Anmerkung: Intro -- Contents -- 1 Biomass-Derived Polyurethanes for Sustainable Future -- Abstract -- 1 Introduction -- 1.1 Chemicals for Preparation of Polyurethanes -- 1.2 Importance of Green Chemicals and Synthesis Methods -- 1.3 Characteristics of Biomaterials for Polyurethanes -- 2 Bio-Oils as a Renewable Resource for Polyurethanes -- 2.1 Epoxidation and Ring-Opening Reactions -- 2.2 Hydroformation and Hydrogenation Reactions -- 2.3 Ozonolysis -- 2.4 Thiol-Ene Reaction -- 2.5 Transesterification Reaction -- 3 Terpenes as Green Starting Chemicals for Polyurethanes -- 4 Lignin for Green Polymers -- 5 Conclusion -- References -- 2 Mechanochemistry: A Power Tool for Green Synthesis -- Abstract -- 1 Introduction -- 2 History of Mechanochemistry -- 3 Principles of Mechanochemistry -- 3.1 Mechanisms and Kinetics of Mechanochemistry -- 3.2 Effects of Reaction Parameters -- 4 Mechanochemical Synthesis of Materials -- 4.1 Mechanochemical Synthesis of Co-crystals -- 4.2 Mechanochemistry in Inorganic Synthesis -- 4.3 Mechanochemistry in Organic Synthesis -- 4.4 Mechanochemistry in Metal-Organic Frameworks (MOFs) -- 4.5 Mechanochemistry in Porous Organic Materials (POMs) -- 4.6 Mechanochemical Synthesis of Polymers -- 5 Conclusions -- References -- 3 Future Trends in Green Synthesis -- Abstract -- 1 Introduction -- 2 Green Chemistry Metrics -- 2.1 Atom Economy (AE) -- 2.2 Environmental Factor (E Factor) -- 2.3 Process Mass Intensity (PMI) -- 2.4 Reaction Mass Efficiency (RME) -- 3 Application of Green Concept in Synthesis -- 3.1 Solvent-Based Organic Synthesis -- 3.2 Aqueous Medium -- 3.2.1 Micellar Media -- 3.2.2 Different Non-Aqueous Media -- Ionic Liquids -- Fluorous Media -- Supercritical Fluid -- Solvent-Free Synthesis -- 4 Future Trends -- References -- 4 Plant-Mediated Green Synthesis of Nanoparticles -- Abstract -- 1 Introduction. , 2 Methods for Metallic Nanoparticle Biosynthesis -- 3 Green Biosynthesis of Metallic NPs -- 3.1 Gold Nanoparticles -- 3.2 Platinum Nanoparticles -- 3.3 Silver Nanoparticles -- 3.4 Zinc Oxide Nanoparticles -- 3.5 Titanium Dioxide Nanoparticles -- 4 Different Parts Used for the Synthesis of Metallic Nanoparticles -- 4.1 Fruit -- 4.2 Stem -- 4.3 Seeds -- 4.4 Flowers -- 4.5 Leaves -- 5 Conclusions -- References -- 5 Green Synthesis of Hierarchically Structured Metal and Metal Oxide Nanomaterials -- Abstract -- 1 Introduction -- 2 Advantages of Green Synthesis Methods -- 3 Green Synthesis Methods for Hierarchically Structured Metal and Metal Oxide Nanomaterials -- 3.1 Biological Methods -- 3.1.1 Using Microorganism -- Microorganisms as Reactant -- Microorganism as Template -- 3.1.2 Using Plant -- Plant as Reactant -- Plant as Template -- 3.1.3 Using Other Green Templates -- 3.2 Physical and Chemical Methods -- 3.2.1 Green Techniques -- 3.2.2 Green Reagents -- 3.2.3 Green Solvents -- 4 Growth Mechanism of Metal and Metal Oxide HSNs -- 4.1 Biological Method -- 4.1.1 Biomolecules as Reagents -- 4.1.2 Biomolecules as Templates -- 4.2 Physical and Chemical Methods -- 5 Applications of Hierarchically Structured Metal and Metal Oxide Nanomaterials -- 5.1 Biomedical Application -- 5.2 Environmental Remediation -- 5.2.1 Wastewater Treatment -- 5.2.2 Energy Storage -- 5.2.3 Sensing -- 6 Present Challenges and Future Prospect -- Acknowledgements -- References -- 6 Bioprivileged Molecules -- Abstract -- 1 Introduction -- 2 Four Carbon 1,4-Diacids -- 2.1 Succinic Acid -- 2.2 Fumaric Acid -- 2.3 Malic Acid -- 3 Furan 2,5-Dicarboxylic Acid (FDCA) -- 4 3-Hydroxypropionic Acid (3-HPA) -- 5 Glucaric Acid -- 6 Glycerol -- 7 Aspartic Acid -- 8 Itaconic Acid -- 9 3-Hydroxybutyrolactone -- 10 Sorbitol -- 11 Xylitol -- 12 Glutamic Acid -- 13 Levulinic Acid. , 14 Emerging Molecules -- 15 Conclusion -- References -- 7 Membrane Reactors for Green Synthesis -- Abstract -- 1 Introduction -- 2 Chemical Reaction Enzymatic MR Using Supercritical CO2-IL -- 2.1 Ionic Liquid Media Effect on Free CLAB -- 2.2 Butyl Propionate Synthesis Using Active Membranes SC-CO2 and SC-CO2/IL -- 2.3 Butyl Propionate Synthesis Using Active Membranes in Hexane/IL -- 3 Mixed Ionic Electronic MR -- 3.1 Methane Flow Rate and Concentration Effects on Side II of Membrane -- 3.2 Steam Flow Effect on Side I of Membrane -- 3.3 Temperature Effect -- 4 Green Synthesis of Methanol in a Membrane Reactor -- 5 Green Fuel Energy -- 5.1 Green H2 Energy -- 5.2 Biofuel Energy -- 5.3 Green Fuel Additive -- 6 Biocatalyst Membrane Reactors -- 7 Photocatalytic Membrane Reactors -- 8 Conclusions -- References -- 8 Application of Membrane in Reaction Engineering for Green Synthesis -- Abstract -- 1 Introduction -- 2 Applications of Membrane Reactors in Reaction Engineering -- 2.1 Syngas Production -- 2.2 Hydrogen Production -- 2.3 CO2 Thermal Decomposition -- 2.4 Higher Hydrocarbon Production -- 2.5 Methane Production -- 2.6 Ammonia Production -- 3 Environmental Impacts -- 4 Conclusions and Future Recommendations -- Acknowledgements -- References -- 9 Photo-Enzymatic Green Synthesis: The Potential of Combining Photo-Catalysis and Enzymes -- Abstract -- 1 Introduction -- 2 Principle -- 3 Enzymes Involved in Light-Driven Catalysis -- 3.1 Heme-Containing Enzymes -- 3.1.1 Cytochrome P450 -- 3.1.2 Peroxidases -- 3.2 Flavin-Based Enzyme -- 3.2.1 Baeyer-Villiger Monooxygenases -- 3.2.2 Old Yellow Enzymes -- 3.3 Metal Cluster-Centered Enzyme -- 3.3.1 Hydrogenases -- 3.3.2 Carbon Monoxide Dehydrogenases -- 4 Nanoparticle-Based Activation of Enzyme -- 5 Applications in Photo-Biocatalysis -- 5.1 Isolated Enzymes/Cell Lysates -- 6 Summary and Future Scope -- References. , 10 Biomass-Derived Carbons and Their Energy Applications -- Abstract -- 1 Introduction -- 2 Types of Biomass Materials -- 2.1 Plant-Based Carbons -- 2.2 Fruit-Based Carbons -- 2.3 Animal-Based Carbons -- 2.4 Microorganism-Based Carbons -- 3 Activation of Biomass-Derived Carbons -- 3.1 Activation of Carbons -- 3.1.1 Chemical Activation of Carbons -- 3.1.2 Carbon Activation Through Physical Method -- 3.1.3 Self-activation of Carbons -- 3.2 Pyrolysis Techniques -- 3.2.1 Effect of Temperature -- 3.2.2 Effect of Residence Time -- 3.2.3 Heating Rate Effect -- 3.2.4 Size of the Particle -- 3.3 Microwave-Assisted Technique -- 3.4 Carbonization by Hydrothermal -- 3.5 Ionothermal Carbonization -- 3.6 Template Method -- 4 Energy Storage Applications of Biomass Carbons -- 4.1 Supercapacitors -- 4.2 Li/Na-Ion Batteries -- 5 Conclusion -- Acknowledgements -- References -- 11 Green Synthesis of Nanomaterials via Electrochemical Method -- Abstract -- 1 Introduction -- 2 Green Synthesis -- 2.1 Application of Biology in Green Synthesis -- 2.2 Green Synthesis Based on the Application of Solvent -- 3 Computational Data and Analysis -- 4 Electrochemical Method -- 5 Electrodeposition Method -- 5.1 Experimental Setup for Electrodeposition -- 6 Research Work: Using Green Electrochemical Methods for Nanomaterials Synthesis -- 7 Conclusion -- References -- 12 Microwave-Irradiated Synthesis of Imidazo[1,2-a]pyridine Class of Bio-heterocycles: Green Avenues and Sustainable Developments -- Abstract -- 1 Introduction -- 2 Microwave-Assisted Synthesis of 2-arylimidazo[1,2-a]pyridines [Abbreviated as 2-Aryl-IPs]. -- 2.1 Synthesis of Fused Bicyclic Heteroaryl Boronates and Imidazopyridine-Quinazoline Hybrids Under MW-irradiations -- 2.2 MW-Irradiated Synthesis of IPs Using Multi-Component Strategy Under Neat Conditions. , 2.3 One-Pot, Three-Component Synthesis of 2-Phenyl-H-Imidazo[1,2-α]pyridine Under MW-Irradiations -- 2.4 Microwave-Assisted Amine-Triggered Benzannulation Strategy for the Preparation of 2,8-Diaryl-6-Aminoimidazo-[1,2-a]pyridines -- 2.5 MW-Assisted NaHCO3-catalyzed Synthesis of Imidazo[1,2-a]pyridines in PEG400 Media and Its Practical Application in the Synthesis of 2,3-Diaryl-IP Class of Bio-Heterocycles -- 2.6 MW-Irradiated, Ligand-Free, Palladium-Catalyzed, One-Pot 3-component Reaction for an Efficient Preparation of 2,3-Diarylimidazo[1,2-a]pyridines -- 2.7 MW-Assisted Water-PEG400-mediated Synthesis of 2-Phenyl-IP via Multi-Component Reaction (MCR) -- 2.8 Microwave-Irradiated Synthesis of Imidazo[1,2-a]pyridines Under Neat, Catalyst-Free Conditions -- 2.9 Green Synthesis of Imidazo[1,2-a]pyridines in H2O -- 2.10 Microwave-Assisted Neat Synthesis of Substituted 2-Arylimidazo[1,2-a]Pyridines -- 2.11 Microwave-Assisted Nano SiO2 Neat Synthesis of Substituted 2-Arylimidazo[1,2-a]pyridines -- 2.12 Microwave-Assisted NaHCO3-Catalyzed Synthesis of 2-phenyl-IPs -- 3 Microwave-Assisted Synthesis of 3-amino-2-arylimidazo[1,2-a]pyridines [3-amino-2-aryl-IPs] -- 3.1 Microwave-Irradiated Synthesis of 3-aminoimidazo[1,2-a]pyridines via Fluorous Multi-component Pathway -- 3.2 MW-Irradiated Synthetic Protocol for 3-aminoimidazo[1,2-a]pyridines via MCR Pathway -- 3.3 MW-Assisted Sequential Ugi/Strecker Reactions Involving 3-Center-4-Component and 3-Center-5-Component MCR Strategy -- 3.4 One-Pot, 4-component Cyclization/Suzuki Coupling Leading to the Rapid Formation of 2,6-Disubstituted-3-Amino-IPs Under Microwave Irradiations -- 3.5 ZnCl2-catalyzed MCR of 3-aminoimidazo[1,2-a]pyridines Using MW Conditions -- 3.6 Microwave-Promoted Preparation of N-(3-arylmethyl-2-oxo-2,3-dihydroimidazo[1,2-a]pyridin-3-Yl)Benzamides. , 3.7 MW-Assisted Multi-component Neat Synthesis of Benzimidazolyl-Imidazo[1,2-a]pyridines.

