ash-bearing cores and showed no relation to the low but variable contents of biogenic opal. Hence, the data suggest that silica concentrations were enhanced by ash dissolution. Thus, the dissolved silica profile measured in one of the sediment cores was used to derive the in-situ dissolution rate of volcanic glass particles in marine sediments. A non-steady state model was run over a period of 43 kyr applying a constant pH of 7.30 and a dissolved Al concentration of 0.05 myM. The kinetic constant (AA) was varied systematically to fit the model to the measured dissolved silica-depth profile. The best fit to the data was obtained applying AA = 1.3 × 10-U9 mol of Si cm- 2 s- 1. This in-situ rate of ash dissolution at the seafloor is three orders of magnitude smaller than the rate of ash dissolution determined in previous laboratory experiments. Our results therefore imply that field investigations are necessary to accurately predict natural dissolution rates of volcanic glasses in marine sediments.
    Type of Medium: Online Resource
    ISSN: 0009-2541
    Language: English
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  • 5
    In: Geochemistry, geophysics, geosystems, Hoboken, NJ : Wiley, 2000, 11(2010), 5, 1525-2027
    In: volume:11
    In: year:2010
    In: number:5
    In: extent:18
    Description / Table of Contents: Submarine slope failures occur at all continental margins, but the processes generating different mass wasting phenomena remain poorly understood. Multibeam bathymetry mapping of the Middle America Trench reveals numerous continental slope failures of different dimensions and origin. For example, large rotational slumps have been interpreted to be caused by slope collapse in the wake of subducting seamounts. In contrast, the mechanisms generating translational slides have not yet been described. Lithology, shear strength measurements, density, and pore water alkalinity from a sediment core across a slide plane indicate that a few centimeters thick intercalated volcanic tephra layer marks the detachment surface. The ash layer can be correlated to the San Antonio tephra, emplaced by the 6000 year old caldera-forming eruption from Masaya-Caldera, Nicaragua. The distal deposits of this eruption are widespread along the continental slope and ocean plate offshore Nicaragua. Grain size measurements permit us to estimate the reconstruction of the original ash layer thickness at the investigated slide. Direct shear test experiments on Middle American ashes show a high volume reduction during shearing. This indicates that marine tephra layers have the highest hydraulic conductivity of the different types of slope sediment, enabling significant volume reduction to take place under undrained conditions. This makes ash layers mechanically distinct within slope sediment sequences. Here we propose a mechanism by which ash layers may become weak planes that promote translational sliding. The mechanism implies that ground shaking by large earthquakes induces rearrangement of ash shards causing their compaction (volume reduction) and produces a rapid accumulation of water in the upper part of the layer that is capped by impermeable clay. The water-rich veneer abruptly reduces shear strength, creating a detachment plane for translational sliding. Tephra layers might act as slide detachment planes at convergent margins of subducting zones, at submarine slopes of volcanic islands, and at submerged volcano slopes in lakes.
    Type of Medium: Online Resource
    Pages: 18 , Ill., graph. Darst
    ISSN: 1525-2027
    Language: English
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  • 6
    In: International journal of earth sciences, Berlin : Springer, 1999, (2009), 1437-3262
    In: year:2009
    In: extent:14
    Description / Table of Contents: We analyzed bare human footprints in Holocene tuff preserved in two pits in the Acahualinca barrio in the northern outskirts of Managua (Nicaragua). Lithology, volcanology, and age of the deposits are discussed in a companion paper (Schmincke et al. Bull Volcanol doi: 10.1007/s00445-008-0235-9, 2008). The footprint layer occurs within a series of rapidly accumulated basalticandesitic tephra that is regionally correlated to the Masaya Triple Layer Tephra. The people were probably trying to escape from a powerful volcanic eruption at Masaya Caldera 20 km farther south that occurred at 2.1 ka BP. We subdivided the swath of footprints, up to 5.6 m wide, in the northern pit (Pit I) into (1) a central group of footprints made by about six individuals, the total number being difficult to determine because people walked in each other’s footsteps one behind the other and (2) two marginal groups on either side of the central group with more widely spaced tracks. The western band comprises tracks of three adjacent individuals and an isolated single footprint farther out. The eastern marginal area comprises an inner band of deep footprints made by three individuals and, farther out, three clearly separated individuals. We estimate the total number of people as 15-16. In the southern narrow and smaller pit (Pit II), we recognize tracks of ca. 12 individuals, no doubt made by the same group. The group represented in both pits probably comprised male and female adults, teenagers and children based on differences in length of footprints and of strides and depth of footprints made in the soft wet ash. The smallest footprints (probably made by children) occur in the central group, where protection was most effective. The footprint layer is composed of a lower 5-15-cm thick, coarse-grained vesicle tuff capped by a medium to fine-grained tuff up to 3 cm thick. The surface on which the people walked was muddy, and the soft ash was squeezed up on the sides of the foot imprints and between toes. Especially, deep footprints are mainly due to local thickening of the water-rich ash, multiple track use, and differences in weight of individuals. The excellent preservation of the footprints, ubiquitous mudcracks, sharp and well-preserved squeeze-ups along the margins of the tracks and toe imprints, and the absence of raindrop impressions all suggest that the eruption occurred during the dry season. The people walked at a brisk pace, as judged from the tight orientation of the swath and the length of the strides. The directions of a major erosional channel in the overlying deposits that probably debouched into Lake Managua and the band of footprints are strictly parallel, indicating that people walked together in stride along the eastern margin of a channel straight toward the lake shore, possibly a site with huts and/or boats for protection and/or escape.
