Description: The interplay between sediment deposition patterns, organic matter type and the quantity and quality of reactive mineral phases determines the accumulation, speciation, and isotope composition of pore water and solid phase sulfur constituents in marine sediments. Here, we present the sulfur geochemistry of siliciclastic sediments from two sites along the Argentine continental slope—a system characterized by dynamic deposition and reworking, which result in non-steady state conditions. The two investigated sites have different depositional histories but have in common that reactive iron phases are abundant and that organic matter is refractory—conditions that result in low organoclastic sulfate reduction rates (SRR). Deposition of reworked, isotopically light pyrite and sulfurized organic matter appear to be important contributors to the sulfur inventory, with only minor addition of pyrite from organoclastic sulfate reduction above the sulfate-methane transition (SMT). Pore-water sulfide is limited to a narrow zone at the SMT. The core of that zone is dominated by pyrite accumulation. Iron monosulfide and elemental sulfur accumulate above and below this zone. Iron monosulfide precipitation is driven by the reaction of low amounts of hydrogen sulfide with ferrous iron and is in competition with the oxidation of sulfide by iron (oxyhydr)oxides to form elemental sulfur. The intervals marked by precipitation of intermediate sulfur phases at the margin of the zone with free sulfide are bordered by two distinct peaks in total organic sulfur (TOS). Organic matter sulfurization appears to precede pyrite formation in the iron-dominated margins of the sulfide zone, potentially linked to the presence of polysulfides formed by reaction between dissolved sulfide and elemental sulfur. Thus, SMTs can be hotspots for organic matter sulfurization in sulfide-limited, reactive iron-rich marine sedimentary systems. Furthermore, existence of elemental sulfur and iron monosulfide phases meters below the SMT demonstrates that in sulfide-limited systems metastable sulfur constituents are not readily converted to pyrite but can be buried to deeper sediment depths. Our data show that in non-steady state systems, redox zones do not occur in sequence but can reappear or proceed in inverse sequence throughout the sediment column, causing similar mineral alteration processes to occur at the same time at different sediment depths.

Description: The 1908 Messina tsunami was the most catastrophic tsunami hitting the coastline of Southern Italy in the younger past. The source of this tsunami, however, is still heavily debated, and both rupture along a fault and a slope failure have been postulated as potential origin of the tsunami. Here we report a newly discovered active Fiumefreddo-Melito di Porto Salvo Fault Zone (F-MPS_FZ), which is located in the outer Messina Strait in a proposed landslide source area of the 1908 Messina tsunami. Tsunami modeling showed that this fault zone would produce devastating tsunamis by assuming slip amounts of ≥5 m. An assumed slip of up to 17 m could even generate a tsunami comparable to the 1908 Messina tsunami, but we do not consider the F-MPS_FZ as a source for the 1908 Messina tsunami because its E-W strike contradicts seismological observations of the 1908 Messina earthquake. Future researches on the F-MPS_FZ, however, may contribute to the tsunami risk assessment in the Messina Strait.

Description: Determining factors that limit coseismic rupture is important to evaluate the hazard of powerful subduction zone earthquakes such as the 2011 Tohoku-Oki event (Mw = 9.0). In 1960 (Mw = 9.5) and 2010 (Mw = 8.8), Chile was hit by such powerful earthquakes, the boundary of which was the site of a giant submarine slope failure with chaotic debris subducted to seismogenic zone depth. Here, a continuous décollement is absent, whereas away from the slope failure, a continuous décollement is seismically imaged. We infer that underthrusting of inhomogeneous slide deposits prevents the development of a décollement, and thus the formation of a thin continuous slip zone necessary for earthquake rupture propagation. Thus, coseismic rupture during the 1960 and 2010 earthquakes seems to be limited by underthrusted upper plate mass-wasting deposits. More generally, our results suggest that upper plate dynamics and resulting surface processes can play a key role for determining rupture size of subduction zone earthquakes