Anmerkung: Intro -- Contents -- 1 Chemical Valorization of CO2 -- Abstract -- 1 Introduction -- 2 CO2-Derived Fuels and Chemicals -- 2.1 Methane -- 2.2 Methanol -- 2.3 Dimethyl Ether -- 2.4 Formic Acid -- 2.5 Ethanol -- 2.6 CO2-Fischer-Tropsch Liquid Fuels -- 2.7 Carbon Monoxide-Syngas -- 3 CO2 Chemically Derived Materials -- 3.1 Polymers -- 3.2 CO2-Derived Building Materials -- 4 Conclusions -- References -- 2 Progress in Catalysts for CO2 Reforming -- Abstract -- 1 Introduction -- 2 Technologies for Capturing and Storing Carbon Dioxide -- 3 Technologies for Using Carbon Dioxide -- 4 Methane Dry Reforming Process -- 4.1 Progress in Catalysts for Methane Dry Reforming (1928-1989) -- 4.2 Progress in Catalysts for Methane Dry Reforming (1990-1999) -- 4.3 Progress in Catalysts for Methane Dry Reforming (2000-2009) -- 4.4 Progress in Catalysts for Methane Dry Reforming (2010-2019) -- 4.5 Current Status in the Catalysts for Methane Dry Reforming -- 5 Dry Reforming of Other Compounds -- 6 Use of Steam or Oxygen in Dry Reforming of Methane and Other Compounds -- 7 Solid Oxide Fuel Cells Fueled with Biogas -- 8 Commercialization of Dry Reforming Process -- 9 Conclusions -- References -- 3 Fuel Generation from CO2 -- Abstract -- 1 Introduction -- 2 Approaches for Directly Converting CO2 to Fuels -- 2.1 Pure CO2 Decomposition Technology -- 2.2 Reagent-Based CO2 Conversion Technology -- 2.2.1 Dry Deformation of Methane Technology -- 2.2.2 Catalytic Hydrogenation of CO2 -- 3 Biological CO2 Fixation for Fuels -- 3.1 Thermochemical Conversion -- 3.1.1 Torrefaction -- 3.1.2 Pyrolysis -- 3.1.3 Thermochemical Liquefaction -- 3.1.4 Gasification -- 3.1.5 Direct Combustion -- 3.2 Biochemical Conversion -- 3.2.1 Biodiesel -- 3.2.2 Bioethanol -- 3.2.3 Biomethane -- 3.2.4 Biohydrogen -- 3.2.5 Bioelectricity -- 3.2.6 Volatile Organic Compounds. , 4 Conclusion and Future Perspectives -- References -- 4 Thermodynamics of CO2 Conversion -- Abstract -- 1 Introduction -- 2 Carbon Dioxide Capture -- 3 Carbon Dioxide Utilisations -- 4 Thermodynamic Considerations -- 5 Thermodynamics of CO2 -- 5.1 The Thermodynamic Attainable Region (AR) -- 5.2 Using Hess's Law to Transform the Extents to G-H AR @ 25˚C -- 5.3 Increasing Temperature on G-H AR -- 6 Conclusion -- Acknowledgements -- References -- 5 Enzymatic CO2 Conversion -- Abstract -- 1 Introduction -- 1.1 CO2 as a Greenhouse Gas -- 1.2 Carbon Capture, Storage, and Utilization -- 1.3 CO2 as a Chemical Feedstock -- 1.4 CO2 Conversion with Enzymes -- 2 Natural Conversion of CO2 in Cells -- 3 Enzymatic Conversion of CO2 in Cells -- 3.1 Conversion of CO2 by a Single Enzyme (in vitro) -- 3.1.1 Formate Dehydrogenase -- 3.1.2 Carbonic Anhydrase -- 3.1.3 Carbon Monoxide Dehydrogenase -- 3.1.4 Ribulose-1,5-bisphosphate Carboxylase/Oxygenase (RuBisCO) -- 3.2 Conversion of CO2 by a Multi-Enzyme Cascade in vitro -- 3.3 Other Ways (Photocatalytic CO2 Methanation) -- 4 Industrial Applications -- 4.1 Alcohols -- 4.2 Organic Acids -- 4.3 Terpenoids -- 4.4 Fatty Acids -- 4.5 Polyhydroxyalkanoates -- 4.6 Calcium Carbonate -- 5 Summary and Future Prospects -- References -- 6 Electrochemical CO2 Conversion -- Abstract -- 1 Introduction -- 2 Electrochemical CO2 Conversion -- 2.1 Fundamentals of the Process -- 2.2 Variants of Electrochemical Conversion of CO2 -- 2.2.1 Aqueous Electrolytes -- 2.2.2 Non-Aqueous Electrolytes -- 2.2.3 Solid Oxide Electrolytes -- 2.2.4 Molten Salt Electrolytes -- 3 Electrochemical CO2 Conversion from Molten Salts -- 3.1 Present State of Electrochemical Reduction of CO2in Molten Salts for the Production of Solid-Phase Carbonaceous Nanomaterials -- 3.2 Direct Electrochemical Reduction of CO2 in Chloride Melts. , 3.3 Indirect Electrochemical Reduction of CO2 in Molten Salts -- 3.4 The Mechanisms of Electrode Reactions Occurring at the Cathode and Anode -- 3.5 Prospects for CO2 Conversion in Molten Salts -- 4 Conclusions -- References -- 7 Supercritical Carbon Dioxide Mediated Organic Transformations -- Abstract -- 1 Introduction -- 2 Applications of Supercritical Carbon Dioxide -- 2.1 Hydrogenation Reactions -- 2.2 Asymmetric Hydrogenation Reactions -- 2.3 Diels-Alder Reaction -- 2.4 Coupling Reaction -- 2.5 Oxidation Reaction -- 2.6 Baeyer-Villiger Oxidation Reaction -- 2.7 Iodination Reaction -- 2.8 Polymerization Reaction -- 2.9 Carbonylation Reaction -- 2.9.1 Acetalization Reaction -- 2.9.2 Olefin Metathesis Reaction -- 2.9.3 Synthesis of heterocycles -- Synthesis of α-alkylidene Cyclic Carbonates -- Synthesis of 4-Methyleneoxazolidin-2-Ones -- Synthesis of 5-Alkylidene-1, 3-Oxazolidin-2-Ones -- Synthesis of 6-Phenyl-3a, 4-Dihydro-1H-Cyclopenta[C]furan-5(3H)-One -- Synthesis of 3, 4, 5, 6-Tetraethyl-2H-Pyran-2-One -- 3 Conclusions -- Acknowledgements -- References -- 8 Theoretical Approaches to CO2 Transformations -- Abstract -- 1 Carbon Dioxide Properties -- 2 CO2 Transformation as an Undeniable Necessity -- 3 CO2 Activation -- 3.1 Methodologies of CO2 Activation -- 4 Theoretical Insight of CO2 Transformation -- 4.1 The Theoretical Approach in CO2 Conversion to Value-Added Chemicals -- 4.1.1 Carbon Monoxide -- 4.1.2 Methane -- 4.1.3 Methanol -- 4.1.4 Formic Acid -- 4.1.5 Heterocycles -- Cyclic Carbonates -- Cyclic Carbamate -- Quiznazoline-2,4(1H,3H)-Dione -- 4.1.6 Summary and Outlook -- 5 Theoretical Designing of Novel Catalysts Based on DFT Studies -- 5.1 Theoretical Designing: Problems and Opportunities -- 6 Conclusion -- References -- 9 Carbon Dioxide Conversion Methods -- Abstract -- 1 Introduction -- 2 Molecular Structure of CO2. , 3 Thermo-Kinetics of CO2 Conversion -- 4 CO2 Conversion Methods and Products -- 4.1 Fischer-Tropsch Gas-to-Liquid (GTL) -- 4.2 Mineralization -- 4.3 Chemical Looping Dry Reforming -- 4.4 Enzymatic Conversion -- 4.5 Photocatalytic and Photo-Electrochemical Conversion -- 4.6 Thermo-Chemical Conversion -- 4.7 Hydrogenation -- 4.8 Reforming -- 5 Economic Assessment of CO2Alteration to Valuable Products -- 5.1 Syngas -- 5.2 Methanol -- 5.3 Formic Acid -- 5.4 Urea -- 5.5 Dimethyl Carbonate (DMC) -- 6 Conclusions and Future Perspective -- Acknowledgements -- References -- 10 Closing the Carbon Cycle -- Abstract -- 1 Introduction -- 2 Methods to Capture CO2 -- 3 CO2 Capture Technologies -- 4 CO2 Capture from the Air -- 5 Biomass and Waste-Based Chemicals -- 6 Advantages of Biomass-Based Chemicals -- 7 Replacement of Carbon-Based Energy Resources -- 8 Biomass Energy -- 9 Wind Energy -- 10 Solar Energy -- 11 Ocean Energy -- 12 Geothermal Energy -- 13 Hydrothermal Energy -- 14 Conclusions -- References -- 11 Carbon Dioxide Utilization to Energy and Fuel: Hydrothermal CO2 Conversion -- Abstract -- 1 Introduction -- 2 Hydrothermal CO2 Conversion -- 2.1 Metals and Catalysts as Reductant -- 2.2 Organic Wastes as Reductant -- 2.3 Inorganic Wastes as Reductant -- 2.4 Biomass as Reductant -- 3 Conclusion -- References -- 12 Ethylenediamine-Carbonic Anhydrase Complex for CO2 Sequestration -- 1 Introduction -- 2 An Overview of Carbonic Anhydrase (CA) -- 3 Mechanism of Action for Biocarbonate Formation -- 4 Historical Background of Carbonic Anhydrase -- 5 Sources of Carbonic Anhydrase -- 6 Carbonic Anhydrase in Microorganism -- 6.1 Micrococcus Lylae, Micrococcus Luteus, and Pseudomonas Fragi -- 6.2 Bacillus Subtilis and Citrobacter Freundii -- 6.3 Neisseria Gonorrhoeae -- 6.4 Helicobacter Pylori -- 7 Plant Carbonic Anhydrase -- 8 Overview of CO2. , 9 Sources of Carbon Dioxide (CO2) -- 10 Effect of Carbon Dioxide (CO2) -- 11 Carbon Dioxide Capturing -- 12 Carbon Dioxide (CO2) Sequestration -- 13 Carbon Dioxide (CO2) Sequestration by Carbonic Anhydrase -- 14 Separation System for CO2 Sequestration -- 15 Cryogenic Separation -- 16 Membrane Separation -- 17 Absorption -- 18 Adsorption -- 19 Bioreactors for CO2 Sequestration -- 20 Carbonic Anhydrase Immobilization -- 21 Ethylenediamine for Carbon Dioxide (CO2) Capturing -- 22 CO2 Capturing and Sequestration with Ethylenediamine-Carbonic Anhydrase Complex -- 23 CO2 Capturing and Sequestration Design and Optimization: Challenges and Future Prospects -- 24 Conclusion -- References -- 13 Green Pathway of CO2 Capture -- Abstract -- 1 Introduction -- 2 Molecular Structure of Carbon Dioxide -- 3 CO2 Capture System -- 3.1 Post-Combustion System -- 3.2 Pre-Combustion System -- 3.3 Oxy-Fuel Combustion System -- 4 Absorption Technology -- 4.1 Green Absorption with Ionic Liquids -- 4.1.1 Properties and Uses of Ionic Liquids -- 4.1.2 CO2 Solubility in PILs -- 4.1.3 CO2 Absorption in PILs with Carboxylate Anion -- 4.2 Reaction Mechanism Involved in CO2-Absorption -- 5 Adsorption Technology -- 5.1 Organic Adsorbents -- 5.1.1 Activated Charcoal -- 5.1.2 Biochar -- 5.1.3 Metal-Organic Frameworks (MOFs) -- 5.2 Other CO2 Adsorbents -- 5.2.1 Metal Oxide-Based Absorbents -- 5.2.2 Zeolites -- 5.3 Biological Processes of CO2Sequestration -- 5.3.1 Carbon Utilization by Forest and Agricultural Management -- 5.3.2 Ocean Fertilization -- 5.3.3 CO2 Capture by Microalgae -- 5.4 Electrochemical Ways for CO2 Capture -- 6 Conclusion -- References -- 14 Carbon Derivatives from CO2 -- Abstract -- 1 Introduction -- 2 Artificial Photoreduction -- 3 Electrochemical Reduction -- 4 Hydrogenation -- 5 Synthesis of Organic Carbonates -- 6 Reforming. , 7 Photocatalytic Reduction of CO2 with Water.

