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  • 1
    Online Resource
    Online Resource
    La Vergne :Royal Society of Chemistry, The,
    Keywords: Nuclear power plants -- Environmental aspects. ; Electronic books.
    Description / Table of Contents: This book is concerned with reviewing the political and social context for nuclear power generation, the nuclear power fuel cycles and their implications for the environment.
    Type of Medium: Online Resource
    Pages: 1 online resource (247 pages)
    Edition: 1st ed.
    ISBN: 9781849732888
    Series Statement: Issn Series
    DDC: 333.7924
    Language: English
    Note: Nuclear Power and the Environment -- Contents -- Nuclear Power Generation - Past, Present and Future -- 1 Introduction -- 2 Origins of Nuclear Power: The Nuclear Weapons Programme -- 3 Expansion of Nuclear Power -- 4 A Period of Decline -- 5 A Nuclear Renaissance? Possibilities and Challenges -- 5.1 Uranium: A Sustainable Energy Source? -- 5.2 Nuclear Power Economics -- 5.3 Shortages in Skilled Labour and Materials -- 5.4 Nuclear Safety -- 5.5 Nuclear Waste Disposal and Decommissioning Nuclear Plants -- 5.6 Proliferation Risks -- 6 Conclusions -- References -- Nuclear Fuel Cycles: Interfaces with the Environment -- 1 Nuclear Fission as an Energy Resource -- 2 Nuclear Fuel -- 2.1 Uranium Mining -- 2.2 Uranium Fuel Production and Use -- 2.3 Modern Civil Reactor Fuels -- 2.3.1 Plutonium -- 2.4 Irradiation of Nuclear Fuel -- 2.5 Alternative Fuels -- 2.5.1 Uranium/Plutonium Fast Reactors -- 2.5.2 Highly Enriched Uranium -- 2.5.3 Thorium -- 3 Nuclear Fuel Recycling -- 3.1 Separation of Uranium and Plutonium -- 3.2 Other Reasons to Reprocess -- 3.3 Historical Reprocessing Technologies -- 3.3.1 Precipitation Processes -- 3.4 Purex -- 3.5 Wastes from Fuel Reprocessing -- 3.6 Other Solvent Extraction Processes -- 4 Waste Management Options -- 4.1 The UK Waste Inventory -- 5 Impact of the ''Global Nuclear Renaissance'' -- 5.1 Growth in Demand -- 5.2 Implications for the Fuel Cycle -- 6 Conclusions -- Acknowledgements -- References -- Nuclear Accidents -- 1 Introduction -- 2 The 1957 Windscale Fire -- 2.1 Events Leading to the Accident -- 2.2 Environmental Contamination -- 2.3 Radiation Exposures and Health Impacts -- 2.4 Social and Psychological Consequences -- 3 The Kyshtym Explosion -- 3.1 Events Leading to the Accident -- 3.2 Environmental Contamination -- 3.3 Radiation Exposures and their Environmental and Health Impacts. , 3.4 Social and Psychological Impacts -- 4 Three-Mile Island -- 4.1 Events Leading to the Accident -- 4.2 Environmental Contamination -- 4.3 Radiation Exposures and their Environmental and Health Impacts -- 4.4 Social and Psychological Impacts -- 5 The Chernobyl Accident -- 5.1 Events Leading to the Accident -- 5.2 Environmental Contamination -- 5.3 Radiation Exposures and their Environmental and Health Impacts -- 5.4 Social and Psychological Impacts -- 6 Conclusions -- References -- Management of Land Contaminated by the Nuclear Legacy -- 1 Introduction -- 2 Contamination at Worldwide Nuclear Facilities -- 2.1 United Kingdom -- 2.1.1 Sellafield -- 2.1.2 Dounreay -- 2.2 Russia -- 2.2.1 Mayak -- 2.3 United States of America -- 2.3.1 Rocky Flats -- 2.3.2 Oak Ridge -- 2.3.3 Hanford -- 3 Depleted Uranium -- 4 Remediation -- 4.1 Bioremediation -- 4.2 Chemical Redox Reactions -- 4.3 Permeable Reactive Barrier -- 4.4 Sediment