Beschreibung: Highlights: • Comparison of global NEMO and FESOM configurations with emphasis on the Agulhas system. • Both models simulate a reasonable and comparable large-scale circulation. • Both models have individual strengths and weaknesses to match the observations of the WBC system. • The numerical cost of FESOM is twice the one of NEMO. Abstract: Many questions in ocean and climate modelling require the combined use of high resolution, global coverage and multi-decadal integration length. For this combination, even modern resources limit the use of traditional structured-mesh grids. Here we compare two approaches: A high-resolution grid nested into a global model at coarser resolution (NEMO with AGRIF) and an unstructured-mesh grid (FESOM) which allows to variably enhance resolution where desired. The Agulhas system around South Africa is used as a testcase, providing an energetic interplay of a strong western boundary current and mesoscale dynamics. Its open setting into the horizontal and global overturning circulations also requires global coverage. Both model configurations simulate a reasonable large-scale circulation. Distribution and temporal variability of the wind-driven circulation are quite comparable due to the same atmospheric forcing. However, the overturning circulation differs, owing each model's ability to represent formation and spreading of deep water masses. In terms of regional, high-resolution dynamics, all elements of the Agulhas system are well represented. Owing to the strong nonlinearity in the system, Agulhas Current transports of both configurations and in comparison with observations differ in strength and temporal variability. Similar decadal trends in Agulhas Current transport and Agulhas leakage are linked to the trends in wind forcing. Although the number of 3D wet grid points used in FESOM is similar to that in the nested NEMO, FESOM uses about two times the number of CPUs to obtain the same model throughput (in terms of simulated model years per day). This is feasible due to the high scalability of the FESOM code.

Beschreibung: Highlights: • We coupled LA-ICP-MS Me/Ca single-chamber composition of four planktonic foraminifera with eddy induced hydrographic changes • The Mg/Ca-based temperature difference between N. dutertrei and G. scitula are likely to be an eddy proxy suitable for down-core application • Near-surface dwelling species inhabit well oxygenated surface waters and show lower test Mn/Ca values, compared to deeper dwelling species • Planktonic foraminifera Mn/Ca test values are in line with water column variability in dissolved Mn concentrations Hydrographic conditions in the Mozambique Channel are dominated by the passing of large anticyclonic eddies, propagating poleward into the upstream Agulhas area. Further south, these eddies have been found to control the shedding of Agulhas rings into the Atlantic ocean, thereby playing a key role in Indo-Atlantic Ocean exchange. The element composition of several planktonic foraminifera species collected from sediment trap samples, was compared to in situ water column data from the Mozambique Channel. Single-chamber trace element composition of these foraminifera reveals a close coupling with hydrographic changes induced by anticyclonic eddies. Obtained Mg/Ca values for the surface dwelling Globigerinoides ruber as well as the thermocline dwelling Neogloboquadrina dutertrei follow temperature changes and reduced temperature stratification during eddy conditions. At greater depth. Globorotalia scitula and Pulleniatina obliquiloculata record stable temperatures and thus respond to hydrographic changes with a deepening in habitat depth. Furthermore, test Mn/Ca values indicate a close relationship between water column oxygenation and Mn incorporation in these planktonic foraminiferal species

Beschreibung: A maximum in the strength of Agulhas leakage has been registered at the interface between the Indian and South Atlantic oceans during glacial Termination II (T-II). This presumably transported the salt and heat necessary for maintaining the Atlantic circulation at rates similar to the present day. However, it was never shown whether these waters were effectively incorporated into the South Atlantic gyre, or whether they retroflected into the Indian and/or Southern oceans. To resolve this question, we investigate the presence of paleo Agulhas rings from a sediment core on the central Walvis Ridge, almost 1800 km farther into the Atlantic Basin than previously studied. Analysis of a 60 yr data set from the global-nested INALT01 model allows us to relate density perturbations at the depth of the thermocline to the passage of individual rings over the core site. Using this relation from the numerical model as the basis for a proxy, we generate a time series of variability of individual Globorotalia truncatulinoides delta O-18. We reveal high levels of pycnocline depth variability at the site, suggesting enhanced numbers of Agulhas rings moving into the South Atlantic Gyre around T-II. Our record closely follows the published quantifications of Agulhas leakage from the east of the Cape Basin, and thus shows that Indian Ocean waters entered the South Atlantic circulation. This provides crucial support for the view of a prominent role of the Agulhas leakage in the shift from a glacial to an interglacial mode of the Atlantic circulation.