Anmerkung: Intro -- Green Sustainable Process for Chemical and Environmental Engineering and Science: Microwaves in Organic Synthesis -- Copyright -- Contents -- Contributors -- Chapter 1: Microwave catalysis in organic synthesis -- 1. Introduction -- 1.1. History -- 1.2. Early development in utilization of microwave heating for organic synthesis -- 2. Factors influencing microwave heating in organic reactions -- 2.1. Microwave heating mechanism -- 2.1.1. Dipolar polarization mechanism -- 2.1.2. Ionic conduction mechanism -- 2.2. Dielectric properties and loss tangent -- 2.3. Superheating effect -- 2.4. Interaction of microwaves with different materials -- 3. Comparison of microwave with conventional heating -- 4. Microwave-assisted catalytic organic reactions -- 4.1. Coupling reactions -- 4.1.1. Suzuki reaction (or Suzuki-Miyaura coupling) -- 4.1.2. Stille coupling reaction -- 4.1.3. Sonogashira coupling -- 4.1.4. Heck reaction -- 4.2. Microwave-assisted heterocyclic chemistry -- 4.2.1. Nitrogen-containing heterocycles -- 4.2.2. Oxygen-containing heterocycles -- 4.2.3. Sulfur-containing heterocycles -- 4.3. Multicomponent reactions -- 4.3.1. Hantzsch reaction -- 4.3.2. Ugi reaction -- 4.3.3. Biginelli reaction -- 4.3.4. Mannich reaction -- 4.3.5. Strecker reaction -- 4.4. Alkylation reactions -- 4.4.1. N-Alkylation -- 4.4.2. C-Alkylation -- 4.4.3. O-Alkylation -- 4.5. Esterification and transesterification reactions -- 5. Microwave reactors -- 6. Current challenges in microwave-assisted synthesis -- 6.1. Energy efficiency -- 6.2. Scale-up of microwave-assisted organic reactions -- 7. Conclusion -- References -- Chapter 2: Microwave-assisted CN formation reactions -- 1. Introduction -- 2. N-Arylations, N-alkylations, and related reactions -- 2.1. Palladium-catalyzed processes-Buchawald-Hartwig amination. , 2.2. Copper-catalyzed reactions-The Ullmann coupling -- 2.3. Application of other metal catalysts -- 2.4. Metal-free transformations -- 2.5. The Petasis borono-Mannich reaction -- 2.6. Three-component propargylations -- 3. Amidations -- 3.1. Direct amidations -- 3.2. Amidation by reacting esters and amines -- 3.3. Transamidations -- 3.4. Oxidative amidations -- 3.5. Miscellaneous processes -- 4. Ring-forming reactions -- 4.1. Rings with one nitrogen atom -- 4.1.1. Synthesis of three- and four-membered rings -- 4.1.2. Synthesis of five-membered rings -- 4.1.3. Six-membered and larger rings -- 4.1.4. Condensed rings: Indoles and structural isomers -- 4.1.5. Condensed rings: Quinolines and isoquinolines -- 4.1.6. Molecules with multiple rings -- 4.2. Ring systems with two nitrogen atoms -- 4.2.1. Synthesis of diazoles -- 4.2.2. Six-membered rings -- 4.2.3. Condensed rings -- 4.2.4. Molecules with multiple rings -- 4.3. Rings with three and four nitrogen atoms -- 4.3.1. Synthesis of azoles -- Synthesis of 1,2,3-triazoles -- Synthesis of 1,2,4-triazoles -- Synthesis of tetrazoles -- 4.3.2. Synthesis of triazines -- 4.3.3. Condensed bicyclic molecules -- 5. Polycyclic condensed ring systems with multiple nitrogen atoms -- 5.1. Molecules containing three nitrogen atoms -- 5.2. Ring systems with four and more nitrogens -- 6. Summary -- References -- Chapter 3: Microwave-assisted multicomponent reactions -- 1. Introduction -- 2. Three-component reactions -- 2.1. Mannich reaction -- 2.2. Betti reaction -- 2.3. Petasis reaction -- 2.4. Kabachnik-Fields reaction -- 2.5. A3-coupling reaction -- 2.6. Povarov reaction -- 2.7. Strecker reaction -- 2.8. Groebke-Blackburn-Bienaymé reaction -- 2.9. Passerini reaction -- 2.10. Pauson-Khand reaction -- 2.11. Kindler reaction -- 2.12. Gewald reaction -- 2.13. Bucherer-Bergs reaction -- 2.14. Biginelli reaction. , 3. Four-component reactions -- 3.1. Ugi reactions -- 3.2. Radziszewski reaction -- 3.3. Hantzsch dihydropyridine synthesis -- 3.4. Kröhnke reaction -- 4. Concluding remarks -- References -- Chapter 4: Catalytic, ultrasonic, and microwave-assisted synthesis of naphthoquinone derivatives by intermolecular and -- 1. Summary -- 2. Introduction -- 3. Synthesis of 2-anilino-1,4-naphthoquinone derivatives -- 4. Synthesis of 2,3-dianilino)-1,4-naphthoquinone derivatives -- 5. Synthesis of 2-anilino-5-hydroxy-1,4-naphthoquinone derivatives -- 6. Synthesis of indolo naphthoquinone derivatives -- 7. Conclusions -- References -- Chapter 5: Microwave-assisted condensation reactions -- 1. Introduction -- 2. Conceptual principles in microwave mechanism -- 3. Microwave-assisted condensation reactions -- 3.1. Microwave-assisted multicomponent condensation reaction -- 3.1.1. Multicomponent synthesis of aminopyrazolo[1,5-a][1,3,5]triazine-8-carboxylates -- 3.1.2. Multicomponent synthesis of 1,3,5,6-tetrasubstituted 2-pyridone -- 3.1.3. Multicomponent synthesis of functionalized steroidal pyridines -- 3.1.4. Multicomponent synthesis of indolyl-coumarin hybrids -- 3.1.5. Multicomponent synthesis of indole-1,3-dione derivatives -- 3.2. Microwave-assisted Knoevenagel condensation reaction -- 3.2.1. Knoevenagel synthetic approach to ethyl 2-cyano-3-phenylacrylate derivatives -- 3.2.2. Knoevenagel synthetic approach to Indole-based Heterocycles -- 3.2.3. Knoevenagel synthetic approach to tetrahydrochromeno[3,4-c]chromen-1(2H)-ones -- 3.2.4. Knoevenagel synthetic approach to pyran-based chalcones -- 3.2.5. Knoevenagel synthetic approach to 3-acetylcoumarin and chalcone affiliates -- 3.2.6. Knoevenagel synthetic approach to 2,3-dihydropyran[2,3-c]pyrazoles -- 3.3. Microwave-assisted aldol condensation reaction -- 3.3.1. Aldol-type synthetic approach to 3-acetyl isocoumarin. , 3.3.2. Aldol-type synthetic approach to aza-fused isoquinoline motifs -- 3.3.3. Aldol-type synthetic approach to dibenzylidenecyclohexanones -- 3.3.4. Aldol-type synthetic approach to dibenzylidenecyclopentanone -- 3.3.5. Aldol-type synthetic approach to 2-benzylideneoctanal -- 3.4. Microwave-assisted Pechmann condensation reaction -- 3.4.1. Amberlyst-15 catalyzed synthetic approach to 4-methylcoumarin -- 3.4.2. Zn [(l)-proline]2 catalyzed synthetic approach to tricyclic 4-methylcoumarin -- 3.4.3. FeF3 catalyzed synthetic approach to 4,7-dimethyl-2H-chromen-2-one -- 3.4.4. Pechmann condensation reaction for synthesis of umbelliferone -- 3.4.5. Microwave-assisted synthesis via two different naphthalenediol -- 3.4.6. ZnCl2 catalyzed synthesis of linear pyranodihydrocoumarin -- 3.5. Microwave-assisted Mannich condensation reaction -- 3.5.1. Mannich synthetic approach to nitrothiazolo[3,2-c]pyrimidines -- 3.5.2. Mannich synthetic approach to 4-hydroxyacetophenone derivatives -- 3.5.3. Mannich synthetic approach to barbituric acid derivatives -- 3.5.4. Mannich synthetic approach to polymethoxychalcone -- 3.6. Other miscellaneous microwave-assisted condensation products -- 4. Conclusion -- References -- Chapter 6: Microwave-assisted oxidation reactions -- 1. Introduction -- 2. C-oxidation -- 2.1. Oxidation of hydrocarbons -- 2.1.1. Oxidation of sp3 hybridized carbons -- Alkane to aldehyde (RCH3RCOH) -- Alkane to glyoxal (RCOCH3RCOCOH) -- Alkane to acid (RCH3RCOOH) -- Alkane to ketone (RCH2RRCOR) -- Cyclic ethers to esters (RCH2ORRCOOR) -- 2.1.2. Oxidation of sp2 hybridized carbons -- Alkene to aldehyde (RCHCHRRCOH) -- 2.1.3. Oxidation of sp hybridized carbons -- Alkyne to glyoxal (RCCHRCOCOH) -- 2.2. Oxidation of alcohols -- 2.2.1. Alcohol to aldehyde (RCH2OHRCOH) -- 2.2.2. Clayfen -- 2.2.3. Cetyltrimethylammonium bromochromate (CTMABC) -- 2.2.4. Magtrieve. , 2.2.5. Zeolite A -- 2.3. Oxidation of aldehyde -- 2.3.1. Aldehyde to acid (RCHORCOOH) -- 2.3.2. Aldehyde to ester (RCHORCOOR1 -- R1 from solvent) -- 2.4. Oxidation of halides -- 2.4.1. Halides to aldehydes (RCH2XRCOH) -- 2.5. Oxidative cyclization -- 2.6. Oxidative aromatization -- 2.7. Oxidative amination -- 2.8. Advancements in named oxidation reactions -- 2.8.1. Baeyer-Villiger oxidation -- 2.8.2. Dess-Martin periodinane reaction -- 2.8.3. Fetizon/Fetison oxidation -- 2.8.4. Jacobsen epoxidation -- 2.8.5. Jones/chromium based oxidation -- 2.8.6. Kornblum oxidation -- 2.8.7. Noyori oxidation -- 2.8.8. Sharpless epoxidation -- Other oxidation reactions -- 3. N-oxidations -- 3.1. N-oxide formation -- 3.2. Amines to imines -- 4. S-oxidations -- 4.1. Sulfides to sulfoxides -- 4.2. Thiols to disulfides -- References -- Chapter 7: Microwave-assisted reduction reactions -- 1. Introduction -- 1.1. Fundamental aspects of microwave radiation -- 1.2. Microwave apparatus -- 1.3. Advantages and disadvantages of microwave irradiation -- 2. Microwave-assisted organic reduction reactions -- 3. Microwave-assisted reduction for the development of inorganic raw materials -- 4. Microwave-assisted reduction for production composites -- 5. Microwave-assisted reduction for nanoparticle synthesis -- 6. Microwave-assisted reduction for catalyst purpose -- 7. Conclusion -- References -- Chapter 8: Microwave-assisted stereoselective organic synthesis -- 1. Introduction -- 2. Microwave-assisted diastereoselective and enantioselective reactions -- 3. Microwave-assisted diastereoselective organic transformation reactions -- 4. Microwave-assisted enantioselective organic transformation reactions -- 5. Conclusion -- References -- Chapter 9: Microwave-assisted heterocyclics -- 1. Introduction -- 2. Microwave-promoted synthesis of heterocyclic compounds. , 2.1. Synthesis of tetrazole-based heterocycles.

