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  • 2015-2019  (3)
  • 1
    Online Resource
    Online Resource
    Millersville, PA :Materials Research Forum LLC,
    Keywords: Water-Electrolysis. ; Electronic books.
    Description / Table of Contents: Aiming at the generation of hydrogen from water, electrochemical water splitting represents a promising clean technology for generating a renewable energy resource. Keywords: Electrochemical Water Splitting, Renewable Energy Resource, Electrocatalysts, Oxygen Evolution Reaction (OER), Noble Metal Catalysts, Earth-Abundant Metal Catalysts, MOF Catalysts, Carbon-based Nanocatalysts, Polymer Catalysts, Transition Metal-based Electrocatalysts, Fe-based Electrocatalysts, Co-based Electrocatalysts, Ni-based Electrocatalysts, Metal Free Catalysts, Transition-Metal Chalcogenides, Prussian Blue Analogues.
    Type of Medium: Online Resource
    Pages: 1 online resource (251 pages)
    Edition: 1st ed.
    ISBN: 9781644900451
    Series Statement: Materials Research Foundations Series ; v.59
    DDC: 665.81
    Language: English
    Note: Intro -- front-matter -- Table of Contents -- Preface -- 1 -- Transition Metal-Based Electrocatalysts for Oxygen-Evolution Reaction beyond Ni, Co, Fe -- 1. Introduction -- 2. Towards transition metal alloys beyond Ni, Co and Fe applied for OER -- 3. Metal oxides for OER beyond Ni, Co, and Fe -- 3.1 Transition metal binary oxide-based electrocatalyst -- 3.2 Perovskites oxides electrocatalysts -- 4. Transition-metals carbides, nitrides, and phosphides applied for OER -- 4.1 Carbides -- 4.2 Nitrides -- 4.3 Phosphides -- Conclusions -- References -- 2 -- Fe-Based Electrocatalysts for Oxygen-Evolution Reaction -- 1. Introduction -- 2. Mechanism of oxygen evolution reaction -- 3. Fe-based catalysts for OER -- 3.1 Fe-based oxides catalysts -- 3.2 Fe-based (oxy)hydroxides catalysts -- 3.3 Fe-based lamellar layered double hydroxide catalysts -- 3.4 Other Fe-based composites -- Conclusions and Outlook -- References -- 3 -- Co-Based Electrocatalysts for Hydrogen-Evolution Reaction -- 1. Introduction -- 2. Various Co-based electrocatalysts -- 2.1 Co metal, alloy, and their composites -- 2.2 Co nitrides -- 2.3 Co phosphides -- 2.4 Co oxide -- 2.5 Cobalt (Co) sulfides -- 2.6 Cobal selenides -- 2.7 Binary nonmetal cobalt compounds -- Conclusions and outlook -- References -- 4 -- Metal Free Catalysts for Water Splitting -- 1. Introduction -- 1.1 Hydrogen evolution reaction (HER) -- 1.2 Oxygen evolution reaction (OER) -- 2. Factors affecting the efficiency of electrochemical water splitting -- 3. Electrochemical matrices used for determining talent of the catalyst -- 4. Electrocatalysts for overall water splitting -- 5. Carbon based metal free catalyst -- 5.1 Graphene based electrocatalysts for water splitting -- 5.2 Carbon nanotube based electrocatalysts for water splitting. , 5.3 Graphitic carbon nitride (g-C3N4) based electrocatalysts for overall water splitting -- 6. Future aspects and outlook -- Reference -- 5 -- Ni-Based Electrocatalyst for Full Water Splitting -- 1. Introduction -- 2. Water splitting -- 2.1 Brief history and basics of water splitting -- 2.2 Few parameters related to t oxygen evolution reaction, hydrogen evolution reaction and catalytic activity -- 2.3 Mechanism of electrochemical water splitting -- 2.3.1 Hydrogen evolution reaction (HER) -- 2.3.2 Oxygen evolution reaction (OER) -- 2.4 Recent advances on