Beschreibung: Mesoscale eddies and meanders have been shown to be one of the dominant sources of flow variability in the world's ocean. One example of an isolated eddy hotspot is the South-West Indian Ridge (SWIR). Several investigations have shown that the SWIR and the corresponding planetary potential vorticity field (f/H) exert a strong influence on the location and dynamics of the Antarctic Circumpolar Current (ACC), resulting in substantial fragmentation of the jets downstream of the ridge. The easterly extension of this eddy corridor appears to be restricted to the deep channel separating the Conrad Rise from the Del Cano and Crozet Plateau. However, while the fate of eddies formed at the SWIR has been widely investigated and the frontal character of this eastward extension is well known, the zone of diminishing variability that extends southwards to approximately 60°S remains poorly sampled. Using a combination of Argo, AVISO and NCEP/NCAR datasets, the character of this eddy corridor as a conduit for warm core eddies to move across the ACC into the Antarctic zone is investigated. In this study, we track a single warm-core eddy as it moves southwards from an original position of 31°E, 50°20'S to where it dissipates 10 months later in the Enderby Basin at 56°20'S. An Argo float entrained within the eddy confirms that its water masses are consistent with water found within the Antarctic Polar Frontal Zone north of the APF. Latent and sensible heat fluxes are on average 8W/m2 and 10W/m2 greater over the eddy than directly east of this feature. It is estimated that the eddy lost an average of 5W/m2 of latent heat and 5W/m2 of sensible heat over a 1-year period, an amount capable of melting approximately 0.92m of sea ice. In addition, using an eddy tracking algorithm a total of 28 eddies are identified propagating southwards, 25 of which are anti-cyclonic in rotation. Based on the new Argo float data, combined with AVISO and NCEP/NCAR datasets, these results suggest that the southward passage of warm-core eddies act as vehicles transporting heat, salt and biota southwards across the ACC and into the eastern boundary of the Weddell gyre.

Beschreibung: Highlights: • Assessment of the Indian Ocean simulation from global forced sea- ice models. • SST biases are 2 times smaller in forced simulations than the coupled simulations. • Coupled model shows large inter-model spread over the eastern equatorial Indian Ocean. • Refinement in model horizontal resolution does not significantly improve simulations. • Uncover a secondary pathway of northward cross-equatorial transport along 75 °E. • Models are unable to capture the observed thick barrier layer in the north Bay of Bengal. Abstract: We present an analysis of annual and seasonal mean characteristics of the Indian Ocean circulation and water masses from 16 global ocean–sea-ice model simulations that follow the Coordinated Ocean-ice Reference Experiments (CORE) interannual protocol (CORE-II). All simulations show a similar large-scale tropical current system, but with differences in the Equatorial Undercurrent. Most CORE-II models simulate the structure of the Cross Equatorial Cell (CEC) in the Indian Ocean. We uncover a previously unidentified secondary pathway of northward cross-equatorial transport along 75 °E, thus complementing the pathway near the Somali Coast. This secondary pathway is most prominent in the models which represent topography realistically, thus suggesting a need for realistic bathymetry in climate models. When probing the water mass structure in the upper ocean, we find that the salinity profiles are closer to observations in geopotential (level) models than in isopycnal models. More generally, we find that biases are model dependent, thus suggesting a grouping into model lineage, formulation of the surface boundary, vertical coordinate and surface salinity restoring. Refinement in model horizontal resolution (one degree versus degree) does not significantly improve simulations, though there are some marginal improvements in the salinity and barrier layer results. The results in turn suggest that a focus on improving physical parameterizations (e.g. boundary layer processes) may offer more near-term advances in Indian Ocean simulations than refined grid resolution.

