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  • 1
    ISSN: 1520-5029
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie , Energietechnik , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Energy & fuels 8 (1994), S. 830-838 
    ISSN: 1520-5029
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie , Energietechnik , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Science Inc
    The @breast journal 9 (2003), S. 0 
    ISSN: 1524-4741
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Medizin
    Notizen: Abstract: It has been shown that early detection of breast cancer saves lives. Recently there has been increasing interest in nipple aspirate fluid as a potential avenue for breast cancer diagnosis. One major challenge regarding studies of nipple aspirate fluid is the ability to obtain adequate samples. Here we describe the use of nasal oxytocin in a group of volunteer women in order to increase the yield of nipple aspirate fluid. 
    Materialart: Digitale Medien
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  • 4
    ISSN: 1573-5079
    Schlagwort(e): Chlamydomonas reinhardtii ; mutagenesis ; photoinhibition ; Photosystem II ; repair cycle ; transformation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract The work outlines the isolation of transformant Chlamydomonas reinhardtii cells that appear to be unable to repair Photosystem II from photoinhibitory damage. A physiological and biochemical characterization of three mutants is presented. The results show differential stability for the D1 reaction center protein in the three mutants compared to the wild type and suggest lesions that affect different aspects of the Photosystem II repair mechanism. In the ag16.2 mutant, significantly greater amounts of D1 accumulate in the thylakoid membrane than in the wild type under steady-state growth conditions, and D1 loss is significantly retarded in the presence of the protein biosynthesis inhibitor chloramphenicol. Moreover, aberrant electrophoretic mobility of D1 in the ag16.2 suggests that this protein is modified to an as yet unknown configuration. These results indicate that the biosynthesis and/or degradation of D1 is altered in this strain. A different type of mutation occurred in the kn66.7 and kn27.4 mutants of C. reinhardtii. The stability of D1 declined much faster as a function of light intensity in these mutants than in the wild type. Thereby, the threshold of photoinhibition in these mutants was significantly lower than that in the wild type. It appears that kn66.7 and kn27.4 are similar conditional mutants, with the only difference between them being the amplitude of the chloroplast response to the mutation and the differential sensitivity they display to the level of irradiance.
    Materialart: Digitale Medien
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  • 5
    ISSN: 1573-5079
    Schlagwort(e): chlorophyll antenna size ; damage and repair cycle ; Dunaliella salina ; photoinhibition ; photosynthesis ; Photosystem-II ; photosystem stoichiometry ; productivity
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract High-light (HL) grown Dunaliella salina cells exhibit lower pigment content, a highly truncated chlorophyll (Chl) antenna size, and accumulation of photodamaged PS II centers in the chloroplast thylakoids (chronic photoinhibition). In HL-grown cells, the rate of photosynthesis saturated at higher irradiances and the quantum yield was lower compared to that of normally-pigmented low-light (LL) grown cells. In spite of these deficiencies, the light-saturated rate of photosynthesis for the HL-cells, when measured on a per chlorophyll basis, was ∼3 times greater than that of the LL-grown cells. To delineate the effect of photoinhibition from the Chl antenna size on quantum yield and rate of photosynthesis, HL-acclimated cells were switched to LL-conditions. Repair of photodamaged PS II, estimated from the recovery of functional PS II centers and from the increase in the quantum yield of photosynthesis, occurred with a half-time of ∼1 h. Chlorophyll accumulation in the cells occurred with a half-time of ∼4 h. The differential kinetics in repair versus Chl accumulation provided a ‘window of opportunity’, within about 2–3 h after the HL→LL shift, when cells exhibited a high quantum yield of photosynthesis, a small Chl antenna size and a light-saturated rate that was ∼6–9 times greater than that of the normally pigmented LL-grown cells. The work provides insight on the temporal sequence of events at the chloroplast and thylakoid membrane levels, leading from a chronic photoinhibition of PS II to repair and recovery. It is suggested that it is possible to maximize photosynthetic productivity and light utilization in mass microalgal cultures by minimizing the light-harvesting Chl antenna size of the photosystems.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Mathematical methods of operations research 51 (2000), S. 459-470 
    ISSN: 1432-5217
    Schlagwort(e): Key words: Newton-like method, variational inequality problems, superlinear convergence
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Mathematik , Wirtschaftswissenschaften
    Notizen: Abstract. In this paper, a Newton-like method for variational inequality problems is considered. One feature of the algorithm is that only the solution of linear systems of equations is required at each iteration and that the strict complementarity assumption is never invoked. Another is that under mild assumptions, the sequence produced by the Newton-like method Q-superlinearly converges to the solution of the VIP. Furthermore, a simpler version of this method is studied and it is shown that it is also superlinearly convergent.
