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  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 450.2007, 7169, E16-, (1 S.) 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Replying to: D. L. Anderson & J. H. Natland Nature 450, doi: 10.1038/nature06376 (2007) Anderson and Natland’scomment does not question our results regarding the velocity structure of mantle upwellings based on uranium-series. We ...
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  • 2
    ISSN: 1435-2451
    Keywords: Farbcodierte Dopplersonographie ; Lebertransplantation ; Thrombose der Arteria hepatica ; Pfortaderthrombose
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Description / Table of Contents: Zusammenfassung Bei 60 Patienten nach Lebertransplantation (75 Transplantate) wurde in der ersten postoperativen Woche dreimal täglich eine farbcodierte Dopplersonographie zum Ausschluβ vaskulärer Komplikationen durchgeführt. Eine Thrombose der Leberarterie wurde bei 7 Patienten diagnostiziert (3, 4, 20, 24, 48, 70 und 84 h nach der Transplantation). Die Diagnose wurde intraoperativ bei Relaparotomie bestätigt, bei einem Patienten erfolgte vor der Revisionsoperation eine Angiographie. Zweimal war eine Thrombektomie der Leberarterie erfolgreich, bei fünf Patienten muβte retransplantiert werden. Eine Pfortaderthrombose wurde bei drei Patienten (24, 26 und 90 h nach der Transplantation) diagnostiziert. Immer war eine Thrombektomie mit partieller Arterialisierung der Pfortader erfolgreich. Falsch negative bzw. falsch positive Befunde wurden nicht erhoben, so daβ die farbcodierte Dopplersonographie mit einer hohen Sensitivität bei einer Spezifität von 100% in der Diagnose von Gefäßkomplikationen nach Lebertransplantation verbunden ist. In der Diagnostik von Gefäßkomplikationen während der frühen postoperativen Phase nach Lebertransplantationen kann die Angiographie durch die farbcodierte Dopplersonographie ersetzt werden. Die Diagnose insbesondere von klinisch noch nicht manifesten Gefäßkomplikationen ist durch engmaschigen Einsatz der Methode möglich und kann durch frühzeitige Relaparotomie zu einer Senkung der Retransplantationsrate führen.
    Notes: Abstract Sixty patients who received 75 consecutive liver grafts and had routine Doppler sonography monitoring in the early postoperative period (three times a day) were reviewed for vascular complications. Thrombosis of the hepatic artery was detected in seven patients (3, 4, 20, 24, 48, 70 and 84 h after liver transplantation) and was then confirmed by emergency laparotomy in six cases. In one patient, thrombosis was verified by angiography before laparotomy. In two patients thrombectomy was successful, in five patients retransplantation had to be performed. Portal vein occlusion was detected in three patients (24, 26 and 90 h after transplantation) and all were successfully treated by thrombectomy and partial arterialization of the portal vein. Colour Doppler sonography was associated with no false-positive or -negative results. The specificity was 100% for the diagnosis of hepatic artery and portal vein thrombosis. In our opinion colour Doppler sonography will be able to replace time-consuming angiography in vascular diagnostics in the early postoperative phase after liver transplantation. Furthermore, there is evidence that frequent use of this non-invasive technique permits early detection of clinically unsuspected vascular complications and subsequent immediate relaparotomy, which is linked to a reduction in the rate of retransplantation.
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  • 3
    Publication Date: 2022-12-07
    Description: The radiogenic isotope heterogeneity of oceanic basalts is often assessed using 2D isotope ratio diagrams. But because the underlying data are at least six dimensional (87Sr/86Sr, 143Nd/144Nd, 176Hf/177Hf, and 208,207,206Pb/204Pb), it is important to examine isotopic affinities in multi‐dimensional data space. Here, we apply t‐distributed stochastic neighbor embedding (t‐SNE), a multi‐variate statistical data analysis technique, to a recent compilation of radiogenic isotope data of mid ocean ridge (MORB) and ocean island basalts (OIB). The t‐SNE results show that the apparent overlap of MORB‐OIB data trends in 2‐3D isotope ratios diagrams does not exist in multi‐dimensional isotope data space, revealing that there is no discrete “component” that is common to most MORB‐OIB mantle sources on a global scale. Rather, MORB‐OIB sample stochastically distributed small‐scale isotopic heterogeneities. Yet, oceanic basalts with the same isotopic affinity, as identified by t‐SNE, delineate several globally distributed regional domains. In the regional geodynamic context, the isotopic affinity of MORB and OIB is caused by capturing of actively upwelling mantle by adjacent ridges, and thus melting of mantle with similar origin in on, near, and off‐ridge settings. Moreover, within a given isotopic domain, subsidiary upwellings rising from a common deep mantle root often feed OIB volcanism over large surface areas. Overall, the t‐SNE results define a fundamentally new basis for relating isotopic variations in oceanic basalts to mantle geodynamics, and may launch a 21st century era of “chemical geodynamics.”
