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  • 1
    Publication Date: 2023-10-26
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉In the Penninic nappe stack of the Western Alps, high‐ to ultrahigh‐pressure metamorphic ophiolites of the Zermatt‐Saas Zone are associated with slivers of continental crust. In one of these slivers, Monte Emilius, the overprinting of pre‐Alpine granulite‐facies rocks by subduction‐related, Alpine eclogite‐facies metamorphism can be studied. Mafic granulites were initially transformed into blueschists. In a second step, shear zones were developed in which the blueschists recrystallized to fine‐grained, foliated glaucophane eclogites, and eclogite veins. The combination of petrographic and field observations as well as whole‐rock compositions suggests that the eclogite assemblage formed only in shear zones where Ca‐metasomatism induced a change in major element composition. These substantial differences in bulk rock composition demonstrate how spatially limited eclogitization may be controlled by chemical redistribution, the degree of fabric development, and associated metamorphic reactions along fluid pathways. Thermodynamic modelling of selected bulk rock compositions yielded only slightly different conditions of 1.8 ± 0.1 GPa/550 ± 50°C for blueschist and 1.9–2.3 GPa/550 ± 50°C for eclogite, constraining Ca‐rich fluid infiltration and transformation to a depth of ~60–70 km. Eclogitization occurred in the Early Eocene at 52.96 ± 0.91 Ma, as indicated by a well‐defined Lu–Hf garnet isochron.〈/p〉
    Description: Deutsche Forschungsgemeinschaft (DFG) http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:552.4 ; eclogite ; Lu–Hf garnet geochronology ; Monte Emilius ; subduction ; thermodynamic modelling ; Zermatt–Saas zone
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2023-12-16
    Description: Cryptogamic organisms such as bryophytes and lichens cover most surfaces within tropical forests, yet their impact on the emission of biogenic volatile organic compounds is unknown. These compounds can strongly influence atmospheric oxidant levels as well as secondary organic aerosol concentrations, and forest canopy leaves have been considered the dominant source of these emissions. Here we present cuvette flux measurements, made in the Amazon rainforest between 2016–2018, and show that common bryophytes emit large quantities of highly reactive sesquiterpenoids and that widespread lichens strongly uptake atmospheric oxidation products. A spatial upscaling approach revealed that cryptogamic organisms emit sesquiterpenoids in quantities comparable to current canopy attributed estimates, and take up atmospheric oxidation products at rates comparable to hydroxyl radical chemistry. We conclude that cryptogamic organisms play an important and hitherto overlooked role in atmospheric chemistry above and within tropical rainforests.
    Description: Cryptogamic organisms such as bryophytes and lichens contribute substantially to emissions of secondary organic aerosol precursors as well as to the uptake of atmospheric oxidation products over the Amazon rainforest, suggest measurements at a remote Amazon rainforest site.
    Description: Bundesministerium für Bildung und Forschung (Federal Ministry of Education and Research) https://doi.org/10.13039/501100002347
    Description: https://doi.org/10.17871/atto.232.15.860
    Keywords: ddc:577.3 ; Atmospheric chemistry ; Biogeochemistry ; Plant sciences
    Language: English
    Type: doc-type:article
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  • 3
    Publication Date: 2023-12-19
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The MErcury Radiometer and Thermal Infrared Spectrometer instrument onboard the BepiColombo spacecraft is designed to investigate Mercury’s surface in the mid‐infrared (mid‐IR). Based on MESSENGER data and modeling, Mercury is thought to be evolved under highly reducing conditions (e.g., McCubbin et al., 2017, 〈ext-link ext-link-type="uri" xlink:href="https://doi.org/10.1002/2017JE005367"〉https://doi.org/10.1002/2017JE005367〈/ext-link〉; Namur & Charlier, 2017, 〈ext-link ext-link-type="uri" xlink:href="https://doi.org/10.1038/ngeo2860"〉https://doi.org/10.1038/ngeo2860〈/ext-link〉). The modeling also indicates that Mercury's surface is rich in feldspar. However, it is unknown if reducing conditions during the emplacement of volcanic melts have an influence on the IR properties of feldspars. Therefore, we investigated basaltic samples from the Bühl quarry in northern Hesse, Germany, that evolved under reducing conditions in the mid‐IR and compared the spectra with samples that experienced more oxidizing conditions during their formation. The Bühl samples are feldspar‐rich and contain metallic iron in some areas. Our investigations show that there are no differences between feldspars that formed under different oxidizing conditions. All spectral properties could be explained by well‐known factors that affect mid‐IR spectra of silicates.〈/p〉