Description: Lake Ohrid, located on the Balkan Peninsula within the Dinaride–Albanide–Hellenide mountain belt, is a tectonically active graben within the South Balkan Extensional Regime (SBER). Interpretation of multichannel seismic cross sections and bathymetric data reveals that Lake Ohrid formed during two main phases of deformation: (1) a transtensional phase which opened a pull-apart basin, and (2) an extensional phase which led to the present geometry of Lake Ohrid. After the initial opening, a symmetrical graben formed during the Late Miocene, bounded by major normal faults on each side in a pull-apart type basin. The early-stage geometry of the basin has a typical rhomboidal shape restricted by two sets of major normal faults. Thick undisturbed sediments are present today at the site where the acoustic basement is deepest, illustrating that Lake Ohrid is a potential target for drilling a long and continuous sediment core for studying environmental changes within the Mediterranean region. Neotectonic activity since the Pliocene takes place along the roughly N–S-striking Eastern and Western Major Boundary Normal Faults that are partly exposed at the present lake floor. The tectono-sedimentary structure of the basin is divided into three main seismic units overlying the acoustic basement associated with fluvial deposits and lacustrine sediments. A seismic facies analysis reveals a prominent cyclic pattern of high- and low-amplitude reflectors. We correlate this facies cyclicity with vegetation changes within the surrounding area that are associated with glacial/interglacial cycles. A clear correlation is possible back to ca. 450 kyrs. Extrapolation of average sedimentation rates for the above mentioned period results in age estimate of ca. 2 Myrs for the oldest sediments in Lake Ohrid.

Description: High-resolution reflection seismic data obtained around Gran Canaria allow a detailed and consistent correlation of seismic reflectors of the northern and southern Canary Basins with the lithology drilled by DSDP Leg 47A SSE of Gran Canaria, as well as with major phases of volcanic activity on Gran Canaria as mapped onshore. Two prominent reflectors were chosen as marker horizons and correlated with the drilled lithology. the results indicate that reflector R7 above the Miocene volcaniclastic debris flows V1-V3 reflects the shield-building phase of Gran Canaria. Reflector R3 is interpreted as corresponding with the Pliocene Roque Nublo formation. The top of the massive island flank of Gran Canaria, defined by seismically chaotic facies, extends 44 to 72 km off the coast of Gran Canaria. West of Gran Canaria the flank of Tenerife onlaps the steeper and older flank of Gran Canaria, which, in turn, is onlapping the older flank of Fuerteventura to the east in a similar way. Erosional channels, which can also be traced up to 50 km from the area between Gran Canaria and Fuerteventura into the deeper northern basin, have been identified in the bathymetry. The data presented provide new detailed information for modelling the submarine and subaerial evolution of the central Canary Islands of Gran Canaria and Tenerife, i.e. the timing of their shield-building phases and later stages of major volcanic activity, as reflected by the position of prominent seismic reflectors in the seismic stratigraphy.

Description: The NW African continental margin is well known for the occurrence of large-scale but infrequent submarine landslides. The aim of this paper is to synthesize the current knowledge on submarine mass wasting off NW Africa with a special focus on the distribution and timing of large landslides. The described area reaches from southern Senegal to the Agadir Canyon. The largest landslides from south to north are the Dakar Slide, the Mauritania Slide, the Cap Blanc Slide, the Sahara Slide and the Agadir Slide. Volumes of individual slides reach several hundreds of cubic kilometres; run-outs are up to 900 km. In addition, giant volcanic debris avalanches are widespread on the flanks of the Canary Islands. All headwall areas are complex with clear indications of multiple failures. The most prominent similarity between all investigated landsides is the existence of widespread glide planes that follow the stratigraphy, which points to weak layers as most important preconditioning factor for the failures. Landslides with volumes larger than 100 m3 are close to being evenly distributed over time, contradicting previous suggestions that landslides off NW Africa occur at periods of low or rising sea level. The risk associated with the landslides off NW Africa, however, is relatively low due to their long recurrence rates.

Description: Upper‐plate normal faults are a widespread structural element in erosive plate margins. Increasing coverage of marine geophysical data has proven that similar features also exist in accretionary margins where horizontal compression usually results in folding and thrust‐faulting. There is a general lack of understanding of the role and importance of normal faulting for the structural and tectonic evolution of accretionary margins. Here, we use high‐resolution 2D and 3D seismic reflection data and derived seismic attributes to map and analyze upper‐plate normal faulting in the marine forearc of the accretionary Hikurangi margin, New Zealand. We document extension of the marine forearc over a wide area along the upper continental slope. The seismically imaged normal faults show low vertical displacements, high dip angles, a preference for landward dip and often en echelon patterns. We evaluate different processes, which may cause the observed extension, including (1) stress change during the earthquake cycle, (2) regional or local uplift and decoupling of shallow strata from compression at depth, as well as (3) rotation of crustal blocks and resulting differential stresses at the block boundaries. The results suggest that normal faults play an important role in the structural and tectonic evolution of accretionary margins, including the northern Hikurangi forearc.