    Description: Plain Language Summary: The isotopic heterogeneity of basalts erupted at mid ocean ridges (MORB) and ocean islands (OIB) reflects the chemical evolution of Earth's mantle. The visual inspection of various 2D isotope ratio diagrams has fueled a four decade‐long discussion whether basalt heterogeneity reflects melting of only a small number of mantle components, and in particular, whether the apparent overlap of local data trends in global 2D isotope ratio diagrams indicates that melting of a common mantle component contributes to most MORB‐OIB. Here, we use multi‐variate statistical data analysis to show that the apparent overlap of MORB‐OIB data trends in 2D isotope ratio diagrams does not exist in multi‐dimensional isotope data space. Our finding invalidates any inference made for mantle compositional evolution based on the previously proposed existence of a common mantle component, its potential nature or distribution within the mantle. Rather, global MORB‐OIB sample small‐scale isotopic heterogeneities that are distributed stochastically in the Earth's mantle. Yet, MORB‐OIB with the same isotopic affinity, as identified by our multi‐variate data analysis, delineate several globally distributed regional domains. Within the regional geodynamic context, this discovery forms a fundamentally new basis for relating isotopic variations in MORB‐OIB to mantle geodynamics.
    Description: Key Points: Multi‐variate statistical data analysis (t‐distributed stochastic neighbor embedding) identifies global Sr‐Nd‐Hf‐Pb isotopic affinities of oceanic basalts. There is no “common mantle component;” rather, global mid ocean ridge‐ocean island basalts sample stochastically distributed small‐scale isotopic heterogeneities. Globally distributed regional domains of isotopically alike oceanic lavas define a new basis for relating isotopic variations to geodynamics.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung http://dx.doi.org/10.13039/501100001711
    Description: DAAD, German Academic Exchange Service
    Description: https://doi.org/10.25625/0SVW6S
    Description: https://doi.org/10.25625/BQENGN
    Keywords: ddc:551.9 ; mantle heterogeneity ; MORB ; OIB ; geodynamics ; t‐SNE ; radiogenic isotopes ; machine learning
    Language: English
    Type: doc-type:article
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  • 4
    Publication Date: 2018-01-23
    Description: High-Mg ultrapotassic volcanic rock occurrences of lamproitic affinity are exposed in southwestern Anatolia, mostly within the Menderes Massif. From north to south the lamproitic volcanism shows increasingly younger ages ranging from 20 to 4 Ma. Volcanism is contemporaneous with more voluminous shoshonitic, high-K calc-alkaline, and ultrapotassic magmatic activity in the Simav–Selendi, Uşak, Kırka, Köroğlu, Afyon and Isparta–Gölcük areas. The southward decrease in the age of the volcanism correlates with changes in geochemical composition, particularly a decrease in 87Sr/86Sr, 207Pb/204Pb, Zr/Nb and Th/Nb, and an increase in 143Nd/144Nd, 176Hf/177Hf, 206Pb/204Pb, 208Pb/204Pb and Ce/Pb, thus delineating a systematic change from orogenic (crust-like) to anorogenic (convecting mantle-like) signatures. Rare earth element compositions of clinopyroxene phenocrysts demonstrate an increasing role for residual garnet for locations in the central parts of the Menderes Massif, indicating a lithosphere thickness greater than 80 km. In contrast, K2O abundances remain nearly constant at around 7%, indicating buffering by phlogopite in the mantle source. Magma genesis in southwestern Anatolia is controlled by post-collisional extensional events initiated after major lithospheric thickening. Geochemical constraints suggest that the mantle source experienced two main geodynamic stages. The first stage caused ultradepletion of the mantle and subsequent metasomatic enrichment, which allowed coupling of the geochemical signatures of ultradepleted harzburgite with those of crust-derived sediments. This happened during the final closure stages of the southern Neotethys Ocean and the accretion of forearc oceanic lithosphere (island-arc type), as shallowly subducted material to the Anatolian lithosphere. The second stage is post-collisional, and is related to the collapse of the orogenic belt and the development of extension-related horst and graben structures. This stage is concurrent with the initiation of a thermal anomaly originating from a gap, identified by seismic tomography, in the subducted slab under western Anatolia. We propose that the lithospheric mantle underwent intense ‘asthenospherization’ owing to lithosphere–asthenosphere interaction, caused by the southward expansion of this gap during slab roll-back. The geochemical resemblance of the lamproites to more voluminous, contemporaneous shoshonitic magmas implies their derivation from a heterogeneous mantle source that had been affected by similar processes. These mantle processes may be closely associated with the major episode of uplift in the Menderes Massif.