Washing -- 4.5 Electrokinetic Remediation -- 5 Case Studies -- 5.1 Hanford Case Study -- 5.2 Rifle Case Study -- 5.3 Oak Ridge Case Study -- 6 Conclusions -- Acknowledgements -- References -- Decommissioning of Nuclear Sites -- 1 Introduction -- 2 The Goal of Decommissioning -- 3 Stages of Decommissioning -- 4 The Scale of the Decommissioning Challenge in the UK -- 5 Decommissioning Techniques -- 6 Selection of a Decommissioning Approach -- 7 Environmental Impacts of Decommissioning -- 8 Conclusions -- References -- Geodisposal of Higher Activity Wastes -- 1 Introduction -- 2 Radioactive Wastes -- 2.1 High Level Wastes -- 2.2 Intermediate Level Waste -- 2.3 Low Level Waste -- 2.4 Other Potential Wastes -- 3 Geological Disposal -- 3.1 The GDF Concept -- 3.2 International Experience -- 3.2.1 Suitable Host Geologies -- 3.2.2 Engineering Approaches -- 3.3 Implementing the UK GDF. , 3.3.1 Historical Perspective, Public Consultation, Policy Decisions, and Responsibilities -- 3.3.2 Guiding Principles and Timeline -- 3.3.3 Site Selection -- 3.3.4 Inventory of Geodisposal Wastes -- 3.3.5 Conditioning and Packaging of Geodisposal Wastes -- 3.3.6 Interim Storage of Geodisposal Wastes -- 3.3.7 Reference Scenarios -- 4 Environmental Chemistry Research Challenges in Geological Disposal -- Acknowledgements -- References -- Pathways of Radioactive Substances in the Environment -- 1 Introduction -- 2 Sources of Radionuclides in the Environment -- 2.1 Nuclear Weapons -- 2.2 Nuclear Fuel Cycle -- 2.3 Depleted Uranium -- 2.4 Naturally Occurring Radioactive Material -- 2.5 Accidental Release -- 3 Environmental Chemistry of Key Contaminants -- 4 Processes and Factors affecting Radionuclide Transport in the Atmosphere -- 5 Processes and Factors affecting Radionuclide Transport in Aquatic Systems -- 5.1 Sorption to Mineral Surfaces -- 5.2 Redox Reactions -- 5.3 Complexation Reactions -- 5.4 (Co-)Precipitation -- 5.5 Colloidal Transport -- 6 Conclusions -- References -- Radiation Protection of the Environment: A Summary of Current Approaches for Assessment of Radionuclides in Terrestrial Ecosystems -- 1 Introduction -- 2 Radiation Protection of Wildlife -- 3 Environmental Transfer in Terrestrial Ecosystems -- 3.1 Atmospheric Deposition -- 3.2 Radionuclides in Soil -- 3.3 Radionuclide Transfer to Plants -- 3.3.1 Quantification of Transfer to Plants -- 3.4 Radionuclide Transfer to Terrestrial Animals -- 3.4.1 Gastrointestinal Absorption -- 3.4.2 Radionuclide Distribution in Animals -- 3.4.3 Quantification of Transfer to Animals -- 4 Dosimetry for Wildlife -- 4.1 Dose Rate Calculation -- 5 Effects on Wildlife -- 5.1 Environmental Radiological Protection -- 6 Benchmarks for Wildlife Assessment -- 6.1 The ICRP's Derived Consideration Reference Levels. , 6.2 Alternative Approaches used in Radiological Risk Assessments -- Acknowledgements -- References -- Radiological Protection of Workers and the General Public -- 1 Introduction -- 2 The Health Effects of Radiation -- 3 The Scientific Framework for the Protection of Humans -- 4 The ICRP's System of Protection -- 4.1 Justification -- 4.2 Optimisation -- 4.3 Dose Limits -- 4.4 Dose Constraints and Reference Levels -- 5 Radiation Protection in Practice in the UK -- 5.1 Radiation Exposure of Workers -- 5.2 Radiation Exposure of the Public -- 6 Experience Gained from Nuclear Accidents Outside the UK -- 7 Conclusions -- References -- Subject Index.