    Materialart: Digitale Medien
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  • 7
    Publikationsdatum: 2022-05-26
    Beschreibung: Author Posting. © The Author(s), 2011. This is the author's version of the work. It is posted here by permission of Nature Publishing Group for personal use, not for redistribution. The definitive version was published in Nature Climate Change 2 (2012): 161-166, doi:10.1038/nclimate1353.
    Beschreibung: Subtropical western boundary currents are warm, fast flowing currents that form on the western side of ocean basins. They carry warm tropical water to the mid-latitudes and vent large amounts of heat and moisture to the atmosphere along their paths, affecting atmospheric jet streams and mid-latitude storms, as well as ocean carbon uptake. The possibility that these highly energetic and nonlinear currents might change under greenhouse gas forcing has raised significant concerns, but detecting such changes is challenging owing to limited observations. Here, using reconstructed sea surface temperature datasets and newly developed century-long ocean and atmosphere reanalysis products, we find that the post-1900 surface ocean warming rate over the path of these currents is two to three times faster than the global mean surface ocean warming rate. The accelerated warming is associated with a synchronous poleward shift and/or intensification of global subtropical western boundary currents in conjunction with a systematic change in winds over both hemispheres. This enhanced warming may reduce ocean's ability to absorb anthropogenic carbon dioxide over these regions. However, uncertainties in detection and attribution of these warming trends remain, pointing to a need for a long-term monitoring network of the global western boundary currents and their extensions.
    Beschreibung: This work is supported by China National Key Basic Research Project (2007CB411800) and National Natural Science Foundation Projects (40788002, 40921004). WC is supported by the Australian Climate Change Science program and the Southeast Australia Climate Initiative. HN is supported in part by the Japanese Ministry of Education, Culture, Sports, Science and Technology through Grant-in-Aid for Scientific Research on Innovative Areas #2205 and by the Japanese Ministry of Environment through Global Environment Research Fund (S-5). MJM is supported by NOAA’s Climate Program Office.
    Beschreibung: 2012-07-29
    Repository-Name: Woods Hole Open Access Server
    Materialart: Preprint
    Format: application/pdf
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  • 8
    Publikationsdatum: 2019-09-23
    Beschreibung: Subtropical western boundary currents are warm, fast-flowing currents that form on the western side of ocean basins. They carry warm tropical water to the mid-latitudes and vent large amounts of heat and moisture to the atmosphere along their paths, affecting atmospheric jet streams and mid-latitude storms, as well as ocean carbon uptake1, 2, 3, 4. The possibility that these highly energetic currents might change under greenhouse-gas forcing has raised significant concerns5, 6, 7, but detecting such changes is challenging owing to limited observations. Here, using reconstructed sea surface temperature datasets and century-long ocean and atmosphere reanalysis products, we find that the post-1900 surface ocean warming rate over the path of these currents is two to three times faster than the global mean surface ocean warming rate. The accelerated warming is associated with a synchronous poleward shift and/or intensification of global subtropical western boundary currents in conjunction with a systematic change in winds over both hemispheres. This enhanced warming may reduce the ability of the oceans to absorb anthropogenic carbon dioxide over these regions. However, uncertainties in detection and attribution of these warming trends remain, pointing to a need for a long-term monitoring network of the global western boundary currents and their extensions.
