Description: It is a longstanding observation that the frequency of volcanism periodically changes at times of global climate change. The existence of causal links between volcanism and Earth's climate remains highly controversial, partly because most related studies only cover one glacial cycle. Longer records are available from marine sediment profiles in which the distribution of tephras records frequency changes of explosive arc volcanism with high resolution and time precision. Here we show that tephras of IODP Hole U1437B (northwest Pacific) record a cyclicity of explosive volcanism within the last 1.1 Myr. A spectral analysis of the dataset yields a statistically significant spectral peak at the similar to 100 kyr period, which dominates the global climate cycles since the Middle Pleistocene. A time-domain analysis of the entire eruption and delta O-18 record of benthic foraminifera as climate/sea level proxy shows that volcanism peaks after the glacial maximum and similar to 13 +/- 2 kyr before the delta O-18 minimum right at the glacial/interglacial transition. The correlation is especially good for the last 0.7 Myr. For the period 0.7-1.1 Ma, during the Middle Pleistocene Transition (MPT), the correlation is weaker, since the 100 kyr periodicity in the delta O-18 record diminishes, while the tephra record maintains its strong 100 kyr periodicity.

Description: Highlights • Individual evolution of temporal and spatial co-existing magma suites • Determination of pre-eruptive magma chamber conditions of the Cão Grande Formation magma chambers • Cão Grande Formation phonolite magmas typically reach H2O-saturation prior to the eruption. Abstract The Cão Grande Formation (CGF) on the western plateau of Santo Antão is a sequence of four phonolitic tephras (Canudo Tephra, Cão Grande I Tephra, Cão Grande II Tephra and Furninha Tephra) produced by highly explosive eruptions that alternatingly originated from a basanitic - phonolitic and a nephelinitic - phonolitic magmatic system. Detailed stratigraphy and petrological investigations of each unit are used to demonstrate the unusual situation that two distinct highly evolved magmas differentiated contemporaneously in separate magmatic systems. Chemical thermobarometry suggests that both magmatic systems not only temporally co-existed, but also that their magma chambers resided close to each other at 7 to 16 km depth, beneath the western plateau of Santo Antão. However, the distinct melt and magma compositions indicate that both systems evolved independently. The only interaction between both magmatic systems was an injection of magma from the nephelinitic - phonolitic magmatic system into the Cão Grande II Tephra (CG II) phonolitic reservoir, which is associated to the basanitic - phonolitic magmatic system. Compositional zonations in the tephra deposits indicate that the eruptions of the CGF tapped stratified magma reservoirs that mainly resulted from crystal accumulation generating downward increasing magma density. However, the CG II tephras also show a significant gradient in melt (glass) compositions. Magmas of the Canudo Tephra (CT) and the Cão Grande I Tephra (CG I) were H2O-saturated and their eruptions were probably triggered by fluid overpressure in the magma chamber. On the other hand, the CG II magma was H2O-undersaturated; we therefore assume that the injection of the hot nephelinitic - phonolitic magma system-type melt/magma triggered the eruption. The zoned deposit of the Furninha Tephra (FT) indicates mafic magma replenishment into a phonolitic reservoir directly prior to the eruption, thus providing a probable triggering mechanism. The new magma chamber models and thermobarometric results for the four CGF units provide constraints for hazard assessments, because similar events may occur in the future considering the longevity of the CGF magma systems.