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  • 2
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: 〈list xml:id="l1" style="custom"〉1 Carbon dioxide and water vapour fluxes were measured for 55 days by eddy covariance over an undisturbed tropical rain forest in Rondonia, Brazil. Profiles of CO2 inside the canopy were also measured.2 During the night, CO2 concentration frequently built up to 500 ppm throughout the canopy as a result of low rates of exchange with the atmosphere. In the early morning hours, ventilation of the canopy occurred.3 Ecosystem gas exchange was calculated from a knowledge of fluxes above the canopy and changes of CO2 stored inside the canopy. Typically, uptake by the canopy was 15 μmol m−2 s−1 in bright sunlight and dark respiration was 6-7 μmol m−2 s−1 The quantum requirement at low irradiance was: 40 mol photons per mol of CO2.4 Bulk stomatal conductance of the ecosystem was maximal in the early morning (0.4-1.0 mol m−2 s−1) and declined over the course of the day as leaf-to-air vapour pressure difference increased.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: The timing of the commencement of photosynthesis (P*) in spring is an important determinant of growing-season length and thus of the productivity of boreal forests. Although controlled experiments have shed light on environmental mechanisms triggering release from photoinhibition after winter, quantitative research for trees growing naturally in the field is scarce. In this study, we investigated the environmental cues initiating the spring recovery of boreal coniferous forest ecosystems under field conditions. We used meteorological data and above-canopy eddy covariance measurements of the net ecosystem CO2 exchange (NEE) from five field stations located in northern and southern Finland, northern and southern Sweden, and central Siberia. The within- and intersite variability for P* was large, 30–60 days. Of the different climate variables examined, air temperature emerged as the best predictor for P* in spring. We also found that ‘soil thaw’, defined as the time when near-surface soil temperature rapidly increases above 0°C, is not a useful criterion for P*. In one case, photosynthesis commenced 1.5 months before soil temperatures increased significantly above 0°C. At most sites, we were able to determine a threshold for air-temperature-related variables, the exceeding of which was required for P*. A 5-day running-average temperature (T5) produced the best predictions, but a developmental-stage model (S) utilizing a modified temperature sum concept also worked well. But for both T5 and S, the threshold values varied from site to site, perhaps reflecting genetic differences among the stands or climate-induced differences in the physiological state of trees in late winter/early spring. Only at the warmest site, in southern Sweden, could we obtain no threshold values for T5 or S that could predict P* reliably. This suggests that although air temperature appears to be a good predictor for P* at high latitudes, there may be no unifying ecophysiological relationship applicable across the entire boreal zone.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: During winter and early spring, evergreen boreal conifers are severely stressed because light energy cannot be used when photosynthesis is pre-empted by low ambient temperatures. To study photosynthetic performance dynamics in a severe boreal climate, seasonal changes in photosynthetic pigments, chloroplast proteins and photochemical efficiency were studied in a Scots pine forest near Zotino, Central Siberia. In winter, downregulation of photosynthesis involved loss of chlorophylls, a twofold increase in xanthophyll cycle pigments and sustained high levels of the light stress-induced zeaxanthin pigment. The highest levels of xanthophylls and zeaxanthin did not occur during the coldest winter period, but rather in April when light was increasing, indicating an increased capacity for thermal dissipation of excitation energy at that time. Concomitantly, in early spring the D1 protein of the photosystem II (PSII) reaction centre and the light-harvesting complex of PSII dropped to their lowest annual levels. In April and May, recovery of PSII activity, chloroplast protein synthesis and rearrangements of pigments were observed as air temperatures increased above 0°C. Nevertheless, severe intermittent low-temperature episodes during this period not only halted but actually reversed the physiological recovery. During these spring low-temperature episodes, protective processes involved a complementary function of the PsbS and early light-induced protein thylakoid proteins. Full recovery of photosynthesis did not occur until the end of May. Our results show that even after winter cold hardening, photosynthetic activity in evergreens responds opportunistically to environmental change throughout the cold season. Therefore, climate change effects potentially improve the sink capacity of boreal forests for atmospheric carbon. However, earlier photosynthesis in spring in response to warmer temperatures is strongly constrained by environmental variation, counteracting the positive effects of an early recovery process.