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  • 1
    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Ion exchange. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (230 pages)
    Edition: 1st ed.
    ISBN: 9783030104306
    DDC: 541.3723
    Language: English
    Note: Intro -- Preface -- Contents -- 1 Green Approach: Microbes for Removal of Dyes and Metals via Ion Binding -- Abstract -- 1.1 Introduction -- 1.2 Pollutants in the Environment -- 1.2.1 Toxic Metals -- 1.2.2 Triphenylmethane Dyes -- 1.3 Bioremediation Approaches in Removing Pollutants -- 1.3.1 Non-microbial Strategies -- 1.3.2 Microbial-Based Strategies -- 1.4 Mechanisms for Removal of Pollutant Ions -- 1.4.1 Mechanisms for Removal of Metal Ions -- 1.4.2 Mechanisms for Removal of Dyes -- 1.5 Innovations in the Removal of Pollutant Ions -- 1.6 Conclusions and Future Prospects -- Acknowledgements -- References -- 2 Removal of Heavy Metal from Wastewater Using Ion Exchange Membranes -- Abstract -- 2.1 Introduction -- 2.2 Heavy Metal -- 2.2.1 Chromium -- 2.2.2 Nickel -- 2.2.3 Copper -- 2.2.4 Zinc -- 2.2.5 Cadmium -- 2.2.6 Mercury -- 2.2.7 Lead -- 2.3 Physical Treatment Methods -- 2.3.1 Ultrafiltration -- 2.3.2 Nanofiltration -- 2.3.3 Reverse Osmosis -- 2.3.4 Forward Osmosis -- 2.3.5 Adsorption -- 2.4 Chemical Treatment Methods -- 2.4.1 Electrodialysis Method -- 2.4.2 Fuel Cell Method -- 2.5 Remaining Challenges and Perspectives -- 2.6 Conclusion -- Acknowledgements -- References -- 3 Separation and Purification of Uncharged Molecules -- Abstract -- 3.1 Introduction -- 3.2 Separation and Purification of Vitamin B12 -- 3.2.1 Downstream Processing of Vitamin B12 for Measurement -- 3.3 Separation and Purification of Haemoglobin -- 3.4 Separation and Purification of Uncharged Dyes -- 3.4.1 Purification and Separation of Dyes -- 3.5 Conclusion -- References -- 4 Aluminosilicate Inorganic Polymers (Geopolymers): Emerging Ion Exchangers for Removal of Metal Ions -- Abstract -- 4.1 Introduction -- 4.2 Methodology and Calculations -- 4.2.1 Terminology: Ion Exchange or Adsorption -- 4.2.2 Evidence for Ion Exchange. , 4.2.3 Modeling of Adsorption of Metal Ions on Geopolymers -- 4.2.4 Geopolymer Preparation -- 4.2.5 Washing of the Geopolymeric Adsorbent -- 4.2.6 Comparison Between Geopolymers and Zeolites -- 4.2.7 Geopolymers as Ion Exchangers -- 4.2.7.1 Geopolymers as Ion Exchangers for Alkali Metal Ions -- 4.2.7.2 Geopolymers as Ion Exchangers for Ammonium Ion -- 4.2.7.3 Geopolymers as Ion Exchangers for Alkaline Earth Metals -- 4.2.7.4 Geopolymers as Ion Exchangers for Heavy Metals -- Metakaolin-Based Geopolymers -- Fly Ash-Based Geopolymers -- Zeolite-Based Geopolymers -- 4.2.7.5 Geopolymers as Ion Exchangers/Adsorbents for Cationic Organic Dyes -- 4.2.8 Comparison of Geopolymers with Zeolites -- 4.2.8.1 Synthesis Conditions -- 4.2.8.2 Crystallinity -- 4.2.8.3 Surface Area and Porosity -- 4.2.8.4 Cation Exchange Capacity -- 4.2.8.5 Selectivity for Metal Ions -- 4.2.8.6 Stability in Acidic Solutions -- 4.2.8.7 Thermal Stability -- 4.2.8.8 Mechanical Strength -- 4.2.8.9 Regeneration -- 4.2.9 Stabilization/Solidification/Encapsulation of Ion Exchangers in Geopolymers -- 4.3 Concluding Remarks -- References -- 5 Microwave-Assisted Hydrothermal Synthesis of Agglomerated Spherical Zirconium Phosphate for Removal of Cs+ and Sr2+ Ions from Aqueous System -- Abstract -- 5.1 Introduction -- 5.2 Materials and Methods -- 5.2.1 Preparation of Agglomerated Spherical Zirconium Phosphate -- 5.2.2 Characterization -- 5.2.3 Ion Exchange Properties -- 5.2.4 Elution Behaviour -- 5.2.5 Distribution Studies -- 5.3 Results and Discussion -- 5.3.1 Fourier-Transform Infrared (FT-IR) Characterization -- 5.3.2 Powder X-ray Diffraction Studies -- 5.3.3 Scanning Electron Microscopy (SEM) and Energy Dispersive (EDS) Characterization -- 5.3.4 Zeta and Surface Area Analysis -- 5.3.5 Ion Exchange Characteristics -- 5.3.6 Mechanism of Sr2+ Interaction with Zirconium Phosphate -- 5.4 Conclusion. , Acknowledgements -- References -- 6 Metal Hexacyanoferrates: Ion Insertion (or Exchange) Capabilities -- Abstract -- 6.1 Introduction -- 6.2 Ion Exchange -- 6.2.1 Ion Exchange in MHCF at Work: Potentiometric Ion Sensors -- 6.2.2 An Ion Exchange-Based Approach for the Recovery of Metal Ions: The Case of Cesium and Thallium -- 6.2.3 Electrochemically Driven Ion Exchange -- 6.2.4 Reversible Ion Insertion in Battery Systems -- 6.3 Conclusion -- References -- 7 Biosorbents and Composite Cation Exchanger for the Treatment of Heavy Metals -- Abstract -- 7.1 Introduction -- 7.2 Agro-Based Biosorbents for Heavy Metal Removal -- 7.3 Biopolymers -- 7.3.1 Functional Groups -- 7.3.2 Cellulose -- 7.3.3 Chitosan -- 7.3.4 Nanofiber Membranes and Packed-Bed Adsorbers -- 7.4 Composite Ion Exchangers -- 7.5 Conclusion and Future Outlook -- References -- 8 Rare Earth Elements-Separation Methods Yesterday and Today -- Abstract -- 8.1 Introduction -- 8.2 Rare Earth Elements -- 8.2.1 General Characteristics -- 8.2.2 The Occurrence of Rare Earth Elements -- 8.2.3 Physicochemical Properties of Rare Earth Elements -- 8.2.4 Application of Rare Earth Metals -- 8.2.5 Production and Consumption of Rare Earth Elements in the World -- 8.3 Rare Earth Element Recovery from Nickel-Metal Hydride Batteries -- 8.4 Rare Earth Element Recovery from Permanent Magnets -- 8.5 Separation of High-Purity Rare Earth Elements -- 8.5.1 Separations of Rare Earth Elements of High Purity Using Cation Exchangers -- 8.5.2 Separations of Rare Earth Elements of High Purity Using Anion Exchangers -- 8.5.3 Separations of Rare Earth Elements of High Purity Using Chelating Ion Exchangers -- 8.6 Current Technologies -- 8.7 Conclusions -- References -- 9 Sequestration of Heavy Metals from Industrial Wastewater Using Composite Ion Exchangers -- Abstract -- 9.1 Introduction -- 9.2 Ion-Exchange Materials. , 9.2.1 Organic Materials -- 9.2.2 Inorganic Materials -- 9.2.3 Composite Materials -- 9.2.3.1 Hybrid Materials -- 9.2.3.2 Nanocomposite -- 9.3 Mechanism of Ion-Exchange Process -- 9.4 Conclusion -- Acknowledgements -- References -- 10 Applications of Organic Ion Exchange Resins in Water Treatment -- Abstract -- 10.1 Introduction -- 10.2 Removal of Heavy Metals -- 10.3 Removal of Organics -- 10.3.1 Natural Organic Matter (NOM) -- 10.3.2 Disinfection by-Products (DBPs) -- 10.3.3 Surfactants -- 10.3.4 Pharmaceuticals -- 10.3.5 Dyes -- 10.3.6 Small Organic Matter -- 10.4 Desalination -- 10.5 Boron Removal -- 10.6 Removal of Anions -- 10.7 Removal of Cations -- 10.7.1 Hardness -- 10.7.2 Ammonium -- 10.8 Conclusions -- References.
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  • 2
    Online Resource
    Online Resource
    Dordrecht :Springer Netherlands,
    Keywords: Chromatographic analysis. ; Chemistry, Analytic -- Technique. ; Sustainable development. ; Electronic books.
    Description / Table of Contents: This book examines counter-current, ion size exclusion, supercritical fluids, high-performance thin layers, and gas and size exclusion chromatographic techniques used to separate and purify organic and inorganic analytes. Includes green prep methods and more.
    Type of Medium: Online Resource
    Pages: 1 online resource (220 pages)
    Edition: 1st ed.
    ISBN: 9789400777354
    DDC: 543.8
    Language: English
    Note: Intro -- Preface -- Acknowledgements -- Contents -- Contributors -- Chapter-1 -- Saving Solvents in Chromatographic Purifications: The Counter-Current Chromatography Technique -- 1.1 Introduction -- 1.2 CCC Theory -- 1.2.1 High Loadability -- 1.2.2 Scale up Capability -- 1.3 Instrumentation -- 1.3.1 Hydrostatic and Hydrodynamic Instruments -- 1.3.2 Liquid Systems -- 1.4 Counter Current Chromatography, a Green Process -- 1.4.1 Saving Solvents -- 1.4.2 Improving Process Parameters -- 1.4.3 Injecting Crude Samples -- 1.4.4 Greener Solvents -- 1.5 Counter Current Chromatography, a Tool for Green Chemistry Development -- 1.5.1 Natural Products -- 1.5.2 Solute Partition Coefficient Determination -- 1.6 Conclusion -- References -- Chapter-2 -- Ion Size Exclusion Chromatohtaphy on Hypercrosslinked Polystyrene Sorbents as a Green Technology of Separating Mineral Elecyrolites -- 2.1 Introduction -- 2.2 Nanoporous Hypercrosslinked Polystyrene Sorbents -- 2.3 Brief Description of Chromatographic Experiments -- 2.4 Dimensions of Hydrated Ions -- 2.5 Separation of Electrolytes on Nanoporous Hypercrosslinked Sorbents -- 2.6 Basic Features of Size Exclusion Chromatography -- 2.7 Conception of "Ideal Separation Process" -- 2.8 Selectivity of Electrolyte Separation Process -- 2.9 Influence of the Electrolyte Concentration on the Selectivity of Separat -- 2.10 "Acid Retardation", "Base Retardation" and "Salt Retardation" Phenomena -- 2.11 Other Convincing Proofs of Separating Electrolytes via Exclusion Mechanism -- 2.12 Do we Really Need Sorbent Functional Groups to Separate Electrolytes? -- 2.13 Productivity of the Ion Size Exclusion Process -- 2.14 Ion Size Exclusion-Green Technology -- 2.15 Conclusion -- References -- Chapter-3 -- Supercritical Fluid Chromatography: A Green Approach for Separation and Purification of Organic and Inorganic Analytes. , 3.1 Introduction to Green Chemistry and Supercritical Fluid Chromatography -- 3.2 Super Critical Fluids -- 3.2.1 Supercritical Fluid Extraction (SFE) -- 3.3 Supercritical Fluid Chromatography (SFC): An Overview -- 3.3.1 History of Development of Supercritical Fluid Chromatography -- 3.3.2 Instrumentation -- 3.3.2.1 Advantages and Disadvantages of Supercritical Fluid Chromatography -- 3.3.3 Properties of SFC compared to GC and HPLC -- 3.4 Industrial Applications of SCFs and SFCs -- 3.5 Conclusion -- References -- Chapter-4 -- High Performance Thin-Layer Chromatography -- 4.1 Introduction -- 4.2 High Performance Thin-Layer Chromatography -- 4.3 Sample Preparation in HPTLC -- 4.4 Green Separation Modalities in HPTLC -- 4.4.1 "Three R" Philosophy-Replacement of Toxic Solvents with Environmental Friendly Mobi -- 4.4.1.1 Reversed-Phase Chromatography -- 4.4.1.2 Hydrophilic Interaction Chromatography (HILIC) in HPTLC -- 4.4.1.3 Salting-Out Chromatography in HPTLC -- 4.5 Conclusion -- References -- Chapter-5 -- Green Techniques in Gas Chromatography -- 5.1 Introduction -- 5.2 Sample Preparation -- 5.2.1 Direct Methods Without Sample Preparation -- 5.2.2 Solventless Sample Preparation Techniques -- 5.2.2.1 Solid Phase Extraction -- 5.2.2.2 Vapor-Phase Extraction -- 5.2.2.3 Thermal Desorption (TD)/Thermal Extraction (TE) -- 5.2.2.4 Membrane Extraction -- 5.2.3 Sample Preparation Using Environmentally Friendly Solvents -- 5.2.3.1 Supercritical Fluid Extraction (SFE) -- 5.2.3.2 Subcritical Water Extraction (SWE) -- 5.2.3.3 Ionic Liquids (ILs) -- 5.2.3.4 Cloud-Point Extraction -- 5.2.4 Assisted Solvent Extraction -- 5.3 Column Considerations for Green Gas Chromatography -- 5.4 Carrier Gas Considerations for Green Gas Chromatography -- 5.5 Coupling GC with Other Analytical Tools -- 5.6 On-Site Analysis. , 5.7 Conclusion -- References -- Chapter-6 -- Preparation and Purification of Garlic-Derived Organosulfur Compound Allicin by Green Methodologies -- 6.1 Introduction -- 6.2 Green RP-HPLC Purification of the Allicin -- 6.3 Characterization of the Allicin by Green Methodologies -- 6.4 Allicin in Different Garlic Extract by Green RP-HPLC -- 6.5 Allicin Green Chemical Synthesis -- 6.6 Stability of Allicin -- 6.7 Conclusions -- References -- Chapter-7 -- Green Sample Preparation Focusing on Organic Analytes in Complex Matrices -- 7.1 Introduction -- 7.1.1 Trends in Green Analytical Chemistry -- 7.1.2 Green Techniques for Sample Preparation -- 7.1.2.1 Reduction and Solvent Replacement -- Supercritical Fluid Extraction -- Membranes -- 7.1.2.2 Solvent Elimination -- Solid Phase Extraction (SPE) -- Matrix Solid-Phase Dispersion (MSPD) -- Sorptive Extraction Techniques -- Solid Phase Microextraction (SPME) -- Stir-Bar Sorptive Extraction -- 7.2 Conclusions -- References -- Chapter-8 -- Studies Regarding the Optimization of the Solvent Consumption in the Determination of Organochlor -- 8.1 Introduction -- 8.2 Materials and Methods -- 8.2.1 Materials -- 8.2.2 Methods -- 8.3 Results -- 8.4 Discussions -- 8.4.1 TRM1 -- 8.4.2 TRM2 -- 8.5 Conclusions -- References -- Chapter-9 -- Size Exclusion Chromatography a Useful Technique For Speciation Analysis of Polydimethylsiloxanes -- 9.1 Introduction to SEC -- 9.2 SEC Retention Mechanisms -- 9.2.1 Ideal Size Exclusion Mechanism -- 9.2.2 Non-Ideal Size Exclusion Mechanism -- 9.3 The Stationary Phase in SEC -- 9.4 The Mobile Phase in SEC -- 9.5 Analytical Problems -- 9.6 Methods for Column Calibration -- 9.7 Applications of SEC Biomedical and Pharmaceutical -- 9.7.1 SEC as a Useful Technique for Linear Polydimethylsiloxanes Speciation Analysis. , 9.8 Methodology for Linear Polydimethylsiloxanes Speciation Analysis -- 9.8.1 Mobile Phase Selection -- 9.8.2 Stationary Phase Selection -- 9.8.3 Column Conditions -- 9.8.4 Column Calibration -- 9.8.5 Separation of Polydimethylsiloxanes -- 9.9 Conclusions -- References -- Erratum -- Index.
