Description: Supra-subduction zone (SSZ) ophiolites such as the Troodos Ophiolite of Cyprus are thought to have formed at spreading centres close to subduction zones. Similarities in the geochemistry between lavas from SSZ ophiolites and fore-arc lavas from active subduction zones, and the presence of boninites in both, have led to the suggestion that SSZ ophiolites represent fragments of fore-arc crust and mantle, formed during subduction initiation. Here we present major and trace element and Sr, Nd and Pb isotope data for fresh volcanic glasses from a section through the lava pile on the southern margin of the Troodos Ophiolite, and compare these to lavas from the Izu–Bonin–Mariana fore-arc. In Troodos, boninites and tholeiitic basalts are interbedded and were derived from a highly depleted mantle source that was later enriched by both fluids and melts derived largely from subducted sediment, before melting beneath the spreading axis. Troodos boninites differ from Izu–Bonin–Mariana boninites by their greater source depletion, enrichment in Nb by small degree melts, and lack of Zr enrichment relative to Sm. Together with the lack of fore-arc basalts in Troodos, our data imply that the Troodos Ophiolite was formed in a fore-arc location at a back-arc spreading centre that propagated into arc crust. The Troodos Ophiolite was thus not formed during subduction initiation and thus may not be used as analogue for the formation of fore-arc basalts.

Description: Highlights • Synthesis of timescales of magmatic processes at spreading centres. • Compilation of drilled MORB glass compositions, chemical stratigraphy of the oceanic crust. • No chemical difference between MORB sampled from active ridges or by drilling. • Chemical variations on timescales 〈 1 ka reflect changes in melt recharge relative to fractionation. • Changes in the composition of melt entering crust occur over timescales of 10 to 100 ka. Abstract Oceanic crust is continuously created at mid-ocean ridges by decompression melting of the upper mantle as it upwells due to plate separation. Decades of research on active spreading ridges have led to a growing understanding of the complex magmatic, tectonic and hydrothermal processes linked to the formation of new oceanic igneous crust. However, less is known about the timescales of magmatic processes at mid-ocean ridges, including melting in and melt extraction from the mantle, fractional crystallisation, crustal assimilation and/or magma mixing. In this paper, we review the timescales of magmatic processes by integrating radiometric dating, chemical and petrological observations of mid-ocean ridge basalts (MORBs) and geophysical models. These different lines of evidence suggest that melt extraction and migration, and crystallisation and mixing processes occur over timescales of 1 to 10,000 a. High-resolution geochemical stratigraphic profiles of the oceanic crust using drill-core samples further show that at fast-spreading ridges, adjacent flow units may differ in age by only a few 100 a. We use existing chemical data and new major- and trace-element analyses of fresh MORB glasses from drill-cores in ancient Atlantic and Pacific crust, together with model stratigraphic ages to investigate how lava chemistry changes over 10 to 100 ka periods, the timescale of crustal accretion at spreading ridges which is recorded in the basalt stratigraphy in drilled sections through the oceanic crust. We show that drilled MORBs have compositions that are similar to those of young MORB glasses dredged from active spreading ridges (lavas that will eventually be preserved in the lowermost part of the extrusive section covered by younger flows), showing that the dredged samples are indeed representative of the bulk oceanic crust. Model stratigraphic ages calculated for individual flows in boreholes, together with the geochemical stratigraphy of the drilled sections, show that at fast-spreading ridges, magma compositions vary over 〈 100 to 1000 a, likely due to variations in the relative rates of crystallisation and melt recharge. However, on longer timescales of 10 to 100 ka, variations in the composition of the primitive melt feeding the ridge lead to chemical variations in the erupted lavas, likely as a function of thermal and/or chemical heterogeneity of the mantle source. The further understanding of these temporal variations in magma composition, especially at shorter timescales of less than a few centuries, is a promising area for future research.