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: 〈list xml:id="l1" style="custom"〉1 Eddy covariance measurements of CO2 flux, based on four and six week campaigns in Rondôdnia, Brazil, have been used in conjunction with a model to scale up data to a whole year, and thus estimate the carbon balance of the tropical forest ecosystem, and the changes in carbon balance expected from small interannual variations in climatological conditions.2 One possible source of error in this estimation arises from the difficulty in measuring fluxes under stably stratified meteorological conditions, such as occur frequently at night. Flux may be ‘lost’ because of low velocity advection, caused by nocturnal radiative cooling at sites on raised ground. Such effects may be detected by plotting the net ecosystem flux of CO2, Feco is a function of wind speed. If flux is ‘lost’ then Feco is expected to decline with wind speed. In the present data set, this did not occur, and Feco was similar to the nocturnal flux estimated independently from chamber measurements.3 The model suggests that in 1992/3, the Gross Primary Productivity (GPP) was 203.3 mol C m−2 y−1 and ecosystem respiration was 194.8 mol C m−2 y−1, giving an ecosystem carbon balance of 8.5 mol C m−2 y−1, equivalent to a sink of 1.0 ton C ha−1 y−1. However, the sign and magnitude of this figure is very sensitive to temperature, because of the strong influence of temperature on respiration.4 The model also suggests that the effect of temperature on the net carbon balance is strongly dependent on the partial pressure of CO2.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Soil microbial properties were studied from localities on a transect along the Yenisei River, Central Siberia. The 1000 km-long transect, from 56°N to 68°N, passed through tundra, taiga and pine forest characteristic of Northern Russia. Soil microbial properties were characterized by dehydrogenase activity, microbial biomass, composition of microbial community (PLFAs), respiration rates, denitrification and N mineralization rates. Relationships between vegetation, latitude, soil quality (pH, texture), soil organic carbon (SOC) and the microbial properties were examined using multivariate analysis. In addition, the temperature responses of microbial growth (net growth rate) and activity (soil respiration rate) were tested by laboratory experiments. The major conclusions of the study are as follows:1. Multivariate analysis of the data revealed significant differences in microbial activity. SOC clay content was positively related to clay content. Soil texture and SOC exhibited the dominant effect on soil microbial parameters, while the vegetation and climatic effects (expressed as a function of latitude) were weaker but still significant. The effect of vegetation cover is linked to SOC quality, which can control soil microbial activity.2. When compared to fine-textured soils, coarse-textured soils have (i) proportionally more SOC bound in microbial biomass, which might result in higher susceptibility of SOC transformation to fluctuation of environmental factors, and (ii) low mineralization potential, but with a substantial part of the consumed C being transformed to microbial products.3. The soil microbial community from the northernmost study region located within the permafrost zone appears to be adapted to cold conditions. As a result, microbial net growth rate became negative when temperature rose above 5 °C and C mineralization then exceeded C accumulation.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1399-3054
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: Leaf gas exchange, water relations and ion content were measured on two-year-old Valencia orange (Citrus sinensis [L.] Osbeck), Washington Navel orange (C. sinensis) and Marsh grapefruit (C. parodisi Macfad) scions budded to either Trifoliata (Poncirus infoliata [L] Raf) or Cleopatra mandarin (C. reticuLua Blanco) rootstoeks. Trees were watered with dülute nutrient solution containing either 0 or 50 mM NaCl for 77 days. Leaf chloride concentrations (cell sap basis) were higher in all scions budded on “Trifoliata but sodium levels were lower than in equivalent foliage budded on Cleopatra mandarin rootstock. Foliar salt levels also varied according to scion. Leaves of Marsh grapefruit had higher levels of both sodium and chloride than leaves of either Valencia orange or Washington Navel orange on both rootstocks. Accumulation of sodium and chloride in salinised leaves caused a reduction in leaf osmotic potential of 0.2–1.4 MPa. and leaf water potential declined by as much as 0.5 MPa. Turgor pressure in salinised leaves was thus maintained at or above the control level. Osmotic potentials determined by psychrometry compared with pressure-volume curves were taken to imply that some accumulation of sodium or chloride in the apoplast of salinised leaves may have occurred.Despite turgor maintenance both co2 assimilation and stomatal conductance were reduced by salinity. Following onset of leaf response to salinisation, gas exchange was impaired to a greater extent in scions budded to Cleopatra mandarin compared to those on Trifoliata. Amongst those scions. leaves of salt-treated Marsh grapefruit showed greater reductions in gas exchange than Valencia orange or Washington Navel orange budded on either rootstock. Increased sensitivity of 1Marsh grapefruit was correlated with a higher foliar sodium and chloride content in this scion. Scion differences in sensitivity of leaf gas exchange to solute concentration were independent of rootstock and appeared unrelated to leaf prolinebetaine concentrations. This implies an inherent difference between scion species with respect to salt tolerance, rather than variation in their capacity to acquire that type of compatible solute.In terms of rootstock effects, all scions proved more sensitive to salinity when budded to Cleopatra mandarin compared with Trifoliata. That response was attributed to a disproportionately higher concentration of leaf sodium in scions on Cleopatra mandarin.