    Description: Plain Language Summary: ESA's and Japan Aerospace Exploration Agency’s spacecraft BepiColombo is equipped, beside other instruments, with a thermal infrared (IR) radiometer and spectrometer called MErcury Radiometer and Thermal Infrared Spectrometer (MERTIS). For the accurate interpretation of the data from the MERTIS instrument, laboratory analog material is necessary. This analog material must fulfill different characteristics, such as different chemical and mineralogical compositions. Another not yet studied property is the availability of oxygen during the formation of the minerals. Depending on how much oxygen is available, different minerals form. However, this is an important feature, because Mercury is thought to have evolved under highly reducing conditions, as opposed to Earth where nearly all material formed significant more oxidizing conditions. One phase that is strongly associated with reducing magma formation conditions is metallic iron. There are only few natural outcrops on Earth, were stronger reducing conditions were present so that metallic iron could be formed. One of these outcrops is the Bühl quarry in northern Hesse, Germany. From there we used different samples to analyze the effect of oxygen availability on mid‐IR spectra of plagioclase feldspars.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉We present infrared spectra of basaltic samples from the Bühl, Hesse, Germany in preparation of the MERTIS experiment〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Comparison of feldspars formed at different oxygen fugacities showed no spectral differences〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉This is an important result for MERTIS, which will investigate Mercury that formed under reducing conditions〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: DLR
    Description: http://bc-mertis-pi.uni-muenster.de/
    Keywords: ddc:549 ; infrared reflectance spectroscopy ; feldspars ; Bühl basalt ; reducing conditions ; Mercury ; MERTIS
    Language: English
    Type: doc-type:article
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  • 4
    Publication Date: 2023-06-23
    Description: Feldspars are major components of terrestrial planetary surfaces. For future space application and the setup of a comprehensive reference database, Na- and K-rich alkali feldspars, NaAlSi3O8 – KAlSi3O8, have been investigated by infrared reflectance spectroscopy. We related the feldspar spectra to the chemical composition and state of Al,Si order/disorder. The infrared measurements were analyzed with respect to band shifts and peak shapes using the autocorrelation function. Natural samples served as starting materials. Some samples were treated by the alkali exchange method to produce pure end-members, which were then heated to generate various states of Al,Si disorder. X-ray diffraction (XRD) methods served to determine the Al,Si distribution. Our autocorrelation allowed to differentiate between the compositional and the order/disorder influences seen in the spectra in the wavelength range between 7 μm up to 14 μm (1429 cm− 1 to 714 cm− 1). Space missions often analyze the surfaces of planetary bodies using remote sensing. Therefore, our results are essential to characterize and distinguish alkali feldspars on the surfaces of terrestrial planetary bodies like Mercury.
    Description: Deutsches Zentrum für Luft- und Raumfahrt https://doi.org/10.13039/501100002946
    Keywords: ddc:549 ; Alkali feldspars ; Infrared spectroscopy ; X-ray diffraction ; Al,Si distribution
    Language: English
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  • 5
    Publication Date: 2023-07-20
    Description: The seismic activity of a planet can be described by the corner magnitude, events larger than which are extremely unlikely, and the seismic moment rate, the long‐term average of annual seismic moment release. Marsquake S1222a proves large enough to be representative of the global activity of Mars and places observational constraints on the moment rate. The magnitude‐frequency distribution of relevant Marsquakes indicates a $b$‐value of 1.06. The moment rate is likely between $1.55\times {10}^{15}\mathrm{N}\mathrm{m}/\mathrm{a}$ and $1.97\times {10}^{18}\mathrm{N}\mathrm{m}/\mathrm{a}$, with a marginal distribution peaking at $4.9\times {10}^{16}\mathrm{N}\mathrm{m}/\mathrm{a}$. Comparing this with pre‐InSight estimations shows that these tended to overestimate the moment rate, and that 30% or more of the tectonic deformation may occur silently, whereas the seismicity is probably restricted to localized centers rather than spread over the entire planet.