Description: This study investigates the types of subaqueous deposits that occur when hot pyroclastic flows turbulently mix with water at the shoreline through field studies of the Znp marine tephra in Japan and flume experiments where hot tephra sample interacted with water. The Znp is a very thick, pumice-rich density current deposit that was sourced from subaerial pyroclastic flows entering the Japan Sea in the Pliocene. Notable characteristics are well-developed grain size and density grading (lithic-rich base, pumice-rich middle, and ash-rich top), preponderance of sedimentary lithic clasts picked up from the seafloor during transport, fine ash depletion in coarse facies, and presence of curviplanar pumice clasts. Flume experiments provide a framework for interpreting the origin and proximity to source of the Znp tephra. On contact of hot tephra sample with water, steam explosions produced a gas-supported pyroclastic density current that advanced over the water while a water-supported density current was produced on the tank floor from the base of a turbulent mixing zone. Experimental deposits comprise proximal lithic breccia, medial pumice breccia, and distal fine ash. Experiments undertaken with cold, water-saturated slurries of tephra sample and water did not produce proximal lithic breccias but a medial basal lithic breccia beneath an upper pumice breccia. Results suggest the characteristics and variations in Znp facies were strongly controlled by turbulent mixing and quenching, proximity to the shoreline, and depositional setting within the basin. Presence of abundant curviplanar pumice clasts in submarine breccias reflects brittle fracture and dismembering that can occur during fragmentation at the vent or during quenching. Subsequent transport in water-supported pumiceous density currents preserves the fragmental textures. Careful study is needed to distinguish the products of subaerial versus subaqueous eruptions.

Description: After more than a decade of multidisciplinary studies of the Central American subduction zone mainly in the framework of two large research programmes, the US MARGINS program and the German Collaborative Research Center SFB 574, we here review and interpret the data pertinent to quantify the cycling of mineral-bound volatiles (H2O, CO2, Cl, S) through this subduction system. For input-flux calculations, we divide the Middle America Trench into four segments differing in convergence rate and slab lithological profiles, use the latest evidence for mantle serpentinization of the Cocos slab approaching the trench, and for the first time explicitly include subduction erosion of forearc basement. Resulting input fluxes are 40–62 (53) Tg/Ma/m H2O, 7.8–11.4 (9.3) Tg/Ma/m CO2, 1.3–1.9 (1.6) Tg/Ma/m Cl, and 1.3–2.1 (1.6) Tg/Ma/m S (bracketed are mean values for entire trench length). Output by cold seeps on the forearc amounts to 0.625–1.25 Tg/Ma/m H2O partly derived from the slab sediments as determined by geochemical analyses of fluids and carbonates. The major volatile output occurs at the Central American volcanic arc that is divided into ten arc segments by dextral strike-slip tectonics. Based on volcanic edifice and widespread tephra volumes as well as calculated parental magma masses needed to form observed evolved compositions, we determine long-term (105 years) average magma and K2O fluxes for each of the ten segments as 32–242 (106) Tg/Ma/m magma and 0.28–2.91 (1.38) Tg/Ma/m K2O (bracketed are mean values for entire Central American volcanic arc length). Volatile/K2O concentration ratios derived from melt inclusion analyses and petrologic modelling then allow to calculate volatile fluxes as 1.02–14.3 (6.2) Tg/Ma/m H2O, 0.02–0.45 (0.17) Tg/Ma/m CO2, and 0.07–0.34 (0.22) Tg/Ma/m Cl. The same approach yields long-term sulfur fluxes of 0.12–1.08 (0.54) Tg/Ma/m while present-day open-vent SO2-flux monitoring yields 0.06–2.37 (0.83) Tg/Ma/m S. Input–output comparisons show that the arc water fluxes only account for up to 40 % of the input even if we include an “invisible” plutonic component constrained by crustal growth. With 20–30 % of the H2O input transferred into the deeper mantle as suggested by petrologic modeling, there remains a deficiency of, say, 30–40 % in the water budget. At least some of this water is transferred into two upper-plate regions of low seismic velocity and electrical resistivity whose sizes vary along arc: one region widely envelopes the melt ascent paths from slab top to arc and the other extends obliquely from the slab below the forearc to below the arc. Whether these reservoirs are transient or steady remains unknown.

