GLORIA

GEOMAR Library Ocean Research Information Access

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • American Chemical Society (ACS)  (16)
  • American Institute of Physics (AIP)  (7)
  • Nature Publishing Group  (5)
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 2843-2860 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Zero electron kinetic energy threshold photoelectron spectroscopy is applied to jet cooled aniline and the van der Waals molecules aniline–Ar, aniline–(Ar)2, and aniline–CH4. The monomer cation spectrum is assigned and more precise values of the vibrational frequencies are determined. The spectra of the cation complexes reveal significant vibronic activity indicative of a significant change in complex geometry upon ionization. The change in complex binding energy upon ionization is obtained from a determination of the complex ionization potentials. For the first time zero electron kinetic energy is used to probe van der Waals complex predissociation on the S1 electronic surface. Both reactants (complex) and products (monomer) of the reaction are observed in the photoelectron spectrum. Details of the mechanism of the zero electron kinetic energy threshold photoionization process and its impact on the observation of van der Waals molecules are discussed.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 2550-2559 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Intramolecular vibrational energy redistribution (IVR) and vibrational predissociation (VP) are measured for a number of vibronic states in the S1 electronic state of the aniline-CH4 complex. The detailed dynamics are monitored using picosecond threshold photoelectron spectroscopy which is shown to be a sensitive probe of van der Waals molecule dynamics. For the lowest vibrational states accessed, the 6a10 and 6a10+24 cm−1 bands, both IVR and VP are observed and their rates are independently determined. At higher excess energy, IVR becomes the rate limiting step and the rate for VP cannot be measured independently. The results are interpreted using a serial dissociation mechanism with a simple kinetic model description. The rates of the reaction are modeled using standard Rice–Ramsperger–Kassel–Marcus (RRKM) theory which qualitatively predicts rates consistent with the experimental observations.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 3133-3136 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Studies are performed which measure the lifetime of very high lying molecular Rydberg states which play a central role in high resolution threshold ionization spectroscopy. The molecular systems investigated are styrene, phenol, and phenanthrene as well as the atomic iron system for comparison. It is shown that the lifetimes of the highest lying levels are determined not by intramolecular nonradiative processes but by intermolecular Rydberg–ion or Rydberg–Rydberg interactions. Under low fluence laser excitation, the highest lying Rydberg states are observed to have a lifetime greater than 25 μs but under high fluence the observed lifetime is ∼4 μs. The long Rydberg lifetimes are utilized to implement a simplified spectrometer for mass analyzed threshold ionization (MATI) spectroscopy.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 100 (1994), S. 2429-2436 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Picosecond pump–probe threshold photoelectron spectroscopy was used to investigate the vibrational dynamics of four vibrational bands in the S1 state of p-difluorobenzene in the range 2000 to 2900 cm−1. In this energy region the vibrations exhibited intermediate case restricted vibrational dynamics as evidenced by observed quantum beats as well as irreversible statistical limit decay. More complete coverage of the S1 state was prohibited by the wavelength restrictions on both the pump and probe laser wavelengths required in the experiment. The observed restricted vibrational redistribution is in contrast to the very rapid irreversible decays inferred from room temperature, high pressure chemical timing experiments on the same molecular bands. The differences are discussed in terms of the role of molecular rotations and the possible different experimental observations.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 8239-8251 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Fluorene–Arn complexes formed in a pulsed supersonic jet have been studied in their S1 state using two color REMPI spectroscopy with mass resolved detection. The appearance and shifts of the S1 origins relative to the fluorene monomer are measured for cluster sizes up to n=30. The shifts and appearance of these bands are used to identify multiple conformations at low n and have indicated a shift from two sided clustering by Ar at low n to primarily one sided clustering at large n. The ionic ground state of the smaller clusters (n≤6) are studied using mass analyzed threshold ionization (MATI) spectroscopy. The change of the ionization potentials as a function of cluster size has been determined. In the case of the fluorene–Ar4 cluster, the MATI spectrum of two separate cluster conformations was measured, revealing significantly different ionization potentials. Vibrational dynamics has been studied in several smaller clusters (n≤3) by measuring MATI and ZEKE spectra when pumping vibronic transitions in the fluorene chromophore. Significantly enhanced coupling of the chromophore to van der Waals modes is observed in going from n=1 to n=3. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 6
    ISSN: 1546-1718
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Medicine
    Notes: [Auszug] We used illegitimate transcription in lymphoblastoid cell lines6 to obtain laminin α2 chain mRNA from probands of consanguineous laminin α2 and non-consanguineous chain-deficient families for mutation analysis by RT-PCR. Twenty-four pairs of overlapping primers (see Methods) were ...
