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  • 1
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    Eruption of a deep-sea mud volcano triggers rapid sediment movement (2014)
    Nature Publishing Group
    In:  Nature Communications, 5 (5385).
    Details
    Publication Date: 2019-07-10
    Description: Submarine mud volcanoes are important sources of methane to the water column. However, the temporal variability of their mud and methane emissions is unknown. Methane emissions were previously proposed to result from a dynamic equilibrium between upward migration and consumption at the seabed by methane-consuming microbes. Here we show non-steady-state situations of vigorous mud movement that are revealed through variations in fluid flow, seabed temperature and seafloor bathymetry. Time series data for pressure, temperature, pH and seafloor photography were collected over 431 days using a benthic observatory at the active Hakon Mosby Mud Volcano. We documented 25 pulses of hot subsurface fluids, accompanied by eruptions that changed the landscape of the mud volcano. Four major events triggered rapid sediment uplift of more than a metre in height, substantial lateral flow of muds at average velocities of 0.4m per day, and significant emissions of methane and CO2 from the seafloor.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Format: text
    DOI: 10.1038/ncomms6385
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 2
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    Active methane venting observed at giant pockmarks along the U.S. mid-Atlantic shelf break (2008)
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © Elsevier B.V., 2007. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Earth and Planetary Science Letters 267 (2008): 341-352, doi:10.1016/j.epsl.2007.11.053.
    Description: Detailed near-bottom investigation of a series of giant, kilometer scale, elongate pockmarks along the edge of the mid-Atlantic continental shelf confirms that methane is actively venting at the site. Dissolved methane concentrations, which were measured with a commercially available methane sensor (METS) designed by Franatech GmbH mounted on an autonomous underwater vehicle (AUV), are as high as 100 nM. These values are well above expected background levels (1-4 nM) for the open ocean. Sediment pore water geochemistry gives further evidence of methane advection through the seafloor. Isotopically light carbon in the dissolved methane samples indicates a primarily biogenic source. The spatial distribution of the near-bottom methane anomalies (concentrations above open ocean background), combined with water column salinity and temperature vertical profiles, indicate that methane-rich water is not present across the entire width of the pockmarks, but is laterally restricted to their edges. We suggest that venting is primarily along the top of the pockmark walls with some advection and dispersion due to local currents. The highest methane concentrations observed with the METS sensor occur at a small, circular pockmark at the southern end of the study area. This observation is compatible with a scenario where the larger, elongate pockmarks evolve through coalescing smaller pockmarks.
    Description: This work was supported by NSF grants OCE- 0242426, OCE-0242804 and OCDE-0242449 and ONR grant N00014-02-1-0691.
    Keywords: Pockmarks ; Seafloor venting ; Methane ; AUV
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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  • 3
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    The 2005 Chios ancient shipwreck survey : new methods for underwater archaeology (2009)
    American School of Classical Studies at Athens
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American School of Classical Studies at Athens, 2009. This article is posted here by permission of American School of Classical Studies at Athens for personal use, not for redistribution. The definitive version was published in Hesperia 78 (2009): 269-305, doi:10.2972/hesp.78.2.269.
    Description: In 2005 a Greek and American interdisciplinary team investigated two shipwrecks off the coast of Chios dating to the 4th-century b.c. and the 2nd/1st century. The project pioneered archaeological methods of precision acoustic, digital image, and chemical survey using an autonomous underwater vehicle (AUV) and in-situ sensors, increasing the speed of data acquisition while decreasing costs. The AUV recorded data revealing the physical dimensions, age, cargo, and preservation of the wrecks. The earlier wreck contained more than 350 amphoras, predominantly of Chian type, while the Hellenistic wreck contained about 40 Dressel 1C amphoras. Molecular biological analysis of two amphoras from the 4th-century wreck revealed ancient DNA of olive, oregano, and possibly mastic, part of a cargo outbound from Chios.