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  • 3
    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Photocatalysis. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (277 pages)
    Edition: 1st ed.
    ISBN: 9783030126193
    Series Statement: Environmental Chemistry for a Sustainable World Series ; v.30
    DDC: 541.395
    Language: English
    Note: Intro -- Preface -- Contents -- Contributors -- Chapter 1: Role of Nano-photocatalysis in Heavy Metal Detoxification -- 1.1 Introduction -- 1.2 Heavy Metals and Their Toxicological Effects -- 1.2.1 Cadmium -- 1.2.2 Chromium -- 1.2.3 Copper -- 1.2.4 Lead -- 1.2.5 Mercury -- 1.2.6 Nickel -- 1.2.7 Zinc -- 1.3 Overview of Photocatalysis -- 1.4 Mechanism of Photocatalysis -- 1.5 Types of Photocatalysis -- 1.5.1 Homogeneous Photocatalysis -- 1.5.2 Heterogeneous Photocatalysis -- 1.6 Overview and Mechanism of Nano-photocatalysis -- 1.7 Photocatalytic Nanoparticle Synthesis -- 1.7.1 Organic Synthesis -- 1.7.1.1 Plant Extracts Aqueous Solutions -- 1.7.1.2 Microorganisms -- 1.7.2 Chemical Synthesis -- 1.7.2.1 Sol-Gel Method -- 1.7.2.2 Hydrothermal Method -- 1.7.2.3 Polyol Synthesis -- 1.7.2.4 Precipitation Method -- 1.7.3 Physical Synthesis -- 1.7.3.1 Ball Milling -- 1.7.3.2 Melt Mixing -- 1.7.3.3 Physical Vapour Deposition (PVD) -- 1.7.3.4 Laser Ablation -- 1.7.3.5 Sputter Deposition -- 1.8 Mode of Operation on Nano-photocatalysis -- 1.9 Parameters Affecting the Photocatalytic Efficiency -- 1.9.1 Effect of pH of the Reaction Solution -- 1.9.2 Effect of Photocatalyst Concentration -- 1.9.3 Effect of Substrate Adsorption -- 1.9.4 Effect of Dissolved Oxygen -- 1.10 Application -- 1.10.1 Chromium -- 1.10.1.1 pH -- 1.10.1.2 Light Intensity -- 1.10.1.3 Photocatalyst Dosage -- 1.10.1.4 Presence of Organic Compounds -- 1.10.2 Mercury -- 1.10.3 Arsenic -- 1.10.4 Uranium -- 1.11 Disadvantages of Photocatalysis -- 1.12 Photocatalyst Modifications -- 1.12.1 Dye Sensitization -- 1.12.2 Ion Doping -- 1.12.3 Composite Semiconductor -- 1.13 Conclusion -- References -- Chapter 2: Solar Photocatalysis Applications to Antibiotic Degradation in Aquatic Systems -- 2.1 Introduction -- 2.2 Solar Photocatalysis Process. , 2.3 Solar Photocatalysis Treatment for Antibiotic Degradation -- 2.3.1 Trimethoprim -- 2.3.2 Sulfamethoxazole -- 2.3.3 Erythromycin -- 2.3.4 Ciprofloxacin -- 2.4 Conclusions -- References -- Chapter 3: Biomass-Based Photocatalysts for Environmental Applications -- 3.1 Introduction -- 3.2 Background of Biomass-Derived Carbon -- 3.2.1 Biochar -- 3.2.2 Activated Carbon (AC) -- 3.3 Synthesis Methods of Biomass-Derived Carbon -- 3.3.1 Pyrolysis -- 3.3.2 Hydrothermal Carbonization -- 3.3.3 Physical and Chemical Activation -- 3.4 Photocatalysts and Photocatalysis Reactions -- 3.5 Functionalized AC and Applications -- 3.5.1 Types of Functionalized AC -- 3.5.2 Functionalized AC Photocatalysts and Its Application -- 3.6 Future Challenges and Conclusions -- References -- Chapter 4: Application of Bismuth-Based Photocatalysts in Environmental Protection -- 4.1 Introduction -- 4.2 Photocatalytic Oxidation of Pharmaceuticals in Water -- 4.2.1 Tetracycline -- 4.2.2 Ciprofloxacin and Other Antibiotics -- 4.2.3 Carbamazepine -- 4.2.4 Ibuprofen and Diclofenac -- 4.2.5 Other Pharmaceuticals -- 4.3 Photocatalytic Oxidation of Industrial Micropollutants -- 4.3.1 Bisphenol A -- 4.3.2 Oxidation of Other Industrial Pollutants -- 4.4 Oxidation of the Indoor Air Pollutant NOx -- 4.5 Photocatalytic Reduction of Pollutants in Water and Air -- 4.5.1 Reduction of Cr(VI) in Water -- 4.5.2 Reduction of CO2 in Air -- 4.6 Water Splitting -- 4.7 Conclusions -- References -- Chapter 5: Phosphors-Based Photocatalysts for Wastewater Treatment -- 5.1 Introduction -- 5.2 Phosphor Materials: A Historical Background -- 5.3 Inorganic Phosphors in Photocatalysis -- 5.3.1 Types of Inorganic Phosphor Materials -- 5.3.2 Down-Conversion Phosphors in Photocatalysis -- 5.3.3 Up-Conversion Phosphors in Photocatalysis -- 5.3.4 Long-Persistent Phosphors in Photocatalysis. , 5.4 Organic Up-Conversion Phosphors in Photocatalysis -- References -- Chapter 6: Nanocarbons-Supported and Polymers-Supported Titanium Dioxide Nanostructures as Efficient Photocatalysts for Remedi... -- 6.1 Introduction -- 6.1.1 Heterogeneous Semiconductor Photocatalysis -- 6.1.2 Potential TiO2-Based Photocatalysts -- 6.1.3 Limitations of the Fine Powder Form of TiO2-Based Photocatalysts -- 6.1.3.1 Comparison of Synthesis Methods -- 6.1.3.2 Improvements in TiO2 Performance by Structural Change, Doping, and Hybridization -- 6.2 TiO2 Photocatalysts with Polymer-Based Hybrid Photocatalysts for Wastewater Treatment -- 6.2.1 Need for Immobilization of TiO2-Based Photocatalysts -- 6.2.1.1 Features of a Stable Substrate, and Available Substrates -- 6.2.1.2 Comparison of Polymeric Supports for Wastewater Treatment -- 6.3 TiO2 Photocatalysts Supported with Nanocarbons for Wastewater Treatment -- 6.3.1 TiO2-Functionalized Nanocarbon-Based Photocatalysts -- 6.3.1.1 Potential Photocatalytic Improvements with Carbon Nanostructures for Wastewater Treatment -- 6.4 Conclusions and Future Outlook -- References -- Chapter 7: Investigation in Sono-photocatalysis Process Using Doped Catalyst and Ferrite Nanoparticles for Wastewater Treatment -- 7.1 Introduction -- 7.2 Dependency of Catalytic Activity -- 7.2.1 Size-Dependent Catalytic Activity -- 7.2.2 Shape-Dependent Catalytic Effect -- 7.2.3 Interparticle Distance-Dependent Catalytic Effect -- 7.2.4 Support Interaction and Charge Transfer-Dependent Reactivity -- 7.3 Type of Nanoparticles -- 7.3.1 Non-metallic Nanoparticles -- 7.3.2 Metallic Nanoparticles -- 7.3.3 Semiconductor Nanoparticles -- 7.3.4 Ceramic Nanoparticles -- 7.3.5 Polymer Nanoparticles -- 7.3.6 Lipid-Based Nanoparticles -- 7.4 Types of Nanoparticles Based on Structure -- 7.5 Synthesis and Applications -- 7.5.1 Discussions -- 7.6 Synergetic Effect. , 7.7 Conclusion and Overview -- References -- Chapter 8: Magnetic-Based Photocatalyst for Antibacterial Application and Catalytic Performance -- 8.1 Introduction -- 8.2 Magnetic-Based Photocatalysts in Inactivation of the Microorganism -- 8.3 Factors Affecting the Photocatalytic Bacterial Inactivation -- 8.3.1 Effect of Magnetic-Based Photocatalyst Concentration and Light Intensity -- 8.3.2 Nature of Microorganism -- 8.3.3 Solution pH of Magnetic-Based Photocatalyst Suspension -- 8.3.4 Initial Bacterial Concentration -- 8.3.5 Physiological State of Bacteria -- 8.4 Proposed Mechanism for Bacteria Disinfection by the Magnetic-Based Photocatalyst -- 8.5 Using Magnetic-Based Catalyst in Photocatalytic Abatement of Organics -- 8.6 Photocatalysis for the Simultaneous Treatment of Bacteria and Organics -- 8.7 Conclusion and Future Prospects -- References -- Chapter 9: Antimicrobial Activities of Photocatalysts for Water Disinfection -- 9.1 Introduction -- 9.2 Mechanisms of Photocatalytic Disinfection -- 9.3 Pure and Modified Photocatalysts -- 9.4 Photocatalytic Films and Biofilms -- 9.5 Photocatalytic Composites and Nanocomposites -- 9.6 Materials with Antimicrobial Activity in the Absence of Light -- 9.7 Case Study: Application of Supported Photocatalysts in Disinfection of Whey-Processing Water -- 9.8 Final Considerations -- References -- Chapter 10: Medicinal Applications of Photocatalysts -- 10.1 Introduction -- 10.1.1 Background -- 10.2 Antifungal Activity -- 10.3 Virucidal Activity -- 10.4 Antimicrobial Activity -- 10.5 Anticancer Activity -- 10.6 Conclusion -- References -- Index.
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  • 4
    Online Resource
    Online Resource
    Singapore :Springer Singapore Pte. Limited,
    Keywords: Botanical chemistry. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (318 pages)
    Edition: 1st ed.