    Description: Plain Language Summary: The seismic moment rate is a measure for how fast quakes accumulate deformation of the planet's rigid outer layer, the lithosphere. In the past decades, several models for the deformation rate of Mars were developed either from the traces quakes leave on the surface, or from mathematical models of how quickly the planet's interior cools down and shrinks. The large marsquake that occurred on the 4th of May 2022 now allows a statistical estimation of the deformation accumulated on Mars per year, and thus to confront these models with reality. It turns out that, although there is a considerable overlap, the models published prior to InSight tend to overestimate the seismic moment rate, and hence the ongoing deformation on Mars. Possible explanations are that 30% or more of the deformation occurs silently, that is, without causing quakes, or that not the entire planet is seismically active but only specific regions.
    Description: Key Points: A single large marsquake suffices to constrain the global seismic moment rate. Pre‐InSight estimations tended to overestimate the moment rate. Either a significant part of the ongoing deformation occurs silent, or seismic activity is restricted to some activity centers, or both.
    Description: Eidgenössische Technische Hochschule Zürich http://dx.doi.org/10.13039/501100003006
    Description: National Aeronautics and Space Administration http://dx.doi.org/10.13039/100000104
    Description: UK Space Agency http://dx.doi.org/10.13039/100011690
    Description: Deutsches Zentrum für Luft‐ und Raumfahrt http://dx.doi.org/10.13039/501100002946
    Description: Insight SFI Research Centre for Data Analytics http://dx.doi.org/10.13039/501100021525
    Description: http://dx.doi.org/10.18715/SEIS.INSIGHT.XB_2016
    Description: http://doi.org/10.17189/1517570
    Keywords: ddc:523 ; Mars ; InSight ; seismic moment rate ; S1222a
    Language: English
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  • 6
    Publication Date: 2023-01-13
    Description: Massif‐type anorthosite and comagmatic associations of rutile‐bearing ilmenitite (RBI) and oxide‐apatite‐rich amphibolite (OARA) from the Chiapas Massif Complex (CMC) in southeastern Mexico display a protracted billion‐year accessory mineral record encompassing magmatic crystallization at c. 1.0 Ga to recent ductile shear deformation at c. 3.0 Ma. Multiple discrete zircon populations between these age end‐members resulted from neoformation/recrystallization during local to regional metamorphism that affected the southeastern portion of the CMC. The ubiquitous presence of relict baddeleyite (ZrO2), along with various zircon generations spatially associated with pristine to partly retrogressed Zr‐bearing igneous and metamorphic minerals (e.g., ilmenite, rutile, högbomite and garnet), suggests significant Zr diffusive re‐equilibration (exsolution) during slow cooling and mineral breakdown followed by crystallization of baddeleyite. The subsequent transformation of baddeleyite into zircon was likely driven by reaction with Si‐bearing fluids in several geochronologically identified metamorphic stages. Strikingly contrasting compositional signatures in coeval zircon from anorthosite (silicate‐dominated) and comagmatic RBI (Ti‐Fe‐oxide‐dominated) indicate a major role of fluids locally equilibrating with the rock matrix, as indicated by distinct zircon trace element and oxygen isotopic compositions. A high‐grade metamorphic event at c. 950 Ma is likely responsible for the formation of coarse‐grained rutile (~0.1–10 mm in diameter), srilankite, zircon and garnet with rutile inclusions as well as metamorphic högbomite surrounding Fe‐Mg spinel. Zr‐in‐rutile minimum temperatures suggest 〉730°C for this event, which may correlate to rutile‐forming granulite facies metamorphism in other Grenvillian‐aged basement rocks in Mexico and northern South America. A younger generation of baddeleyite exsolution occurred during post‐peak cooling of coarse‐grained rutile, reflected in rimward Zr depletion and formation of discontinuous baddeleyite coronas. Baddeleyite around rutile was then transformed into zircon possibly during subsequent metamorphism at c. 920 or 620 Ma, resulting from syn‐kinematic and contact metamorphism, respectively. Regional metamorphism at c. 450 and 250 Ma extensively overprinted the existing zircon population, especially during the Triassic event, as suggested by a significant presence of zircon with this age. Nearly pristine baddeleyite occurring interstitial to ilmenite yielded an isochron age of c. 232 Ma according to in situ U–Pb secondary ion mass spectrometry (SIMS), suggesting either formation during metamorphic peak conditions or post‐peak cooling. Zircon with ages of c. 80–100 Ma in anorthosite is identified for the first time within the CMC and coincides with cooling ages of c. 100 Ma for coarse‐grained rutile. This age is similar to those of rocks occurring ~200 km further to the east in Guatemala, which are also bounded to the Polochic fault system but overprinted by eclogite facies metamorphism. A high‐pressure event in the southern CMC after 200 Ma, however, is presently unsupported. Although the abundance of rutile and ilmenite is unusually high in the CMC anorthosite assemblage compared with common igneous rocks, the reactions documented here nonetheless stress the importance of these phases for generating Zr‐bearing accessory minerals over a wide range of metamorphic conditions.