    Description: We gratefully acknowledge the support of the Hellenic Ministry of Culture, the Hellenic Centre for Marine Research, the U.S. National Science Foundation; the SeaBED AUV and the efforts of its team were funded by the Censsis Engineering Research Center under NSF grant no. EEC9986821.
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 4
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    The Kallisti Limnes, carbon dioxide-accumulating subsea pools (2015)
    Nature Publishing Group
    Details
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Scientific Reports 5 (2015): 12152, doi:10.1038/srep12152.
    Description: Natural CO2 releases from shallow marine hydrothermal vents are assumed to mix into the water column, and not accumulate into stratified seafloor pools. We present newly discovered shallow subsea pools located within the Santorini volcanic caldera of the Southern Aegean Sea, Greece, that accumulate CO2 emissions from geologic reservoirs. This type of hydrothermal seafloor pool, containing highly concentrated CO2, provides direct evidence of shallow benthic CO2 accumulations originating from sub-seafloor releases. Samples taken from within these acidic pools are devoid of calcifying organisms, and channel structures among the pools indicate gravity driven flow, suggesting that seafloor release of CO2 at this site may preferentially impact benthic ecosystems. These naturally occurring seafloor pools may provide a diagnostic indicator of incipient volcanic activity and can serve as an analog for studying CO2 leakage and benthic accumulations from subsea carbon capture and storage sites.
    Description: This research was supported by the Eurofleets Caldera 2012 Project (EU), a NASA Astrobiology Science & Technology for Exploring Planets grant #NNX09AB76G (USA), a CAREER Award grant #OCE-0955674 to R. Camilli from the National Science Foundation (USA), and IPGP (France).
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 5
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    Toward extraplanetary under-ice exploration : robotic steps in the Arctic (2009)
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2009. This is the author's version of the work. It is posted here by permission of John Wiley & Sons for personal use, not for redistribution. The definitive version was published in Journal of Field Robotics 26 (2009): 411-429, doi:10.1002/rob.20288.
    Description: This paper describes the design and use of two new autonomous underwater vehicles, Jaguar and Puma, which were deployed in the summer of 2007 at sites at 85°N latitude in the ice-covered Arctic Ocean to search for hydrothermal vents. These robots are the first to be deployed and recovered through ice to the deep ocean (〉 3500m) for scientific research. We examine the mechanical design, software architecture, navigation considerations, sensor suite and issues with deployment and recovery in the ice based on the missions they carried out. Successful recoveries of vehicles deployed under the ice requires two-way acoustic communication, flexible navigation strategies, redundant localization hardware, and software that can cope with several different kinds of failure. The ability to direct an AUV via the low bandwidth and intermittently functional acoustic channel, is of particular importance. Based on our experiences, we also discuss the applicability of the technology and operational approaches of this expedition to the exploration of Jupiter's ice-covered moon Europa.
    Description: This work was made possible in part through NSF OPP grant OPP-0425838, through the NASA ASTEP program through grant Z601701, through NSF Censsis ERC through grant EEC-9986821 and through funding from the Woods Hole Oceanographic Institution.
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 6
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    Toward autonomous exploration in confined underwater environments (2017)
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    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2015. This is the author's version of the work. It is posted here by permission of John Wiley & Sons for personal use, not for redistribution. The definitive version was published in Journal of Field Robotics 33 (2016): 994-1012, doi:10.1002/rob.21640.
    Description: In this field note we detail the operations and discuss the results of an experiment conducted in the unstructured environment of an underwater cave complex, using an autonomous underwater vehicle (AUV). For this experiment the AUV was equipped with two acoustic sonar to simultaneously map the caves’ horizontal and vertical surfaces. Although the caves’ spatial complexity required AUV guidance by a diver, this field deployment successfully demonstrates a scan matching algorithm in a simultaneous localization and mapping (SLAM) framework that significantly reduces and bounds the localization error for fully autonomous navigation. These methods are generalizable for AUV exploration in confined underwater environments where surfacing or pre-deployment of localization equipment are not feasible and may provide a useful step toward AUV utilization as a response tool in confined underwater disaster areas.