Description: New major and trace element and Sr, Nd, and Pb isotope data, together with 39Ar-40Ar ages for lavas from the extinct Galapagos Rise spreading center in the eastern Pacific reveal the evolution in magma compositions erupted during slowdown and after the end of active spreading at a mid-ocean ridge. Lavas erupted at 9.2 Ma, immediately prior to the end of spreading are incompatible element depleted mid-ocean ridge tholeiitic basalts, whereas progressively younger (7.5 to 5.7 Ma) postspreading lavas are increasingly alkalic, have higher concentrations of incompatible elements, higher La/Yb, K/Ti, 87Sr/86Sr, and lower 143Nd/144Nd ratios and were produced by smaller degrees of mantle melting. The large, correlated variations in trace element and isotope compositions can only be explained by melting of heterogenous mantle, in which incompatible trace element enriched lithologies preferentially contribute to smaller degree mantle melts. The effects of variable degrees of melting of heterogeneous mantle on lava compositions must be taken into account when using mid-ocean ridge basalt (MORB) to infer the conditions of melting beneath active spreading ridges. For example, the stronger “garnet signature” inferred from Sm/Nd and 143Nd/144Nd ratios for postspreading lavas from the Galapagos Rise results from a larger contribution from enriched lithologies with high La/Yb and Sm/Yb, rather than from a greater proportion of melting in the stability field of garnet peridotite. Correlations between ridge depth and Sm/Yb and fractionation-corrected Na concentrations in MORB worldwide could result from variations in mantle fertility and/or variations in the average degree of melting, rather than from large variations in mantle temperature. If more fertile mantle lithologies are preferentially melted beneath active spreading ridges, then the upper mantle may be significantly more “depleted” than is generally inferred from the compositions of MORB.

Description: This study aims to provide a more detailed understanding of the behavior of 231Pa/230Th under varying ocean circulation regimes. The North Atlantic provides a unique sedimentary setting with its ice-rafted detritus (IRD) layers deposited during glacial times. These layers have been found north of 40° N (Ruddiman Belt) and are most pronounced during Heinrich Stadials. Most of these sediments have been recovered from the deep North Atlantic basin typically below 3000 m water depth. This study reports sedimentological and sediment geochemical data from one of the few sites at intermediate depth of the open North Atlantic (core SU90-I02, 45° N 39° W, 1965 m water depth) within the Ruddiman Belt. The time periods of Heinrich Stadials 1 and 2 of this core were identified with the help of the major element composition by XRF scanning and by IRD counting. Along the core profile, the sedimentary 231Pa/230Th activity ratio has been measured as a kinematic proxy for the circulation strength. The 231Pa/230Th record shows highest values during the Holocene and Last Glacial Maximum, above the natural production ratio of these isotopes. During Heinrich Stadials 1 and 2, when Atlantic meridional overturning circulation was most reduced, the 231Pa/230Th record shows overall lowest values below the production ratio. This behavior is contrary to classical findings of 231Pa/230Th from the northwestern Atlantic where a strong Holocene circulation is associated with low values. However, this behavior at the presented location is in agreement with results from simulations of the 231Pa/230Th-enabled Bern3D Earth system model.

Description: Global climatic changes during the last Glacial and Deglacial have been related to variations of the Atlantic Meridional Overturning Circulation (AMOC). Here, we present new and refined 231Pa/230Th down‐core profiles extending back to 30 ka BP from the northwestern Atlantic along the Atlantic Deep Western Boundary Current (DWBC), which is the main component of the southward deep backflow of the AMOC. Besides the well‐known Bermuda Rise records, available high‐resolution 231Pa/230Th data in the northwestern Atlantic are still sparse. Our new records along with reconstructions of deep water provenance from Nd isotopes constrain the timing and magnitude of past changes in AMOC from an additional northwestern Atlantic region forming a depth transect between 3000 and 4760 m water depth. Our extended and improved dataset confirms the weakening of the AMOC during deglacial cold spells such as Heinrich Event 1 and the Younger Dryas interrupted by a reinvigoration during the Bølling‐Allerød interstadial as seen in the prominent 231Pa/230Th records from the Bermuda Rise. However, in contrast to the Bermuda Rise records we find a clearly reduced circulation strength during the Last Glacial Maximum in the deep Atlantic.