    Description: Consejo Nacional de Ciencia y Tecnología (CONACYT) http://dx.doi.org/10.13039/501100003141
    Description: Deutsche Forschungsgemeinschaft (DFG)
    Keywords: ddc:549 ; Diffusion ; SIMS ; Srilankite ; Ti‐Fe deposits ; Ti‐in‐zircon ; Zr‐in‐rutile
    Language: English
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  • 7
    Publication Date: 2023-06-08
    Description: The consistent management of research data is crucial for the success of long-term and large-scale collaborative research. Research data management is the basis for efficiency, continuity, and quality of the research, as well as for maximum impact and outreach, including the long-term publication of data and their accessibility. Both funding agencies and publishers increasingly require this long term and open access to research data. Joint environmental studies typically take place in a fragmented research landscape of diverse disciplines; researchers involved typically show a variety of attitudes towards and previous experiences with common data policies, and the extensive variety of data types in interdisciplinary research poses particular challenges for collaborative data management. In this paper, we present organizational measures, data and metadata management concepts, and technical solutions to form a flexible research data management framework that allows for efficiently sharing the full range of data and metadata among all researchers of the project, and smooth publishing of selected data and data streams to publicly accessible sites. The concept is built upon data type-specific and hierarchical metadata using a common taxonomy agreed upon by all researchers of the project. The framework’s concept has been developed along the needs and demands of the scientists involved, and aims to minimize their effort in data management, which we illustrate from the researchers’ perspective describing their typical workflow from the generation and preparation of data and metadata to the long-term preservation of data including their metadata.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:550.2 ; Research data management ; Interdisciplinary environmental research ; Metadata ; Taxonomy
    Language: English
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  • 8
    Publication Date: 2023-08-18
    Description: Salinity observations in the Vietnamese upwelling area in June 2016 indicated a significant increase in the salinity of the maximum salinity water (MSW). The source of MSW inflow into the South China Sea (SCS) is a mixture of the Western North Pacific Central Water and the North Pacific Equatorial Water. Although the East Asian winter monsoon is correlated with both the El Niño Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO), the mean salinity of MSW is only spuriously lag correlated to the PDO, but highly correlated to all tropical climate modes (except El Niño Modoki) with a time lag up to 7 months. Composite analyses indicate that the modulation of ENSO by a PDO in a positive phase results in optimal inflow conditions. A comparison of two post-El Niño years with different PDO polarity (negative in 2003 and positive in 2016) shows that the dominant driver is the variability in outgoing long-wave radiation (OLR) and in zonal wind in the tropics. In 2003, enhanced convective activity over the West Pacific warm pool resulted in a cyclonic circulation. In 2016, convective activity was weak and an anticyclonic circulation was intensified, which transported the saltier North Pacific Equatorial Water into the SCS. This observed increase in the salinity of MSW requires a modification of the previous definitions of characteristic water masses, which is presented here. The question of whether or not the increase in MSW salinity is a transient phenomenon cannot be answered. It might be possible that the increase in salinity is related to global warming.
    Description: Deutsche Forschungsgemeinschaft DFG
    Description: Leibniz-Institut für Ostseeforschung Warnemünde (IOW) (3484)
    Keywords: ddc:551.46 ; ENSO ; PDO ; East Asian monsoon ; Water mass analysis ; South China Sea ; Western Tropical Pacific
    Language: English
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  • 9
    Publication Date: 2023-11-24
    Description: This study investigates the impact of increased global warming on heat stress changes and the potential number of people exposed to heat risks over Africa. For this purpose a heat index has been computed based on an ensemble‐mean of high‐resolution regional climate model simulations from the Coordinated Output for Regional Evaluations embedded in the COordinated Regional Climate Downscaling EXperiment, under two Representative Concentration Pathways (RCPs) scenarios (RCP2.6 and RCP8.5), combined with projections of population growth developed based on the Shared Socioeconomic Pathways (SSPs) scenarios (SSP1 and SSP5). Results show that by the late 21st century, the increased global warming is expected to induce a 12‐fold increase in the area extent affected by heat stress of high‐risk level. This would result in an increase of about 10%–30% in the number of days with high‐risk heat conditions, as well as about 6%–20% in their magnitude throughout the seasonal cycle over West, Central, and North‐East Africa. Therefore, and because of the lack of adaptation and mitigation policies, the exacerbation of ambient heat conditions could contribute to the exposure of about 2–8.5 million person‐events to heat stress of high‐risk level over Burkina Faso, Ghana, Niger, and Nigeria. Furthermore, it was found that the interaction effect between the climate change and population growth seems to be the most dominant in explaining the total changes in exposure due to moderate and high heat‐related risks over all subregions of the African continent.