    Materialart: Article , PeerReviewed
    Format: text
    Format: text
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  • 9
    Publikationsdatum: 2021-09-29
    Beschreibung: Highlights • DGT is a feasible technique for simultaneous measurement of REEs in soils. • REE elution efficiencies ranged from 86.5% to 93.8% using 2 M HCl. • DGT uptake was independent of solution pH (3–9) and ionic strength (3 mM- 100 mM). • Chelex®100 DGT had capacities of 5.39–6.75 μg cm−2 for measurement of mixed REEs. A new method for simultaneous measurement of fifteen rare earth elements (REEs) [La (Ⅲ), Ce (Ⅲ), Pr (Ⅲ), Nd (Ⅲ), Sm (Ⅲ), Eu (Ⅲ), Gd (Ⅲ), Tb (Ⅲ), Dy (Ⅲ), Ho (Ⅲ), Er (Ⅲ), Tm (Ⅲ), Yb (Ⅲ), Lu (Ⅲ), and Y (Ⅲ)] was established in this study using the diffusive gradients in thin films (DGT) technique with Chelex®100 binding gel. Five different types of ion exchange resins (Chelex®100, D418, D001-cc, 001 × 7, and HSTY®-SS) were selected for the initial investigation of their adsorption performance for REEs. The Chelex®100 binding gel had the greatest uptake efficiencies of 〉95% for the fifteen REE ions, which was used for all subsequent experiments. The binding gel exhibited rapid binding dynamics to REEs in mixed solution of the fifteen REE ions. Elution efficiencies ranging from 86.5% to 93.8% for these REEs were obtained based on extraction using 2.0 M HCl. The Chelex®100 DGT uptake of the fifteen REE ions increased linearly with the deployment time and found to be independent of pH (3–9) and ionic strength (3 mM–100 mM). The capacities of Chelex®100 DGT for measurement of the mixed elements were determined at a range of 5.39–6.75 μg cm−2. Application of the DGT for soil analysis showed that Chelex®100 DGT was a useful tool in simultaneous measurement of the fifteen REE ions, even in a soil with high concentrations of REEs. This study demonstrated the advantage of Chelex®100 DGT in simultaneous measurement of the fifteen REE ions due to high uptake efficiencies and a wide tolerance to environmental interference.
    Materialart: Article , PeerReviewed
    Format: text
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  • 10
    Publikationsdatum: 2015-07-15
    Beschreibung: A novel method for chiral separation of flurbiprofen enantiomers was developed using aqueous two-phase extraction (ATPE) coupled with biphasic recognition chiral extraction (BRCE). An aqueous two-phase system (ATPS) was used as an extracting solvent which was composed of ethanol (35.0% w/w) and ammonium sulfate (18.0% w/w). The chiral selectors in ATPS for BRCE consideration were L-dioctyl tartrate and L-tryptophan, which were screened from amino acids , β-cyclodextrin derivatives, and L-tartrate esters. Factors such as the amounts of L-dioctyl tartrate and L-tryptophan, pH, flurbiprofen concentration, and the operation temperature were investigated in terms of chiral separation of flurbiprofen enantiomers. The optimum conditions were as follows: L-dioctyl tartrate, 80 mg; L-tryptophan, 40 mg; pH, 4.0; flurbiprofen concentration, 0.10 mmol/L; and temperature, 25 °C. The maximum separation factor α for flurbiprofen enantiomers could reach 2.34. The mechanism of chiral separation of flurbiprofen enantiomers is discussed and studied. The results showed that synergistic extraction has been established by L-dioctyl tartrate and L-tryptophan, which enantioselectively recognized R- and S-enantiomers in top and bottom phases, respectively. Compared to conventional liquid–liquid extraction, ATPE coupled with BRCE possessed higher separation efficiency and enantioselectivity without the use of any other organic solvents. The proposed method is a potential and powerful alternative to conventional extraction for separation of various enantiomers. Chirality 00:000–000, 2015 . © 2015 Wiley Periodicals, Inc.
    Print ISSN: 0899-0042
    Digitale ISSN: 1520-636X
    Thema: Chemie und Pharmazie
    Publiziert von Wiley-Blackwell
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