Description: Volcanic flank collapses, especially those in island settings, have generated some of the most voluminous mass transport deposits on Earth and can trigger devastating tsunamis. Reliable tsunami hazard assessments for flank collapse-driven tsunamis require an understanding of the complex emplacement processes involved. The seafloor sequence southeast of Montserrat (Lesser Antilles) is a key site for the study of volcanic flank collapse emplacement processes that span subaerial to submarine environments. Here, we present new 2D and 3D seismic data as well as MeBo drill core data from one of the most extensive mass transport deposits offshore Montserrat, which exemplifies multi-phase landslide deposition from volcanic islands. The deposits reveal emplacement in multiple stages including two blocky volcanic debris avalanches, secondary seafloor failure and a late-stage erosive density current that carved channel-like incisions into the hummocky surface of the deposit about 15 km from the source region. The highly erosive density current potentially originated from downslope-acceleration of fine-grained material that was suspended in the water column earlier during the slide. Late-stage erosive turbidity currents may be a more common process following volcanic sector collapse than has been previously recognized, exerting a potentially important control on the observed deposit morphology as well as on the runout and the overall shape of the deposit. Key Points Landslide emplacement offshore Montserrat included volcanic flank collapses, sediment incorporation, and a late-stage erosive flow Highly erosive flows are likely to be common processes during volcanic flank collapse deposition Pre-existing topography plays a major role in shaping flank collapse-associated mass transport deposits Plain Language Summary Disintegration of volcanic islands can cause very large landslides and destructive tsunamis. To assess the tsunami hazard of such events, it is crucial to understand the processes that are involved in their formation. We present new insights from seismic data and drill cores from a landslide deposit offshore Montserrat, a volcanic island in the Lesser Antilles Arc in the Caribbean. Our analysis reveals the emplacement of landslide material in several stages, including multiple volcanic flank collapses, incorporation of seafloor sediments and an erosive flow that carved channels into the top of the deposit right after its emplacement. We suggest that highly erosive flows are a common process during volcanic flank collapse deposition and that they play a significant role in the shaping of the deposit's appearance.

Description: A site at the gas hydrate stability limit was investigated offshore northwestern Svalbard to study methane transport in sediment. The site was characterized by chemosynthetic communities (sulfur bacteria mats, tubeworms) and gas venting. Sediments were sampled with in‐situ porewater collectors and by gravity coring followed by analyses of porewater constituents, sediment and carbonate geochemistry, and microbial activity, taxonomy, and lipid biomarkers. Sulfide and alkalinity concentrations showed concentration maxima in near‐surface sediments at the bacterial mat and deeper maxima at the gas vent site. Sediments at the periphery of the chemosynthetic field were characterized by two sulfate‐methane transition zones (SMTZ) at ~204 and 45 cm depth, where activity maxima of microbial anaerobic oxidation of methane (AOM) with sulfate were found. Amplicon sequencing and lipid biomarker indicate that AOM at the SMTZs was mediated by ANME‐1 archaea. A 1D numerical transport reaction model suggests that the deeper SMTZ‐1 formed on centennial scale by vertical advection of methane, while the shallower SMTZ‐2 could only be reproduced by non‐vertical methane injections starting on decadal scale. Model results were supported by age distribution of authigenic carbonates, showing youngest carbonates within SMTZ‐2. We propose that non‐vertical methane injection was induced by increasing blockage of vertical transport or formation of sediment fractures. Our study further suggests that the methanotrophic response to the non‐vertical methane injection was commensurate with new methane supply. This finding provides new information about for the response time and efficiency of the benthic methane filter in environments with fluctuating methane transport.

Description: Submarine geomorphology underwent significant development in the second half of the 20 th century, largely thanks to advances in technology by the military, navigation and hydrocarbon industry, which were later transferred to the academic and commercial sectors. In this chapter we summarise the development of the key methods used in submarine geomorphology between 1950 and 2000, which include sidescan sonar, multibeam echosounder, reflection seismology, seafloor sampling and marine robotic systems. We then highlight the progress in our understanding of seafloor processes and landforms made using these methods, focusing on continental shelf landforms, slope instability, submarine canyons, submarine fans and channels, and current-controlled landforms.