    Type: Article , PeerReviewed
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  • 5
    Publication Date: 2019-09-23
    Description: Highlights: • Geochemical data from high-T leucogranites imply pure crustal melting. • New U–Pb monazite ages constrain intrusion time close to peak metamorphism. • Updated Sr–Nd–Pb isotope data imply metasedimentary sources. Two suites of leucogranites were emplaced at 508 ± 5.9 Ma in the Okombahe District of the Damara belt (Namibia) synchronous with the peak of regional high-temperature metamorphism. The Sr (87Sr/86Srinit: 0.707 to 0.711), Nd (εNdinit: − 4.5 to − 6.6), and Pb isotopic (206Pb/204Pb: 18.51–19.13; 207Pb/204Pb: 15.63–15.69; 208Pb/204Pb: 38.08–38.66) compositions indicate that these peraluminous S-type granites were derived from mid- to lower-crustal rocks, which are slightly different to the metapelitic rocks into which they intruded. Since the leucogranites are unfractionated and show no evidence for assimilation or contamination, they constrain the temperature and pressure conditions of their formation. Calculated Zr and LREE saturation temperatures of ca. 850 °C indicate high-temperature crustal melts. High Rb/Sr and low Sr/Ba ratios are consistent with biotite dehydration melting of pelitic source rocks. Qz–Ab–Or systematics reveal that melting and segregation for the least fractionated samples occurred at ca. 7 kbar corresponding to a mid-crustal level of ca. 26 km. However, there is no evidence for a mantle component that could have served as a local heat source for crustal melting. Therefore, the hot felsic magmas that formed close to the time of peak metamorphism are the result of long-lasting high temperature regional metamorphic conditions and intra-crustal collision.
    Type: Article , PeerReviewed
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  • 6
    Publication Date: 2017-09-13
    Description: The Pan-African Damara orogen of Namibia is characterized by large-scale granitoid intrusions. Two plutons in the Northern Central Zone (NCZ) of the Damara orogen within the Okombahe district have U–Pb zircon ages of 576.2 ± 5.7 Ma and 570.9 ± 4.9 Ma that predate the time of high grade regional metamorphism which occurred between 540 and 480Ma. The intrusive rocks are magnesian high-K alkali-calcic granodiorites to granites, are enriched in HFSE and REE, and have undergone only a limited degree of fractional crystallization, and do not contain xenoliths of local country rocks. Initial isotope compositions are unevolvedwith 87Sr/86Sr between 0.704 and 0.706 and initial εNd ranging from −1.9 to−3.9. Lead isotopes are radiogenic (206Pb/204Pb: 18.32 to 18.61, 207Pb/204Pb: 15.61 to 15.69 and 208Pb/204Pb: 37.87 to 39.29) with variable 207Pb/204Pb ratios at almost constant 206Pb/204Pb and 208Pb/204Pb ratios, suggesting a derivation from ancient sources with comparatively high U/Pb but low Th/Pb ratios. The limited variations in Sr, Nd and Pb isotopes were not caused by crustal contamination or magma mixing, but instead reflect source heterogeneities. Strontium and Nd isotope compositions suggest mafic lithologies similar to amphibolites from the Kalahari Craton basement as potential sources. A comparison with amphibolite melting experiments confirms the possible derivation of the granodiorites from an amphibolitic source. Calculated maximum zircon saturation temperatures at insignificant amounts of inherited zircon, indicate intrusion temperatures of up to 900 °C. Apatite saturation temperatures are higher, up to ca. 950 °C. Pressures of 5 to 10 kbar are determined through Qz-Ab-Or systematics and are interpreted as minimum pressures at the site of melting suggesting that the granodiorites/granites represent high temperature partial melts generated in the lower crust. Although there are some compositional similarities with granites generated in subduction zones, radiogenic Pb isotope ratios and high δ18O values suggest that reprocessed amphibolitic rocks are more likely sources.