    ISBN: 9789811566073
    Series Statement: Environmental and Microbial Biotechnology Series
    DDC: 579
    Language: English
    Note: Intro -- Preface -- Contents -- 1: Application of Microbial Biosurfactants in the Food Industry -- 1.1 Surfactants in the Food Industry -- 1.1.1 Food Additives -- 1.1.2 Biosurfactants as Food Preservatives -- 1.1.2.1 Emulsifying Agents -- 1.1.2.2 Antibiofilm Agents -- 1.1.2.3 Antimicrobial Agents -- 1.1.2.4 Antioxidant Agents -- 1.1.3 Industrial Prospects -- References -- 2: Microbial Biosurfactants for Contamination of Food Processing -- 2.1 Introduction -- 2.1.1 Food Contamination -- 2.1.2 Contamination in Food Processing -- 2.2 Microbial Biosurfactants Use in Food Processing -- 2.2.1 Glycolipids -- 2.2.2 Lipopeptides -- 2.3 Application of Microbial Surfactants in Food Processing -- 2.3.1 Biofilm Control -- 2.3.2 Food Preservatives -- 2.4 Concluding Remarks -- References -- 3: Antioxidant Biosurfactants -- 3.1 Introduction -- 3.2 Sources of Biosurfactants -- 3.2.1 Plant-Based Biosurfactants -- 3.2.1.1 Saponins -- Structure, Properties, and Types of Saponins -- Saponins as a Biosurfactants -- 3.2.2 Microbe-Based Biosurfactants -- 3.2.2.1 Types of Microbial Surfactants -- Glycolipids -- Rhamnolipids -- Sophorolipids -- Trehalolipids -- Succinoyl Trehalolipids -- Cellobiose Lipids -- Mannosylerythritol Lipids -- Xylolipids -- Mannose Lipids -- Lipopeptides or Lipoprotein -- Bacillus-Related Lipopeptides -- Surfactin -- Fengycin -- Iturin -- Kurstakins -- Lichenysins -- Pseudomonas-Related Lipopeptides -- Actinomycetes-Related lipopeptides -- Fungal-Related Lipopeptides -- Phospholipids, Fatty Acids (Mycolic Acids), and Neutral Lipids -- Polymeric Surfactants -- Particulate Surfactants -- 3.3 Factors Affecting Biosurfactant Production -- 3.3.1 pH and Temperature -- 3.3.2 Aeration and Agitation -- 3.3.3 Effect of Salt Salinity -- 3.3.4 Optimization of Cultivation Medium -- 3.3.4.1 Effect of Carbon Source -- 3.3.4.2 Effect of Nitrogen Source. , 3.3.4.3 Effect of Carbon to Nitrogen (C/N) Ratio -- 3.4 Screening of Microorganisms for Biosurfactant Production -- 3.4.1 Oil Spreading Assay -- 3.4.2 Drop Collapse Assay -- 3.4.3 Blood Agar Method/Hemolysis Assay -- 3.4.4 Hydrocarbon Overlay Agar -- 3.4.5 Bacterial Adhesion to Hydrocarbon (BATH) Assay -- 3.4.6 CTAB Agar Plate Method/Blue Agar Assay -- 3.4.7 Phenol: Sulfuric Acid Method -- 3.4.8 Microplate Assay -- 3.4.9 Penetration Assay -- 3.4.10 Surface/Interface Activity -- 3.4.11 Emulsification Activity -- 3.5 Antioxidant Properties of Biosurfactant -- 3.6 Conclusion -- References -- 4: Classification and Production of Microbial Surfactants -- 4.1 Introduction -- 4.1.1 Global Biosurfactant Market -- 4.2 Types of Biosurfactants -- 4.2.1 Glycolipids -- 4.2.1.1 Rhamnolipids -- 4.2.1.2 Sophorolipids -- 4.2.1.3 Trehalolipids -- 4.2.2 Lipoproteins and Lipopeptides -- 4.2.3 Fatty Acids -- 4.2.4 Phospholipids -- 4.2.5 Polymeric Biosurfactants -- 4.3 Factors Influencing Biosurfactant Productivity -- 4.3.1 Nutritional Factors -- 4.3.1.1 Carbon Source -- 4.3.1.2 Low-Cost and Waste Substrates -- 4.3.1.3 Nitrogen Source -- 4.3.1.4 Minerals -- 4.3.2 Environmental Factors -- 4.3.3 Cultivation Strategy -- 4.3.3.1 Solid-State Fermentation (SSF) -- 4.3.3.2 Submerged Fermentations (SmF) -- References -- 5: Microbial Biosurfactants and Their Potential Applications: An Overview -- 5.1 Introduction -- 5.2 Classes of Biosurfactants -- 5.2.1 Glycolipids -- 5.2.2 Lipopolysaccharides -- 5.2.3 Lipopeptides and Lipoproteins -- 5.2.4 Phospholipids -- 5.2.5 Fatty Acids -- 5.3 Microbial Production of Biosurfactants -- 5.4 Genes Involved in the Production of Microbial Biosurfactants -- 5.5 Applications -- 5.5.1 In Petroleum Industry -- 5.5.1.1 Mechanism of MEOR -- 5.5.2 Biosurfactant-Mediated Bioremediation -- 5.5.3 In Food Industry -- 5.5.4 In Agriculture. , 5.5.5 In Cosmetics -- 5.5.6 Biosurfactant in Nanotechnology -- 5.5.7 Biosurfactants as Drug Delivery Agents -- 5.5.8 Antimicrobial Activity of Biosurfactants -- 5.5.9 Biosurfactant as Anti-Adhesive Agent -- 5.5.10 In Fabric Washing -- 5.6 Conclusions -- References -- 6: Biodegradation of Hydrophobic Polycyclic Aromatic Hydrocarbons -- 6.1 Introduction -- 6.2 Health Related to PAHs -- 6.2.1 Consequences of Consistent of PAH Exposure by Human -- 6.2.2 Problems Associated with PAHs Via Cytochrome P450 -- 6.3 Biodegradation of PAHs -- 6.3.1 Challenges of Limited Aqueous Solubility in Water -- 6.3.2 Biodegradation Pathway of PAHs -- 6.3.2.1 Naphthalene -- 6.3.2.2 Pyrene -- 6.3.2.3 Fluoranthene -- 6.4 Biosurfactants -- 6.4.1 Biosurfactants -- 6.4.1.1 Glycolipid -- Rhamnolipids -- Cellobiose Lipids -- Sophorolipids -- Trehalolipids -- Mannosylerythritol Lipid -- 6.4.1.2 Lipopeptides -- 6.4.1.3 Phospholipids -- 6.4.2 Polymeric Biosurfactants -- 6.5 Enhanced Biodegradation of PAHs by Biosurfactant -- 6.5.1 Biodegradation in Micelles -- 6.5.2 Biosurfactant Acting as Bioemulsifier -- 6.6 Conclusions -- References -- 7: Surfactin: A Biosurfactant Against Breast Cancer -- 7.1 Introduction -- 7.2 Biosurfactants and Its Types -- 7.2.1 Glycolipids -- 7.2.1.1 Rhamnolipids -- 7.2.1.2 Sophorolipids -- 7.2.1.3 Trehalolipids -- 7.2.2 Lipopeptides -- 7.2.3 Fatty Acids -- 7.2.4 Phospholipids -- 7.2.5 Polymeric Biosurfactant -- 7.3 Surfactin: Structure, Membrane Interaction, Biosynthesis, and Regulation -- 7.3.1 Structure -- 7.3.2 Membrane Interaction -- 7.3.3 Biosynthesis -- 7.3.4 Regulation -- 7.4 Surfactin and Breast Cancer -- 7.5 Conclusion -- References -- 8: Anti-Cancer Biosurfactants -- 8.1 Introduction -- 8.2 Biosurfactants Classification and Structure -- 8.2.1 Mannosylerythritol Lipids (MELs) -- 8.2.2 Succinoyl Trehalose Lipids (STLs) -- 8.2.3 Sophorolipids. , 8.2.4 Rhamnolipids (RLs) -- 8.2.5 Myrmekiosides -- 8.2.6 Cyclic Lipopeptides (CLPs) -- 8.2.6.1 Amphisin, Tolaasin, and Syringomycin CLPs -- 8.2.6.2 Iturin and fengycin CLPs -- 8.2.6.3 Surfactin CLP -- 8.2.7 Rakicidns and Apratoxins -- 8.2.8 Serrawettins -- 8.2.9 Monoolein -- 8.2.10 Fellutamides -- 8.3 Biosurfactants Production -- 8.3.1 Factors Involved in Biosurfactants Production -- 8.3.1.1 Source of Carbon -- 8.3.1.2 Source of Nitrogen -- 8.3.1.3 Effect of Ions -- 8.3.1.4 Physical Factors -- 8.4 Anti-Cancer Activity of Biosurfactants -- 8.4.1 Breast Cancer -- 8.4.2 Lung Cancer -- 8.4.3 Leukemia -- 8.4.4 Melanoma -- 8.4.5 Colon Cancer -- 8.5 Biosurfactants as Drug Delivery System (DDS) -- 8.5.1 Liposomes -- 8.5.2 Niosomes -- 8.5.3 Nanoparticles -- 8.6 Conclusions and Future Challenges -- References -- 9: Biosurfactants for Oil Pollution Remediation -- 9.1 Introduction -- 9.2 Oil Pollution and Its Remediation -- 9.2.1 Oil Pollution -- 9.2.2 Oil Remediation in Polluted Environments -- 9.3 Biosurfactants -- 9.3.1 Synthesis of Biosurfactants -- 9.3.2 Biosurfactant Role in Oil Degradation -- 9.4 Application of Biosurfactants Used for Oil Remediation -- 9.4.1 Oil-Polluted Soil Bioremediation -- 9.4.2 Bioremediation of Marine Oil Spills and Petroleum Contamination -- 9.4.3 Cleaning of Oil Tanks and Pipelines -- 9.4.4 Bioremediation of Heavy Metals and Toxic Pollutants -- 9.5 Conclusion -- References -- 10: Potential Applications of Anti-Adhesive Biosurfactants -- 10.1 Introduction -- 10.2 Biosurfactants That Display Anti-Adhesive Activity -- 10.3 Biofilms and the Adhesion Process: Mechanisms and Effects -- 10.4 Applications of Biosurfactants as Anti-Adhesive Agents -- 10.4.1 Anti-Adhesive Applications in the Biomedical Field -- 10.4.2 Anti-Adhesive Applications in the Food Industry Surfaces -- 10.5 Future Trends and Conclusions -- References. , 11: Applications of Biosurfactant for Microbial Bioenergy/Value-Added Bio-Metabolite Recovery from Waste Activated Sludge -- 11.1 Introduction -- 11.2 Applications of Surfactants for Value-Added Bio-Metabolites Recovery from WAS -- 11.3 Applications of Surfactants for Energy Recovery from WAS -- 11.4 Applications of Surfactants for Refractory Organic Decontamination from WAS -- 11.4.1 PAHs Decontamination -- 11.4.2 Dye Decontamination -- 11.4.3 PCB Decontamination -- 11.5 Applications of Surfactants for WAS Dewatering -- 11.6 Applications of Surfactants for Heavy Metal Removal from WAS -- 11.7 State-of-the-Art Processes to Promote Organics Biotransformation from WAS -- 11.7.1 Co-Pretreatment -- 11.7.2 Interfacing AD with Bioelectrochemical Systems -- 11.7.3 Optimizing Process Conditions -- 11.8 Conclusion -- References -- 12: Application of Microbial Biosurfactants in the Pharmaceutical Industry -- 12.1 Introduction -- 12.2 Mechanism of Interaction of Biosurfactants -- 12.3 Physiochemical Properties -- 12.3.1 Surface Tension -- 12.3.2 Biosurfactant and Self-Assembly -- 12.3.3 Emulsification Activity -- 12.4 Application of Biosurfactants in Pharmaceutical Industry -- 12.4.1 Biosurfactant as an Antitumor/AntiCancer Agent -- 12.4.2 Biosurfactants as Drug Delivery Agents -- 12.4.3 Wound Healing and Dermatological Applications -- 12.4.4 Potential Antimicrobial Application -- 12.4.5 Other Applications in the Pharmaceutical Field -- 12.5 Applications of Surfactin in Pharmaceutical Industry -- 12.6 Concluding Remarks -- References -- 13: Antibacterial Biosurfactants -- 13.1 Introduction -- 13.2 Glycolipids -- 13.2.1 Rhamnolipids -- 13.2.2 Sophorolipids -- 13.2.3 Trehalose Lipids -- 13.3 Lipopeptides -- 13.4 Phospholipids -- 13.5 Antibacterial Activity -- 13.6 Polymeric Surfactants -- 13.7 Fatty Acids -- 13.7.1 Bio-Sources of Fatty Acids. , 13.7.2 Role of Fatty Acids as Antimicrobials.
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  • 5
    Online Resource
    Online Resource
    Singapore :Springer Singapore Pte. Limited,
    Keywords: Microbial biotechnology. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (734 pages)
    Edition: 1st ed.