Description: During IODP Expedition 322, an interval of Late Miocene (7.6 to ∼9.1 Ma) tuffaceous and volcaniclastic sandstones was discovered in the Shikoku Basin (Site C0011B), Nankai region. This interval consists of bioturbated silty claystone including four 1–7 m thick interbeds of tuffaceous sandstones (TST) containing 57–82% (by volume) pyroclasts. We use major and trace element glass compositions, as well as radiogenic isotope compositions, to show that the tuffaceous sandstones beds derived from single eruptive events, and that the majority (TST 1, 2, 3a) came from different eruptions from a similar source region, which we have identified to be the Japanese mainland, 350 km away. In particular, diagnostic trace element ratios (e.g., Th/La, Sm/La, Rb/Hf, Th/Nb, and U/Th) and isotopic data indicate a marked contribution from a mantle source beneath continental crust, which is most consistent with a Japanese mainland source and likely excludes the Izu-Bonin island arc and back arc as a source region for the younger TST beds. Nevertheless, some of the chemical data measured on the oldest sandstone bed (TST 3b, Unit IIb) show affinity to or can clearly be attributed to an Izu-Bonin composition. While we cannot completely exclude the possibility that all TST beds derived from unknown and exotic Izu-Bonin source(s), the collected lines of evidence are most consistent with an origin from the paleo-Honshu arc for TST 1 through 3a. We therefore suggest the former collision zone between the Izu-Bonin arc and Honshu paleo-arc as the most likely region where the eruptive products entered the ocean, also concurrent with nearby (∼200 km) possible Miocene source areas for the tuffaceous sandstones at the paleo-NE-Honshu arc. Estimating the distribution area of the tuffaceous sandstones in the Miocene between this source region and the ∼350 km distant Expedition 322, using bathymetric constraints, we calculate that the sandstone beds represent minimum erupted magma volumes between ∼1 and 17 km3 (Dense Rock Equivalent (DRE)). We conclude that several large volume eruptions occurred during the Late Miocene time next to the collision zone of paleo-Honshu and Izu-Bonin arc and covered the entire Philippine Sea plate with meter thick, sheet-like pyroclastic deposits that are now subducted in the Nankai subduction zone.

Description: The structural, temporal, compositional and volcanic evolution of oceanic intraplate islands is one of the major research areas in our department. A regional focus is on the island groups and seamounts along the passive margin off Northwest Africa. The Canary Islands which are characterized by an unususally large compositional spectrum of igneous rocks and long magmatic histories, exceeding 20 Ma in some islands, are the main target area for our ongoing combined on- and offshore studies. We here report on specific events and stages in the structural and chemical evolution of the island of Gran Canaria and its sedimentary apron using a variety of methods. Detailed studies of constructive and destructive processes during island evolution have allowed to predict - and verify by deep sea drilling - the submarine and subaerial evolution of Gran Canaria and its surrounding sedimentary basins. Our aim is to develop a globally representative model explaining the evolution of volcanic islands including aspects of volcanic hazards related to explosive eruptions and tsunamis triggered by island flank collapses.

Description: Drilling at Integrated Ocean Drilling Program Site U1381 on the Cocos Ridge offshore Costa Rica recovered 67 primary Miocene (ca. 8 Ma to ca. 16.5 Ma) marine fallout ash layers. Geochemical, volcanological, and geological criteria link these ashes to Plinian eruptions that carried ash to at least 50–450 km from the Galápagos hotspot. These ash layers are the first documentation of highly explosive Miocene Galápagos hotspot volcanism. This volcanism is bimodal with two-thirds of the tephra layers generated by basaltic magmas (glass compositions 〈57 wt% SiO2) and one-third by rhyolitic magmas. The temporal distribution of the tephra layers, inferred from sediment accumulation rates calibrated by 40Ar/39Ar and biostratigraphic ages, reveals a distinct increase in eruption frequency and hence increased volcanic activity of the Galápagos hotspot after 14 Ma which we interpret in the context of dynamic interaction between the Galápagos plume and spreading ridge.

Description: A rigorous detection of Milankovitch periodicities in volcanic output across the Pleistocene-Holocene ice age has remained elusive. We report on a spectral analysis of a large number of well-preserved ash plume deposits recorded in marine sediments along the Pacific Ring of Fire. Our analysis yields a statistically significant detection of a spectral peak at the obliquity period. We propose that this variability in volcanic activity results from crustal stress changes associated with ice age mass redistribution. In particular, increased volcanism lags behind the highest rate of increasing eustatic sea level (decreasing global ice volume) by 4.0 ± 3.6 k.y. and correlates with numerical predictions of stress changes at volcanically active sites. These results support the presence of a causal link between variations in ice age climate, continental stress field, and volcanism.

