Description: Establishing an accurate chronostratigraphy is essential in reconstructing paleoenvironmental changes in the Arctic Ocean. This requisition, however, has been impeded by the lack of biogenic remnants such as calcareous and siliceous microfossils, as well as alteration of paleomagnetic properties by post-depositional processes. Consequently, foundation of chronostratigraphy in the Arctic Ocean has been mostly relying on stratigraphic correlations. This study examines lithological features and physical properties of sediments of gravity core ARA03B-41GC02 collected in the Makarov Basin and correlates with previously studied cores from the western Arctic Ocean, in order to establish an age model that could eventually facilitate a precise reconstruction of paleoenvironmental changes in the western Arctic Ocean. Age control in the uppermost part was determined by AMS 14C dating of planktonic foraminifera and inter-core correlation was conducted in the upper ca. 3.8 m of the core which corresponded to MIS 15. Age constraints older than MIS 15 were treated using cyclostratigraphic model based on Mn-δ18O stack comparison, assuming that brown and high Mn concentration layers represent generally interglacial or interstadial periods. Based on our result, the core bottom corresponds to MIS 28 with an average sedimentation rate of ca. 0.5 cm/ky. The first appearance of detrital carbonate, planktonic foraminifera, and benthic foraminifera occurred during MIS 16, 11, and 7, respectively. MIS 16 is known as the coldest glacial period when δ18O of the LR04 stack first becomes heavier than 5‰; the occurrence of detrital carbonate likely transported from the Canadian Arctic indicates the initial buildup of the large ice sheets in the North America during this time. Since MIS 11 which is known as the warmest interglacial period during the late Pleistocene in the Northern Hemisphere, the appearance of planktonic foraminifera represents the warmer condition during interglacial periods in the western central Arctic Ocean. Additional geochemical and mineralogical proxies need to be conducted for better understanding of depositional environments and sediment provenance as well as transport pathways.

Description: The modern polar cryosphere reflects an extreme climate state with profound temperature gradients towards high-latitudes. It developed in association with stepwise Cenozoic cooling, beginning with ephemeral glaciations and the appearance of sea ice in the late middle Eocene. The polar ocean gateways played a pivotal role in changing the polar and global climate, along with declining greenhouse gas levels. The opening of the Drake Passage finalized the oceanographic isolation of Antarctica, some 40 Ma ago. The Arctic Ocean was an isolated basin until the early Miocene when rifting and subsequent sea-floor spreading started between Greenland and Svalbard, initiating the opening of the Fram Strait / Arctic-Atlantic Gateway (AAG). Although this gateway is known to be important in Earth’s past and modern climate, little is known about its Cenozoic development. However, the opening history and AAG’s consecutive widening and deepening must have had a strong impact on circulation and water mass exchange between the Arctic Ocean and the North Atlantic. To study the AAG’s complete history, ocean drilling at two primary sites and one alternate site located between 73°N and 78°N in the Boreas Basin and along the East Greenland continental margin are proposed. These sites will provide unprecedented sedimentary records that will unveil (1) the history of shallow-water exchange between the Arctic Ocean and the North Atlantic, and (2) the development of the AAG to a deep-water connection and its influence on the global climate system. The specific overarching goals of our proposal are to study: (1) the influence of distinct tectonic events in the development of the AAG and the formation of deep water passage on the North Atlantic and Arctic paleoceanography, and (2) the role of the AAG in the climate transition from the Paleogene greenhouse to the Neogene icehouse for the long-term (~50 Ma) climate history of the northern North Atlantic. Getting a continuous record of the Cenozoic sedimentary succession that recorded the evolution of the Arctic-North Atlantic horizontal and vertical motions, and land and water connections will also help better understanding the post-breakup evolution of the NE Atlantic conjugate margins and associated sedimentary basins.

Description: Organic-walled dinoflagellate cysts and acritarchs are a vital tool for reconstructing past environmental change, in particular in the Neogene of the high northern latitudes where marine deposits are virtually barren of traditionally used calcareous microfossils. Yet only little is known about the paleoenvironmental value of fossil assemblages that do not have modern analogues, so that reconstructions remain qualitative. Thus, extracting their paleoecological signals still poses a major challenge, in particular on pre-Quaternary timescales. Here we unravel the relationship between species relative abundance and sea surface temperature for extinct dinoflagellate cyst and acritarch taxa from the Neogene of the Iceland Sea using palynological assemblages and organic geochemical (alkenone) data generated from the same set of samples. The reconstructed temperatures for the Miocene to Pliocene sequence of Ocean Drilling Program Site 907 range from 3 to 26 °C and our database consists of 68 dinoflagellate cyst and acritarch samples calibrated to alkenone data. The temperature range of five extant species co-occurring in the fossil assemblage agrees well with their present-day distribution providing confidence to inferred temperature ranges for extinct taxa. The 14 extinct dinoflagellate cyst and acritarch species clearly exhibit a temperature dependency in their occurrence throughout the analysed section. The dinoflagellate cyst species Batiacasphaera hirsuta, Labyrinthodinium truncatum, Cerebrocysta irregulare, Cordosphaeridium minimum, Impagidinium elongatum and Operculodinium centrocarpum s.s., and the acritarch Lavradosphaera elongatum, which are confined to the Miocene, have highest relative abundances and restricted temperature ranges at the warm end of the reconstructed temperature spectrum. The latter five species disappear when Iceland Sea surface temperatures permanently drop below 20 °C, thus indicating a distinct threshold on their occurrence. In contrast, species occurring in both the Miocene and Pliocene interval (Batiacasphaera micropapillata, Habibacysta tectata, Reticulatosphaera actinocoronata, Cymatiosphaera? invaginata) show a broader temperature range and a tolerance towards cooler conditions. Operculodinium? eirikianum may have a lower limit on its occurrence at around 10 °C. The calibration of species relative abundance versus reconstructed sea surface temperature provides a quantitative assessment of temperature ranges for extinct Miocene to Pliocene species indicating that temperature is a decisive ecological factor for regional extinctions that may explain the frequently observed asynchronous highest occurrences across different ocean basins. It demonstrates that qualitative assessments of ecological preferences solely based on (paleo) biogeographic distribution should be treated with caution. In addition to enhancing knowledge on marine palynomorph paleoecology, this study ultimately improves the application of palynomorphs for paleoenvironmental reconstructions in the Neogene of the Arctic and subarctic seas, a region essential for understanding past global climate.