Anmerkung: Cover -- Half-Title Page -- Series Page -- Title Page -- Copyright Page -- Contents -- Preface -- 1 Natural Polysaccharides From Aloe vera L. Gel (Aloe barbadensis Miller): Processing Techniques and Analytical Methods -- 1.1 Introduction -- 1.1.1 Gel Composition from A. vera -- 1.2 Applications of A. vera Mucilaginous Gel or Fractions -- 1.3 Aloe vera Gel Processing -- 1.3.1 Obtaining Polysaccharide Fraction or Acemannan -- 1.4 Analytical Methods Applied -- 1.4.1 Total Carbohydrates, Oligosaccharides, Acemannan and Free Sugars -- 1.4.2 Analytical Techniques -- 1.4.2.1 Chromatography Analysis -- 1.4.2.2 Infrared Spectroscopy (IR) -- 1.4.2.3 Nuclear Magnetic Resonance Spectroscopy -- 1.4.2.4 Mass Spectrometry -- 1.4.2.5 Ultraviolet-Visible Spectroscopy -- 1.4.2.6 Comprehensive Microarray Polymer Profiling -- 1.5 Conclusion -- References -- 2 Cell Wall Polysaccharides -- 2.1 Introduction to Cell Wall -- 2.2 Plant Cell Wall Polysaccharides -- 2.2.1 Cellulose -- 2.2.2 Hemicellulose -- 2.2.2.1 Xyloglucan -- 2.2.2.2 Xylans -- 2.2.2.3 Mannans -- 2.2.3 Callose -- 2.2.4 Pectic Polysaccharides -- 2.2.4.1 Homogalacturonan (HG) -- 2.2.4.2 Arabinan -- 2.3 Algal Cell Wall Polysaccharides -- 2.3.1 Alginates -- 2.3.2 Sulfated Galactans -- 2.3.3 Fucoidans -- 2.4 Fungal Cell Wall Polysaccharides -- 2.4.1 Glucan -- 2.4.2 Chitin and Chitosan -- 2.5 Bacterial Cell Wall Polysaccharides -- 2.5.1 Peptidoglycan -- 2.5.2 Lipopolysaccharides -- References -- 3 Marine Polysaccharides: Properties and Applications -- 3.1 Introduction -- 3.2 Polysaccharide Origins -- 3.3 Properties -- 3.3.1 Cellulose -- 3.3.2 Chitosan -- 3.3.3 Alginate -- 3.3.4 Carrageenan -- 3.3.5 Agar -- 3.3.6 Porphyran -- 3.3.7 Fucoidan -- 3.3.8 Ulvan -- 3.3.9 Exopolysaccharides From Microalgae -- 3.4 Applications of Polysaccharides -- 3.4.1 Biomedical Applications -- 3.4.1.1 Cellulose -- 3.4.1.2 Chitosan. , 3.4.1.3 Alginate -- 3.4.2 Food Applications -- 3.4.2.1 Cellulose -- 3.4.2.2 Chitosan -- 3.4.2.3 Alginates -- 3.4.2.4 Carrageenan -- 3.4.2.5 Agar -- 3.4.3 Pharmaceutical and Nutraceutical Applications -- 3.4.3.1 Cellulose -- 3.4.3.2 Chitosan -- 3.4.3.3 Alginate -- 3.4.3.4 Carrageenan -- 3.4.3.5 Porphyran -- 3.4.3.6 Fucoidan -- 3.4.4 Agriculture -- 3.5 Conclusions -- References -- 4 Seaweed Polysaccharides: Structure, Extraction and Applications -- 4.1 Introduction -- 4.1.1 Agar -- 4.1.2 Carrageenan -- 4.1.3 Alginate (Alginic Acid, Algin) -- 4.1.4 Fucoidan -- 4.1.5 Laminaran -- 4.1.6 Ulvan -- 4.2 Conclusion -- References -- 5 Agars: Properties and Applications -- 5.1 History and Origin of Agar -- 5.1.1 Agarophytes Used in Agar Manufacturing -- 5.2 Physical Properties of Agar Producing Seaweeds -- 5.3 Agar Manufacturing -- 5.3.1 Types of Agar Manufacturing -- 5.3.1.1 Freeze-Thaw Method -- 5.3.1.2 Syneresis Method -- 5.4 Structure of Agar -- 5.5 Heterogeneity of Agar -- 5.6 Physico-Chemical Characteristics of Agar -- 5.7 Chemical Characteristics of Agar -- 5.8 Factors Influencing the Characteristics of Agar -- 5.8.1 Techniques to Analyze the Fine Chemical Structure of Agar -- 5.8.2 Synergies and Antagonisms of Agar Gels -- 5.9 Uses of Agar in Various Sectors -- 5.9.1 Applications of Agar in Food Industry -- 5.9.2 Application of Agar in Harvesting Insects and Worms -- 5.9.3 Vegetable Tissue Culture Formulations -- 5.9.4 Culture Media for Microbes -- 5.9.5 Industrial Applications of Agar -- 5.10 Conclusion and Discussion -- References -- 6 Biopolysaccharides: Properties and Applications -- 6.1 Structure and Classification of Biopolysaccharides -- 6.1.1 Structure -- 6.1.2 Classification -- 6.1.3 Structural Characterization Techniques -- 6.2 Uses and Applications of Biopolysaccharides -- 6.2.1 Functional Fibers -- 6.2.2 Biomedicine. , 6.2.2.1 Tissue Engineering -- 6.2.2.2 Wound Healing -- 6.2.2.3 Drug Loading and Delivery -- 6.2.2.4 Therapeutics -- 6.2.3 Cosmetics -- 6.2.4 Foods and Food Ingredients -- 6.2.5 Biofuels -- 6.2.6 Wastewater Treatment -- 6.2.7 Textiles -- 6.3 Conclusion -- References -- 7 Chitosan Derivatives: Properties and Applications -- 7.1 Introduction -- 7.2 Properties of Chitosan Derivatives -- 7.2.1 Physiochemical Properties -- 7.2.2 Functional Properties -- 7.2.3 Biological Properties of Chitosan -- 7.3 Applications of Chitosan Derivatives -- 7.3.1 Anticancer Agents -- 7.3.2 Bone Tissue Material Formation -- 7.3.3 Wound Healing, Tissue Regeneration and Antimicrobial Resistance -- 7.3.4 Drug Delivery -- 7.3.5 Chromatographic Separations -- 7.3.6 Waste Management -- 7.3.7 Food Industry -- 7.3.8 In Cosmetics -- 7.3.9 In Paint as Antifouling Coatings -- 7.4 Conclusions -- Acknowledgement -- References -- 8 Green Seaweed Polysaccharides Inventory of Nador Lagoon in North East Morocco -- 8.1 Introduction -- 8.2 Nador Lagoon: Situation and Characteristics -- 8.3 Seaweed -- 8.4 Polysaccharides in Seaweed -- 8.5 Algae Polysaccharides in Nador Lagoon's Seaweed -- 8.5.1 C. prolifera -- 8.5.1.1 Sulfated Galactans -- 8.5.2 U. rigida & -- E. intestinalis -- 8.5.2.1 Ulvan -- 8.5.3 C. adhaerens, C. bursa, C. tomentosum -- 8.5.3.1 Sulfated Arabinans -- 8.5.3.2 Sulfated Arabinogalactans -- 8.5.3.3 Mannans -- 8.6 Conclusion -- References -- 9 Salep Glucomannan: Properties and Applications -- 9.1 Introduction -- 9.2 Production -- 9.3 Composition and Physicochemical Structure -- 9.4 Rheological Properties -- 9.5 Purification and Deacetylation -- 9.6 Food Applications -- 9.6.1 Beverage -- 9.6.2 Ice Cream and Emulsion Stabilizing -- 9.6.3 Edible Film/Coating -- 9.6.4 Gelation -- 9.7 Health Benefits -- 9.8 Conclusions and Future Trends -- References. , 10 Exudate Tree Gums: Properties and Applications -- 10.1 Introduction -- 10.1.1 Gum Arabic -- 10.1.2 Gum Karaya -- 10.1.3 Gum Kondagogu -- 10.1.4 Gum Ghatti -- 10.1.5 Gum Tragacanth -- 10.1.6 Gum Olibanum -- 10.2 Nanobiotechnology Applications -- 10.3 Minor Tree Gums -- 10.4 Conclusions -- Acknowledgment -- References -- 11 Cellulose and its Derivatives: Properties and Applications -- 11.1 Introduction -- 11.2 Main Raw Materials -- 11.3 Composition and Chemical Structure of Lignocellulosic Materials -- 11.4 Cellulose: Chemical Backbone and Crystalline Formats -- 11.5 Cellulose Extraction -- 11.5.1 Mechanical Methods -- 11.5.2 Chemical Methods -- 11.6 Cellulose Products and its Derivatives -- 11.7 Main Applications -- 11.8 Conclusion -- References -- 12 Starch and its Derivatives: Properties and Applications -- 12.1 Introduction -- 12.2 Physicochemical and Functional Properties of Starch -- 12.2.1 Size, Morphology and Crystallinity of Starch Granules -- 12.2.2 Physical Properties due to Associated Lipids, Proteins and Phosphorus With Starch Granules -- 12.2.3 Solubility and Swelling Capacity of Starch -- 12.2.4 Gelatinization and Retrogradation of Starch -- 12.2.5 Birefringence and Glass Transition Temperature of Starch -- 12.2.6 Rheological and Thermal Properties of Starch -- 12.2.7 Transmittance and Opacity of Starch -- 12.2.8 Melt Processability of Starch -- 12.3 Modification of Starch -- 12.3.1 Physical Modification of Starch -- 12.3.2 Chemical Modification of Starch -- 12.3.3 Dual Modification of Starch -- 12.3.4 Enzymatic Modification of Starch -- 12.3.5 Genetic Modification of Starch -- 12.4 Application of Starch and its Derivatives -- 12.4.1 In Food Industry -- 12.4.2 In Paper Industry -- 12.4.3 Starch as Binders -- 12.4.4 In Detergent Products -- 12.4.5 As Biodegradable Thermoplastic Materials or Bioplastics. , 12.4.6 In Pharmaceutical and Cosmetic Industries -- 12.4.7 As Industrial Raw Materials -- 12.4.8 As Adsorbents for Environmental Applications -- 12.4.9 As Food Packaging Materials -- 12.4.10 In Drug Delivery -- 12.4.11 As Antimicrobial Films and Coatings -- 12.4.12 In Advanced Functional Materials -- 12.5 Conclusion -- References -- 13 Crystallization of Polysaccharides -- 13.1 Introduction -- 13.2 Principles of Crystallization of Polysaccharides -- 13.3 Techniques for Crystallinity Measurement -- 13.4 Crystallization Behavior of Polysaccharides -- 13.4.1 Cellulose -- 13.4.2 Chitosan and Chitin -- 13.4.3 Starch -- 13.5 Polymer/Polysaccharide Crystalline Nanocomposites -- 13.6 Conclusion -- References -- 14 Polysaccharides as Novel Materials for Tissue Engineering Applications -- 14.1 Introduction -- 14.2 Types of Scaffolds for Tissue Engineering -- 14.3 Biomaterials for Tissue Engineering -- 14.4 Polysaccharide-Based Scaffolds for Tissue Engineering -- 14.4.1 Alginate-Based Scaffolds -- 14.4.2 Chitosan-Based Scaffolds -- 14.4.3 Cellulose-Based Scaffolds -- 14.4.4 Dextran and Pullulan-Based Scaffolds -- 14.4.5 Starch-Based Scaffolds -- 14.4.6 Xanthan-Based Scaffolds -- 14.4.7 Glycosaminoglycans-Based Scaffolds -- 14.5 Current Challenges and Future Perspectives -- Acknowledgements -- References -- 15 Structure and Solubility of Polysaccharides -- 15.1 Introduction -- 15.2 Polysaccharide Structure and Solubility in Water -- 15.3 Solubility and Molecular Weight -- 15.4 Solubility and Branching -- 15.5 Polysaccharide Solutions -- 15.6 Conclusions -- Acknowledgments -- References -- 16 Polysaccharides: An Efficient Tool for Fabrication of Carbon Nanomaterials -- 16.1 Introduction -- 16.2 Aerogels -- 16.2.1 Plant and Bacterial Cellulose -- 16.2.2 Carbon Derived From Nanocrystalline Cellulose of Plant Origin. , 16.2.3 Carbon Aerogels Produced From Bacterial Cellulose.

Anmerkung: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 Application of MOFs and Their Derived Materials in Sensors -- 1.1 Introduction -- 1.2 Application of MOFs and Their Derived Materials in Sensors -- 1.2.1 Optical Sensor -- 1.2.1.1 Colorimetric Sensor -- 1.2.1.2 Fluorescence Sensor -- 1.2.1.3 Chemiluminescent Sensor -- 1.2.2 Electrochemical Sensor -- 1.2.2.1 Amperometric Sensor -- 1.2.2.2 Impedimetric, Electrochemiluminescence, and Photoelectrochemical Sensor -- 1.2.3 Field-Effect Transistor Sensor -- 1.2.4 Mass-Sensitive Sensor -- 1.3 Conclusion -- Acknowledgments -- References -- Chapter 2 Applications of Metal-Organic Frameworks (MOFs) and Their Derivatives in Piezo/Ferroelectrics -- 2.1 Introduction -- 2.1.1 Brief Introduction to Piezo/Ferroelectricity -- 2.2 Fundamentals of Piezo/Ferroelectricity -- 2.3 Metal-Organic Frameworks for Piezo/ Ferroelectricity -- 2.4 Ferro/Piezoelectric Behavior of Various MOFs -- 2.5 Conclusion -- References -- Chapter 3 Fabrication and Functionalization Strategies of MOFs and Their Derived Materials "MOF Architecture" -- 3.1 Introduction -- 3.2 Fabrication and Functionalization of MOFs -- 3.2.1 Metal Nodes -- 3.2.2 Organic Linkers -- 3.2.3 Secondary Building Units -- 3.2.4 Synthesis Methods -- 3.2.4.1 Hydrothermal and Solvothermal Method -- 3.2.4.2 Microwave Synthesis -- 3.2.4.3 Electrochemical Method -- 3.2.4.4 Mechanochemical Synthesis -- 3.2.4.5 Sonochemical (Ultrasonic Assisted) Method -- 3.2.4.6 Diffusion Method -- 3.2.4.7 Template Method -- 3.2.5 Synthesis Strategies -- 3.3 MOF Derived Materials -- 3.4 Conclusion -- References -- Chapter 4 Application of MOFs and Their Derived Materials in Molecular Transport -- 4.1 Introduction -- 4.2 MOFs as Nanocarriers for Membrane Transport -- 4.2.1 MIL-89 -- 4.2.2 MIL-88A -- 4.2.3 MIL-100 -- 4.2.4 MIL-101 -- 4.2.5 MIL-53 -- 4.2.6 ZIF-8. , 4.2.7 Zn-TATAT -- 4.2.8 BioMOF-1 (Zn) -- 4.2.9 UiO (Zr) -- 4.3 Conclusion -- References -- Chapter 5 Role of MOFs as Electro/-Organic Catalysts -- 5.1 What Is MOFs -- 5.2 MOFs as Electrocatalyst in Sensing Applications -- 5.3 MOFs as Organic Catalysts in Organic Transformations -- 5.4 Conclusion and Future Prospects -- References -- Chapter 6 Application of MOFs and Their Derived Materials in Batteries -- 6.1 Introduction -- 6.2 Metal-Organic Frameworks -- 6.2.1 Classification and Properties of Metal-Organic Frameworks -- 6.2.2 Potential Applications of MOFs -- 6.2.3 Synthesis of MOFs -- 6.3 Polymer Electrolytes -- 6.3.1 Historical Perspectives and Classification of Polymer Electrolytes -- 6.3.2 MOF Based Polymer Electrolytes -- 6.4 Ionic Liquids -- 6.4.1 Properties of Ionic Liquids -- 6.4.2 Ionic Liquid Incorporated MOF -- 6.5 Ion Transport in Polymer Electrolytes -- 