    Description: Plain Language Summary: This study investigates the impact of increased global warming on heat stress changes and the potential number of persons likely to be exposed to heat risks over Africa. Results show that by the end of the 21st century, the increased global warming is expected to induce a 12‐fold increase in the total area affected by dangerous heat conditions over the continent. This would result in an increase of about 10%–30% in the number of days with these heat conditions, as well as about 6%–20% in their magnitude throughout the seasonal cycle over West, Central and North‐East Africa. Therefore, because of the lack of adaptation and mitigation policies, the exacerbation of ambient heat conditions could contribute to the exposure of about 2–8.5 million person‐events to heat stress of high‐risk level over Burkina Faso, Ghana, Niger, and Nigeria. Since these heat events would be partly driven by interactions effects between climate change and population growth, efficient measures allowing not only to mitigate the increased greenhouse gas emissions, but also the effects of high heat on the human body must be urgently implemented on the affected countries' scale, in order to significantly decrease the vulnerability of their populations to potential heat‐related health problems.
    Description: Key Points: Increased global warming induces more spatially and temporally widespread extreme heat events over West, Central and North‐East Africa. Populations of some West African countries are projected to be particularly exposed to moderate and high heat conditions. Change in population exposure to dangerous heat categories is mainly driven by the interaction effect between climate and population growth.
    Description: Deutscher Akademischer Austauschdienst http://dx.doi.org/10.13039/501100001655
    Description: Projekt DEAL
    Description: https://esg-dn1.nsc.liu.se/search/cordex/
    Description: https://esgf-data.dkrz.de/projects/esgf-dkrz/
    Description: https://www.isimip.org/gettingstarted/details/31
    Description: https://sedac.ciesin.columbia.edu/data/set/popdynamics-1-8th-pop-base-year-projection-ssp-2000-2100-rev01/data-download
    Description: https://cds.climate.copernicus.eu/cdsapp#!/dataset/reanalysis-era5-single-levels?tab=form
    Keywords: ddc:551.6 ; Africa ; climate change ; heat stress index ; global warming
    Language: English
    Type: doc-type:article
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  • 10
    Publication Date: 2024-02-28
    Description: The AlpArray experiment and the deployment of Swath-D together with the dense permanent network in Italy allow for detailed imaging of the spatio-temporal imaging complexity of seismic wave-fields within the greater Alpine region. The distance of any point within the area to the nearest station is less than 30 km, resulting in an average inter-station distance of about 45 km. With a much denser deployment in a smaller region of the Alps (320 km in length and 140 km wide), the Swath-D network possesses an average inter-station distance of about 15 km. We show that seismogram sections with a spatial sampling of less than 5 km can be obtained using recordings of these regional arrays for just a single event. Multiply reflected body waves can be observed for up to 2 h after source time. In addition, we provide and describe animations of long-period seismic wave-fields using recordings of about 1300–1600 broadband stations for six representative earthquakes. These illustrate the considerable spatio-temporal variability of the wave-field’s properties at a high lateral resolution. Within denser station distributions like those provided by Swath-D, even shorter period body and surface wave features can be recovered. The decrease of the horizontal wavelength from P to S to surface waves, deviations from spherically symmetric wavefronts, and the capability to detect multi-orbit arrivals are demonstrated qualitatively by the presented wave-field animations, which are a valuable tool for educational, quality control, and research purposes. We note that the information content of the acquired datasets can only be adequately explored by application of appropriate quantitative methods accounting for the considerable complexity of the seismic wave-fields as revealed by the now available station configuration.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Christian-Albrechts-Universität zu Kiel (3094)
    Keywords: ddc:551.22 ; Seismology ; Wave-fields ; Animations ; Alps ; AlpArray ; Swath-D
    Language: English
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