Beschreibung: Ballast water treatment is required for vessels to prevent the introduction of potentially invasive neobiota. Some treatment methods use chemical disinfectants which produce a variety of halogenated compounds as disinfection by-products (DBPs). One of the most abundant DBP from oxidative ballast water treatment is bromoform (CHBr3) where we find an average concentration of 894±560nmolL-1 (226±142μgL-1) in the undiluted ballast water from measurements and literature. Bromoform is a relevant gas for atmospheric chemistry and ozone depletion, especially in the tropics where entrainment into the stratosphere is possible. The spread of DBPs in the tropics over months to years is assessed here for the first time. With Lagrangian trajectories based on the NEMO-ORCA12 model velocity field, we simulate DBP spread in the sea surface and try to quantify the oceanic bromoform concentration and emission to the atmosphere from ballast water discharge at major harbours in the tropical region of Southeast Asia. The exemplary simulations of two important regions, Singapore and the Pearl River Delta, reveal major transport pathways of the DBPs and the anthropogenic bromoform concentrations in the sea surface. Based on our simulations, we expect DBPs to spread into the open ocean, along the coast and also an advection with monsoon-driven currents into the North Pacific and Indian Ocean. Furthermore, anthropogenic bromoform concentrations and emissions are predicted to increase locally around large harbours. In the sea surface around Singapore we estimate an increase in bromoform concentration by 9% compared to recent measurement. In a moderate scenario where 70% of the ballast water is chemically treated bromoform emissions to the atmosphere can locally exceed 1000pmolm-2h-1 and double climatological emissions. In the Pearl River Delta all bromoform is directly outgassed which leads to an additional bromine (Br) input into the atmosphere of 495kmolBr (∼42tCHBr3) a-1. From Singapore ports the additional atmospheric Br input is calculated as 312kmolBr (∼26tCHBr3) a-1. We estimate the global anthropogenic Br input from ballast water into the atmosphere of up to 13Mmola-1. This is 0.1% global Br input from background bromoform emissions and thus probably not relevant for stratospheric ozone depletion.

Beschreibung: The Agulhas Current, the western boundary current of the South Indian Ocean, has been shown to play an important role in the connectivity between the Indian and Atlantic oceans. The greater Agulhas Current system is highly dominated by mesoscale dynamics. To investigate their influence on the regional and global circulations, a family of high-resolution ocean general circulation model configurations based on the NEMO code has been developed. Horizontal resolution refinement is achieved by embedding “nests” covering the South Atlantic and the western Indian oceans at 1/10∘ (INALT10) and 1/20∘ (INALT20) within global hosts with coarser resolutions. Nests and hosts are connected through two-way interaction, allowing the nests not only to receive boundary conditions from their respective host but also to feed back the impact of regional dynamics onto the global ocean. A double-nested configuration at 1/60∘ resolution (INALT60) has been developed to gain insights into submesoscale processes within the Agulhas Current system. Large-scale measures such as the Drake Passage transport and the strength of the Atlantic meridional overturning circulation are rather robust among the different configurations, indicating the important role of the hosts in providing a consistent embedment of the regionally refined grids into the global circulation. The dynamics of the Agulhas Current system strongly depend on the representation of mesoscale processes. Both the southward-flowing Agulhas Current and the northward-flowing Agulhas Undercurrent increase in strength with increasing resolution towards more realistic values, which suggests the importance of improving mesoscale dynamics as well as bathymetric slopes along this narrow western boundary current regime. The exploration of numerical choices such as lateral boundary conditions and details of the implementation of surface wind stress forcing demonstrates the range of solutions within any given configuration.

Beschreibung: The consideration of marine biogeochemistry is essential for simulating the carbon cycle in an Earth system model. Here we present the implementation and evaluation of a marine biogeochemical model, Model of Oceanic Pelagic Stoichiometry (MOPS) in the Flexible Ocean and Climate Infrastructure (FOCI) climate model. FOCI-MOPS enables the simulation of marine biological processes, the marine carbon, nitrogen and oxygen cycles, air-sea gas exchange of CO2 and O2, and simulations with prescribed atmospheric CO2 or CO2 emissions. A series of experiments covering the historical period (1850–2014) were performed following the DECK (Diagnostic, Evaluation and Characterization of Klima) and CMIP6 (Coupled Model Intercomparison Project 6) protocols. Overall, modelled biogeochemical tracer distributions and fluxes, as well as transient evolution in surface air temperature, air-sea CO2 fluxes, and changes of ocean carbon and heat, are in good agreement with observations. Modelled inorganic and organic tracer distributions are quantitatively evaluated by statistically-derived metrics. Results of the FOCI-MOPS model, also including sea surface temperature, surface pH, oxygen (100–600 m), nitrate (0–100 m), and primary production, are within the range of other CMIP6 model results. Overall, the evaluation of FOCI-MOPS indicates its suitability for Earth climate system simulations