    Type of Medium: Online Resource
    Pages: 14 , Ill., graph. Darst
    ISSN: 1437-3262
    Language: English
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  • 7
    Publication Date: 2020-05-01
    Description: We present geochemical data collected from volcanic ash-bearing sediments on the upper slope of the northern Hikurangi margin during the RV SONNE SO247 expedition in 2016. Gravity coring and seafloor drilling with the MARUM-MeBo200 allowed for collection of sediments down to 105 meters below seafloor (mbsf). Release of dissolved Sr2+with isotopic composition enriched in 86Sr (87Sr/86Sr minimum = 0.708461 at 83.5 mbsf) is indicative of ash alteration. This reaction releases other cations in the 30-70 mbsf depth interval as reflected by maxima in pore-water Ca2+and Ba2+concentrations. In addition, we posit that Fe(III) in volcanogenic glass serves as an electron acceptor for methane oxidation, a reaction that releases Fe2+measured in the pore fluids to a maximum concentration of 184 μM. Several lines of evidence support our proposed coupling of ash alteration with Fe-mediated anaerobic oxidation of methane (Fe-AOM) beneath the sulfate-methane transition (SMT), which lies at ∼7 mbsf at this site. In the ∼30-70 mbsf interval, we observe a concurrent increase in Fe2+and a depletion of CH4with a well-defined decrease in δ13C-CH4values indicative of microbial fractionation of carbon. The negative excursions in δ13C values of both DIC and CH4are similar to that observed by sulfate-driven AOM at low SO2−4concentrations, and can only be explained by the microbially-mediated carbon isotope equilibration between CH4and DIC. Mass balance considerations reveal that the iron cycled through the coupled ash alteration and AOM reactions is consumed as authigenic Fe-bearing minerals. This iron sink term derived from the mass balance is consistent with the amount of iron present as carbonate minerals, as estimated from sequential extraction analyses. Using a numerical modeling approach we estimate the rate of Fe-AOM to be on the order of 0.4μmol cm−2yr−1, which accounts for ∼12% of total CH4removal in the sediments. Although not without uncertainties, the results presented reveal that Fe-AOM in ash-bearing sediments is significantly lower than the sulfate-driven CH4consumption, which at this site is 3.0μmol cm−2yr−1. We highlight that Fe(III) in ash can potentially serve as an electron acceptor for methane oxidation in sulfate-depleted settings. This is relevant to our understanding of C-Fe cycling in the methanic zone that typically underlies the SMT and could be important in supporting the deep biosphere.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 8
    Publication Date: 2021-06-30
    Description: The climactic Los Chocoyos (LCY) eruption from Atitlán caldera (Guatemala) is a key chronostratigraphic marker for the Quaternary period given the extensive distribution of its deposits that reached both the Pacific and Atlantic Oceans. Despite LCY tephra being an important marker horizon, a radioisotopic age for this eruption has remained elusive. Using zircon (U–Th)/He geochronology, we present the first radioisotopically determined eruption age for the LCY of 75 ± 2 ka. Additionally, the youngest zircon crystallization 238U–230Th rim ages in their respective samples constrain eruption age maxima for two other tephra units that erupted from Atitlán caldera, W‐Fall (130 +16/−14 ka) and I‐Fall eruptions (56 +8.2/−7.7 ka), which under‐ and overlie LCY tephra, respectively. Moreover, rim and interior zircon dating and glass chemistry suggest that before eruption silicic magma was stored for 〉80 kyr, with magma accumulation peaking within ca. 35 kyr before the LCY eruption during which the system may have developed into a vertically zoned magma chamber. Based on an updated distribution of LCY pyroclastic deposits, a new conservatively estimated volume of ~1220 ± 150 km3 is obtained (volcanic explosivity index VEI 〉 8), which confirms the LCY eruption as the first‐ever recognized supereruption in Central America.