Description: The hydrogen isotopic composition (2H/1H, or d2H) of palmitic acid (PA) was measured in surface sediments from the Laptev and Kara Seas in the Russian Arctic to evaluate its use as a paleohydrographic proxy. d2HPA values in surface sediments varied by 118‰ over a 21 ppt range in mean annual surface salinity, and the two properties were highly correlated (R2 ¼ 0.8, p 〈 0.001) according to the relationship d2HPA ¼ 4.22 (±0.60)*S - 338 (±15). In contrast, d2H values of vascular plant wax n-alkanes (nC27, nC29, nC31) did not change systematically with salinity. These differing lipid d2H trends support the interpretation of PA as derived primarily from marine microalgae at these sites. Both the range and absolute values of d2HPA compared favorably to those predicted from published Arctic Ocean salinity and water isotope data and the expected response of d2HPA to salinity in cultured phytoplankton. Some 64e74% of the observed sedimentary d2HPA increase is estimated to have resulted from increasing d2Hwater values, with the remainder resulting from decreased 2H-discrimination during lipid biosynthesis at higher salinities. The large signal and high sensitivity of d2HPA to surface salinity changes in the Russian Arctic was exploited to test the hypothesis that floodwaters emanated from the Mackenzie River during the late deglacial period. Measurements of d2HPA were performed in a sediment core from the continental slope off the Mackenzie River in the Canadian Arctic. In samples from the top Bølling/Allerød-Younger Dryas period, reconstructed surface salinities (and d2HPA values) off the Mackenzie River declined from 20 ("253‰) to 16 ("269‰) before rebounding to 24 ("236‰) in the early Holocene, close to the modern value of ~25. A large salinity depression in the Canadian Arctic just prior to the start of the Younger Dryas would support the hypothesis of a northern routing of flood-waters from glacial Lake Agassiz via the Mackenzie River as a trigger for the Younger Dryas event.

Description: The modern polar cryosphere reflects an extreme climate state with profound temperature gradients towards high-latitudes. It developed in association with stepwise Cenozoic cooling, beginning with ephemeral glaciations and the appearance of sea ice in the late middle Eocene. The polar ocean gateways played a pivotal role in changing the polar and global climate, along with declining greenhouse gas levels. The opening of the Drake Passage finalized the oceanographic isolation of Antarctica, some 40 Ma ago. The Arctic Ocean was an isolated basin until the early Miocene when rifting and subsequent sea-floor spreading started between Greenland and Svalbard, initiating the opening of the Fram Strait / Arctic-Atlantic Gateway (AAG). Although this gateway is known to be important in Earth’s past and modern climate, little is known about its Cenozoic development. However, the opening history and AAG’s consecutive widening and deepening must have had a strong impact on circulation and water mass exchange between the Arctic Ocean and the North Atlantic. To study the AAG’s complete history, ocean drilling at two primary sites and one alternate site located between 73°N and 78°N in the Boreas Basin and along the East Greenland continental margin are proposed. These sites will provide unprecedented sedimentary records that will unveil (1) the history of shallow-water exchange between the Arctic Ocean and the North Atlantic, and (2) the development of the AAG to a deep-water connection and its influence on the global climate system. The specific overarching goals of our proposal are to study: (1) the influence of distinct tectonic events in the development of the AAG and the formation of deep water passage on the North Atlantic and Arctic paleoceanography, and (2) the role of the AAG in the climate transition from the Paleogene greenhouse to the Neogene icehouse for the long-term (~50 Ma) climate history of the northern North Atlantic. Getting a continuous record of the Cenozoic sedimentary succession that recorded the evolution of the Arctic-North Atlantic horizontal and vertical motions, and land and water connections will also help better understanding the post-breakup evolution of the NE Atlantic conjugate margins and associated sedimentary basins.

Description: In this study, we present new detailed biomarker-based sea ice records from two sediment cores recovered in the Chukchi Sea and the East Siberian Sea. These new biomarker data may provide new insights on processes controlling recent and past sea ice changes. The biomarker proxy records show (i) minimum sea ice extent during the Early Holocene, (ii) a prominent Mid-Holocene short-term high-amplitude variability in sea ice, primary production and Pacific-Water inflow, and (iii) significantly increased sea ice extent during the last ca. 4.5k cal a BP. This Late Holocene trend in sea ice change in the Chukchi and East Siberian Seas seems to be contemporaneous with similar changes in sea ice extent recorded from other Arctic marginal seas. The main factors controlling the millennial variability in sea ice (and surface-water productivity) are probably changes in surface water and heat flow from the Pacific into the Arctic Ocean as well as the long-term decrease in summer insolation. The short-term centennial variability observed in the high-resolution Middle Holocene record is probably related to solar forcing. Our new data on Holocene sea ice variability may contribute to synoptic reconstructions of regional to global Holocene climate change based on terrestrial and marine archives.