    Type: Article , PeerReviewed
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  • 7
    Publication Date: 2019-09-23
    Description: The Tsomtsaub pluton (central Damara orogen, Namibia) consists of quartz diorites, granodiorites and granites. Intrusion ages of the undeformed and unmetamorphosed quartz diorites and granites are constrained by LA-ICP-MS U-Pb zircon analyses, which yielded ages of 541 ± 3 Ma (quartz diorites) and 506 ± 6 Ma (granodiorites), respectively. The older age predates the main phase of high-T regional metamorphism and the younger age fits to the inferred age of the main peak of regional metamorphism. Elemental and isotope variations are decoupled, indicating that combined assimilation-fractional crystallization processes were not important during evolution of these rocks. Therefore, Sr-Nd isotope compositions (quartz diorites: ɛNd(init.): −1.5 to −1.8; 87Sr/86Sr(init.): 0.7049 to 0.7058; granodiorites/granites: ɛNd(init.): −2.7 to −5.3; 87Sr/86Sr(init.): 0.7044 to 0.7096) indicate that generation of the quartz diorites and granodiorites involved distinct sources. Lead isotope ratios show some overlap between quartz diorites (206Pb/204Pb: 18.36 to 18.38; 207Pb/204Pb: 15.66 to 15.67; 208Pb/204Pb: 38.09 to 38.12) and granodiorites/granites (206Pb/204Pb: 18.39 to 18.78; 207Pb/204Pb: 15.62 to 15.67; 208Pb/204Pb: 37.90 to 38.17). However, a large variation in 207Pb/204Pb at relatively constant 206Pb/204Pb is apparent for all rock types. Based on a comparison with results from fluid-absent melting experiments using amphibolites, a lower crustal metabasalt, probably enriched in K2O, is a likely source rock for the quartz diorites. For the granodiorites, a high-K andesitic or tonalitic source is likely. The granites are interpreted as fractionation products of the granodiorites. Semi-quantitative pressure-temperature estimates using Qtz-Ab-Or systematics and Zr saturation temperatures indicate pressures in excess of 5 kbar and temperature of c. 900°C, placing the site of melting in the lower crust. The weakly evolved Sr-Nd isotope ratios and the moderate radiogenic Pb isotope ratios are consistent with juvenile mafic to intermediate sources for the quartz diorites and granodiorites. This contrasts with previous suggestions favouring an origin of quartz diorites and granodiorites by either melting of an enriched mantle source during Pan-African times followed by AFC processes, or by melting of ancient, depleted mafic crust.
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  • 8
    Publication Date: 2018-02-27
    Description: We present new analytical data of major and trace elements for the geological MPI-DING glasses KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, BM90/21-G, T1-G, and ATHO-G. Different analytical methods were used to obtain a large spectrum of major and trace element data, in particular, EPMA, SIMS, LA-ICPMS, and isotope dilution by TIMS and ICPMS. Altogether, more than 60 qualified geochemical laboratories worldwide contributed to the analyses, allowing us to present new reference and information values and their uncertainties (at 95% confidence level) for up to 74 elements. We complied with the recommendations for the certification of geological reference materials by the International Association of Geoanalysts (IAG). The reference values were derived from the results of 16 independent techniques, including definitive (isotope dilution) and comparative bulk (e.g., INAA, ICPMS, SSMS) and microanalytical (e.g., LA-ICPMS, SIMS, EPMA) methods. Agreement between two or more independent methods and the use of definitive methods provided traceability to the fullest extent possible. We also present new and recently published data for the isotopic compositions of H, B, Li, O, Ca, Sr, Nd, Hf, and Pb. The results were mainly obtained by high-precision bulk techniques, such as TIMS and MC-ICPMS. In addition, LA-ICPMS and SIMS isotope data of B, Li, and Pb are presented.