    ISBN: 9789811622250
    Series Statement: Environmental and Microbial Biotechnology Series
    Language: English
    Note: Intro -- Contents -- About the Editors -- 1: Application of Endophyte Microbes for Production of Secondary Metabolites -- 1.1 Introduction -- 1.2 Origin and Evolution of Endophytes -- 1.3 Endophyte Diversity -- 1.4 Close Relationship Between Endophytes and Medicinal Herbs -- 1.5 Endophytes and Secondary Metabolites -- 1.6 Terpenoids -- 1.7 Phenolics -- 1.8 Flavonoids -- 1.9 Alkaloids -- 1.10 Glycosides -- 1.11 Saponins -- 1.12 Polyketides -- 1.13 Coumarins -- 1.14 Steroids -- 1.15 Conclusion and Perspectives -- References -- 2: Application of Microbes in Synthesis of Electrode Materials for Supercapacitors -- 2.1 Introduction -- 2.1.1 Basics of Supercapacitors -- 2.1.2 Electrode Materials for Supercapacitors -- 2.1.3 Why Microbes in Energy Storage Devices? -- 2.2 Different Microbes Commonly Used in EES -- 2.2.1 Bacteria -- What so Special About Bacterial Cellulose? -- 2.2.2 Viruses -- 2.2.3 Fungi -- 2.3 Microbes as Bio-templates for Energy Storage Materials -- 2.3.1 Bacteria as Bio-templates -- 2.3.2 Fungi as Bio-templates -- 2.3.3 Viruses as Bio-templates -- 2.4 Microbe-Based Carbon Materials as Supporting Matrix -- 2.5 Microbe-Derived Carbons for Energy Storage Applications -- 2.5.1 Bacteria-Derived Carbons for Energy storage applications -- 2.5.2 Fungi-Derived Carbons for Energy Storage Applications -- 2.5.3 Microbe-Derived Carbon-Based Nanocomposites as Energy Storage Materials -- 2.6 Conclusion and Future Prospects -- References -- 3: Application of Microbes in Climate-Resilient Crops -- 3.1 Introduction -- 3.2 Heat Stress Tolerance -- 3.3 Cold Stress Tolerance -- 3.4 Submergence Stress Tolerance -- 3.5 Salinity and Drought Stress Tolerance -- 3.6 Conclusion and Future Perspectives -- References -- 4: Application of Microbes in Biotechnology, Industry, and Medical Field -- 4.1 Overview of Microorganisms -- 4.1.1 Prokaryotic Microorganisms. , Bacteria -- Archaea -- 4.1.2 Eukaryotic Microorganisms -- Protist -- Fungi -- Virus -- 4.2 Principles -- 4.2.1 Screening for Microbial Products -- Screening Methods -- 4.2.2 Microbial Bioprocess -- Optimization -- Sustainable Technologies -- 4.2.3 Enzymology -- 4.2.4 Gene Manipulation -- Recombinant DNA Technology -- 4.3 Applications -- 4.3.1 Industry -- Food-Fermented Foods -- Improvement of Food Quality -- Improvement Efficiency and Productivity of Process -- Food Additives -- Agroindustry -- Pest in Crops -- Crop Yield and Product Quality -- Construction -- Chemical Industry -- Cleaning -- Bioremediation -- Chemical-Based Cleaning Products -- 4.3.2 Environment -- Wastewater Treatment -- Solid Hazardous Treatment -- Composting -- Anaerobic Digestion -- Metal Recovery -- Microbial Biofuels -- Biomethanol -- Bioethanol -- Butanol -- Biodiesel -- Medical Biotechnology -- 4.4 Conclusions -- References -- 5: Applications of Microbes for Energy -- 5.1 Introduction -- 5.2 Microbes for Energy Applications -- 5.2.1 Microbes for Fuel Cells -- 5.2.2 Microbes for Hydrogen Production -- 5.2.3 Microbes for Methane Production -- 5.2.4 Microbes for Ethanol Production -- 5.2.5 Microbes for Biodiesel Production -- 5.2.6 Microbes for Electrosynthesis -- 5.2.7 Microbes for Energy Storage -- 5.3 Conclusion and Future Remarks -- References -- 6: Applications of Microbes in Electric Generation -- 6.1 Introduction -- 6.2 Different BFC Types -- 6.2.1 DET-BFC -- 6.2.2 MET-BFC -- 6.2.3 EBFC -- 6.2.4 MFC -- 6.3 Electrocatalytic Nanomaterials for EBFC -- 6.3.1 Carbon Materials -- 6.3.2 Metal Nanoparticles -- 6.3.3 Composite Materials -- 6.4 Electrocatalytic Nanomaterials for MFC -- 6.4.1 Electrocatalytic Nanomaterials for MFC Anode -- Carbon Nanomaterials -- Metal Nanomaterials -- Conductive Polymers -- 6.4.2 Electrocatalytic Nanomaterials for MFC Cathode. , Noble Metal-Based Materials -- Non-noble Metal-Based Materials -- 6.5 Summary and Prospect -- References -- 7: Application of Microbes in Household Products -- 7.1 Introduction -- 7.2 Household Products -- 7.2.1 Cleaning Product -- 7.2.2 Cosmeceutical -- 7.2.3 Textiles -- 7.2.4 Others -- 7.3 Benefits and Challenges -- 7.4 Conclusion -- References -- 8: Electricity Generation and Wastewater Treatment with Membrane-Less Microbial Fuel Cell -- 8.1 Introduction -- 8.2 Electricity Generation -- 8.2.1 Anode and Cathode Electrodes -- Cathode Electrode -- Anode Electrode -- 8.2.2 Effect of Operating Temperature -- 8.2.3 Effect of pH -- 8.2.4 Effect of Substrate Pretreatment -- 8.2.5 Effect of Reactor Design -- 8.2.6 Effect of Electrode Surface Area and Electrode Spacing -- 8.2.7 Effect of Substrate Conductivity -- 8.3 Water Treatment (Substrate) -- 8.4 Conclusion -- References -- 9: Microbes: Applications for Power Generation -- 9.1 Introduction -- 9.2 Reduction of the Environmental and Air Pollution -- 9.2.1 Natural Aerosols from Vegetation -- 9.2.2 Landfill Gas -- 9.2.3 Biogas -- Using Leachate of the Waste -- 9.2.4 Biodiesel -- 9.2.5 Bioethanol -- Using Celluloses -- Using Starch -- Using Sugar -- 9.2.6 Sewer -- 9.3 Energy Efficiency -- 9.3.1 Microorganisms -- 9.3.2 Microbial Fuel Cells -- Using Natural Fermentation -- Using Biomass -- Using Domestic Wastewater -- Using Industrial Wastewater -- Using Sewage -- Using Crop Residue -- Using Mud -- Using Biogas Slurry -- 9.3.3 Newer Microbial Fuel Cells -- Using Electronophore (Traditional) -- Using Biochar (Latest) -- 9.3.4 Biogas -- Using Sewage -- Using Animal Waste -- Using Animal Manure -- 9.3.5 Biohydrogen -- 9.4 Availability -- 9.4.1 Biomass -- 9.5 Clean Energy -- 9.5.1 Algae -- 9.5.2 Microbial Biophotovoltaic Cells -- Using Algae -- Using Cyanobacteria -- Using Plant Rhizodeposition. , 9.6 Sustainability -- 9.6.1 Biomass -- Crop Residue -- 9.6.2 Camphor -- 9.7 Conclusion -- 9.8 Future Approach -- References -- 10: Applications of Microbes in Food Industry -- 10.1 Introduction -- 10.2 Applications of Microorganisms in Food Industry -- 10.2.1 Baking Industry Applications -- 10.2.2 Alcohol and Beverage Industry Applications -- 10.2.3 Enzyme Production and Its Applications -- 10.2.4 Production of Amino Acids -- 10.2.5 Microbial Detergents as Food Stain Removers -- 10.2.6 Dairy Industry Applications -- 10.2.7 Pigment Production -- 10.2.8 Organic Acid Production -- 10.2.9 Aroma and Flavouring Agents Production -- 10.2.10 Miscellaneous Applications -- Xanthan Gum Production -- Ripening Process -- Food Grade Paper Production -- Single-Cell Protein -- Applications in Other Foods -- 10.3 Summary -- References -- 11: Applications of Microbes in Human Health -- 11.1 Introduction -- 11.2 Human Microbiome -- 11.3 Probiotics -- 11.4 Properties of Probiotics -- 11.5 Probiotics Mechanism of Action -- 11.6 Oral Probiotics -- 11.6.1 Probiotics in Preventing Dental Caries Progression -- 11.6.2 Probiotics in Prevention of Gingival Inflammation -- 11.6.3 Probiotics in Prevention of Periodontal Diseases -- 11.7 Probiotics in Halitosis -- 11.7.1 Probiotics in Oral Mucositis -- 11.7.2 Benefits of Probiotics in General Health -- 11.7.3 Anti-Inflammatory Property -- 11.8 Antimicrobial Properties -- 11.9 Antioxidant Properties -- 11.10 Anticancer Properties -- 11.10.1 Probiotics in Treatment of Upper Respiratory Tract Infections -- 11.10.2 Probiotics in Treatment of Urogenital Infections -- 11.10.3 Probiotics in Improvement of Intestinal Health -- 11.10.4 Probiotics in Treatment of Chemotherapy and Radiotherapy Induced Diarrhea -- 11.10.5 Probiotics in Treatment of Anemia -- 11.11 Treatment and Prevention of Obesity -- 11.12 Probiotics as Immunomodulator. , 11.13 Conclusion -- References -- 12: Applications of Microbes in Soil Health Maintenance for Agricultural Applications -- 12.1 Introduction -- 12.2 Microbial Sources -- 12.2.1 Microalgae and Cyanobacteria -- 12.2.2 Fungi -- 12.2.3 Bacteria -- 12.3 Applications of Microbes -- 12.3.1 Plant Growth Regulators -- 12.3.2 Volatile Organic Compounds (VOCs) -- 12.3.3 Biotic Elicitors -- 12.3.4 Bioremediation -- 12.3.5 Biocontrol -- 12.3.6 Different Types of Microbes -- 12.4 Healthy Soil and Eco-Friendly Environment -- 12.4.1 Biofertilizers -- 12.4.2 Biopesticides -- 12.4.3 Bioherbicides -- 12.4.4 Bioinsecticides -- 12.5 Microbiome and Sustainable Agriculture -- 12.5.1 Benefits of Mycorrhizal Fungi -- 12.5.2 Soil and Environmental Health -- 12.6 Conclusion -- References -- 13: Co-functional Activity of Microalgae: Biological Wastewater Treatment and Bio-fuel Production -- 13.1 Introduction -- 13.2 Wastewater Treatment Using Microalgae -- 13.2.1 Wastewater Composition -- 13.2.2 Nutrient Removal -- Influence of Additives in Wastewater on Nutrient Removal by Microalgae -- 13.2.3 Heavy Metal Removal -- 13.3 Microalgae Cultivation and Harvesting -- 13.3.1 Open Ponds -- 13.3.2 Closed System (Photobioreactor PBRs) -- 13.3.3 Hybrid System -- 13.3.4 Harvesting Techniques -- 13.4 Bio-refinery -- 13.5 Bio-fuel Production Using Microalgae -- 13.5.1 Thermochemical Conversion -- 13.5.2 Biochemical Conversion/Fermentation -- 13.5.3 Chemical Reaction/Transesterification -- 13.5.4 Direct Combustion -- 13.6 Sustainability of Energy from Microalgae -- 13.7 Conclusions -- References -- 14: Microalgae Application in Chemicals, Enzymes, and Bioactive Molecules -- 14.1 Introduction -- 14.2 Microalgae-Based Products -- 14.2.1 Chemical Products -- 14.2.2 Bioactive Molecules -- 14.3 Microalgae Enzymes -- 14.4 Industrial Applications of Microalgae. , 14.5 Conclusions and Future Perspectives.
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  • 6
    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Renewable energy sources. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (354 pages)
    Edition: 1st ed.
    ISBN: 9783030728779
    Series Statement: Advances in Science, Technology and Innovation Series
    DDC: 628.532
    Language: English