materials and performance of Ni based materials for overall water splitting -- 2.4.1 Ni- based oxides and hydroxides -- 2.4.2 Ni-based phosphides -- 2.4.3 Ni-based nitrides -- 2.4.4 Ni-based sulfides -- 2.4.4 Ni-based selenides -- Conclusions -- Acknowledgement -- References -- 6 -- Transition-Metal Chalcogenides for Oxygen-Evolution Reaction -- 1. Introduction -- 1.1 Mechanism of oxygen evolution reaction (OER) -- 1.2 Kinetic parameters used to find the suitable catalysts for OER -- 1.2.1 Overpotential -- 1.2.2. Exchange current density -- 1.2.3 Tafel equation and Tafel plot -- 1.2.4 Electrochemical active surface area (ECSA) -- 1.2.5 Faraday efficiency (FE) -- 1.3 Experimental methods used to study the OER behavior and stability of catalysts -- 2. Transition metal chalcogenides as replacement of state-of-art catalyst for OER -- 2.1 Transition metal sulphide for oxygen evolution reaction -- 2.2 Transition metal selenide for oxygen evolution reaction -- 2.3 Transition metal telluride for oxygen evolution reaction -- Conclusion and Future prospective -- References -- 7 -- Interface-Engineered Electrocatalysts for Water Splitting -- 1. The surface/interface mechanism in photoelectrochemical water splitting. , 2. Enhanced photoelectrochemical water splitting performance by interface-engineered electrocatalysts -- 2.1 Impurity doping -- 2.2 Surface plasmon resonance effect -- 2.3 Z-scheme system -- References -- 8 -- Application of Prussian Blue Analogues and Related Compounds for Water Splitting -- 1. Introduction -- 2. The coordination chemistry of Prussian blue analogues and other metal cyanides -- 3. Crystal structure of Prussian blue analogues and related coordination polymers -- 4. Photo-induced charge transfer in Prussian blue analogues and related solids -- 5. Electrochemical behavior of PBAs in aqueous solutions -- 6. The water splitting reaction using transition metal cyanides -- 6.1 Oxygen evolution reaction (OER) -- 6.2 Hydrogen evolution reaction (HER) -- 6.3 Use as co-catalyst in photoelectrochemical cells -- Concluding remarks -- Acknowledgments -- References -- 9 -- Ni-Based Electrocatalysts for Oxygen Evolution Reaction -- 1. Introduction -- 2. The mechanism involved in oxygen evolution reaction and judging parameters -- 3. Nickel based OER catalysts -- 3.1 Ni-hydroxide based OER catalysts -- 3.2 Ni-oxide based OER catalysts -- 3.3 Ni-sulphides and selenides for OER -- Conclusion -- Acknowledgements -- References -- back-matter -- Keyword Index -- About the Editors.
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  • 2
    Online Resource
    Online Resource
    Millersville, PA :Materials Research Forum LLC,
    Keywords: Inorganic compounds-Analysis. ; Electronic books.
    Description / Table of Contents: This is the very first book on the highly promising topic of MXenes; focusing on their fundamental characteristics and properties, fabrication techniques and applications. Keywords: MXenes, Nanomaterials, Two-dimensional Materials, Transition Metal Carbides, Transition Metal Nitrides, Electrical Conductivity, Hydrophilicity, Chemical Stability, Catalysis, Membrane Separation, Supercapacitors, Hybrid-ion Capacitors, Batteries, Flexible electronics, Hydrogen Storage, Nanoelectronics, Sensors, Energy R&D, Environmental Applications, Electronic Devices, Biomedical Applications.
    Type of Medium: Online Resource
    Pages: 1 online resource (224 pages)
    Edition: 1st ed.