    Description: Deutsche Forschungsgemeinschaft SCH 2521/6‐1
    Keywords: 551.701 ; 238U–230Th disequilibrium ; geochronology ; tephrochronology ; (U–Th)/He ; zircon
    Type: article
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  • 9
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 16 (2015): 505–521, doi:10.1002/2014GC005586.
    Description: The Late Quaternary variability of the South Asian (or Indian) monsoon has been linked with glacial-interglacial and millennial scale climatic changes but past rainfall intensity in the river catchments draining into the Andaman Sea remains poorly constrained. Here we use radiogenic Sr, Nd, and Pb isotope compositions of the detrital clay-size fraction and clay mineral assemblages obtained from sediment core NGHP Site 17 in the Andaman Sea to reconstruct the variability of the South Asian monsoon during the past 60 kyr. Over this time interval εNd values changed little, generally oscillating between −7.3 and −5.3 and the Pb isotope signatures are essentially invariable, which is in contrast to a record located further northeast in the Andaman Sea. This indicates that the source of the detrital clays did not change significantly during the last glacial and deglaciation suggesting the monsoon was spatially stable. The most likely source region is the Irrawaddy river catchment including the Indo-Burman Ranges with a possible minor contribution from the Andaman Islands. High smectite/(illite + chlorite) ratios (up to 14), as well as low 87Sr/86Sr ratios (0.711) for the Holocene period indicate enhanced chemical weathering and a stronger South Asian monsoon compared to marine oxygen isotope stages 2 and 3. Short, smectite-poor intervals exhibit markedly radiogenic Sr isotope compositions and document weakening of the South Asian monsoon, which may have been linked to short-term northern Atlantic climate variability on millennial time scales.
    Description: Part of this work was funded by German Science Foundation (DFG), grant HA5751/3-1.
    Description: 2015-08-24
    Keywords: Marine sediments ; Clay minerals ; Radiogenic isotopes ; Andaman Sea ; South Asian monsoon
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/msword
    Format: application/pdf
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  • 10
    Publication Date: 2023-01-30
    Description: Here we present zircon petrochronological data, tephra whole-rock/glass compositions, and amphibole thermobarometry comprising the last four explosive eruptions of Ilopango Caldera in El Salvador (Tierra Blanca eruptive suite, TB). Our datasets include 238U-230Th disequilibrium geochronology, trace-elements, and oxygen isotope compositions from polished and unpolished zircon crystals analyzed using a CAMECA IMS 1280-HR secondary ion mass spectrometer (SIMS) at Heidelberg University, Germany. Additionally, pumice clasts whole-rock chemical analyses from the TB suite were performed at the German Research Centre for Geosciences (GFZ) using a PANalytical AXIOS Advanced wavelength-dispersive spectrometer, whereas major and trace-elements, glass shard, and mineral compositions were collected using an electron microprobe analysis (EMPA) at GEOMAR - Helmholtz-Centre for Ocean Research Kiel and by Laser Ablation Inductively Coupled Plasma - Mass Spectrometry (LA-ICP-MS) at Institute of Earth Sciences, Academia Sinica in Taipei. Whole-rock Sr-Nd isotope determinations were carried out at Departamento de Geología, Centro de Investigación Científica y de Educación Superior de Ensenada (CICESE; Mexico) with a Nu-Instruments thermal ionization mass spectrometer (Nu-TIMS), whereas whole-rock U-series were determined using a ThermoFisher Neptune inductively-coupled mass-spectrometer multi-collector (ICP-MS-MC) at the University of Wyoming (UWYO, USA).
    Keywords: Central America; E009; E012; E014; E015; E017; E021; E023; E044; E047; E053; Geochemistry; geochronology; GLASS; ROCK; Rock sample; TB_E020; TB_E021; TB_E022; TB_E029; TB_E032; TB_E033; TB_E035; TB_E038; TB_E039; TB_E040; TB_E042; TB_E043; TB_E044; TB_E078; TB_E079; TB_E084; zircon
    Type: Dataset
    Format: application/zip, 8 datasets
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