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 7
    ISSN: 1072-8368
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Medicine
    Notes: [Auszug] DNA-adenine methylation at certain GATC sites plays a pivotal role in bacterial and phage gene expression as well as bacterial virulence. We report here the crystal structures of the bacteriophage T4Dam DNA adenine methyltransferase (MTase) in a binary complex with the methyl-donor product ...
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 8
    facet.materialart.
    Unknown
    Nature Publishing Group
    In:  EPIC3Nature, Nature Publishing Group, 512(7514), pp. 290-294, ISSN: 0028-0836
    Publication Date: 2014-09-04
    Description: During glacial periods of the Late Pleistocene, an abundance of proxy data demonstrates the existence of large and repeated millennial-scale warming episodes, known as Dansgaard–Oeschger (DO) events1. This ubiquitous feature of rapid glacial climate change can be extended back as far as 800,000 years before present (BP) in the ice core record2, and has drawn broad attention within the science and policy-making communities alike3. Many studies have been dedicated to investigating the underlying causes of these changes, but no coherent mechanism has yet been identified3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15. Here we show, by using a comprehensive fully coupled model16, that gradual changes in the height of the Northern Hemisphere ice sheets (NHISs) can alter the coupled atmosphere–ocean system and cause rapid glacial climate shifts closely resembling DO events. The simulated global climate responses—including abrupt warming in the North Atlantic, a northward shift of the tropical rainbelts, and Southern Hemisphere cooling related to the bipolar seesaw—are generally consistent with empirical evidence1, 3, 17. As a result of the coexistence of two glacial ocean circulation states at intermediate heights of the ice sheets, minor changes in the height of the NHISs and the amount of atmospheric CO2 can trigger the rapid climate transitions via a local positive atmosphere–ocean–sea-ice feedback in the North Atlantic. Our results, although based on a single model, thus provide a coherent concept for understanding the recorded millennial-scale variability and abrupt climate changes in the coupled atmosphere–ocean system, as well as their linkages to the volume of the intermediate ice sheets during glacials.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 9
    Publication Date: 2020-04-14
    Description: The Asian monsoon (AM) played an important role in the dynastic history of China, yet it remains unknown whether AM-mediated shifts in Chinese societies affect earth surface processes to the point of exceeding natural variability. Here, we present a dust storm intensity record dating back to the first unified dynasty of China (the Qin Dynasty, 221–207 B.C.E.). Marked increases in dust storm activity coincided with unified dynasties with large populations during strong AM periods. By contrast, reduced dust storm activity corresponded to decreased population sizes and periods of civil unrest, which was co-eval with a weakened AM. The strengthened AM may have facilitated the development of Chinese civilizations, destabilizing the topsoil and thereby increasing the dust storm frequency. Beginning at least 2000 years ago, human activities might have started to overtake natural climatic variability as the dominant controls of dust storm activity in eastern China.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 10
    Publication Date: 2021-02-03
    Description: The dominant feature of large-scale mass transfer in the modern ocean is the Atlantic meridional overturning circulation (AMOC). The geometry and vigour of this circulation influences global climate on various timescales. Palaeoceanographic evidence suggests that during glacial periods of the past 1.5 million years the AMOC had markedly different features from today; in the Atlantic basin, deep waters of Southern Ocean origin increased in volume while above them the core of the North Atlantic Deep Water (NADW) shoaled. An absence of evidence on the origin of this phenomenon means that the sequence of events leading to global glacial conditions remains unclear. Here we present multi-proxy evidence showing that northward shifts in Antarctic iceberg melt in the Indian–Atlantic Southern Ocean (0–50°E) systematically preceded deep-water mass reorganizations by one to two thousand years during Pleistocene-era glaciations. With the aid of iceberg-trajectory model experiments, we demonstrate that such a shift in iceberg trajectories during glacial periods can result in a considerable redistribution of freshwater in the Southern Ocean. We suggest that this, in concert with increased sea-ice cover, enabled positive buoyancy anomalies to ‘escape’ into the upper limb of the AMOC, providing a teleconnection between surface Southern Ocean conditions and the formation of NADW. The magnitude and pacing of this mechanism evolved substantially across the mid-Pleistocene transition, and the coeval increase in magnitude of the ‘southern escape’ and deep circulation perturbations implicate this mechanism as a key feedback in the transition to the ‘100-kyr world’, in which glacial–interglacial cycles occur at roughly 100,000-year periods.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...