    ISBN: 9781644900253
    Series Statement: Materials Research Foundations Series ; v.51
    DDC: 543.0858
    Language: English
    Note: Intro -- front-matter -- Table of Contents -- Preface -- 1 -- MXenes for Sensors -- 1. Introduction -- 2. Synthesis of MXenes -- 3. MXenes for sensing applications -- 3.1 Electronic sensors -- 3.2 Biosensing -- 4. Characterization -- 5. Final Remarks -- Acknowledgements -- References -- 2 -- A Newly Emerging MXene Nanomaterial for Environmental Applications -- 1. Introduction -- 2. Physiochemical properties of MXenes nanomaterials -- 2.1 Crystal structure -- 2.1.2 Surface chemical structure -- 2.1.3 Band gap structure -- 2.2 Synthesis of MXenes nanomaterials -- 3. MXenes for environmental application -- 3.1 Adsorption -- 3.1.1 Adsorption of organic pollutants -- 3.1.2 Adsorption of inorganic pollutants -- 3.1.3 Adsorption of gaseous pollutants -- 3.1.4 Adsorption of other pollutants -- 3.2 Photocatalysis -- 3.3 Antimicrobial activity -- 3.4 Membrane filtration -- Conclusion and remarks -- Acknowledgments -- References -- 3 -- Two-Dimensional MXene as a Promising Material for Hydrogen Storage -- 1. Introduction -- 2. Family of Mxenes -- 3. Structural properties of Mxenes -- 4. Preparation of Mxenes -- 5. Mxenes for hydrogen storage -- 6. Computational and theoretical study on hydrogen storage over MXenes -- 7. Experimental study of Mxenes -- Conclusion -- Acknowledgments -- References -- 4 -- MXenes for Electrocatalysis -- 1. Introduction -- 2. MXenes forHER -- 2.1 The mechanism of HER -- 2.2 MXene-based catalysts for HER -- 3. MXene for OER -- 3.1 The mechanism of OER -- 3.2 MXene-based catalysts for OER -- 4. MXene for NRR -- 4.1 The mechanism of NRR -- 4.2 MXene-based catalysts for NRR -- Conclusion and outlook -- References -- 5 -- MXenes Composites -- 1. Introduction -- 2. Significance of MXenes composites -- 3. MAX phases in MXenes -- 4. Processing of MXene composites -- 4.1 Synthesis of MXenes -- 4.2 Surface modifications. , 5. Structural and mechanical properties -- 6. Electronic properties -- 7. Surface state properties -- 8. Transport and optical properties -- 9. Magnetic properties -- 10. Applications of MXenes in different fields -- 10.1 Low work function emitters -- 10.2 Catalysts and photocatalysts for hydrogen evolution -- 10.3 Energy conversion for thermoelectric devices -- 10.4 Energy storage -- 10.5 Biomedical applications -- Conclusions -- References -- 6 -- MXenes for Supercapacitors -- 1. Introduction -- 2. Supercapacitor background -- 3. Synthesis approaches -- 3.1 MXene -- 3.2 Element doped MXenes -- 3.3 MXene-based nanocomposites -- 3.4 MXene quantum dots -- 4. Structures, properties and supercapacitor applications -- 4.1 Single/few-layered MXene-based supercapacitors -- 4.2 Element doped MXenes -- 4.3 MXene composites-based supercapacitors -- Summary and outlook -- References -- 7 -- MXenes for Sodium-Ion Batteries -- 1. Introduction -- 2. Na-ion batteries -- 3. Summary -- References -- 8 -- MXenes for Biomedical Applications -- 1. Introduction -- 2. MXenes as antibacterial agent -- 3. MXenes as biosensors -- 4. MXenes in bio-imaging -- 5. Therapeutic applications of MXenes -- Discussion -- References -- 9 -- MXene and its Sensing Applications -- 1. Introduction -- 2. MXenes based sensors -- 2.1 MXene for electrochemical (bio) sensing -- 2.2 MXenes for optical sensing -- 2.3 MXene for gas sensing -- 2.4 MXene for piezoresistive sensing -- Conclusion -- Abbreviations -- References -- back-matter -- Keyword Index -- About the Editors.
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  • 3
    Online Resource
    Online Resource
    Milton :Taylor & Francis Group,
    Keywords: Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (353 pages)
    Edition: 1st ed.