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  • 9
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Uncertainty in biomass estimates is one of the greatest limitations to models of carbon flux in tropical forests. Previous comparisons of field-based estimates of the aboveground biomass (AGB) of trees greater than 10 cm diameter within Amazonia have been limited by the paucity of data for western Amazon forests, and the use of site-specific methods to estimate biomass from inventory data. In addition, the role of regional variation in stand-level wood specific gravity has not previously been considered. Using data from 56 mature forest plots across Amazonia, we consider the relative roles of species composition (wood specific gravity) and forest structure (basal area) in determining variation in AGB.Mean stand-level wood specific gravity, on a per stem basis, is 15.8% higher in forests in central and eastern, compared with northwestern Amazonia. This pattern is due to the higher diversity and abundance of taxa with high specific gravity values in central and eastern Amazonia, and the greater diversity and abundance of taxa with low specific gravity values in western Amazonia. For two estimates of AGB derived using different allometric equations, basal area explains 51.7% and 63.4%, and stand-level specific gravity 45.4% and 29.7%, of the total variation in AGB. The variation in specific gravity is important because it determines the regional scale, spatial pattern of AGB. When weighting by specific gravity is included, central and eastern Amazon forests have significantly higher AGB than stands in northwest or southwest Amazonia. The regional-scale pattern of species composition therefore defines a broad gradient of AGB across Amazonia.
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  • 10
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: We studied the seasonal variation in carbon dioxide, water vapour and energy fluxes in a broad-leafed semi-arid savanna in Southern Africa using the eddy covariance technique. The open woodland studied consisted of an overstorey dominated by Colophospermum mopane with a sparse understorey of grasses and herbs. Measurements presented here cover a 19-month period from the end of the rainy season in March 1999 to the end of the dry season September 2000.During the wet season, sensible and latent heat fluxes showed a linear dependence on incoming solar radiation (I) with a Bowen ratio (β) typically just below unity. Although β was typically around 1 at low incoming solar radiation (150 W m−2) during the dry season, it increased dramatically with I, typically being as high as 4 or 5 around solar noon. Thus, under these water-limited conditions, almost all available energy was dissipated as sensible, rather than latent heat.Marked spikes of CO2 release occurred at the onset of the rainfall season after isolated rainfall events and respiration dominated the balance well into the rainfall season. During this time, the ecosystem was a constant source of CO2 with an average flux of 3–5 μmol m−2 s−1 to the atmosphere during both day and night. But later in the wet season, for example, in March 2000 under optimal soil moisture conditions, with maximum leaf canopy development (leaf area index 0.9–1.3), the peak ecosystem CO2 influx was as much as 10 μmol m−2 s−1. The net ecosystem maximum photosynthesis at this time was estimated at 14 μmol m−2 s−1, with the woodland ecosystem a significant sink for CO2. During the dry season, just before leaf fall in August, maximum day- and night-time net ecosystem fluxes were typically −3 μmol m−2 s−1 and 1–2 μmol m−2 s−1, respectively, with the ecosystem still being a marginal sink.Over the course of 12 months (March 1999–March 2000), the woodland was more or less carbon neutral, with a net uptake estimated at only about 1 mol C m−2 yr−1. The annual net photosynthesis (gross primary production) was estimated at 32.2 mol m−2 yr−1.
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