    Description: This research work was partially sponsored by the EU FP7-Projects: Tecniospring- Marie Curie (TECSPR13-1-0052), MORPH (FP7-ICT-2011-7-288704), Eurofleets2 (FP7-INF-2012-312762), and the National Science Foundation (OCE-0955674).
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 7
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    Dissolved methane distributions and air-sea flux in the plume of a massive seep field, Coal Oil Point, California (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 34 (2007): L22603, doi:10.1029/2007GL031344.
    Description: Large quantities of natural gas are emitted from the seafloor into the stratified coastal ocean near Coal Oil Point, Santa Barbara Channel, California. Methane was quantified in the down current surface water at 79 stations in a 280 km2 study area. The methane plume spread over an area of ~70 km2 and emitted on the order of 5 × 104 mol d−1 to the atmosphere. A monthly time series at 14 stations showed variable methane concentrations which were correlated with changing sub-mesoscale surface currents. Air-sea fluxes estimated from the time series indicate that the air-sea flux derived for the 280 km2 area is representative of the daily mean flux from this area. Only 1% of the dissolved methane originating from Coal Oil Point enters the atmosphere within the study area. Most of it appears to be transported below the surface and oxidized by microbial activity.
    Description: The research was supported by the University of California Energy Institute and the National Science Foundation (OCE 0447395).
    Keywords: Air-sea flux ; Shallow marine seep ; Methane
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/postscript
    Format: application/pdf
    Format: text/plain
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  • 8
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    Coupled radon, methane and nitrate sensors for large-scale assessment of groundwater discharge and non-point source pollution to coastal waters (2010)
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2009. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Journal of Environmental Radioactivity 101 (2010): 553-563, doi:10.1016/j.jenvrad.2009.12.004.
    Description: We constructed a survey system of radon/methane/nitrate/salinity to find sites of submarine groundwater discharge (SGD) and groundwater nitrate input. We deployed the system in Waquoit Bay and Boston Harbor, MA where we derived SGD rates using a mass balance of radon with methane serving as a fine resolution qualitative indicator of groundwater. In Waquoit Bay we identified several locations of enhanced groundwater discharge, out of which two (Childs and Quashnet Rivers) were studied in more detail. The Childs River was characterized by high nitrate input via groundwater discharge, while the Quashnet River SGD was notable but not a significant source of nitrate. Our radon survey of Boston Harbor revealed several sites with significant SGD, out of these Inner Harbor and parts of Dorchester Bay and Quincy Bay had groundwater fluxes accompanied by significant water column nitrogen concentrations. The survey system has proven effective in revealing areas of SGD and non-point source pollution.
    Description: R. Camilli acknowledges the National Ocean Partnership Program (NOPP) for supporting the development of the TETHYS mass spectrometer through research grant #OCE-0537173. H. Dulaiova, M. A. Charette and R. Camilli acknowledge funding support from the WHOI Coastal Institute and MIT Sea Grant College Program under NOAA grant number NA06OAR4170019, project number 5710002173. H. Dulaiova was funded by the WHOI Academic Program’s postdoctoral scholarship.
    Keywords: Non-point source pollution ; Submarine groundwater discharge ; Methane ; Radon ; Nitrate ; Waquoit Bay ; Boston Harbor
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 9
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    Chemical data quantify Deepwater Horizon hydrocarbon flow rate and environmental distribution (2012)
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2011. This is the author's version of the work. It is posted here by permission of National Academy of Sciences for personal use, not for redistribution. The definitive version was published in Proceedings of the National Academy of Sciences of the United States of America (2012), doi:10.1073/pnas.1110564109.