    ISBN: 9780429510885
    Language: English
    Note: Cover -- Half Title -- Title Page -- Copyright Page -- Table of Contents -- Preface -- Contributors -- Editors -- Chapter 1. Polythiophene-Based Battery Applications -- 1.1 Introduction -- 1.2 Synthesis -- 1.2.1 Electrochemical Polymerization -- 1.2.2 Chemical Synthesis -- 1.3 Battery Applications of PTs -- 1.3.1 PTs as Cathodic Materials -- 1.3.1.1 PTs as Active Materials -- 1.3.1.2 PTs as Binder -- 1.3.1.3 PTs as Conduction-Promoting Agents -- 1.3.2 PTs as Air Cathode -- 1.3.2.1 Li-Air Batteries -- 1.3.2.2 Aluminum-Air Battery -- 1.3.2.3 Zinc-Air Battery -- 1.3.3 PTs as Anodic Materials -- 1.3.3.1 PTs as Active Materials for Anode -- 1.3.3.2 PTs as Binders -- 1.3.3.3 PTs as Conduction Promoting Agents (CPAs) -- 1.3.4 PTs as Battery Separators -- 1.3.4.1 Li-Ion Batteries -- 1.3.4.2 Li-S Batteries -- 1.3.4.3 Li-O2 Batteries -- 1.3.5 PTs as Electrolytes -- 1.3.6 PTs as Coin-cell Cases -- 1.3.7 PTs as Li-O2 Catalyst -- 1.4 Conclusion -- References -- Chapter 2. Synthetic Strategies and Significant Issues for Pristine Conducting Polymers -- 2.1 Introduction -- 2.2 Conduction Mechanism -- 2.3 Synthesis of Conducting Polymers -- 2.3.1 Synthesis through Polymerization -- 2.3.1.1 Chain-Growth Polymerization -- 2.3.1.2 Step-Growth Polymerization -- 2.3.2 Synthesis by Doping with Compatible Dopants -- 2.3.2.1 Types of Doping Agents -- 2.3.2.2 Doping Techniques -- 2.3.2.3 Mechanism of Doping -- 2.3.2.4 Influence of Doping on Conductivity -- 2.3.3 Electrochemical Polymerization -- 2.3.4 Photochemical Synthesis -- 2.4 Various Issues for Synthesis -- 2.4.1 Vapor-Phase Polymerization -- 2.4.2 Hybrid Conducting Polymers -- 2.4.3 Nanostructure Conducting Polymers -- 2.4.4 Narrow Bandgap Conducting Polymers -- 2.4.5 Synthesis in Supercritical CO2 -- 2.4.6 Biodegradability and Biocompatibility of Conducting Polymers -- 2.5 Applications. , 2.6 Future Scope for Applications -- 2.7 Conclusions -- Abbreviations -- References -- Chapter 3. Conducting Polymer Derived Materials for Batteries -- 3.1 Introduction -- 3.2 Theory -- 3.3 Discussion on Conducting Polymer-Derived Materials -- 3.3.1 PEDOT Derivatives -- 3.3.1.1 Structural Properties -- 3.3.1.2 Electrochemical Studies of PEDOT and Its Derivatives -- 3.3.1.3 Magnetic Properties -- 3.3.2 PPy for the Energy-Storage Devices -- 3.3.2.1 Structural Property of PPy -- 3.3.2.2 Electrochemical Properties of Polypyrrol -- 3.3.2.3 Magnetic Properties -- 3.3.3 PANI for Battery Application -- 3.3.3.1 Structural Properties -- 3.3.3.2 Electrochemical Properties of PANI for Battery Electrode -- 3.3.3.3 Magnetic Properties of PANI -- 3.4 Summary and Conclusions -- References -- Chapter 4. An Overview on Conducting Polymer-Based Materials for Battery Application -- 4.1 Introduction -- 4.2 Principle of Conducting Polymer Battery -- 4.3 Assortment of Conducting Polymer Electrodes for Battery Application -- 4.4 Mechanism of Conducting Polymers in Rechargeable Batteries -- 4.5 Organic Conducting Polymer for Lithium-ion Battery -- 4.5.1 Types of Organic Conducting Polymers -- 4.6 Synthesis of Conducting Polymer -- 4.6.1 Hard-template Method -- 4.6.2 Soft-template Method -- 4.6.3 Template-free Technique -- 4.6.4 Self-Assembly or Interfacial -- 4.6.5 Electrospinning -- 4.7 Characterization -- 4.7.1 Surface Characterization by AFM and AFMIR -- 4.7.2 Transmission Electron Microscopy -- 4.7.3 Electrochemical Characterization -- 4.8 Applications of Various Conducting Polymers in Battery -- 4.8.1 Polyacetylene Battery -- 4.8.2 Polyaniline Batteries -- 4.8.3 Poly (p-phenylene) Batteries -- 4.8.4 Heterocyclic Polymer Batteries -- 4.9 Summary and Outlook -- References -- Chapter 5. Polymer-Based Binary Nanocomposites -- 5.1 Introduction -- 5.2 Binary Composites. , 5.3 Nanostructured CPs -- 5.4 Strategies to Improve Performance -- 5.4.1 Low-dimensional Capacitors -- 5.4.2 Hybrid Capacitors -- 5.4.2.1 Hybrid Electrode Material -- 5.5 CP/Carbon-based Binary Composite -- 5.6 CP/Metal Oxides Binary Composites -- 5.7 CP/Metal Sulfides Binary Complexes -- 5.8 Other Cp-supported Binary Complexes -- 5.9 Conclusion -- References -- Chapter 6. Polyaniline-Based Supercapacitor Applications -- 6.1 Introduction -- 6.2 Polyaniline (PANI) and Its Application Potential -- 6.3 Supercapacitors -- 6.3.1 PANI in Supercapacitors -- 6.3.2 PANI and Carbon Composites -- 6.3.3 PANI/Porous and Carbon Composites -- 6.3.4 PANI/Graphene Composites -- 6.3.5 PANI/CNTs Composites -- 6.3.6 Polyaniline Activation/Carbonization -- 6.3.7 Composites of Polyaniline with Various Conductive Polymer Blends -- 6.3.8 Composites of Polyaniline with Transition Metal Oxides -- 6.3.9 Composites of Polyaniline Core-Shells with Metal Oxides -- 6.3.10 PANI-modified Cathode Materials -- 6.3.11 PANI-modified Anode Materials -- 6.4 Redox-active Electrolytes for PANI Supercapacitors -- 6.5 Examples of Various Polyaniline-based Supercapacitor -- 6.5.1 Composites of Polyaniline Doped with CoCl2 as Materials for Electrodes -- 6.5.2 Composites of Polyaniline Nanofibers with Graphene as materials for electrodes -- 6.5.3 Composites of Polyaniline (PANI) with Graphene Oxide as Electrode Materials -- 6.5.4 Hybrid Films of Manganese Dioxide and Polyaniline as Electrode Materials -- 6.5.5 Composites of Activated Carbon/Polyaniline with Tungsten Trioxide as Electrode Materials -- 6.5.6 PANI- and MOF-based Flexible Solid-state Supercapacitors -- 6.5.7 Polyaniline-based Nickel Electrodes for Electrochemical Supercapacitors -- 6.5.8 Hydrogel of Ultrathin Pure Polyaniline Nanofibers in Supercapacitor Application -- Conclusion -- Acknowledgements -- References. , Chapter 7. Conductive Polymer-derived Materials for Supercapacitor -- 7.1 Introduction -- 7.2 Types of Supercapacitor -- 7.3 Parameters of Supercapacitors -- 7.4 Conducting Polymers (CPs) as Electrode Materials -- 7.4.1 Class of Conducting Polymer as Supercapacitor Electrode -- 7.5 Polyaniline (PANI)-based Electrode -- 7.6 Polypyrrole (PPy)-based Electrode -- 7.7 Polythiophene (PTh)-based Electrode -- 7.8 Conclusions -- Acknowledgement -- References -- Chapter 8. Conducting Polymer-Metal Based Binary Composites for Battery Applications -- 8.1 Conducting polymer (CPs) -- 8.2 Conducting polymers conductivity -- 8.3 Conducting polymer composites -- 8.3.1 Metal center