6.5.1 General Description of Ionic Conductivity -- 6.5.2 Models for Ionic Transport in Polymer Electrolytes -- 6.5.3 Impedance Spectroscopy and Ionic Conductivity Measurements -- 6.5.4 Concept of Mismatch and Relaxation -- 6.5.5 Scaling of ac Conductivity -- 6.6 IL Incorporated MOF Based Composite Polymer Electrolytes -- 6.7 Conclusion and Perspectives -- References -- Chapter 7 Fine Chemical Synthesis Using Metal-Organic Frameworks as Catalysts -- 7.1 Introduction -- 7.2 Oxidation Reaction -- 7.2.1 Epoxidation -- 7.2.2 Sulfoxidation -- 7.2.3 Aerobic Oxidation of Alcohols -- 7.3 1,3-Dipolar Cycloaddition Reaction -- 7.4 Transesterification Reaction -- 7.5 C-C Bond Formation Reactions -- 7.5.1 Heck Reactions -- 7.5.2 Sonogashira Coupling -- 7.5.3 Suzuki Coupling -- 7.6 Conclusion -- References -- Chapter 8 Application of Metal Organic Framework and Derived Material in Hydrogenation Catalysis -- 8.1 Introduction -- 8.1.1 The Active Centers in Parent MOF Materials. , 8.1.2 The Active Centers in MOF Catalyst -- 8.1.3 Metal Nodes -- 8.2 Hydrogenation Reactions -- 8.2.1 Hydrogenation of Alpha-Beta Unsaturated Aldehyde -- 8.2.2 Hydrogenation of Cinnamaldehyde -- 8.2.3 Hydrogenation of Nitroarene -- 8.2.4 Hydrogenation of Nitro Compounds -- 8.2.5 Hydrogenation of Benzene -- 8.2.6 Hydrogenation of Quinoline -- 8.2.7 Hydrogenation of Carbon Dioxide -- 8.2.8 Hydrogenation of Aromatics -- 8.2.9 Hydrogenation of Levulinic Acid -- 8.2.10 Hydrogenation of Alkenes and Alkynes -- 8.2.11 Hydrogenation of Phenol -- 8.3 Conclusion -- References -- Chapter 9 Application of MOFs and Their Derived Materials in Solid-Phase Extraction -- 9.1 Solid-Phase Extraction -- 9.1.1 Materials in SPE -- 9.2 MOFs and COFs in Miniaturized Solid-Phase Extraction (µSPE) -- 9.3 MOFs and COFs in Miniaturized Dispersive Solid-Phase Extraction (D-µSPE) -- 9.4 MOFs and COFs in Magnetic-Assisted Miniaturized Dispersive Solid-Phase Extraction (m-D-µSPE) -- 9.5 Concluding Remarks -- Acknowledgments -- References -- Chapter 10 Anticancer and Antimicrobial MOFs and Their Derived Materials -- 10.1 Introduction -- 10.2 Anticancer MOFs -- 10.2.1 MOFs as Drug Carriers -- 10.2.2 MOFs in Phototherapy -- 10.3 Antibacterial MOFs -- 10.4 Antifungal MOFs -- References -- Chapter 11 Theoretical Investigation of Metal-Organic Frameworks and Their Derived Materials for the Adsorption of Pharmaceutical and Pe -- 11.1 Introduction -- 11.2 General Synthesis Routes -- 11.2.1 Hydrothermal Synthesis -- 11.2.2 Solvothermal Synthesis of MOFs -- 11.2.3 Room Temperature Synthesis -- 11.2.4 Microwave Assisted Synthesis -- 11.2.5 Mechanochemical Synthesis -- 11.2.6 Electrochemical Synthesis -- 11.3 Postsynthetic Modification in MOF -- 11.4 Computational Method -- 11.5 Results and Discussion. , 11.5.1 Binding Behavior Between MIL-100 With the Adsorbates (Diclofenac, Ibuprofen, Naproxen, and Oxybenzone) -- 11.6 Conclusion -- References -- Chapter 12 Metal-Organic Frameworks and Their Hybrid Composites for Adsorption of Volatile Organic Compounds -- 12.1 Introduction -- 12.2 VOCs and Their Potential Hazards -- 12.2.1 Other Sources of VOCs -- 12.3 VOCs Removal Techniques -- 12.4 Fabricated MOF for VOC Removal -- 12.4.1 MIL Series MOFs -- 12.4.2 Isoreticular MOFs -- 12.4.2.1 Adsorption Comparison of the Isoreticular MOFs -- 12.4.3 NENU Series MOFs -- 12.4.4 MOF-5, Eu-MOF, and MOF-199 -- 12.4.5 Amine-Impregnated MIL-100 -- 12.4.6 Biodegradable MOFs MIL-88 Series -- 12.4.7 Catalytic MOFs -- 12.4.8 Photo-Degradating MOFs -- 12.4.9 Some Other Studied MOFs -- 12.5 MOF Composites -- 12.5.1 MIL-101 Composite With Graphene Oxide -- 12.5.2 MIL-101 Composite With Graphite Oxide -- 12.6 Generalization Adsorptive Removal of VOCs by MOFs -- 12.7 Simple Modeling the Adsorption -- 12.7.1 Thermodynamic Parameters -- 12.7.2 Dynamic Sorption Methods -- 12.8 Factor Affecting VOCs Adsorption -- 12.8.1 Breathing Phenomena -- 12.8.2 Activation of MOFs -- 12.8.3 Applied Pressure -- 12.8.4 Relative Humidity -- 12.8.5 Breakthrough Conditions -- 12.8.6 Functional Group of MOFs -- 12.8.7 Concentration, Molecular Size, and Type of VOCs -- 12.9 Future Perspective -- References -- Chapter 13 Application of Metal-Organic Framework and Their Derived Materials in Electrocatalysis -- List of Abbreviations -- 13.1 Introduction -- 13.2 Perspective Synthesis of MOF and Their Derived Materials -- 13.3 MOF for Hydrogen Evolution Reaction -- 13.4 MOF for Oxygen Evolution Reaction -- 13.5 MOF for Oxygen Reduction Reaction -- 13.6 MOF for CO2 Electrochemical Reduction Reaction -- 13.6.1 Electrosynthesis of MOF for CO2 Reduction -- 13.6.2 Composite Electrodes as MOF for CO2 Reduction. , 13.6.3 Continuous Flow Reduction of CO2 -- 13.6.4 CO2 Electrochemical Reduction in Ionic Liquid -- 13.7 MOF for Electrocatalytic Sensing -- 13.8 Electrocatalytic Features of MOF -- 13.9 Conclusion -- Acknowledgment -- References -- Chapter 14 Applications of MOFs and Their Composite Materials in LightDriven Redox Reactions -- 14.1 Introduction -- 14.1.1 MOFs as Photocatalysts -- 14.1.2 Charge Transfer Mechanisms -- 14.1.3 Methods of Synthesis -- 14.2 Pristine MOFs and Their Application in Photocatalysis -- 14.2.1 Group 4 Metallic Clusters -- 14.2.2 Groups 8, 9, and 10 Metallic Clusters -- 14.2.3 Group 11 Metallic Clusters -- 14.2.4 Group 12 Metallic Clusters -- 14.3 Metal Nanoparticles-MOF Composites and Their Application in Photocatalysis -- 14.3.1 Ag-MOF Composites -- 14.3.2 Au-MOF Composites -- 14.3.3 Cu-MOF Composites -- 14.3.4 Pd-MOF Composites -- 14.3.5 Pt-MOF Composites -- 14.4 Semiconductor-MOF Composites and Their Application in Photocatalysis -- 14.4.1 TiO2-MOF Composites -- 14.4.2 Graphitic Carbon Nitride-MOF Composites -- 14.4.3 Bismuth-Based Semiconductors -- 14.4.4 Reduced Graphene Oxide-MOF Composites -- 14.4.5 Silver-Based Semiconductors -- 14.4.6 Other Semiconductors -- 14.5 MOF-Based Multicomponent Composites and Their Application in Photocatalysis -- 14.5.1 Semiconductor-Semiconductor-MOF Composites -- 14.5.2 Semiconductor-Metal-MOF Composites -- 14.6 Conclusions -- References -- Index -- Also of Interest -- Check out these other forthcoming and published titles from Scrivener Publishing -- EULA.

Anmerkung: Intro -- Green Sustainable Process for Chemical and Environmental Engineering and Science: Green Inorganic Synthesis -- Copyright -- Contents -- Contributors -- Chapter 1: Microwave-assisted green synthesis of inorganic nanomaterials -- Description -- Key features -- 1. Introduction -- 2. Technical aspects of microwave technique -- 2.1. Principles and heating mechanism of microwave method -- 2.2. Green solvents for microwave reactions -- 2.3. Microwave versus conventional synthesis -- 2.4. Microwave instrumentation -- 2.5. Advantages and limitations -- 3. MW-assisted green synthesis of inorganic nanomaterials -- 3.1. Metallic nanostructured materials -- 3.2. Metal oxides nanostructured materials -- 3.3. Metal chalcogenides nanostructured materials -- 3.4. Quantum dot nanostructured materials -- 4. Conclusions and future aspects -- 4.1. Challenges and scope to further study -- References -- Chapter 2: Green synthesis of inorganic nanoparticles using microemulsion methods -- Description -- Key features -- 1. Introduction -- 2. Fundamental aspects of microemulsion synthesis -- 2.1. Microemulsion and types -- 2.2. Micelles, types, and formation mechanism -- 2.3. Hydrophilic-lipophilic balance number -- 2.4. Surfactants and types -- 2.5. Advantages and limitations of microemulsion synthesis of nanomaterials -- 3. Microemulsion-assisted green synthesis of inorganic nanostructured materials -- 3.1. General mechanism microemulsion method for nanomaterial synthesis -- 3.2. Preparation of metallic and bimetallic nanoparticles -- 3.3. Metal oxide synthesis by microemulsion -- 3.4. Synthesis of metal chalcogenide nanostructured materials -- 3.5. Synthesis of inorganic quantum dots -- 4. Conclusions, challenges, and scope to further study -- References -- Chapter 3: Synthesis of inorganic nanomaterials using microorganisms -- 1. Introduction. , 2. Green approach for synthesis of nanoparticles -- 3. General mechanisms of biosynthesis -- 4. Optimization of nanoparticles biosynthesis -- 4.1. Effect of the temperature -- 4.2. Effect of pH -- 4.3. Effect of metal precursor concentration -- 4.4. Effect of culture medium composition -- 4.5. Effect of biomass quantity and age -- 4.6. Synthesis time -- 5. Biosynthesis of metal oxide nanoparticles -- 5.1. Bacteria-mediated synthesis -- 5.2. Fungi-mediated synthesis -- 5.3. Yeast-mediated synthesis -- 5.4. Algae- and viruses-mediated synthesis -- 6. Biosynthesis of metal chalcogenide nanoparticles -- 7. Final considerations -- References -- Chapter 4: Challenge and perspectives for inorganic green synthesis pathways -- 1. Introduction -- 2. Synthesis methods -- 2.1. Physical synthesis -- 2.1.1. Advantages -- 2.1.2. Inconvenient -- 2.2. Chemical synthesis -- 2.2.1. Advantages -- 2.2.2. Inconvenient -- 2.3. Green synthesis of inorganic nanomaterials and application -- 3. Challenge and perspectives -- 4. Conclusion -- References -- Chapter 5: Synthesis of inorganic nanomaterials using carbohydrates -- 1. Introduction -- 1.1. Types of nanomaterials -- 1.2. Approaches for the synthesis of inorganic nanomaterials -- 1.3. Characterization of inorganic nanomaterials -- 1.4. What are carbohydrates? -- 1.4.1. Types of carbohydrates -- Monosaccharides -- Oligosaccharides -- Polysaccharides -- 2. Synthesis of inorganic nanomaterials using carbohydrates -- 2.1. Synthesis of metal nanomaterials using carbohydrates -- 2.2. Synthesis of metal oxide-based nanomaterials using carbohydrates -- 2.3. Synthesis of nanomaterials using polysaccharides extracted from fungi and plant -- 3. The advantages and disadvantages of inorganic nanomaterials -- 4. Conclusion and future scope -- References -- Chapter 6: Fundamentals for material and nanomaterial synthesis. , 1. Introduction -- 2. Fundamental synthesis for materials -- 2.1. Solid-state synthesis -- 2.2. Chemical vapor transport -- 2.3. Sol-gel process -- 2.4. Melt growth (MG) method -- 2.5. Chemical vapor deposition -- 2.6. Laser ablation methods -- 2.7. Sputtering method -- 2.8. Molecular beam epitaxy method -- 3. Fundamental synthesis for nanomaterials -- 3.1. Top-down and bottom-up approaches -- 3.1.1. Ball milling (BL) synthesis process -- 3.1.2. Electron beam lithography -- 3.1.3. Inert gas condensation synthesis method -- 3.1.4. Physical vapor deposition methods -- 3.1.5. Laser pyrolysis methods -- 3.2. Chemical synthesis methods -- 3.2.1. Sol-gel method -- 3.2.2. Chemical vapor deposition method -- 3.2.3. Hydrothermal synthesis -- 3.2.4. Polyol process -- 3.2.5. Microemulsion technique -- 3.2.6. Microwave-assisted (MA) synthesis -- 3.3. Bio-assisted (B-A) methods -- 4. Conclusion -- References -- Chapter 7: Bioinspired synthesis of inorganic nanomaterials -- 1. Introduction -- 1.1. Nanomaterials and current limitations -- 1.2. Bioinspired synthesis -- 2. General mechanism of interaction -- 3. Bioinspired synthesis of inorganic nanomaterials -- 3.1. Microorganisms-mediated synthesis -- 3.2. Plant-mediated synthesis -- 3.2.1. Root extract assisted synthesis -- 3.2.2. Leaves extract assisted synthesis -- 3.2.3. Shoot-mediated synthesis -- 3.3. Protein templated synthesis -- 3.4. DNA-templated synthesis -- 3.5. Butterfly wing scales-templated synthesis -- 4. Applications of bioinspired nanomaterials -- 5. Conclusions -- References -- Chapter 8: Polysaccharides for inorganic nanomaterials synthesis -- 1. Introduction -- 2. Polysaccharides -- 2.1. Types of polysaccharides -- 2.1.1. Cellulose -- 2.1.2. Starch -- 2.1.3. Chitin -- 2.1.4. Chitosan -- 2.1.5. Properties of polysaccharides for bioapplications -- 3. Nanomaterials -- 3.1. Types of nanomaterials. , 3.1.1. Organic nanomaterials -- Carbon nanotubes -- Graphene -- Fullerenes -- 3.1.2. Inorganic nanomaterials -- Magnetic nanoparticles -- Metal nanoparticles -- Metal oxide nanoparticles -- Luminescent inorganic nanoparticles -- 3.2. Health effects of nanomaterials -- 