Beschreibung: Bromoform is the major by-product from chlorination of cooling water in coastal power plants. The number of power plants in East and Southeast Asian economies has increased rapidly, exceeding mean global growth. Bottom-up estimates of bromoform emissions based on few measurements appear to under-represent the industrial sources of bromoform from East Asia. Using oceanic Lagrangian analyses, we assess the amount of bromoform produced from power plant cooling-water treatment in East and Southeast Asia. The spread of bromoform is simulated as passive particles that are advected using the three-dimensional velocity fields over the years 2005/2006 from the high-resolution NEMO-ORCA0083 ocean general circulation model. Simulations are run for three scenarios with varying initial bromoform concentrations based on the range of bromoform measurements in cooling-water discharge. Comparing the modelled anthropogenic bromoform to in situ observations in the surface ocean and atmosphere, the two lower scenarios show the best agreement, suggesting initial bromoform concentrations in cooling water to be around 20–60 µg L−1. Based on these two scenarios, the model produces elevated bromoform in coastal waters of East Asia with average concentrations of 23 and 68 pmol L−1 and maximum values in the Yellow Sea, Sea of Japan and East China Sea. The industrially produced bromoform is quickly emitted into the atmosphere with average air–sea flux of 3.1 and 9.1 nmolm−2h−1 , respectively. Atmospheric abundances of anthropogenic bromoform are derived from simulations with the Lagrangian particle dispersion model FLEXPART based on ERA-Interim wind fields in 2016. In the marine boundary layer of East Asia, the FLEXPART simulations show mean anthropogenic bromoform mixing ratios of 0.4–1.3 ppt, which are 2–6 times larger compared to the climatological bromoform estimate. During boreal winter, the simulations show that some part of the anthropogenic bromoform is transported by the northeasterly winter monsoon towards the tropical regions, whereas during boreal summer anthropogenic bromoform is confined to the Northern Hemisphere subtropics. Convective events in the tropics entrain an additional 0.04–0.05 ppt of anthropogenic bromoform into the stratosphere, averaged over tropical Southeast Asia. In our simulations, only about 10 % of anthropogenic bromoform is outgassed from power plants located in the tropics south of 20∘ N, so that only a small fraction of the anthropogenic bromoform reaches the stratosphere. We conclude that bromoform from cooling-water treatment in East Asia is a significant source of atmospheric bromine and might be responsible for annual emissions of 100–300 Mmol of Br in this region. These anthropogenic bromoform sources from industrial water treatment might be a missing factor in global flux estimates of organic bromine. While the current emissions of industrial bromoform provide a significant contribution to regional tropospheric budgets, they provide only a minor contribution to the stratospheric bromine budget of 0.24–0.30 ppt of Br.

Beschreibung: Bottom pressure observations on both sides of the Atlantic basin, combined with satellite measurements of sea level anomalies and wind stress data, are utilized to estimate variations of the Atlantic Meridional Overturning Circulation (AMOC) at 11∘ S. Over the period 2013–2018, the AMOC and its components are dominated by seasonal variability, with peak-to-peak amplitudes of 12 Sv for the upper-ocean geostrophic transport, 7 Sv for the Ekman and 14 Sv for the AMOC transport. The characteristics of the observed seasonal cycles of the AMOC and its components are compared to results from an ocean general circulation model, which is known to reproduce the variability of the Western Boundary Current on longer timescales. The observed seasonal variability of zonally integrated geostrophic velocity in the upper 300 m is controlled by pressure variations at the eastern boundary, while at 500 m depth contributions from the western and eastern boundaries are similar. The model tends to underestimate the seasonal pressure variability at 300 and 500 m depth, especially at the western boundary, which translates into the estimate of the upper-ocean geostrophic transport. In the model, seasonal AMOC variability at 11∘ S is governed, besides the Ekman transport, by the geostrophic transport variability in the eastern basin. The geostrophic contribution of the western basin to the seasonal cycle of the AMOC is instead comparably weak, as transport variability in the western basin interior related to local wind curl forcing is mainly compensated by the Western Boundary Current. Our analyses indicate that while some of the uncertainties of our estimates result from the technical aspects of the observational strategy or processes not being properly represented in the model, uncertainties in the wind forcing are particularly relevant for the resulting uncertainties of AMOC estimates at 11∘ S.