nanoparticles -- 8.3.2 Metal nanoparticles -- 8.4 Conducting Polymer Based Binary Composites -- 8.4.1 Metal Matrix Composites (MMC) -- 8.4.2 Poly (Thiophene) composite -- 8.4.3 Poly (Para-Phenylene Vinylene) composite -- 8.4.4 Poly (Carbazole) composite -- 8.4.5 Vanadium oxide based conducting composite -- 8.4.6 PANI-V2O5 composite -- 8.4.7 Poly(N-sulfo propyl aniline)-V2O5 composite -- 8.5 Conducting polymer composite battery applications -- 8.5.1 Conducting polymer composite for Lithium-ion (Li+) based battery -- 8.5.2 Conducting polymer composites for Sodium-ion (Na+) based Battery -- 8.5.3 Conducting Polymer composite for Mg-Ion (Mg+2) Based Battery -- 8.6 Conducting polymer based composites for electrode materials -- References -- Chapter 9. Novel Conducting Polymer-Based Battery Application -- 9.1 Conducting Polymers (CPs) -- 9.1.1 Poly(Acetylene) -- 9.1.2 Poly(Thiophene) -- 9.1.3 Poly(Aniline) -- 9.1.4 Poly(Pyrrole) -- 9.1.5 Poly(Paraphenylene) and Poly(Phenylene) -- 9.2 Battery Applications of Conducting Polymers -- 9.2.1 Lithium Sulfide batteries -- 9.2.2 Binder for Lithium sulfide battery cathode -- 9.2.3 Sulfur encapsulation for electrode materials. , 9.2.4 Sulfur Encapsulation through Conductive Polymers -- 9.2.5 Conducting polymer anodes for Lithium sulfide battery -- 9.2.6 Conducting polymer as materials interlayer -- 9.3 Li+-ion-based Battery Applications of Conducting Polymers -- 9.4 Na+- ion-based Battery Applications of Conducting Polymers -- 9.5 Mg+2-ion-based Battery Applications of Conducting Polymers -- References -- Chapter 10. Conducting Polymer-Carbon-Based Binary Composites for Battery Applications -- Abbreviations -- 10.1 Introduction -- 10.2 Batteries -- 10.2.1 Types of Batteries -- 10.2.2 Electrode Materials -- 10.3 Conducting Polymer-Carbon-Based Binary Composite in Battery Applications -- 10.3.1 Polyaniline PANI-Carbon-Based Composite -- 10.3.2 Polypyrrole (PPy)-Carbon-Based Composite -- 10.3.3 Poly(3,4-ethylenedioxythiophene) (PEDOT)-Carbon-Based Composite -- 10.3.4 Others Conducting Polymer-Carbon-Based Composite -- 10.4 Conclusions -- Acknowledgements -- References -- Chapter 11. Polyethylenedioxythiophene-Based Battery Applications -- 11.1 Chemistry of PEDOT -- 11.1.1 PEDOT Synthesis and Morphology -- 11.1.1.1 Synthetic Techniques to Achieve Desired Morphologies -- 11.1.2 PEDOT-Based Nanocomposites -- 11.2 PEDOT-Based Polymers in Lithium-Sulfur Batteries -- 11.3 Lithium-Air Battery Based on PEDOT or PEDOT:PSS -- 11.3.1 PEDOT-Based Nanocomposites for Li-O2 Batteries -- 11.3.2 PEDOT:PSS-Based Li-O2 Battery Cathodes -- 11.4 Lithium and Alkali Ion Polythiophene Batteries -- 11.4.1 Cathodes -- 11.4.1.1 Cathode Binders and Composites -- 11.4.2 Anodes -- 11.4.2.1 Anode Binders and Composites -- 11.4.3 All-Polythiophene and Metal-Free Batteries -- References -- Chapter 12. Polythiophene-Based Supercapacitor Applications -- 12.1 Introduction -- 12.2 Properties of Polythiophene (PTh) -- 12.3 Synthesis of Polythiophene -- 12.4 Charge Storage in Polythiophene Electrochemical Capacitors. , 12.5 Polythiophene Electrode Fabrication.
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