4. Polysaccharide-based nanomaterials -- 4.1. Cellulose nanomaterials -- 4.1.1. Preparation of cellulose nanomaterials -- 4.1.2. Structure of cellulose nanomaterials -- 4.2. Chitin nanomaterials -- 4.2.1. Preparation of chitin nanomaterials -- 4.2.2. Structure and properties of chitin nanomaterials -- 4.3. Starch nanomaterials -- 4.3.1. Preparation of starch nanomaterials -- 4.3.2. Structure and properties of starch nanomaterials -- 5. Preparation of polysaccharide-based inorganic nanomaterials -- 5.1. Bulk nanocomposites -- 5.2. Composite nanoparticles -- 6. Applications of polysaccharide-based inorganic nanomaterials -- 6.1. Biotechnological applications -- 6.1.1. Bioseparation -- 6.1.2. Biolabeling and biosensing -- 6.1.3. Antimicrobial applications -- 6.2. Biomedical applications -- 6.2.1. Drug delivery -- 6.2.2. Digital imaging -- 6.2.3. Cancer treatment -- 6.3. Agricultural applications -- 7. Characterization of polysaccharide-based nanomaterials -- 7.1. Spectroscopy -- 7.1.1. Infrared (IR) spectroscopy -- 7.1.2. Surface-enhanced Raman scattering (SERS) -- 7.1.3. UV-visible absorbance spectroscopy -- 7.2. Microscopy -- 7.2.1. Scanning electron microscopy (SEM) -- 7.2.2. Transmission electron microscopy (TEM) -- 7.3. X-ray methods -- 7.4. Thermal analysis -- 8. Future prospects -- 9. Concluding remarks -- References -- Chapter 9: Supercritical fluids for inorganic nanomaterials synthesis -- 1. Introduction -- 2. The supercritical fluid as a substitute technology -- 2.1. What is supercritical fluid? -- 2.2. Supercritical antisolvent precipitation. , 2.3. Supercritical-assisted atomization -- 2.4. Sol-gel drying method -- 3. Synthesis in supercritical fluids -- 3.1. Route of supercritical fluids containing nanomaterials synthesis -- 3.2. Sole supercritical fluid -- 3.3. Mixed supercritical fluid -- 4. Theory of the synthesis of supercritical fluids containing nanomaterials -- 4.1. Supercritical fluids working process -- 4.2. Origin of nanoparticles -- 4.3. The rapid expansion of supercritical solutions -- 5. Conclusion -- References -- Chapter 10: Green synthesized zinc oxide nanomaterials and its therapeutic applications -- 1. Introduction -- 2. Green synthesis -- 3. ZnO NPs characterization -- 4. ZnO NPs synthesis by plant extracts -- 5. ZnO NPs synthesis by bacteria and actinomycetes -- 6. ZnO NPs synthesis by algae -- 7. ZnO NPs synthesis by fungi -- 8. NPs synthesis by virus -- 9. ZnO NPs synthesis with alternative green sources -- 10. Therapeutic applications -- 11. Conclusions -- References -- Chapter 11: Sonochemical synthesis of inorganic nanomaterials -- 1. Background -- 2. Inorganic nanomaterials in sonochemical synthesis -- 3. Applications -- 4. Final comments -- References -- Index.

Anmerkung: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 Progress in Separators for Rechargeable Batteries -- 1.1 Separator Overview -- 1.2 Polymer Membrane -- 1.2.1 Polyolefin Separators -- 1.2.2 PVDF -- 1.2.3 PTFE -- 1.2.4 PU -- 1.2.5 PVA -- 1.2.6 Cellulose -- 1.2.7 Other Polymer -- 1.3 Non-Woven Fabric Separator -- 1.3.1 PET -- 1.3.2 PAN -- 1.3.3 PVDF -- 1.3.4 PTFE -- 1.3.5 PVA -- 1.3.6 PI -- 1.4 Polymer Electrolyte -- 1.5 Conclusions -- References -- Chapter 2 Pb Acid Batteries -- 2.1 History of Batteries -- 2.2 Primary Batteries -- 2.3 Secondary Batteries -- 2.4 Flow Batteries -- 2.4.1 All Vanadium Redox Flow Batteries (VRBs) -- 2.4.2 Zinc-Bromine Flow Cells -- 2.5 Lead-Acid Batteries -- 2.5.1 Early Applications of Lead-Acid Batteries -- 2.5.2 Comparison With Other Types of Secondary Batteries -- 2.5.3 Electrochemistry of Lead-Acid Batteries -- 2.5.4 Basic Components of Lead-Acid Cells -- 2.5.5 Types of Lead-Acid Batteries -- 2.5.6 Charging -- 2.5.7 Maintenance -- 2.5.8 Failure Modes -- List of Abbreviations -- References -- Chapter 3 Flexible Batteries -- 3.1 Introduction -- 3.2 Battery Types -- 3.2.1 Lead-Acid Battery -- 3.2.2 Nickel Cadmium -- 3.2.3 Nickel/Hydrogen and Nickle/Metal Hydride -- 3.2.4 Lithium-Ion Batteries -- 3.3 Storage Mechanism -- 3.3.1 Flexible Electrode -- 3.3.2 Carbon Base Flexible Electrodes -- 3.4 Graphene Base Flexible Batteries -- 3.5 Metal Oxide-Based Flexible Batteries -- 3.6 Fiber-Shape Designed Flexible Batteries -- 3.7 Natural Fiber Base Flexible Batteries -- 3.8 Flexible Electrolytes -- 3.9 Conclusion -- References -- Chapter 4 Polymer Electrolytes in Rechargeable Batteries -- 4.1 Introduction -- 4.2 Solid Electrolytes for Rechargeable Batteries -- 4.2.1 Solid Oxide Electrolytes -- 4.2.2 Sulfide Solid Electrolytes -- 4.2.3 Inorganic-Organic Hybrid Electrolytes. , 4.2.4 Solid Polymer Electrolytes in Rechargeable Batteries -- 4.3 Polymer-Based Electrolytes -- 4.4 Classification of Polymer-Based Electrolytes -- 4.4.1 Polymer-Salt Complexes -- 4.4.2 Plasticized Polymer Electrolytes -- 4.4.3 Rubbery Electrolytes -- 4.4.4 Solvent-Swollen Polymers -- 4.4.5 Polyelectrolytes -- 4.4.6 Gel Polymer Electrolytes -- 4.4.7 Composite Polymer Electrolytes (CPEs) -- 4.4.8 Ionic Liquid Incorporated Polymer/Gel Electrolytes -- 4.5 Conclusion and Future Prospects -- References -- Chapter 5 Advancement in Electrolytes for Rechargeable Batteries -- 5.1 Introduction -- 5.2 Aqueous Electrolytes -- 5.2.1 Lithium Nitrate -- 5.2.2 Saturated LiCl Electrolyte -- 5.2.3 Aqueous Sodium Salts -- 5.3 Non-Aqueous Electrolytes -- 5.4 Polymer Electrolytes -- 5.4.1 Solid Polymer Electrolytes (SPE) -- 5.4.2 Gel Polymer Electrolytes (GPE) -- 5.5 Ionic Liquids Electrolytes (ILE) -- 5.6 Hybrid Electrolytes -- 5.7 Conclusions -- Acknowledgements -- References -- Chapter 6 Fabrication Assembly Techniques for K-Ion Batteries -- 6.1 Introduction -- 6.2 Battery and Its Types -- 6.3 Ni-Cd Batteries -- 6.4 Li-Ion Batteries -- 6.5 Advantages of Rechargeable Batteries -- 6.6 Disadvantages of Rechargeable Batteries -- 6.7 K-Ion Batteries -- 6.8 Advantages -- 6.9 Disadvantages -- 6.10 Honeycomb Structure of K-Ion Batteries -- 6.10.1 Methods/Synthesis of Potassium Tellurates -- 6.11 Negative Electrode Materials for K-Ion Batteries -- 6.12 K-Ion Batteries Based on Patterned Electrodes -- 6.13 Conclusion -- Acknowledgement -- References -- Chapter 7 Recent Advances in Ni-Fe Batteries as Electrical Energy Storage Devices -- 7.1 Introduction -- 7.2 Structure of Ni-Fe Batteries -- 7.3 Discussion on Electrochemical Parameters of Various Materials for Ni-Fe Batteries -- 7.4 Conclusions -- References -- Chapter 8 Nickel-Metal Hydride (Ni-MH) Batteries -- 8.1 Introduction. , 8.2 History -- 8.3 Invention of the Rechargeable Battery -- 8.4 Metal Hydrides (MH) -- 8.5 Thermodynamics and Crystal Structures of Ni-MH Battery Materials -- 8.5.1 Thermodynamics -- 8.5.2 Crystal Structures of Battery Materials -- 8.5.3 Crystal Structure of AB -- 8.5.3 Crystal Structure of AB5 and AB2 Materials -- 8.5.4 Structure of AB5 Compounds -- 8.5.5 Structure of AB2 Compounds -- 8.5.6 Substitutions of A and B Components in AB5 and AB2 -- 8.5.7 Mg-Based Alloys -- 8.5.8 Rare Earth-Mg-Ni-Based Alloys -- 8.5.9 Ti-V-Based Alloys -- 8.6 Ni-MH Batteries -- 8.7 Mechanism of Ni-MH Batteries -- 8.7.1 Battery Description -- 8.7.2 Principle -- 8.7.3 Negative Electrode -- 8.7.4 Positive Electrode -- 8.7.5 Electrolyte -- 8.7.6 Separator -- 8.8 Materials -- 8.9 Charging Nickel-Based Batteries -- 8.9.1 Guidelines for Charging -- 8.10 Performance -- 8.11 Factors Affecting Life -- 8.11.1 Exposure to Elevated Temperatures -- 8.11.2 Reversal -- 8.11.3 Extended Storage under Load -- 8.11.4 Limiting Mechanisms -- 8.12 Advantages -- 8.13 Applications -- 8.13.1 Electric Vehicles -- 8.13.2 Fuel Cell (FC) EVs -- 8.13.3 Pure EVs -- 8.13.4 Hybrid EVs -- 8.13.5 Applications in Traditional Portable Electronic Devices -- 8.13.5.1 Mobile Phones -- 8.13.5.2 Digital Cameras -- 8.14 Recent Developments and Research Work -- 8.15 Shortcomings -- References -- Chapter 9 Ni-Cd Batteries -- 9.1 Introduction -- 9.2 History -- 9.3 Characteristics -- 9.4 Construction and Working -- 9.5 Types of NiCd Batteries -- 9.6 Memory Effect -- 9.7 Maintenance and Safety -- 9.8 Availability and Cost -- 9.9 Applications -- 9.9.1 Transportation in Hybrid and Electric Vehicles -- 9.9.2 Aircrafts -- 9.9.3 Electronic Flash Units -- 9.9.4 Cordless Applications -- 9.9.5 Motorized Equipment -- 9.9.6 Two Ways Radios -- 9.9.7 Medical Instrumentation -- 9.9.8 Toys -- 9.10 Advantages and Disadvantages. , 9.11 Recycling of NiCd Batteries -- 9.12 Comparison With Other Batteries -- 9.13 Conclusion -- Acknowledgement -- References -- Chapter 10 Ca-Ion Batteries -- 10.1 Introduction -- 10.2 Selection of Anodic and Cathodic Materials -- 10.2.1 Alloy Anodes -- 10.2.1.1 Choice of Cathodes for Calcium-Ion Batteries -- 10.2.1.2 Choice of Anodes for Calcium-Ion Batteries -- 10.3 Electrochemical Arrangement -- 10.4 Electrode Materials -- 10.5 Conclusions and Perspectives -- References -- Chapter 11 Analytical Investigations in Rechargeable Batteries -- 11.1 Introduction -- 11.2 Components of a Battery -- 11.3 Principle of Rechargeable Battery -- 11.4 Aging of Rechargeable Battery -- 11.5 Analysis Techniques Used for Rechargeable Batteries -- 11.5.1 X-Ray Based -- 11.5.2 Neutron Based -- 11.5.3 Optical Analysis Techniques -- 11.5.4 Electron Based -- 11.5.5 Vibrational Analysis Techniques -- 11.5.6 Magnetism Based -- 11.5.7 Gravimetric-Based Analysis Techniques -- 11.6 Conclusion -- References -- Chapter 12 Remediation of Spent Rechargeable Batteries -- 12.1 Introduction -- 12.2 A Brief History of Battery Origin -- 12.3 The Types of Batteries -- 12.3.1 Types of Primary Batteries -- 12.3.1.1 Types of Secondary Batteries -- 12.4 Recharge the Battery -- 12.5 Battery Life -- 12.6 A Lithium-Ion Battery (LIB) -- 12.6.1 Advantages of Li-Ion Batteries -- 12.6.2 Disadvantages of Li-Ion Batteries -- 12.7 Impact of Batteries on Health -- 12.7.1 Protection Against Battery Disadvantages [101] -- 12.8 Mercury (Hg) -- 12.9 Remediation of Spent Rechargeable Batteries -- 12.9.1 Future and Challenges: Nanotechnology in Batteries -- 12.10 Conclusions -- References -- Chapter 13 Classification, Modeling, and Requirements for Separators in Rechargeable Batteries -- Acronyms -- 13.1 Introduction and Area -- 13.2 Separators in Rechargeable Batteries. , 13.3 Classification of Separator in Rechargeable Batteries -- 13.3.1 Nonwoven Separators -- 13.3.2 Microporous Membrane Separators -- 13.3.3 Ion-Exchange Membrane Separators -- 13.3.4 Nanoporous Membrane Separators -- 13.4 Properties of Separator in Rechargeable Batteries -- 13.5 Requirements for Separator in Rechargeable Batteries -- 13.6 Modeling of Separator in Rechargeable Batteries -- 13.7 Results and Discussions -- 13.8 Future Approach -- 13.9 Conclusion -- References -- Chapter 14 Research and Development and Commercialization in Rechargeable Batteries -- 14.1 Introduction -- 14.1.1 Types of Rechargeable Batteries (RBs) and Challenges Faced Towards Practical Applications -- 14.1.1.1 Li-Ion Batteries (LIBs) -- 14.1.1.2 Na and K-Ion Batteries -- 14.1.1.3 Magnesium Rechargeable Batteries (MgRBs) -- 14.1.1.4 Aqueous RBs -- 14.1.1.5 Pb-Acid, Ni-Cd, and Ni-MH Batteries -- 14.1.1.6 Zinc-Ion RBs -- 14.1.1.7 Metal-Air Batteries -- 14.1.1.8 Flexible RBs -- 14.1.2 Nanotechnology Interventions in Rechargeable Batteries -- 14.2 Research and Development in Rechargeable Batteries -- 14.2.1 Zinc Rechargeable Batteries (ZnRBs) -- 14.2.2 Magnesium Rechargeable Batteries (MgRBs) -- 14.2.3 Aqueous RBs and Hybrid Aqueous RBs -- 14.2.4 Li-Based RBs -- 14.3 Commercialization Aspects of Rechargeable Batteries -- 14.4 Future Prospects of RBs -- 14.5 Conclusion -- References -- Chapter 15 Alkaline Batteries -- 15.1 Introduction -- 15.1.1 How Batteries Work -- 15.2 History -- 15.3 Advantages -- 15.4 Disadvantages -- 15.4.1 Internal Resistance -- 15.4.2 Leakage and Damages -- 15.5 Spent ARBs -- 15.6 Classification of ABs -- 15.6.1 Ni/Co Batteries -- 15.6.2 Ni/Ni ARBs -- 15.7 Application of ABs -- 15.8 Conclusion -- Acknowledgements -- References -- Chapter 16 Advances in "Green" Ion-Batteries Using Aqueous Electrolytes -- 16.1 Introduction. , 16.2 Monovalent Ion Aqueous Batteries.