    Type: Article , PeerReviewed
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  • 9
    Publication Date: 2013-09-16
    Description: Hornblende-bearing basanites and alkali basalts from the Rhön area of Germany (part of the Central European Volcanic Province; CEVP) have high TiO 2 (3–4 wt %), moderately high Mg# (mostly 〉0·50), variable Cr (400–30 ppm) and Ni (160–20 ppm) abundances, and are enriched in incompatible trace elements and rare earth elements (REE). In primitive mantle-normalized multi-element diagrams they show a strong depletion in Ba, Rb, and K relative to trace elements of similar incompatibility. Some alkali basalts and more differentiated rocks have lower Mg# and lower abundances of Ni and Cr, and have undergone fractionation of olivine, clinopyroxene, Fe–Ti oxides and amphibole. The trace element constraints (e.g. low Nb/U and Ce/Pb and the Nd–Sr–Pb isotope compositions of some basalts) indicate that assimilation of lower crustal material has modified the composition of the primary mantle-derived magmas. Most of the basanites and alkali basalts approach the Sr–Nd–Pb isotope compositions inferred for the EAR (European Asthenospheric Reservoir) component. Variations in REE abundances and correlations between REE ratios suggest partial melting of amphibole-bearing spinel peridotite containing a significant portion of non-peridotitic material (i.e. pyroxenite). The presence of residual amphibole, indicated by depletion of K and Rb relative to Ba and Nb, requires melting close to the asthenosphere–lithosphere boundary or within the lithospheric mantle, most probably of a veined mantle source. Temperature and pressure estimates indicate a depth of melting for the most primitive lavas at ~80 km at temperatures of ~1290°C. Based on Sr–Nd isotope and trace element constraints it is proposed that asthenospheric melts similar in composition to EAR melts observed elsewhere in the CEVP froze at the asthenosphere–lithosphere thermal boundary as veins in the lithospheric mantle. These veins were remelted after only short storage times by ascending asthenospheric melts, imposing the prominent amphibole signature upon the basalts. The fairly radiogenic Pb isotope signatures are expected to originate from melting of enriched, low melting temperature components incorporated in the depleted upper (asthenospheric) mantle and therefore do not require upwelling of deep-seated mantle sources for the Rhön or many other continental alkaline lavas with similar Pb isotope signatures.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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  • 10
    Publication Date: 2011-12-23
    Description: New trace element and Hf–Nd isotope data on post-glacial basalts from Iceland's main rift zones are used in conjunction with literature data to evaluate the relative importance of source heterogeneity and the melting process for the final melt composition. Correlations between Hf and Nd isotope compositions and trace element ratios indicate that at least two source components are sampled systematically as a function of the degree and pressure of melting beneath Iceland. Strong depletion in Rb, Ba, U and Th and enrichment in Nb and Ta compared with La in the most enriched samples from the Reykjanes Peninsula and Western Rift Zone suggests that the enriched source component is similar to ancient recycled enriched mid-ocean ridge basalt (E-MORB) crust. Highly incompatible trace element ratios such as Nb/La and Nb/U and Pb isotope ratios are variable across Iceland. This observation suggests that either the enriched component is intrinsically heterogeneous, or that there is a larger proportion of the enriched source component beneath the Southwestern Rift Zone compared with the Northern Rift Zone. The relative effect of source heterogeneity and melting on the final melt composition was evaluated with a one-dimensional polybaric melt mixing model in which accumulated melts from a depleted MORB mantle and a recycled E-MORB crust are mixed in different ways. Two styles of melt mixing were simulated: (1) complete mixing of melts with variable proportions of the depleted mantle and recycled E-MORB components; (2) incomplete mixing with a fixed initial proportion of the two source components. Calculated pressure-dependent compositional changes using these simple two-component melting models can explain the observed trends in trace element ratio and isotope ratio diagrams for Icelandic basalts, even in cases where conventional binary mixing models would require more than two source components. The example of Iceland demonstrates that melt mixing during extraction from the mantle is a key process for controlling the trace element and isotope variability observed in basaltic lavas and must be evaluated before inferring the presence of multiple source components.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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