    Note: Intro -- Contents -- 1 Chemical Valorization of CO2 -- Abstract -- 1 Introduction -- 2 CO2-Derived Fuels and Chemicals -- 2.1 Methane -- 2.2 Methanol -- 2.3 Dimethyl Ether -- 2.4 Formic Acid -- 2.5 Ethanol -- 2.6 CO2-Fischer-Tropsch Liquid Fuels -- 2.7 Carbon Monoxide-Syngas -- 3 CO2 Chemically Derived Materials -- 3.1 Polymers -- 3.2 CO2-Derived Building Materials -- 4 Conclusions -- References -- 2 Progress in Catalysts for CO2 Reforming -- Abstract -- 1 Introduction -- 2 Technologies for Capturing and Storing Carbon Dioxide -- 3 Technologies for Using Carbon Dioxide -- 4 Methane Dry Reforming Process -- 4.1 Progress in Catalysts for Methane Dry Reforming (1928-1989) -- 4.2 Progress in Catalysts for Methane Dry Reforming (1990-1999) -- 4.3 Progress in Catalysts for Methane Dry Reforming (2000-2009) -- 4.4 Progress in Catalysts for Methane Dry Reforming (2010-2019) -- 4.5 Current Status in the Catalysts for Methane Dry Reforming -- 5 Dry Reforming of Other Compounds -- 6 Use of Steam or Oxygen in Dry Reforming of Methane and Other Compounds -- 7 Solid Oxide Fuel Cells Fueled with Biogas -- 8 Commercialization of Dry Reforming Process -- 9 Conclusions -- References -- 3 Fuel Generation from CO2 -- Abstract -- 1 Introduction -- 2 Approaches for Directly Converting CO2 to Fuels -- 2.1 Pure CO2 Decomposition Technology -- 2.2 Reagent-Based CO2 Conversion Technology -- 2.2.1 Dry Deformation of Methane Technology -- 2.2.2 Catalytic Hydrogenation of CO2 -- 3 Biological CO2 Fixation for Fuels -- 3.1 Thermochemical Conversion -- 3.1.1 Torrefaction -- 3.1.2 Pyrolysis -- 3.1.3 Thermochemical Liquefaction -- 3.1.4 Gasification -- 3.1.5 Direct Combustion -- 3.2 Biochemical Conversion -- 3.2.1 Biodiesel -- 3.2.2 Bioethanol -- 3.2.3 Biomethane -- 3.2.4 Biohydrogen -- 3.2.5 Bioelectricity -- 3.2.6 Volatile Organic Compounds. , 4 Conclusion and Future Perspectives -- References -- 4 Thermodynamics of CO2 Conversion -- Abstract -- 1 Introduction -- 2 Carbon Dioxide Capture -- 3 Carbon Dioxide Utilisations -- 4 Thermodynamic Considerations -- 5 Thermodynamics of CO2 -- 5.1 The Thermodynamic Attainable Region (AR) -- 5.2 Using Hess's Law to Transform the Extents to G-H AR @ 25˚C -- 5.3 Increasing Temperature on G-H AR -- 6 Conclusion -- Acknowledgements -- References -- 5 Enzymatic CO2 Conversion -- Abstract -- 1 Introduction -- 1.1 CO2 as a Greenhouse Gas -- 1.2 Carbon Capture, Storage, and Utilization -- 1.3 CO2 as a Chemical Feedstock -- 1.4 CO2 Conversion with Enzymes -- 2 Natural Conversion of CO2 in Cells -- 3 Enzymatic Conversion of CO2 in Cells -- 3.1 Conversion of CO2 by a Single Enzyme (in vitro) -- 3.1.1 Formate Dehydrogenase -- 3.1.2 Carbonic Anhydrase -- 3.1.3 Carbon Monoxide Dehydrogenase -- 3.1.4 Ribulose-1,5-bisphosphate Carboxylase/Oxygenase (RuBisCO) -- 3.2 Conversion of CO2 by a Multi-Enzyme Cascade in vitro -- 3.3 Other Ways (Photocatalytic CO2 Methanation) -- 4 Industrial Applications -- 4.1 Alcohols -- 4.2 Organic Acids -- 4.3 Terpenoids -- 4.4 Fatty Acids -- 4.5 Polyhydroxyalkanoates -- 4.6 Calcium Carbonate -- 5 Summary and Future Prospects -- References -- 6 Electrochemical CO2 Conversion -- Abstract -- 1 Introduction -- 2 Electrochemical CO2 Conversion -- 2.1 Fundamentals of the Process -- 2.2 Variants of Electrochemical Conversion of CO2 -- 2.2.1 Aqueous Electrolytes -- 2.2.2 Non-Aqueous Electrolytes -- 2.2.3 Solid Oxide Electrolytes -- 2.2.4 Molten Salt Electrolytes -- 3 Electrochemical CO2 Conversion from Molten Salts -- 3.1 Present State of Electrochemical Reduction of CO2in Molten Salts for the Production of Solid-Phase Carbonaceous Nanomaterials -- 3.2 Direct Electrochemical Reduction of CO2 in Chloride Melts. , 3.3 Indirect Electrochemical Reduction of CO2 in Molten Salts -- 3.4 The Mechanisms of Electrode Reactions Occurring at the Cathode and Anode -- 3.5 Prospects for CO2 Conversion in Molten Salts -- 4 Conclusions -- References -- 7 Supercritical Carbon Dioxide Mediated Organic Transformations -- Abstract -- 1 Introduction -- 2 Applications of Supercritical Carbon Dioxide -- 2.1 Hydrogenation Reactions -- 2.2 Asymmetric Hydrogenation Reactions -- 2.3 Diels-Alder Reaction -- 2.4 Coupling Reaction -- 2.5 Oxidation Reaction -- 2.6 Baeyer-Villiger Oxidation Reaction -- 2.7 Iodination Reaction -- 2.8 Polymerization Reaction -- 2.9 Carbonylation Reaction -- 2.9.1 Acetalization Reaction -- 2.9.2 Olefin Metathesis Reaction -- 2.9.3 Synthesis of heterocycles -- Synthesis of α-alkylidene Cyclic Carbonates -- Synthesis of 4-Methyleneoxazolidin-2-Ones -- Synthesis of 5-Alkylidene-1, 3-Oxazolidin-2-Ones -- Synthesis of 6-Phenyl-3a, 4-Dihydro-1H-Cyclopenta[C]furan-5(3H)-One -- Synthesis of 3, 4, 5, 6-Tetraethyl-2H-Pyran-2-One -- 3 Conclusions -- Acknowledgements -- References -- 8 Theoretical Approaches to CO2 Transformations -- Abstract -- 1 Carbon Dioxide Properties -- 2 CO2 Transformation as an Undeniable Necessity -- 3 CO2 Activation -- 3.1 Methodologies of CO2 Activation -- 4 Theoretical Insight of CO2 Transformation -- 4.1 The Theoretical Approach in CO2 Conversion to Value-Added Chemicals -- 4.1.1 Carbon Monoxide -- 4.1.2 Methane -- 4.1.3 Methanol -- 4.1.4 Formic Acid -- 4.1.5 Heterocycles -- Cyclic Carbonates -- Cyclic Carbamate -- Quiznazoline-2,4(1H,3H)-Dione -- 4.1.6 Summary and Outlook -- 5 Theoretical Designing of Novel Catalysts Based on DFT Studies -- 5.1 Theoretical Designing: Problems and Opportunities -- 6 Conclusion -- References -- 9 Carbon Dioxide Conversion Methods -- Abstract -- 1 Introduction -- 2 Molecular Structure of CO2. , 3 Thermo-Kinetics of CO2 Conversion -- 4 CO2 Conversion Methods and Products -- 4.1 Fischer-Tropsch Gas-to-Liquid (GTL) -- 4.2 Mineralization -- 4.3 Chemical Looping Dry Reforming -- 4.4 Enzymatic Conversion -- 4.5 Photocatalytic and Photo-Electrochemical Conversion -- 4.6 Thermo-Chemical Conversion -- 4.7 Hydrogenation -- 4.8 Reforming -- 5 Economic Assessment of CO2Alteration to Valuable Products -- 5.1 Syngas -- 5.2 Methanol -- 5.3 Formic Acid -- 5.4 Urea -- 5.5 Dimethyl Carbonate (DMC) -- 6 Conclusions and Future Perspective -- Acknowledgements -- References -- 10 Closing the Carbon Cycle -- Abstract -- 1 Introduction -- 2 Methods to Capture CO2 -- 3 CO2 Capture Technologies -- 4 CO2 Capture from the Air -- 5 Biomass and Waste-Based Chemicals -- 6 Advantages of Biomass-Based Chemicals -- 7 Replacement of Carbon-Based Energy Resources -- 8 Biomass Energy -- 9 Wind Energy -- 10 Solar Energy -- 11 Ocean Energy -- 12 Geothermal Energy -- 13 Hydrothermal Energy -- 14 Conclusions -- References -- 11 Carbon Dioxide Utilization to Energy and Fuel: Hydrothermal CO2 Conversion -- Abstract -- 1 Introduction -- 2 Hydrothermal CO2 Conversion -- 2.1 Metals and Catalysts as Reductant -- 2.2 Organic Wastes as Reductant -- 2.3 Inorganic Wastes as Reductant -- 2.4 Biomass as Reductant -- 3 Conclusion -- References -- 12 Ethylenediamine-Carbonic Anhydrase Complex for CO2 Sequestration -- 1 Introduction -- 2 An Overview of Carbonic Anhydrase (CA) -- 3 Mechanism of Action for Biocarbonate Formation -- 4 Historical Background of Carbonic Anhydrase -- 5 Sources of Carbonic Anhydrase -- 6 Carbonic Anhydrase in Microorganism -- 6.1 Micrococcus Lylae, Micrococcus Luteus, and Pseudomonas Fragi -- 6.2 Bacillus Subtilis and Citrobacter Freundii -- 6.3 Neisseria Gonorrhoeae -- 6.4 Helicobacter Pylori -- 7 Plant Carbonic Anhydrase -- 8 Overview of CO2. , 9 Sources of Carbon Dioxide (CO2) -- 10 Effect of Carbon Dioxide (CO2) -- 11 Carbon Dioxide Capturing -- 12 Carbon Dioxide (CO2) Sequestration -- 13 Carbon Dioxide (CO2) Sequestration by Carbonic Anhydrase -- 14 Separation System for CO2 Sequestration -- 15 Cryogenic Separation -- 16 Membrane Separation -- 17 Absorption -- 18 Adsorption -- 19 Bioreactors for CO2 Sequestration -- 20 Carbonic Anhydrase Immobilization -- 21 Ethylenediamine for Carbon Dioxide (CO2) Capturing -- 22 CO2 Capturing and Sequestration with Ethylenediamine-Carbonic Anhydrase Complex -- 23 CO2 Capturing and Sequestration Design and Optimization: Challenges and Future Prospects -- 24 Conclusion -- References -- 13 Green Pathway of CO2 Capture -- Abstract -- 1 Introduction -- 2 Molecular Structure of Carbon Dioxide -- 3 CO2 Capture System -- 3.1 Post-Combustion System -- 3.2 Pre-Combustion System -- 3.3 Oxy-Fuel Combustion System -- 4 Absorption Technology -- 4.1 Green Absorption with Ionic Liquids -- 4.1.1 Properties and Uses of Ionic Liquids -- 4.1.2 CO2 Solubility in PILs -- 4.1.3 CO2 Absorption in PILs with Carboxylate Anion -- 4.2 Reaction Mechanism Involved in CO2-Absorption -- 5 Adsorption Technology -- 5.1 Organic Adsorbents -- 5.1.1 Activated Charcoal -- 5.1.2 Biochar -- 5.1.3 Metal-Organic Frameworks (MOFs) -- 5.2 Other CO2 Adsorbents -- 5.2.1 Metal Oxide-Based Absorbents -- 5.2.2 Zeolites -- 5.3 Biological Processes of CO2Sequestration -- 5.3.1 Carbon Utilization by Forest and Agricultural Management -- 5.3.2 Ocean Fertilization -- 5.3.3 CO2 Capture by Microalgae -- 5.4 Electrochemical Ways for CO2 Capture -- 6 Conclusion -- References -- 14 Carbon Derivatives from CO2 -- Abstract -- 1 Introduction -- 2 Artificial Photoreduction -- 3 Electrochemical Reduction -- 4 Hydrogenation -- 5 Synthesis of Organic Carbonates -- 6 Reforming. , 7 Photocatalytic Reduction of CO2 with Water.
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  • 7
    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Renewable energy sources. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (474 pages)
    Edition: 1st ed.
    ISBN: 9783319527390
    DDC: 541.372
    Language: English
    Note: Intro -- Preface -- Acknowledgements -- Contents -- Editors and Contributors -- 1 Organic-Inorganic Membranes Impregnated with Ionic Liquid -- Abstract -- 1 Introduction -- 2 Ionic Liquids: General Properties and Applications -- 3 Ionic Liquids as Electrolytes in Fuel Cells -- 4 Ionic Liquid Polymer Membranes for Fuel Cells -- 4.1 Ionic Liquid/Polymer Membranes -- 4.2 Polymerized Ionic Liquid Membranes -- 4.3 IL Gel and Composite Polymer Membranes -- 5 Conclusions -- Acknowledgements -- References -- 2 Organic/TiO2 Nanocomposite Membranes: Recent Developments -- Abstract -- 1 Introduction -- 2 TiO2-Polymer Electrolyte Membranes (PEMs) -- 2.1 Perfluorinated Organic-Inorganic Nanocomposite Polymer Electrolyte Membranes (PEMs) -- 2.2 Acid-Base Polymer Complex-Based Organic-Inorganic Nanocomposite PEMs -- 2.3 TiO2-Modified Polytetrafluoroethylene Membranes -- 2.4 Poly(ether ether ketone)-Based Nanocomposite PEMs -- 2.5 PANI Based Membranes -- 2.6 PES Based Membranes -- 2.7 Polysulfone-Based Membranes -- 2.8 TiO2 Solar Cells -- 2.9 Carbon Materials and Metal-Carbon Nanotube (CNTs)-TiO2 Composites -- 2.9.1 Carbon-TiO2 Composites -- 2.9.2 Graphene (GN)-TiO2 Composites -- 3 Conclusions -- Acknowledgements -- References -- 3 Organic/Silica Nanocomposite Membranes -- Abstract -- 1 Introduction -- 2 Silica Nanoparticle-Based Membranes -- 3 Conclusion -- References -- 4 Organic/Zeolites Nanocomposite Membranes -- Abstract -- 1 Introduction -- 2 Basic Concepts About Zeolites -- 3 Polymer-Zeolite Composite Membranes: The Role of the Zeolite -- 3.1 Influence of Si/Al Ratio -- 3.2 Proton Mobility in Zeolites -- 3.3 Internal and External Surface Area -- 3.4 Configurational Diffusion -- 3.5 Crystallite Size [17, 18] -- 3.6 Functionalization of Zeolite Surface -- 3.7 Selectivity, Proton Conductivity, and Permeability. , 4 Techniques for Producing Organic/Zeolite Nanocomposite Membranes -- 5 Synthetic Polymers/Zeolite Nanocomposite Membranes for PEMFCs -- 5.1 Route 1: Zeolite + Organic Monomers -- 5.2 Route 3: Inorganic Precursor + Organic Polymer -- 5.3 Route 4: Zeolite + Organic Polymer -- 6 Natural Polymers/Zeolite Nanocomposite Membranes for PEMFCs -- 7 Conclusions -- Acknowledgements -- References -- 5 Composite Membranes Based on Heteropolyacids and Their Applications in Fuel Cells -- Abstract -- 1 Introduction -- 2 Heteropolyacids Types and Structures -- 3 HPAs and Proton Transport in Fuel Cells -- 4 HPAs in PEM Fuel Cell -- 5 HPAs in High-Temperature and Low-Humidity PEMFC -- 6 HPAs in DMFC -- 7 Concluding Remarks and Future Perspectives -- Acknowledgements -- References -- 6 Organic/Montmorillonite Nanocomposite Membranes -- Abstract -- 1 Introduction -- 2 Membrane Fabrication Methods -- 2.1 Phase Inversion -- 2.2 Immersion Precipitation -- 2.3 Evaporation-Induced Phase Separation -- 3 Montmorillonite-Based Nanocomposites Membranes -- 