    Description: Detailed airborne, surface, and subsurface chemical measurements, primarily obtained in May and June 2010, are used to quantify initial hydrocarbon compositions along different transport pathways – in deep subsurface plumes, in the initial surface slick, and in the atmosphere – during the Deepwater Horizon (DWH) oil spill. Atmospheric measurements are consistent with a limited area of surfacing oil, with implications for leaked hydrocarbon mass transport and oil drop size distributions. The chemical data further suggest relatively little variation in leaking hydrocarbon composition over time. While readily soluble hydrocarbons made up ~25% of the leaking mixture by mass, subsurface chemical data show these compounds made up ~69% of the deep plume mass; only ~31% of deep plume mass was initially transported in the form of trapped oil droplets. Mass flows along individual transport pathways are also derived from atmospheric and subsurface chemical data. Subsurface hydrocarbon composition, dissolved oxygen, and dispersant data are used to provide a new assessment of release of hydrocarbons from the leaking well. We use the chemical measurements to estimate that (7.8±1.9) x106 kg of hydrocarbons leaked on June 10, 2010, directly accounting for roughly three-quarters of the total leaked mass on that day. The average environmental release rate of (10.1 ± 2.0) x106 kg/day derived using atmospheric and subsurface chemical data agrees within uncertainties with the official average leak rate of (10.2 ± 1.0) x106 kg/day derived using physical and optical methods.
    Description: This research was supported by the National Science Foundation through grants to D. Blake (AGS-1049952), J. Kessler (OCE-1042650 and OCE-0849246), D. Valentine (OCE-1042097 and OCE-0961725), E. Kujawinski (OCE-1045811), and R. Camilli (OCE-1043976), by U.S. Coast Guard contract to R. Camilli (Contract HSCG3210CR0020), and by U.S. Department of Energy grant to D. Valentine (DE- NT0005667). The August, September, and October research cruises were funded by NOAA through a contract with Consolidated Safety Services, Incorporated. The NOAA P-3 oil spill survey flights were funded in part by NOAA and in part by a U.S. Coast Guard Pollution Removal Funding Authorization to NOAA.
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 10
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    Flow rate and source reservoir identification from airborne chemical sampling of the uncontrolled Elgin platform gas release (2018)
    Copernicus Publications on behalf of the European Geosciences Union
    Details
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Atmospheric Measurement Techniques 11 (2018): 1725-1739, doi:10.5194/amt-11-1725-2018.
    Description: An uncontrolled gas leak from 25 March to 16 May 2012 led to evacuation of the Total Elgin wellhead and neighbouring drilling and production platforms in the UK North Sea. Initially the atmospheric flow rate of leaking gas and condensate was very poorly known, hampering environmental assessment and well control efforts. Six flights by the UK FAAM chemically instrumented BAe-146 research aircraft were used to quantify the flow rate. The flow rate was calculated by assuming the plume may be modelled by a Gaussian distribution with two different solution methods: Gaussian fitting in the vertical and fitting with a fully mixed layer. When both solution methods were used they compared within 6 % of each other, which was within combined errors. Data from the first flight on 30 March 2012 showed the flow rate to be 1.3 ± 0.2 kg CH4 s−1, decreasing to less than half that by the second flight on 17 April 2012. δ13CCH4 in the gas was found to be −43 ‰, implying that the gas source was unlikely to be from the main high pressure, high temperature Elgin gas field at 5.5 km depth, but more probably from the overlying Hod Formation at 4.2 km depth. This was deemed to be smaller and more manageable than the high pressure Elgin field and hence the response strategy was considerably simpler. The first flight was conducted within 5 days of the blowout and allowed a flow rate estimate within 48 h of sampling, with δ13CCH4 characterization soon thereafter, demonstrating the potential for a rapid-response capability that is widely applicable to future atmospheric emissions of environmental concern. Knowledge of the Elgin flow rate helped inform subsequent decision making. This study shows that leak assessment using appropriately designed airborne plume sampling strategies is well suited for circumstances where direct access is difficult or potentially dangerous. Measurements such as this also permit unbiased regulatory assessment of potential impact, independent of the emitting party, on timescales that can inform industry decision makers and assist rapid-response planning by government.
    Repository Name: Woods Hole Open Access Server
    Type: Article
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