Anmerkung: Intro -- front-matter -- Table of Contents -- Preface -- 1 -- Transition Metal-Based Electrocatalysts for Oxygen-Evolution Reaction beyond Ni, Co, Fe -- 1. Introduction -- 2. Towards transition metal alloys beyond Ni, Co and Fe applied for OER -- 3. Metal oxides for OER beyond Ni, Co, and Fe -- 3.1 Transition metal binary oxide-based electrocatalyst -- 3.2 Perovskites oxides electrocatalysts -- 4. Transition-metals carbides, nitrides, and phosphides applied for OER -- 4.1 Carbides -- 4.2 Nitrides -- 4.3 Phosphides -- Conclusions -- References -- 2 -- Fe-Based Electrocatalysts for Oxygen-Evolution Reaction -- 1. Introduction -- 2. Mechanism of oxygen evolution reaction -- 3. Fe-based catalysts for OER -- 3.1 Fe-based oxides catalysts -- 3.2 Fe-based (oxy)hydroxides catalysts -- 3.3 Fe-based lamellar layered double hydroxide catalysts -- 3.4 Other Fe-based composites -- Conclusions and Outlook -- References -- 3 -- Co-Based Electrocatalysts for Hydrogen-Evolution Reaction -- 1. Introduction -- 2. Various Co-based electrocatalysts -- 2.1 Co metal, alloy, and their composites -- 2.2 Co nitrides -- 2.3 Co phosphides -- 2.4 Co oxide -- 2.5 Cobalt (Co) sulfides -- 2.6 Cobal selenides -- 2.7 Binary nonmetal cobalt compounds -- Conclusions and outlook -- References -- 4 -- Metal Free Catalysts for Water Splitting -- 1. Introduction -- 1.1 Hydrogen evolution reaction (HER) -- 1.2 Oxygen evolution reaction (OER) -- 2. Factors affecting the efficiency of electrochemical water splitting -- 3. Electrochemical matrices used for determining talent of the catalyst -- 4. Electrocatalysts for overall water splitting -- 5. Carbon based metal free catalyst -- 5.1 Graphene based electrocatalysts for water splitting -- 5.2 Carbon nanotube based electrocatalysts for water splitting. , 5.3 Graphitic carbon nitride (g-C3N4) based electrocatalysts for overall water splitting -- 6. Future aspects and outlook -- Reference -- 5 -- Ni-Based Electrocatalyst for Full Water Splitting -- 1. Introduction -- 2. Water splitting -- 2.1 Brief history and basics of water splitting -- 2.2 Few parameters related to t oxygen evolution reaction, hydrogen evolution reaction and catalytic activity -- 2.3 Mechanism of electrochemical water splitting -- 2.3.1 Hydrogen evolution reaction (HER) -- 2.3.2 Oxygen evolution reaction (OER) -- 2.4 Recent advances on materials and performance of Ni based materials for overall water splitting -- 2.4.1 Ni- based oxides and hydroxides -- 2.4.2 Ni-based phosphides -- 2.4.3 Ni-based nitrides -- 2.4.4 Ni-based sulfides -- 2.4.4 Ni-based selenides -- Conclusions -- Acknowledgement -- References -- 6 -- Transition-Metal Chalcogenides for Oxygen-Evolution Reaction -- 1. Introduction -- 1.1 Mechanism of oxygen evolution reaction (OER) -- 1.2 Kinetic parameters used to find the suitable catalysts for OER -- 1.2.1 Overpotential -- 1.2.2. Exchange current density -- 1.2.3 Tafel equation and Tafel plot -- 1.2.4 Electrochemical active surface area (ECSA) -- 1.2.5 Faraday efficiency (FE) -- 1.3 Experimental methods used to study the OER behavior and stability of catalysts -- 2. Transition metal chalcogenides as replacement of state-of-art catalyst for OER -- 2.1 Transition metal sulphide for oxygen evolution reaction -- 2.2 Transition metal selenide for oxygen evolution reaction -- 2.3 Transition metal telluride for oxygen evolution reaction -- Conclusion and Future prospective -- References -- 7 -- Interface-Engineered Electrocatalysts for Water Splitting -- 1. The surface/interface mechanism in photoelectrochemical water splitting. , 2. Enhanced photoelectrochemical water splitting performance by interface-engineered electrocatalysts -- 2.1 Impurity doping -- 2.2 Surface plasmon resonance effect -- 2.3 Z-scheme system -- References -- 8 -- Application of Prussian Blue Analogues and Related Compounds for Water Splitting -- 1. Introduction -- 2. The coordination chemistry of Prussian blue analogues and other metal cyanides -- 3. Crystal structure of Prussian blue analogues and related coordination polymers -- 4. Photo-induced charge transfer in Prussian blue analogues and related solids -- 5. Electrochemical behavior of PBAs in aqueous solutions -- 6. The water splitting reaction using transition metal cyanides -- 6.1 Oxygen evolution reaction (OER) -- 6.2 Hydrogen evolution reaction (HER) -- 6.3 Use as co-catalyst in photoelectrochemical cells -- Concluding remarks -- Acknowledgments -- References -- 9 -- Ni-Based Electrocatalysts for Oxygen Evolution Reaction -- 1. Introduction -- 2. The mechanism involved in oxygen evolution reaction and judging parameters -- 3. Nickel based OER catalysts -- 3.1 Ni-hydroxide based OER catalysts -- 3.2 Ni-oxide based OER catalysts -- 3.3 Ni-sulphides and selenides for OER -- Conclusion -- Acknowledgements -- References -- back-matter -- Keyword Index -- About the Editors.

Anmerkung: Intro -- front-matter -- Table of Contents -- Preface -- 1 -- Transition Metal Chalcogenides for Photoelectrochemical Water Splitting -- 1. Introduction -- 2. Typical structures of transition metal chalcogenides -- 3. Binary chalcogenides applied to photoelectrochemical water splitting -- 4. Transition metal-based ternary and multinary chalcogenides for photoelectrochemical water splitting -- 4.1 P-type copper-based chalcogenides -- 4.2. Silver-based chalcogenides for water splitting -- Conclusions -- References -- 2 -- Selection of Materials and Cell Design for Photoelectrochemical Decomposition of Water -- 1. Introduction -- 2. Principle and theory of water decomposition -- 3. Challenges in designing of a photoelectrochemical cell -- 4. Design configurations of PEC -- 4.1 Type 1 photo anodes -- 4.2 Type II heterojunction photomaterials -- 4.3 Type III wired type PEC tandem cells -- 4.4 Type IV wireless type PEC -- 4.5 Type V PV−EC systems -- Conclusions -- References -- 3 -- Interfacial Layer/Overlayer Effects in Photoelectrochemical Water Splitting -- 1. Introduction -- 2. PEC cell photoelectrode: Required characteristics and recent trends -- 3. Interface layering/over-layering: An effective strategy -- 4. Interface layering/over-layering of metal oxide semiconductors -- 4.1 Interface layering with BiVO4 -- 4.2 Interface layering with CuO/Cu2O -- 4.3 Interface layering with hematite (α-Fe2O3) -- 4.4 Interface layering with WO3 -- 4.5 Interface layering with TiO2 -- 5. Interface layering with carbon materials -- 6. Interface layering with low-cost non-metallic semiconductors -- 7. Interface layering/integration with metal nanoparticles -- Conclusion and future directions -- Acknowledgements -- References -- 4 -- Narrow Bandgap Semiconductors for Photoelectrochemical Water Splitting -- 1. Introduction. , 2. Narrow band gap materials as a strategy to improve photoresponse of the material -- 2.1 Bismuth sulfide (Bi2S3) -- 2.2 CuO -- 2.3 Fe2O3 -- 2.4 BiOI -- Spray Pyrolysis -- BiOI/BiOBr -- BiOI/TiO2 -- Conclusion -- References -- 5 -- Ti-based Materials for Photoelectrochemical Water Splitting -- 1. Introduction -- 2. Basic principle of PEC water splitting -- 3. Material selection for PEC water splitting -- 4. TiO2 photocatalyst for PEC water splitting -- 5. Tuning the photocatalytic of TiO2 into the visible light region -- Conclusion -- Acknowledgements -- References -- 6 -- BiVO4 Photoanodes for Photoelectrochemical Water Splitting -- 1. Introduction -- 2. Crystal and electronic band structure of BiVO4 -- 3. The band gap of monoclinic BiVO4 -- 3.1 BiVO4 photoanode band alignment at a liquid interface -- 4. Influence of crystal facet -- 5. Carrier dynamics in BiVO4 -- 6. Intrinsic defects/Oxygen vacancies in BiVO4 -- 7. Polarons in BiVO4 -- 8. Doping BiVO4 -- 8.1 W doping into BiVO4 -- 8.2 Mo doping into BiVO4 -- 8.3 Other dopants in BiVO4 -- 8.4 Lanthanide ion doping into BiVO4 -- 8.5 Codoping in BiVO4 (multiple ion doping) -- 9. The side of illumination on BiVO4 photoanode -- 10. Photo-charged BiVO4 -- 11. Hole blocking layer for BiVO4 -- 12. Catalyst coatings on BiVO4 photoanode -- 13. Plasmon-induced resonant energy transfer -- Conclusions and future perspective -- References -- 7 -- Noble Materials for Photoelectrochemical Water Splitting -- 1. Introduction -- 2. Fundamental properties of noble metals for photocatalytic activity -- 2.1 Fundamentals of the Localized Surface Plasmon Resonance (LSPR) -- 2.2 Schottky junction -- 3. Photoelectrodes materials -- 3.1 Titania (TiO2) -- 3.2 Haematite (Fe2O3) -- 3.3 Zinc oxide (ZnO) -- 4. Fundamental role of noble materials in PEC water splitting -- 4.1 Platinum (Pt) -- 4.2 Gold (Au) -- 4.3 Silver (Ag). , 4.4 Palladium (Pd) -- 4.5 Copper (Cu) -- 5. Noble bimetallic nanocomposites for PEC water splitting -- 5.1 Au-Pt bimetallic nanocomposites -- 5.2 Au-Pd bimetallic nanocomposites -- 5.3 Au-Ag bimetallic nanocomposites -- 5.4 Ag-Cu bimetallic nanocomposites -- 6. A brief note on bimetallic non-noble NPs for photoelectrochemical (PEC) water splitting -- Conclusion -- References -- back-matter -- Keyword Index -- About the Editors.