Description: The Rio Grande Rise in the western South Atlantic Ocean has been interpreted as either an oceanic plateau related to the Tristan-Gough mantle plume, or a fragment of detached continental crust. Here we present new major and trace element data for volcanic rocks from the western and eastern Rio Grande Rise and the adjacent Jean Charcot Seamount Chain. The eastern Rio Grande Rise and older parts of the western Rio Grande Rise are comprised of tholeiitic basalt with moderately enriched trace element compositions and likely formed above the Tristan-Gough mantle plume close to the southern Mid-Atlantic Ridge. Younger alkalic lavas from the western Rio Grande Rise and the Jean Charcot Seamount Chain were formed by lower degrees of melting beneath thicker lithosphere in an intraplate setting possibly during rifting of the plateau. There is no clear geochemical evidence that remnants of continental crust are present beneath the Rio Grande Rise.

Description: As part of the Atlantic Meridional Overturning Circulation (AMOC) the Deep Western Boundary Current (DWBC) transports newly formed NADW southward along the North American continental rise representing the most important lower limb of modern AMOC. Resolving its evolution since the last glacial will drastically improve our understanding about the evolution of AMOC and its connection to (paleo)climate. For our investigations we sampled ODP sites 1059 - 1062 located on the Blake Bahama Outer Ridge (BBOR). The BBOR is ideally located within the modern flow path of the DWBC and is therefore well suited to record past changes in geometry and intensity of the DWBC. We applied the 231Pa/230Th kinematic circulation proxy on sediments from the BBOR that form a depth transect from 3000 to 4700 m water depth. In addition to sortable-silt data from the BBOR, which provide information mainly about changes in the very bottom current strength, the 231Pa/230Th kinematic circulation proxy provides a record of an integrated signal from the overlying water column. In combination with new εNd records from the very same samples, used for identifying the provenance of the prevailing water masses, our 231Pa/230Th records provide insight into past circulation states and the strength of the DWBC over the last 30 ka. Climatic key features such as the Last Glacial Maximum (LGM), deglaciation and Holocene in high-resolution are clearly resolvable. Both 231Pa/230Th and εNd indicate reduced circulation during the Younger Dryas and Heinrich Stadial 1 and 2 in agreement with records from the Bermuda Rise, including ODP site 1063. During the LGM circulation strength was slightly weaker compared to the deep and strong Holocene circulation but still active. With this new depth transect of combined proxy data we are able to reconstruct the intensity of the DWBC more robustly.

Description: Estimates of the relative motion between the Hawaiian and Louisville hotspots have consequences for understanding the role and character of deep Pacific-mantle return flow. The relative motion between these primary hotspots can be inferred by comparing the age records for their seamount trails. Our new 40Ar/39Ar ages for 18 lavas from 10 seamounts along the Hawaiian-Emperor Seamount Chain (HESC) show that volcanism started in the sharp portion of the Hawaiian-Emperor Bend (HEB) at �47.5 Ma and continued for �5 Myr (O’Connor et al., 2013). The slope of the along-track distance from the currently active Hawaiian hotspot plotted versus age is remarkably linear between �57 and 25 Ma in the central �1900 km of the seamount chain, including the HEB. This model predicts an age for the oldest Emperor Seamounts that matches published ages, implying that a linear age-distance relationship might extend back to at least 82 Ma. In contrast, Hawaiian age progression was much faster since at least �15 Ma and possibly as early as �27 Ma. Linear age-distance relations for the Hawaii-Emperor and Louisville seamount chains predict �300 km overall hotspot relative motion between 80 and 47.5 Ma, in broad agreement with numerical models of plumes in a convecting mantle, and paleomagnetic data. We show that a change in hotspot relative motion may also have occurred between �55 Ma and �50 Ma. We interpret this change in hotspot motion as evidence that the HEB reflects a combination of hotspot and plate motion changes driven by the same plate/mantle reorganization. O’Connor et al. (2013), Constraints on past plate and mantle motion from new ages for the Hawaiian-Emperor Seamount Chain, Geochem. Geophys. Geosyst., 14, 4564–4584, doi:10.1002/ggge.20267