4 Conclusion -- References -- 7 Electrospun Nanocomposite Materials for Polymer Electrolyte Membrane Methanol Fuel Cells -- Abstract -- 1 Introduction -- 2 Methanol Crossover and Low Proton Conductivity -- 3 Composite SPEEK -- 4 SPEEK-Clay Nanocomposite as PEM for DMFC -- 5 Morphology Types and the Importance of Exfoliated Surface Structure on DMFC Performance -- 6 Preparation of Exfoliated Nanocomposite Membranes -- 7 Electrospinning as a Membrane Morphological Modification Technique -- 8 Electrospun Polymer-Based Nanofiber Membranes for DMFC Application -- 9 Electrospinning Parameters -- 10 Future Directions and Conclusion -- References -- 8 A Basic Overview of Fuel Cells: Thermodynamics and Cell Efficiency -- Abstract -- 1 What Is a Fuel Cell? -- 2 Fuel Cell Structure and Classification -- 3 Fuel Cell Construction. , 4 PEMFC Types, Electrode Reactions, and Cell Potential -- 4.1 H2/O2 PEMFC -- 4.2 Direct Methanol Fuel Cells (DMFC) -- 4.3 Direct Ethanol Fuel Cells (DEFC) -- 4.4 Direct Formic Acid Fuel Cells (DFAFC) -- 4.5 Direct Borohydride Fuel Cells (DBFCs) -- 5 Fuel Cell Thermodynamics -- 5.1 Effect of Temperature -- 5.2 Effect of Pressure -- 5.3 Effect of Concentration of Reactant -- 6 Fuel Cell Efficiency -- 6.1 Losses in Actual System -- 6.2 Activation Overpotential -- 6.3 Ohmic Polarization Losses -- 6.4 Mass Transport Overpotential -- 7 Conclusion -- References -- 9 Organic/Inorganic and Sulfated Zirconia Nanocomposite Membranes for Proton-Exchange Membrane Fuel Cells -- Abstract -- 1 Introduction -- 1.1 Proton-Exchange Membranes (PEMs) -- 2 Organic/Inorganic Hybrid Membranes -- 3 Organic-Sulfated Metal Oxide Hybrid Membrane -- 4 Sulfated Zirconia Nanocomposite Membranes -- 5 Conclusion and Future Prospects -- Acknowledgements -- References -- 10 Electrochemical Promotional Role of Under-Rib Convection-Based Flow-Field in Polymer Electrolyte Membrane Fuel Cells -- Abstract -- 1 Introduction -- 2 General Description of Performance Improvements in PEMFCs -- 2.1 Proton Exchange Membrane -- 2.2 Electrode and Catalyst -- 2.3 Gas Diffusion Layer -- 2.4 Membrane Electrode Assembly -- 2.5 Bipolar Plate -- 2.6 Single Cell and Stack -- 2.6.1 Water and Heat Management -- 2.6.2 Fuel Crossover, Oxidation, and CO Poisoning -- 2.6.3 Scale-up and Long-Term Experiments -- 3 Structured Techniques for Flow-Field Optimization -- 3.1 Experimental Approaches to Flow-Field Optimization -- 3.1.1 Current Density Measurement -- 3.1.2 Flow Visualization -- 3.1.3 Polarization Curve Evaluation -- 3.2 Modeling Approaches to Flow Optimization -- 3.2.1 Computational Fluid Dynamic Modeling -- 3.2.2 Two-Phase Modeling for Water Management -- 3.2.3 Complex Flow-field Interaction Modeling. , 3.3 Validation of Experimental and Numerical Results -- 4 New Flow-field Optimization Approaches Utilizing Under-Rib Convection -- 4.1 Homogeneous Distribution of the Reactants -- 4.2 Uniformity of Temperature and Current Density Distributions -- 4.3 Facilitation of Liquid Water Discharge -- 4.4 Reduction in Pressure Drop -- 4.5 Improvement in Output Power -- 5 Summary -- References -- 11 Methods for the Preparation of Organic-Inorganic Nanocomposite Polymer Electrolyte Membranes for Fuel Cells -- Abstract -- 1 Introduction -- 2 Methods for Preparation of Nanocomposite Polymer Electrolyte Membranes -- 2.1 Blending of Nanoparticles in Polymer Matrix -- 2.1.1 Phase Inversion Method for Preparation of PEMs -- 2.1.2 Solution Casting Method -- 2.1.3 Hot Press -- 2.2 Doping or Infiltration and Precipitation of Nanoparticles and Precursors -- 2.3 Self-assembly of Nanoparticles -- 2.4 Non-hydrolytic Sol-Gel (NHSG) Method -- 2.5 Layer-by-Layer Fabrication Method -- 2.6 Nonequilibrium Impregnation Reduction -- 2.7 Surface Patterning Method -- 3 Future Directions and Conclusion -- References -- 12 An Overview of Chemical and Mechanical Stabilities of Polymer Electrolytes Membrane -- Abstract -- 1 Introduction -- 2 Durability of Polymer Electrolyte Membrane (PEM) -- 3 Proton Conductivity of PEM -- 4 Chemical Stabilities and Degradation of PEM -- 5 Mechanical Stability and Degradation of PEM -- 6 Conclusion -- Acknowledgements -- References -- 13 Electrospun Nanocomposite Materials for Polymer Electrolyte Membrane Fuel Cells -- Abstract -- 1 Introduction -- 2 Electrospinning Process -- 2.1 Electrospun Fibers -- 2.1.1 Poly(vinylidene fluoride) (PVDF) -- 2.1.2 Poly(vinyl alcohol) (PVA) -- 2.1.3 Poly(phenylene oxide) (PPO) -- 2.1.4 Poly(arylene ether)s -- 2.1.5 Poly(imide)s -- 2.1.6 Poly(benzimidazole) (PBI) -- 2.2 Crosslinking of Electrospun Fibers. , 2.3 Interface Bonding -- 3 Reducing Methanol Crossover -- 4 Improving Proton Conductivity -- 4.1 Electrospinning of Nafion -- 4.2 Aligned Nanofibers -- 5 Other Applications of Electrospinning in Fuel Cells -- 6 Conclusion -- References -- 14 Fabrication Techniques for the Polymer Electrolyte Membranes for Fuel Cells -- Abstract -- 1 Introduction -- 2 Recent Developments of PEM-Based on Organic-Inorganic Nanocomposites -- 3 Fabrication Techniques for the Preparation of PEM -- 3.1 Different Polymerization Routes -- 3.2 Plasma Methods -- 3.3 Sol-Gel Method -- 3.4 Ultrasonic Coating Technique -- 3.5 Phase Inversion Method -- 3.6 In Situ Reduction -- 3.7 Catalyst-Coated Membrane by Screen Printing Method -- 3.8 Solution Casting Method -- 3.9 Other Methods -- 4 Summary -- Acknowledgements -- References -- 15 Chitosan-Based Polymer Electrolyte Membranes for Fuel Cell Applications -- Abstract -- 1 Introduction -- 2 Chitosan: An Overview -- 3 Characterization of the Polymer Membrane and Their Desired Properties -- 4 Chitosan Based Membranes for Polymer Electrolyte -- 4.1 Chitosan Blend Polymer Electrolyte -- 4.2 Chitosan Cross-Linked Polymer Electrolyte -- 4.3 Chitosan Polymer Composite Based Polymer Electrode -- 5 Chitosan for Fuel Cell -- 6 Chitosan for Biofuel Cell -- 6.1 Microbial Biofuel Cell -- 6.2 Enzymatic Biofuel Cell -- 7 Conclusions -- Acknowledgements -- References -- 16 Fuel Cells: Construction, Design, and Materials -- Abstract -- 1 Introduction -- 2 Different Types of Fuel Cells -- 3 Construction and Design of Different FC -- 3.1 PEMFC -- 3.2 DMFC -- 3.3 AEMFC -- 3.4 PAFC -- 3.5 SOFC -- 3.6 MCFC -- 4 Catalysts for Different FCs -- 5 Materials and Methods for Preparation of PEM for Fuel Cells -- 6 Characterizations and Characteristic Properties of PEM for Different FC -- 7 Summary -- References. , 17 Proton Conducting Polymer Electrolytes for Fuel Cells via Electrospinning Technique.
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  • 8
    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Green chemistry. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (299 pages)
    Edition: 1st ed.
    ISBN: 9783030678845
    Series Statement: Advances in Science, Technology and Innovation Series
    DDC: 660.0286
    Language: English
    Note: Intro -- Contents -- 1 Biomass-Derived Polyurethanes for Sustainable Future -- Abstract -- 1 Introduction -- 1.1 Chemicals for Preparation of Polyurethanes -- 1.2 Importance of Green Chemicals and Synthesis Methods -- 1.3 Characteristics of Biomaterials for Polyurethanes -- 2 Bio-Oils as a Renewable Resource for Polyurethanes -- 2.1 Epoxidation and Ring-Opening Reactions -- 2.2 Hydroformation and Hydrogenation Reactions -- 2.3 Ozonolysis -- 2.4 Thiol-Ene Reaction -- 2.5 Transesterification Reaction -- 3 Terpenes as Green Starting Chemicals for Polyurethanes -- 4 Lignin for Green Polymers -- 5 Conclusion -- References -- 2 Mechanochemistry: A Power Tool for Green Synthesis -- Abstract -- 1 Introduction -- 2 History of Mechanochemistry -- 3 Principles of Mechanochemistry -- 3.1 Mechanisms and Kinetics of Mechanochemistry -- 3.2 Effects of Reaction Parameters -- 4 Mechanochemical Synthesis of Materials -- 4.1 Mechanochemical Synthesis of Co-crystals -- 4.2 Mechanochemistry in Inorganic Synthesis -- 4.3 Mechanochemistry in Organic Synthesis -- 4.4 Mechanochemistry in Metal-Organic Frameworks (MOFs) -- 4.5 Mechanochemistry in Porous Organic Materials (POMs) -- 4.6 Mechanochemical Synthesis of Polymers -- 5 Conclusions -- References -- 3 Future Trends in Green Synthesis -- Abstract -- 1 Introduction -- 2 Green Chemistry Metrics -- 2.1 Atom Economy (AE) -- 2.2 Environmental Factor (E Factor) -- 2.3 Process Mass Intensity (PMI) -- 2.4 Reaction Mass Efficiency (RME) -- 3 Application of Green Concept in Synthesis -- 3.1 Solvent-Based Organic Synthesis -- 3.2 Aqueous Medium -- 3.2.1 Micellar Media -- 3.2.2 Different Non-Aqueous Media -- Ionic Liquids -- Fluorous Media -- Supercritical Fluid -- Solvent-Free Synthesis -- 4 Future Trends -- References -- 4 Plant-Mediated Green Synthesis of Nanoparticles -- Abstract -- 1 Introduction. , 2 Methods for Metallic Nanoparticle Biosynthesis -- 3 Green Biosynthesis of Metallic NPs -- 3.1 Gold Nanoparticles -- 3.2 Platinum Nanoparticles -- 3.3 Silver Nanoparticles -- 3.4 Zinc Oxide Nanoparticles -- 3.5 Titanium Dioxide Nanoparticles -- 4 Different Parts Used for the Synthesis of Metallic Nanoparticles -- 4.1 Fruit -- 4.2 Stem -- 4.3 Seeds -- 4.4 Flowers -- 4.5 Leaves -- 5 Conclusions -- References -- 5 Green Synthesis of Hierarchically Structured Metal and Metal Oxide Nanomaterials -- Abstract -- 1 Introduction -- 2 Advantages of Green Synthesis Methods -- 3 Green Synthesis Methods for Hierarchically Structured Metal and Metal Oxide Nanomaterials -- 3.1 Biological Methods -- 3.1.1 Using Microorganism -- Microorganisms as Reactant -- Microorganism as Template -- 3.1.2 Using Plant -- Plant as Reactant -- Plant as Template -- 3.1.3 Using Other Green Templates -- 3.2 Physical and Chemical Methods -- 3.2.1 Green Techniques -- 3.2.2 Green Reagents -- 3.2.3 Green Solvents -- 4 Growth Mechanism of Metal and Metal Oxide HSNs -- 4.1 Biological Method -- 4.1.1 Biomolecules as Reagents -- 4.1.2 Biomolecules as Templates -- 4.2 Physical and Chemical Methods -- 5 Applications of Hierarchically Structured Metal and Metal Oxide Nanomaterials -- 5.1 Biomedical Application -- 5.2 Environmental Remediation -- 5.2.1 Wastewater Treatment -- 5.2.2 Energy Storage -- 5.2.3 Sensing -- 6 Present Challenges and Future Prospect -- Acknowledgements -- References -- 6 Bioprivileged Molecules -- Abstract -- 1 Introduction -- 2 Four Carbon 1,4-Diacids -- 2.1 Succinic Acid -- 2.2 Fumaric Acid -- 2.3 Malic Acid -- 3 Furan 2,5-Dicarboxylic Acid (FDCA) -- 4 3-Hydroxypropionic Acid (3-HPA) -- 5 Glucaric Acid -- 6 Glycerol -- 7 Aspartic Acid -- 8 Itaconic Acid -- 9 3-Hydroxybutyrolactone -- 10 Sorbitol -- 11 Xylitol -- 12 Glutamic Acid -- 13 Levulinic Acid. , 14 Emerging Molecules -- 15 Conclusion -- References -- 7 Membrane Reactors for Green Synthesis -- Abstract -- 1 Introduction -- 2 Chemical Reaction Enzymatic MR Using Supercritical CO2-IL -- 2.1 Ionic Liquid Media Effect on Free CLAB -- 2.2 Butyl Propionate Synthesis Using Active Membranes SC-CO2 and SC-CO2/IL -- 2.3 Butyl Propionate Synthesis Using Active Membranes in Hexane/IL -- 3 Mixed Ionic Electronic MR -- 3.1 Methane Flow Rate and Concentration Effects on Side II of Membrane -- 3.2 Steam Flow Effect on Side I of Membrane -- 3.3 Temperature Effect -- 4 Green Synthesis of Methanol