Description: During IODP NanTroSEIZE Expedition 322, four packages of tuffaceous sandstones (TST 1, 2, 3a, 3b) were recovered within a moderately lithified and bioturbated silty claystone succession in the Late Miocene (〉 7.6 to ~ 9.1 Ma) upper part of the middle Shikoku Basin deposits. To assess the emplacement processes of the tuffaceous sandstones we investigate modal and geochemical compositions of 24 thin sections that reveal systematic vertical changes within each bed. TST 1, 2 and 3b are single beds whereas TST 3a is composed of at least two beds suggesting several rapidly succeeding sedimentation events. The beds are density-graded such that low-density pyroclasts including pumice lapilli are enriched at the top whereas dense lithic components and minerals are enriched at the bottom. The volcanic glass particles (pumice and shards) that are the dominant modal constituents of each sandstone bed have homogeneous geochemical compositions in each bed. Moreover, TST 1, 2, and 3a glass compositions overlap completely but TST 3b glass has a different composition, as is analogously observed for the mineral compositions. This unique multistage approach of sedimentological and geochemical methods facilitated the detailed investigation of distal volcano-derived, probably tsunamogenic, turbidites in order to contribute to the distinction between primary and secondary induced mass flows. We interpret that all tuffaceous sandstones were emplaced by turbidity currents that were formed during major explosive volcanic eruptions. However, while TST 1, 2, and 3a turbidity currents formed by the entry into the ocean of voluminous pyroclastic flows erupted at a volcano on mainland Japan, TST 3b was emplaced by a turbidity current formed by a shallow submarine or subaerial volcanic eruption at the Izu–Bonin arc where it collided with Japan. These results regarding distal turbidites encourage the revisiting of older marine deposits in the scope of hazard evaluation through past events, especially in regions near to volcanic sources.

Description: We distinguish three eruptive units of pyroclastic flows (T1, T2, and T3; T for trass) within the late Quaternary Laacher See tephra sequence. These units differ in the chemical/mineralogical composition of the essential pyroclasts ranging from highly differentiated phonolite in T1 to mafic phonolite in T3. T1 and T2 flows were generated during Plinian phases, and T3 flows during a late Vulcanian phase. The volume of the pyroclastic flow deposits is about 0.6 km3. The lateral extent of the flows from the source vent decreases from 〉 10 km (T1) to 〈 4.5 km (T3). In the narrow valleys north of Laacher See, the total thickness of the deposits exceeds 60 m. At least 19 flow units in T1, 6 in T2, and 4 in T3 can be recognized at individual localities. Depositional cycles of 2 to 5 flow units are distinguished in the eruptive units. Thickness and internal structure of the flow units are strongly controlled by topography. Subfacies within flow units such as strongly enriched pumice and lithic concentration zones, dust layers, lapilli pipes, ground layers, and lithic breccias are all compositionally related to each other by enrichment or depletion of clasts depending on their size and density in a fluidized flow. While critical diameters of coarse-tail grading were found to mark the boundary between the coarse nonfluidized and the finer fluidized grain-size subpopulations, we document the second boundary between the fluidized and the very fine entrained subpopulations by histograms and Rosin-Rammler graphs. Grain-size distribution and composition of the fluidized middle-size subpopulations remained largely unchanged during transport. Rheological properties of the pyroclastic flows are deduced from the variations in flow-unit structure within the valleys. T1 flows are thought to have decelerated from 25 m/s at 4 km to 〈 15 m/s at 7 km from the vent; flow density was probably 600–900 kg/m3, and viscosity 5–50 P. The estimated yield strength of the flows of 200– 〉 1000 N/m2 is consistent with the divergence of lithic size/distance curves from purely Newtonian models; the transport of lithics must be treated as in a Bingham fluid. The flow temperature probably decreased from T1 (300°–500°C) to T3 (〈200°C). A large-scale longitudinal variation in the flow units from proximal through medial to distal facies dominantly reflects temporal changes during the progressive collapse of an eruption column. Only a small amount of fallout tephra was generated in the T1 phase of eruption. The pyroclastic flows probably formed from relatively low ash fountains rather than from high Plinian eruption columns.