Anmerkung: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 2D Metal-Organic Frameworks -- 1.1 Introduction -- 1.2 Synthesis Approaches -- 1.2.1 Selection of Synthetic Raw Materials -- 1.2.2 Solvent Volatility Method -- 1.2.3 Diffusion Method -- 1.2.3.1 Gas Phase Diffusion -- 1.2.3.2 Liquid Phase Diffusion -- 1.2.4 Sol-Gel Method -- 1.2.5 Hydrothermal/Solvothermal Synthesis Method -- 1.2.6 Stripping Method -- 1.2.7 Microwave Synthesis Method -- 1.2.8 Self-Assembly -- 1.2.9 Special Interface Synthesis Method -- 1.2.10 Surfactant-Assisted Synthesis Method -- 1.2.11 Ultrasonic Synthesis -- 1.3 Structures, Properties, and Applications -- 1.3.1 Structure and Properties of MOFs -- 1.3.2 Application in Biomedicine -- 1.3.3 Application in Gas Storage -- 1.3.4 Application in Sensors -- 1.3.5 Application in Chemical Separation -- 1.3.6 Application in Catalysis -- 1.3.7 Application in Gas Adsorption -- 1.4 Summary and Outlook -- Acknowledgements -- References -- Chapter 2 2D Black Phosphorus -- 2.1 Introduction -- 2.2 The Research on Black Phosphorus -- 2.2.1 The Structure and Properties -- 2.2.1.1 The Structure of Black Phosphorus -- 2.2.1.2 The Properties of Black Phosphorus -- 2.2.2 Preparation Methods -- 2.2.2.1 Mechanical Exfoliation -- 2.2.2.2 Liquid-Phase Exfoliation -- 2.2.3 Antioxidant -- 2.2.3.1 Degradation Mechanism -- 2.2.3.2 Adding Protective Layer -- 2.2.3.3 Chemical Modification -- 2.2.3.4 Doping -- 2.3 Applications of Black Phosphorus -- 2.3.1 Electronic and Optoelectronic -- 2.3.1.1 Field-Effect Transistors -- 2.3.1.2 Photodetector -- 2.3.2 Energy Storage and Conversion -- 2.3.2.1 Catalysis -- 2.3.2.2 Batteries -- 2.3.2.3 Supercapacitor -- 2.3.3 Biomedical -- 2.4 Conclusion and Outlook -- Acknowledgements -- References -- Chapter 3 2D Metal Carbides -- 3.1 Introduction -- 3.2 Synthesis Approaches -- 3.2.1 Ti3C2 Synthesis. , 3.2.2 V2C Synthesis -- 3.2.3 Ti2C Synthesis -- 3.2.4 Mo2C Synthesis -- 3.3 Structures, Properties, and Applications -- 3.3.1 Structures and Properties of 2D Metal Carbides -- 3.3.1.1 Structures and Properties of Ti3C2 -- 3.3.1.2 Structural Properties of Ti2C -- 3.3.1.3 Structural Properties of Mo2C -- 3.3.1.4 Structural Properties of V2C -- 3.3.2 Carbide Materials in Energy Storage Applications -- 3.3.2.1 Ti3C2 -- 3.3.2.2 Ti2C -- 3.3.2.3 V2C -- 3.3.2.4 Mo2C -- 3.3.3 Metal Carbide Materials in Catalysis Applications -- 3.3.3.1 Ti3C2 -- 3.3.3.2 V2C -- 3.3.3.3 Mo2C -- 3.3.4 Metal Carbide Materials in Environmental Management Applications -- 3.3.4.1 Ti3C2 in Environmental Management Applications -- 3.3.4.2 Ti2C in Environmental Management Applications -- 3.3.4.3 V2C in Environmental Management Applications -- 3.3.4.4 Mo2C in Environmental Management Applications -- 3.3.5 Carbide Materials in Biomedicine Applications -- 3.3.5.1 Ti3C2 in Biomedicine Applications -- 3.3.5.2 Ti2C in Biomedicine Applications -- 3.3.5.3 V2C in Biomedicine Applications -- 3.3.5.4 Mo2C in Biomedicine Applications -- 3.3.6 Carbide Materials in Gas Sensing Applications -- 3.3.6.1 Ti3C2 in Gas Sensing Applications -- 3.3.6.2 Ti2C in Gas Sensing Applications -- 3.3.6.3 V2C in Gas Sensing Applications -- 3.3.6.4 Mo2C in Gas Sensing Applications -- 3.4 Summary and Outlook -- Acknowledgements -- References -- Chapter 4 2D Carbon Materials as Photocatalysts -- 4.1 Introduction -- 4.2 Carbon Nanostructured-Based Materials -- 4.2.1 Forms of Carbon -- 4.2.2 Synthesis of Carbon Nanostructured-Based Materials -- 4.3 Photo-Degradation of Organic Pollutants -- 4.3.1 Graphene, Graphene Oxide, Graphene Nitride (g-C3N4) -- 4.3.1.1 Graphene-Based Materials -- 4.3.1.2 Graphene Nitride (g-C3N4) -- 4.3.2 Carbon Dots (CDs) -- 4.3.3 Carbon Spheres (CSs). , 4.4 Carbon-Based Materials for Hydrogen Production -- 4.5 Carbon-Based Materials for CO2 Reduction -- References -- Chapter 5 Sensitivity Analysis of Surface Plasmon Resonance Biosensor Based on Heterostructure of 2D BlueP/MoS2 and MXene -- 5.1 Introduction -- 5.2 Proposed SPR Sensor, Design Considerations, and Modeling -- 5.2.1 SPR Sensor and Its Sensing Principle -- 5.2.2 Design Consideration -- 5.2.2.1 Layer 1: Prism for Light Coupling -- 5.2.2.2 Layer 2: Metal Layer -- 5.2.2.3 Layer 3: BlueP/MoS2 Layer -- 5.2.2.4 Layer 4: MXene (Ti3C2Tx) Layer as BRE for Biosensing -- 5.2.2.5 Layer 5: Sensing Medium (RI-1.33-1.335) -- 5.2.3 Proposed Sensor Modeling -- 5.3 Results Discussion -- 5.3.1 Role of Monolayer BlueP/MoS2 and MXene (Ti3C2Tx) and Its Comparison With Conventional SPR -- 5.3.2 Influence of Varying Heterostructure Layers for Proposed Design -- 5.3.3 Effect of Changing Prism Material and Metal on Performance of Proposed Design -- 5.4 Conclusion -- References -- Chapter 6 2D Perovskite Materials and Their Device Applications -- 6.1 Introduction -- 6.2 Structure -- 6.2.1 Crystal Structure -- 6.2.2 Electronic Structure of 2D Perovskites -- 6.2.3 Structure of Photovoltaic Cell -- 6.3 Discussion and Applications -- 6.4 Conclusion -- References -- Chapter 7 Introduction and Significant Parameters for Layered Materials -- 7.1 Graphene -- 7.2 Phosphorene -- orthorhombic rhombohedral Simple cubic -- semiconductor semimetal metal -- 7.3 Silicene -- 7.4 ZnO -- 7.5 Transition Metal Dichalcogenides (TMDCs) -- 7.6 Germanene and Stanene -- 7.7 Heterostructures -- References -- Chapter 8 Increment in Photocatalytic Activity of g-C3N4 Coupled Sulphides and Oxides for Environmental Remediation -- 8.1 Introduction -- 8.2 GCN Coupled Metal Sulphide Heterojunctions for Environment Remediation -- 8.2.1 GCN and MoS2-Based Photocatalysts. , 8.2.2 GCN and CdS-Based Heterojunctions -- 8.2.3 Some Other GCN Coupled Metal Sulphide Photocatalysts -- 8.3 GCN Coupled Metal Oxide Heterojunctions for Environment Remediation -- 8.3.1 GCN and MoO3-Based Heterojunctions -- 8.3.2 GCN and Fe2O3-Based Heterojunctions -- 8.3.3 Some Other GCN Coupled Metal Oxide Photocatalysts -- 8.4 Conclusions and Outlook -- References -- Chapter 9 2D Zeolites -- 9.1 Introduction -- 9.1.1 What is 2D Zeolite? -- 9.1.2 Advancement in Zeolites to 2D Zeolite -- 9.2 Synthetic Method -- 9.2.1 Bottom-Up Method -- 9.2.2 Top-Down Method -- 9.2.3 Support-Assisted Method -- 9.2.4 Post-Synthesis Modification of 2D Zeolites -- 9.3 Properties -- 9.4 Applications -- 9.4.1 Petro-Chemistry -- 9.4.2 Biomass Conversion -- 9.4.2.1 Pyrolysis of Solid Biomass -- 9.4.2.2 Condensation Reactions -- 9.4.2.3 Isomerization -- 9.4.2.4 Dehydration Reactions -- 9.4.3 Oxidation Reactions -- 9.4.4 Fine Chemical Synthesis -- 9.4.5 Organometallics -- 9.5 Conclusion -- References -- Chapter 10 2D Hollow Nanomaterials -- 10.1 Introduction -- 10.2 Structural Aspects of HNMs -- 10.3 Synthetic Approaches -- 10.3.1 Template-Based Strategies -- 10.3.1.1 Hard Templating -- 10.3.1.2 Soft Templating -- 10.3.2 Self-Templating Strategies -- 10.3.2.1 Surface Protected Etching -- 10.3.2.2 Ostwald Ripening -- 10.3.2.3 Kirkendall Effect -- 10.3.2.4 Galvanic Replacement -- 10.4 Medical Applications of HNMs -- 10.4.1 Imaging and Diagnosis Applications -- 10.4.2 Applications of Nanotube Arrays -- 10.4.2.1 Pharmacy and Medicine -- 10.4.2.2 Cancer Therapy -- 10.4.2.3 Immuno and Hyperthermia Therapy -- 10.4.2.4 Infection Therapy and Gene Therapy -- 10.4.3 Hollow Nanomaterials in Diagnostics and Therapeutics -- 10.4.4 Applications in Regenerative Medicine -- 10.4.5 Anti-Neurodegenerative Applications -- 10.4.6 Photothermal Therapy -- 10.4.7 Biosensors. , 10.5 Non-Medical Applications of HNMs -- 10.5.1 Catalytic Micro or Nanoreactors -- 10.5.2 Energy Storage -- 10.5.2.1 Lithium Ion Battery -- 10.5.2.2 Supercapacitor -- 10.5.3 Nanosensors -- 10.5.4 Wastewater Treatment -- 10.6 Toxicity of 2D HNMs -- 10.7 Future Challenges -- 10.8 Conclusion -- Acknowledgement -- References -- Chapter 11 2D Layered Double Hydroxides -- 11.1 Introduction -- 11.2 Structural Aspects -- 11.3 Synthesis of LDHs -- 11.3.1 Co-Precipitation Method -- 11.3.2 Urea Hydrolysis -- 11.3.3 Ion-Exchange Method -- 11.3.4 Reconstruction Method -- 11.3.5 Hydrothermal Method -- 11.3.6 Sol-Gel Method -- 11.4 Nonmedical Applications of LDH -- 11.4.1 Adsorbent -- 11.4.2 Catalyst -- 11.4.3 Sensors -- 11.4.4 Electrode -- 11.4.5 Polymer Additive -- 11.4.6 Anion Scavenger -- 11.4.7 Flame Retardant -- 11.5 Biomedical Applications -- 11.5.1 Biosensors -- 11.5.2 Scaffolds -- 11.5.3 Anti-Microbial Agents -- 11.5.4 Drug Delivery -- 11.5.5 Imaging -- 11.5.6 Protein Purification -- 11.5.7 Gene Delivery -- 11.6 Toxicity -- 11.7 Conclusion -- Acknowledgement -- References -- Chapter 12 Experimental Techniques for Layered Materials -- 12.1 Introduction -- 12.2 Methods for Synthesis of Graphene Layered Materials -- 12.3 Selection of a Suitable Metallic Substrate -- 12.4 Graphene Synthesis by HFTCVD -- 12.5 Graphene Transfer -- 12.6 Characterization Techniques -- 12.6.1 X-Ray Diffraction Technique -- d D k -- 12.6.2 Field Emission Scanning Electron Microscopy (FESEM) -- 12.6.3 Transmission Electron Microscopy (TEM) -- 12.6.4 Fourier Transform Infrared Radiation (FTIR) -- 12.6.5 UV-Visible Spectroscopy -- 12.6.6 Raman Spectroscopy -- 12.6.7 Low Energy Electron Microscopy (LEEM) -- 12.7 Potential Applications of Graphene and Derived Materials -- 12.8 Conclusion -- Acknowledgement -- References -- Chapter 13 Two-Dimensional Hexagonal Boron Nitride and Borophenes. , 13.1 Two-Dimensional Hexagonal Boron Nitride (2D h-BN): An Introduction.