in a Membrane Reactor -- 5 Green Fuel Energy -- 5.1 Green H2 Energy -- 5.2 Biofuel Energy -- 5.3 Green Fuel Additive -- 6 Biocatalyst Membrane Reactors -- 7 Photocatalytic Membrane Reactors -- 8 Conclusions -- References -- 8 Application of Membrane in Reaction Engineering for Green Synthesis -- Abstract -- 1 Introduction -- 2 Applications of Membrane Reactors in Reaction Engineering -- 2.1 Syngas Production -- 2.2 Hydrogen Production -- 2.3 CO2 Thermal Decomposition -- 2.4 Higher Hydrocarbon Production -- 2.5 Methane Production -- 2.6 Ammonia Production -- 3 Environmental Impacts -- 4 Conclusions and Future Recommendations -- Acknowledgements -- References -- 9 Photo-Enzymatic Green Synthesis: The Potential of Combining Photo-Catalysis and Enzymes -- Abstract -- 1 Introduction -- 2 Principle -- 3 Enzymes Involved in Light-Driven Catalysis -- 3.1 Heme-Containing Enzymes -- 3.1.1 Cytochrome P450 -- 3.1.2 Peroxidases -- 3.2 Flavin-Based Enzyme -- 3.2.1 Baeyer-Villiger Monooxygenases -- 3.2.2 Old Yellow Enzymes -- 3.3 Metal Cluster-Centered Enzyme -- 3.3.1 Hydrogenases -- 3.3.2 Carbon Monoxide Dehydrogenases -- 4 Nanoparticle-Based Activation of Enzyme -- 5 Applications in Photo-Biocatalysis -- 5.1 Isolated Enzymes/Cell Lysates -- 6 Summary and Future Scope -- References. , 10 Biomass-Derived Carbons and Their Energy Applications -- Abstract -- 1 Introduction -- 2 Types of Biomass Materials -- 2.1 Plant-Based Carbons -- 2.2 Fruit-Based Carbons -- 2.3 Animal-Based Carbons -- 2.4 Microorganism-Based Carbons -- 3 Activation of Biomass-Derived Carbons -- 3.1 Activation of Carbons -- 3.1.1 Chemical Activation of Carbons -- 3.1.2 Carbon Activation Through Physical Method -- 3.1.3 Self-activation of Carbons -- 3.2 Pyrolysis Techniques -- 3.2.1 Effect of Temperature -- 3.2.2 Effect of Residence Time -- 3.2.3 Heating Rate Effect -- 3.2.4 Size of the Particle -- 3.3 Microwave-Assisted Technique -- 3.4 Carbonization by Hydrothermal -- 3.5 Ionothermal Carbonization -- 3.6 Template Method -- 4 Energy Storage Applications of Biomass Carbons -- 4.1 Supercapacitors -- 4.2 Li/Na-Ion Batteries -- 5 Conclusion -- Acknowledgements -- References -- 11 Green Synthesis of Nanomaterials via Electrochemical Method -- Abstract -- 1 Introduction -- 2 Green Synthesis -- 2.1 Application of Biology in Green Synthesis -- 2.2 Green Synthesis Based on the Application of Solvent -- 3 Computational Data and Analysis -- 4 Electrochemical Method -- 5 Electrodeposition Method -- 5.1 Experimental Setup for Electrodeposition -- 6 Research Work: Using Green Electrochemical Methods for Nanomaterials Synthesis -- 7 Conclusion -- References -- 12 Microwave-Irradiated Synthesis of Imidazo[1,2-a]pyridine Class of Bio-heterocycles: Green Avenues and Sustainable Developments -- Abstract -- 1 Introduction -- 2 Microwave-Assisted Synthesis of 2-arylimidazo[1,2-a]pyridines [Abbreviated as 2-Aryl-IPs]. -- 2.1 Synthesis of Fused Bicyclic Heteroaryl Boronates and Imidazopyridine-Quinazoline Hybrids Under MW-irradiations -- 2.2 MW-Irradiated Synthesis of IPs Using Multi-Component Strategy Under Neat Conditions. , 2.3 One-Pot, Three-Component Synthesis of 2-Phenyl-H-Imidazo[1,2-α]pyridine Under MW-Irradiations -- 2.4 Microwave-Assisted Amine-Triggered Benzannulation Strategy for the Preparation of 2,8-Diaryl-6-Aminoimidazo-[1,2-a]pyridines -- 2.5 MW-Assisted NaHCO3-catalyzed Synthesis of Imidazo[1,2-a]pyridines in PEG400 Media and Its Practical Application in the Synthesis of 2,3-Diaryl-IP Class of Bio-Heterocycles -- 2.6 MW-Irradiated, Ligand-Free, Palladium-Catalyzed, One-Pot 3-component Reaction for an Efficient Preparation of 2,3-Diarylimidazo[1,2-a]pyridines -- 2.7 MW-Assisted Water-PEG400-mediated Synthesis of 2-Phenyl-IP via Multi-Component Reaction (MCR) -- 2.8 Microwave-Irradiated Synthesis of Imidazo[1,2-a]pyridines Under Neat, Catalyst-Free Conditions -- 2.9 Green Synthesis of Imidazo[1,2-a]pyridines in H2O -- 2.10 Microwave-Assisted Neat Synthesis of Substituted 2-Arylimidazo[1,2-a]Pyridines -- 2.11 Microwave-Assisted Nano SiO2 Neat Synthesis of Substituted 2-Arylimidazo[1,2-a]pyridines -- 2.12 Microwave-Assisted NaHCO3-Catalyzed Synthesis of 2-phenyl-IPs -- 3 Microwave-Assisted Synthesis of 3-amino-2-arylimidazo[1,2-a]pyridines [3-amino-2-aryl-IPs] -- 3.1 Microwave-Irradiated Synthesis of 3-aminoimidazo[1,2-a]pyridines via Fluorous Multi-component Pathway -- 3.2 MW-Irradiated Synthetic Protocol for 3-aminoimidazo[1,2-a]pyridines via MCR Pathway -- 3.3 MW-Assisted Sequential Ugi/Strecker Reactions Involving 3-Center-4-Component and 3-Center-5-Component MCR Strategy -- 3.4 One-Pot, 4-component Cyclization/Suzuki Coupling Leading to the Rapid Formation of 2,6-Disubstituted-3-Amino-IPs Under Microwave Irradiations -- 3.5 ZnCl2-catalyzed MCR of 3-aminoimidazo[1,2-a]pyridines Using MW Conditions -- 3.6 Microwave-Promoted Preparation of N-(3-arylmethyl-2-oxo-2,3-dihydroimidazo[1,2-a]pyridin-3-Yl)Benzamides. , 3.7 MW-Assisted Multi-component Neat Synthesis of Benzimidazolyl-Imidazo[1,2-a]pyridines.
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  • 9
    Online Resource
    Online Resource
    Dordrecht :Springer Netherlands,
    Keywords: Solvents. ; Electronic books.
    Description / Table of Contents: This book offers an overview of types of solvents and discusses their applications in extraction, organic synthesis, biocatalytic processes, production of fine chemicals, biochemical transformations, composite material, energy storage, polymers and more.
    Type of Medium: Online Resource
    Pages: 1 online resource (517 pages)
    Edition: 1st ed.
    ISBN: 9789400728912
    DDC: 541.3482
    Language: English
    Note: Intro -- Green Solvents II -- Preface -- Editor's Biography -- Acknowledgments -- Contents -- Contributors -- Chapter 1: Ionic Liquids as Green Solvents: Progress and Prospects -- 1.1 Introduction -- 1.2 History of Ionic Liquids (ILs) -- 1.3 Structure of Ionic Liquids (ILs) -- 1.3.1 Cations -- 1.3.2 Anions -- 1.4 Synthesis of Ionic Liquids (ILs) -- 1.4.1 Quaternization Reactions -- 1.4.2 Anion-Exchange Reactions -- 1.4.2.1 Lewis-Acid-Based Ionic Liquids (ILs) -- 1.4.2.2 Anion Metathesis -- 1.5 Properties of Ionic Liquids (ILs) -- 1.5.1 Melting Point -- 1.5.2 Volatility -- 1.5.3 Thermal Stability -- 1.5.4 Viscosity -- 1.5.5 Density -- 1.5.6 Polarity -- 1.5.7 Conductivity and Electrochemical Window -- 1.5.8 Toxicity -- 1.5.9 Air and Moisture Stability -- 1.5.10 Cost and Biodegradability -- 1.6 Solvent Properties and Solvent Effects -- 1.6.1 Solute-Ionic Liquids (ILs) Interactions -- 1.6.1.1 Interaction of Ionic Liquids (ILs) with Water -- 1.6.1.2 Interaction of Ionic Liquids (ILs) with Acid and Base -- 1.6.1.3 Interaction of Ionic Liquids (ILs) with Aromatic Hydrocarbon -- 1.6.1.4 Interaction with Chiral Substrates -- 1.7 Conclusions -- References -- Chapter 2: Ionic Liquids as Green Solvents for Alkylation and Acylation -- 2.1 Introduction -- 2.2 Alkylation -- 2.2.1 Ionic Liquids as Green Solvents -- 2.2.2 Ionic Liquids as Dual Green Solvents and Catalysts -- 2.2.3 Ionic Liquids Immobilized on Solid Supports -- 2.3 Acylation -- 2.3.1 Ionic Liquids as Green Solvents -- 2.3.2 Ionic Liquids in Dual Role as Green Solvents and Catalysts -- 2.3.3 Immobilized Ionic Liquids -- 2.4 Remarks -- References -- Chapter 3: Ionic Liquids as Green Solvents for Glycosylation Reactions -- 3.1 Introduction -- 3.2 Preparation of Acid-Ionic Liquids -- 3.3 Reusability of Acid-Ionic Liquids -- 3.4 Tunability and Basicity of Ionic Liquids. , 3.5 Nonvolatility of Ionic Liquids -- 3.6 Conclusions -- References -- Chapter 4: Ionic Liquid Crystals -- 4.1 Introduction -- 4.2 Ionic Liquid Crystals Based on Organic Cationsand Anions -- 4.2.1 Imidazolium-Based Ionic Liquid Crystals -- 4.2.2 Pyrrolidinium-Based Ionic Liquid Crystals -- 4.2.3 Pyridinium and Bipyridinium-Based IonicLiquid Crystals -- 4.2.4 Morpholinium-, Piperazinium-, and Piperidinium-BasedIonic Liquid Crystals -- 4.2.5 Ammonium-Based Ionic Liquid Crystals -- 4.2.6 Guanidinium-Based Ionic Liquid Crystals -- 4.2.7 Phosphonium-Based Ionic Liquid Crystals -- 4.2.8 Anions -- 4.3 Ionic Liquid Crystals Based on Metal Ions -- 4.4 Polymeric Ionic Liquid Crystals -- 4.4.1 Main-Chain Ionic Liquid-Crystalline Polymers -- 4.4.2 Side-Chain Ionic Liquid-Crystalline Polymers -- 4.4.3 Dendrimers -- 4.5 Applications of Ionic Liquid Crystals -- 4.6 Conclusions -- References -- Chapter 5: Application of Ionic Liquids in Extraction and Separation of Metals -- 5.1 Introduction -- 5.2 Processing Metal Oxides and Ores with Ionic Liquids -- 5.2.1 Metal Oxides Processing -- 5.2.2 Mineral Processing -- 5.3 Electrodeposition of Metals Using Ionic Liquids -- 5.3.1 Electrodeposition of Aluminum -- 5.3.2 Electrodeposition of Magnesium -- 5.3.3 Electrodeposition of Titanium -- 5.4 Ionic Liquids in Solvent Extraction of Metal Ions -- 5.5 Conclusions -- References -- Chapter 6: Potential for Hydrogen Sulfide Removal Using Ionic Liquid Solvents -- 6.1 Introduction -- 6.2 Ionic Liquids as Physical Solvents for H 2 S Removal -- 6.3 Hybrid Solvents Comprising Ionic Liquids and Amines -- 6.4 Conclusions and Outlook -- References -- Chapter 7: Biocatalytic Reactions in Ionic Liquid Media -- 7.1 Introduction -- 7.2 Biocatalyst Tested in Ionic Liquids -- 7.2.1 Lipases -- 7.2.2 Esterases and Proteases -- 7.2.3 Glycosidases -- 7.2.4 Oxidoreductases. , 7.3 Effect of the Ionic Liquid Composition on the Activity and Stability of Enzymes -- 7.4 Biotransformation in Ionic Liquids -- 7.4.1 Synthesis of Flavour Esters -- 7.4.2 Biotransformations of Polysaccharides and Nucleotides -- 7.4.3 Synthesis of Biodiesel -- 7.4.4 Synthesis of Polyesters -- 7.4.5 Resolution of Racemates -- 7.4.6 Synthesis of Carbohydrates -- 7.5 Conclusions -- References -- Chapter 8: Ionic Liquids/Supercritical Carbon Dioxide as Advantageous Biphasic Systems in Enzymatic Synthesis -- 8.1 Introduction -- 8.2 Supercritical Carbon Dioxide in Enzymatic Synthesis -- 8.3 Ionic Liquids as Reaction Media in Enzymatic Synthesis -- 8.4 Supercritical Carbon Dioxide/Ionic Liquid Biphasic System in Enzymatic Synthesis -- 8.5 Conclusions -- References -- Chapter 9: Ionic Liquids as Lubricants -- 9.1 Introduction -- 9.2 Overview of Ionic Liquids (ILs) -- 9.2.1 Definition and Types of Ionic Liquids (ILs) -- 9.2.2 Relationship Between Molecular Structure and Properties of Ionic Liquids (ILs) -- 9.3 Common Ionic Liquids (ILs) as Lubricants -- 9.3.1 Ionic Liquids (ILs) as Lubrication Oils -- 9.3.1.1 Ionic Liquids (ILs) as Lubrication Oils for Fe Alloy/Steel or Steel/Steel Contacts -- 9.3.1.2 Ionic Liquids (ILs) as Lubrication Oils of Light Alloys -- 9.3.1.3 Ionic Liquids (ILs) as Lubrication Oils for Specific Contacts -- 9.3.1.4 Ionic Liquids (ILs) as Lubrication Oils Under Vacuum -- 9.3.2 Ionic Liquids (ILs) as Lubrication Additives -- 9.3.2.1 Ionic Liquids (ILs) as Water Additives -- 9.3.2.2 Ionic Liquids (ILs) as Mineral Oil Additives -- 9.3.2.3 Ionic Liquids (ILs) as Synthetic Oil and Lubrication Grease Additives -- 9.3.2.4 Ionic Liquids (ILs) as Polymer Material Additives -- 9.3.3 Additives of Ionic Liquid (IL) Lubricants -- 9.3.4 Thin Films -- 9.4 Function of Ionic Liquids (ILs) as Lubricants. , 9.4.1 Function of Ionic Liquids (ILs) as Lubrication Oils -- 9.4.2 Function of Ionic Liquids (ILs) as Additives or Thin Films -- 9.5 Lubrication Mechanism -- 9.6 Conclusions and Outlook -- References -- Chapter 10: Stability and Activity of Enzymes in Ionic Liquids -- 10.1 Introduction -- 10.1.1 Ionic Liquid in Reference to Its Origin -- 10.1.2 Ionic Liquid as a Solvent -- 10.1.3 Enzymes in Ionic Liquids -- 10.2 Enzyme Stability in Ionic Liquids -- 10.2.1 Stability of Lipases -- 10.2.2 Stability of Monellin -- 10.2.3 Stability of Cytochrome c -- 10.2.4 Stability of α -Chymotrypsin -- 10.2.5 Stability of Penicillin G Acylase -- 10.3 Methods of Stabilizing Proteins/Enzymes in Ionic Liquids -- 10.3.1 Stabilization by Ionic Liquid Coating -- 10.3.2 Stabilization by Anchoring with Carbon Nanotubes -- 10.3.3 Stabilization by Capping with Nanoparticles -- 10.3.4 Stabilization by Entrapment in Hydrogels -- 10.3.5 Stabilization by Enzyme Modification -- 10.3.6 Stabilization by Emulsification of Ionic Liquids -- 10.4 Catalytic Activity of Enzymes in Ionic Liquids -- 10.4.1 Biotransformations by Lipases and Esterases -- 10.4.1.1 Esterification and Transesterification Reaction -- 10.4.1.2 Enantioselective Hydrolysis Reaction -- 10.4.1.3 Enantioselective Acylation Reaction -- 10.4.1.4 Kinetic Resolution of Alcohols -- 10.4.2 Reactions Catalyzed by Proteases -- 10.4.3 Carbohydrate Synthesis by Glycosidases -- 10.4.4 Hydrocyanation Reaction by Lyases -- 10.4.5 Biocatalytic Redox Reactions by Oxidoreductases -- 10.4.6 Enzymatic Polymerization Reaction in Ionic Liquids -- 10.5 Stability/Activity Vis-à-vis Solvent Property of Ionic Liquids: A Structure-Activity Relationship (SAR) Analysis -- 10.6 Conclusions -- References -- Chapter 11: Supported Ionic Liquid Membranes: Preparation, Stability and Applications -- 11.1 Introduction. , 11.2 Methods of Preparation and Characterization of Supported Ionic Liquid Membranes -- 11.3 Stability of Supported Ionic Liquid Membranes -- 11.4 Mechanism of Transport Through Supported Ionic Liquid Membranes -- 11.5 Fields of Application of Supported Liquid Membranes -- 11.6 Conclusions -- References -- Chapter 12: Application of Ionic Liquids in Multicomponent Reactions -- 12.1 Introduction -- 12.1.1 Ionic Liquids Based on 1-Butyl-3-methylimidazolium -- 12.1.1.1 1-Butyl-3-methylimidazolium -- 12.1.1.2 1-Butyl-3-methylimidazolium Hexafluorophosphate -- 12.1.1.3 1-n-Butyl-3-methylimidazolium Bromide -- 12.1.1.4 Butyl Methyl Imidazolium Hydroxide -- 12.1.1.5 Other 1-Butyl-3-methylimidazolium-Based Ionic Liquids -- 12.1.2 Other Imidazole-Based Ionic Liquids -- 12.1.2.1 Ionic Liquid-Supported Iodoarenes -- 12.1.2.2 1,3- n -Dibutylimidazolium Bromide -- 12.1.2.3 1- n -Butylimidazolium Tetrafluoroborate -- 12.1.2.4 1-Ethyl-3-methylimidazole Acetate -- 12.1.2.5 An Acidic Ionic Liquid -- 12.1.2.6 Task-Specific Ionic Liquids -- 12.1.2.7 1-Methyl-3-heptyl-imidazolium Tetrafluoroborate -- 12.1.2.8 1-[2-(Acetoacetyloxy)ethyl]-3-methylimidazolium Hexafluorophosphate-Bound Acetoacetate -- 12.1.2.9 1-[2-(Acetoacetyloxy)ethyl]-3-methylimidazolium Tetrafluoroborate- or Hexafluorophosphate-Bound b -oxo Esters -- 12.1.2.10 1-(2-Hydroxyethyl)-3-methylimidazolium Tetrafluoroborate or Hexafluorophosphate and N -(2-Hydroxyethyl)pyridinium Tetrafluoroborate or Hexafluorophosphate -- 12.1.2.11 PEG-1000-Based Dicationic Acidic Ionic Liquid -- 12.1.2.12 1-Ethyl-3-methylimidazolium ( S)-2-Pyrrolidinecarboxylic Acid Salt -- 12.1.2.13 1-Methyl-3-pentylimidazolium Bromide -- 12.1.2.14 3-Methyl-1-sulfonic Acid Imidazolium Chloride -- 12.1.3 Other Ionic Liquids -- 12.2 Conclusions -- References. , Chapter 13: Ionic Liquids as Binary Mixtures with Selected Molecular Solvents, Reactivity Characterisation and Molecular-Microscopic Properties.
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  • 10
    Online Resource
    Online Resource
    Cham :Springer International Publishing AG,
    Keywords: Carbon sequestration. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (284 pages)
    Edition: 1st ed.
    ISBN: 9783030293376
    Series Statement: Sustainable Agriculture Reviews Series ; v.38
    DDC: 577.14400000000001
    Language: English
    Note: Intro -- Preface -- Contents -- Chapter 1: Nanosponges for Carbon Dioxide Sequestration -- 1.1 Introduction -- 1.1.1 General Overview -- 1.1.2 Technologies to Capture CO2 -- 1.1.3 Functionalization -- 1.2 Characterization Techniques -- 1.2.1 N2 Adsorption/Desorption Isotherms at −196.15 °C -- 1.2.2 Transmission Electronic Microscopy -- 1.2.3 X Ray Diffraction -- 1.2.4 Elemental and Thermogravimetric Analysis -- 1.2.5 Nuclear Magnetic Resonance -- 1.2.6 Infrared Spectroscopy -- 1.2.7 Calorimetry -- 1.3 Amine-Functionalized Adsorbents -- 1.3.1 Amine Functionalized Zeolites -- 1.3.2 Amine Functionalized Activated Carbons -- 1.3.3 Amine Functionalized Metal Organic Frameworks -- 1.3.4 Amine-Functionalized Polymers -- 1.3.5 Amine-Functionalized Pore Expanded Silicas and Silica Nanosponges -- 1.3.6 Amine-Functionalized Modified Clays -- 1.4 Final Remarks -- References -- Chapter 2: Absorbents, Media, and Reagents for Carbon Dioxide Capture and Utilization -- 2.1 Introduction -- 2.2 Absorbents for Carbon Dioxide Capture and Subsequent Utilization -- 2.2.1 Amine Solution -- 2.2.2 Metal Hydroxide Solution -- 2.2.3 Ionic Liquid -- 2.2.4 Weak Base -- 2.2.5 Amino Acid Salt -- 2.2.6 Other Types of Absorbent -- 2.2.7 Overview -- 2.3 Conclusion -- References -- Chapter 3: Metal Oxides for Carbon Dioxide Capture -- 3.1 Introduction -- 3.2 Adsorption Technology for Carbon Dioxide Capture -- 3.3 High Temperature Solid Looping -- 3.3.1 Chemical Looping -- 3.4 Magnesium Oxide Based Adsorbents -- 3.4.1 Adsorption Mechanism -- 3.4.2 Performance Enhancement Strategies -- 3.5 Layered Double Oxides -- 3.5.1 Methodologies for Improving Capture Characteristics -- 3.6 Calcium Oxide Based Adsorbents -- 3.6.1 Strategies for Sustainable Reactivity -- 3.7 Metal Oxides for Oxygen Transfer in Chemical Looping Technology -- 3.8 Conclusions -- References. , Chapter 4: Hybrid Membranes for Carbon Capture -- 4.1 Introduction -- 4.2 Background -- 4.3 Mixed Matrix Membranes -- 4.3.1 Zeolites -- 4.3.2 Silica -- 4.3.3 Carbon Nano Tube -- 4.3.4 Carbon Molecular Sieve -- 4.3.5 Metal Organic Framework -- 4.3.6 Graphene -- 4.4 Preparation of Mixed Matrix Membranes -- 4.5 Summary and Outlook -- References -- Chapter 5: Ionic Liquids for Carbon Dioxide Capture -- 5.1 Introduction -- 5.2 Thermophysical Properties of Ionic Liquids -- 5.2.1 Viscosity -- 5.2.2 Thermal Stability -- 5.2.3 Biodegradability -- 5.3 Pure Ionic Liquids for CO2 Capture -- 5.3.1 Conventional Ionic Liquids -- 5.3.2 Task-Specific Ionic Liquids -- 5.3.3 Polymerized Ionic Liquids in CO2 Capture -- 5.4 CO2 Capture with Ionic Liquids Functionalized Solvents -- 5.4.1 Functionalizing the Anion of Ionic Liquid with Alkaline Group-NH2 -- 5.4.2 Attach the Anion of Ionic Liquid with Functional Group -- 5.5 CO2 Adsorption -- 5.5.1 Conventional Adsorbents -- 5.5.2 Solid Ionic Liquids -- 5.5.3 Supported Ionic Liquids onto a Solid Porous Material -- References -- Chapter 6: Carbon Sequestration in Alkaline Soils -- 6.1 Introduction -- 6.2 Management of Alkaline Soils -- 6.3 Carbon Stocks in Alkaline Soils -- 6.4 Factor Affecting Soil Carbon Degradation and Decomposition -- 6.5 Carbon Sequestration -- 6.6 Strategies for Carbon Sequestration in Alkaline Soils -- 6.6.1 Application of Amendments Containing Divalent Metals -- 6.6.2 Conservation Farming -- 6.6.3 Cover Crops -- 6.6.4 Manures and Composts -- 6.6.5 Crop Rotation/Selection -- 6.6.6 Biochar Intervention -- 6.6.7 Controlling Soil Erosion -- 6.6.8 Crop Residue Management -- 6.7 Conclusion and Future Research Opportunities -- References -- Chapter 7: Metal-Organic Frameworks for Carbon Dioxide Capture -- 7.1 Introduction -- 7.2 Literature Survey -- 7.2.1 Carbon Dioxide Capture and Storage. , 7.2.1.1 Carbon Dioxide Capture -- 7.2.1.2 Carbon Dioxide Transport and Storage -- 7.3 Current Carbon Dioxide Capture Technologies -- 7.3.1 Absorption- Amine Based Scrubbing -- 7.3.2 Absorption: Aqueous Ammonium Absorption -- 7.3.3 Surface Adsorption -- 7.4 Introduction to Metal-Organic Frameworks -- 7.4.1 Structure of Metal Organic Frameworks -- 7.4.2 MOF Properties and Applications -- 7.4.3 Zinc Based Metal Organic Frameworks (ZIFs) -- 7.5 Carbon Capture Using Metal Organic Frameworks -- 7.5.1 Adsorption of Carbon Dioxide on a Zirconium Based Metal Organic Framework (MOF) -- 7.5.1.1 Synthesis of Zirconium Based MOF (Zr-MOF) -- 7.5.1.2 Characterization of Prepared MOF -- 7.5.1.3 Results and Discussions -- 7.5.2 Adsorption of Carbon Dioxide on a Porous Carbon Material Derived from Zinc Based MOF -- 7.6 Conclusion -- References -- Chapter 8: Ionic Liquids for Carbon Dioxide Capture -- 8.1 Introduction -- 8.2 Ionic Liquids -- 8.3 Characteristics of Ionic Liquids -- 8.3.1 Melting Point -- 8.3.2 Critical Properties -- 8.3.3 Vapor Pressure -- 8.3.4 Thermal Stability -- 8.3.5 Density -- 8.3.6 Viscosity -- 8.3.7 Biodegradability -- 8.3.8 Solubility -- 8.3.9 Selectivity -- 8.3.10 Conductivity -- 8.4 Improving Ionic Liquids Performance -- 8.5 Previous Research -- 8.6 Important Factors for Choosing Suitable Ionic Liquid for Carbon Dioxide Capturing -- 8.7 Economic View -- 8.8 Challenge -- 8.9 Conclusion -- References -- Chapter 9: Methods for the Recovery of CO2 from Chemical Solvents -- 9.1 Introduction -- 9.2 Chemical and Physical Absorption -- 9.3 Characteristics of Chemical Solvents -- 9.3.1 Alkanolamines -- 9.3.2 Blend of Alkanolamines -- 9.3.3 Sterically Hindered Amines -- 9.3.4 Novel Amine-Based Solvents -- 9.3.5 Potassium Carbonate -- 9.3.6 Alkali Metal Hydroxide Solution -- 9.3.7 Ammonia Aqueous Solution -- 9.4 Methods of CO2 Recovery. , 9.4.1 Absorption/Desorption Process Through Packed Columns -- 9.4.2 Membrane Method -- 9.4.2.1 Polymeric Based Membranes -- 9.4.2.2 Ceramic and Metallic Membranes -- 9.4.2.3 Microporous Solid Membranes -- 9.4.3 Superiority of Membrane Method over Absorption/Desorption through Packed Columns Method -- 9.4.4 Membrane Flash Process -- 9.4.5 Eelectro Dialysis Membrane Process -- 9.4.6 Electrolysis Membrane Process -- 9.5 Conclusion -- References -- Chapter 10: Cryogenic CO2 Capture -- 10.1 Introduction -- 10.2 Pre-combustion Carbon Dioxide Capture -- 10.3 Oxy-Fuel Combustion Carbon Dioxide Capture -- 10.4 Post Combustion Carbon Dioxide Capture -- 10.5 Low Temperature Carbon Dioxide Capture Strategies -- 10.5.1 Cryogenic Distillation CO2 Capture -- 10.5.2 External Cooling Loop Cryogenic Carbon Dioxide Capture -- 10.5.3 Cryogenic Packed Bed -- 10.5.4 CO2 Cryogenic De-sublimation -- 10.5.5 Stirling Cooler Strategy -- 10.5.6 CryoCell System -- 10.5.7 Controlled Frosting Zone -- 10.6 Hybrid Methods for CO2 Capture -- 10.6.1 Cryogenic-Hydrate Technologies -- 10.6.2 Cryogenic -Membrane Technologies -- 10.6.3 Low Temperature Absorption Technologies -- 10.7 Advantages and Limitations of CO2 Capture Methods Based on Cryogenic Process -- 10.8 Conclusions -- References -- Index.
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