Description: Benthic foraminiferal d18O and Mg/Ca of sediment cores off tropical NW Africa are used to study the properties of Atlantic central waters during the Last Glacial Maximum (LGM) and Heinrich Stadial 1 (HS1). We combined our core top data with published results to develop a new Mg/Ca-temperature calibration for Planulina ariminensis, which shows a Mg/Ca-temperature sensitivity of 0.19 mmol/mol per °C. Estimates of the LGM and HS1 thermocline temperatures are comparable to the present-day values between 200 and 400 m water depth, but were 1.2-1.5°C warmer at 550-570 m depth. The HS1 thermocline waters (200-570 m depth) did not show any warming relative to the LGM. This is in contrast to previous climate model studies, which concluded that tropical Atlantic thermocline waters warmed significantly when Atlantic meridional overturning circulation was reduced. However, our results suggest that thermocline temperatures of the northeastern tropical Atlantic show no pronounced sensitivity to changes in the thermohaline circulation during glacial periods. In contrast, we find a significant increase in thermocline-water salinity during the LGM (200-550 m depth) and HS1 (200-400 m depth) with respect to the present-day, which we relate to changes in the wind-driven circulation. We infer that the LGM thermocline (200-550 m depth) and the HS1 upper thermocline (200-400 m depth) in the northeastern tropical Atlantic was ventilated by surface waters from the North Atlantic rather than the southern-sourced waters. This suggests that the frontal zone between the modern South Atlantic and North Atlantic Central Waters was probably shifted southward during the LGM and HS1.

Description: The hydrogen isotopic composition of plant leaf-wax n-alkanes (dDwax) is a novel proxy for estimating dD of past precipitation (dDp). However, vegetation life-form and relative humidity exert secondary effects on dDwax, preventing quantitative estimates of past dDp. Here, we present an approach for removing the effect of vegetation-type and relative humidity from dDwax and thus for directly estimating past dDp. We test this approach on modern day (late Holocene; 0-3 ka) sediments from a transect of 9 marine cores spanning 21°N-23°S off the western coast of Africa. We estimate vegetation type (C3 tree versus C4 grass) using d13C of leaf-wax n-alkanes and correct dDwax for vegetation-type with previously-derived apparent fractionation factors for each vegetation type. Late Holocene vegetation-corrected dDwax (dDvc) displays a good fit with modern-day dDp, suggesting that the effects of vegetation type and relative humidity have both been removed and thus that dDvc is a good estimate of dDp. We find that the magnitude of the effect of C3 tree - C4 grass changes on dDwax is small compared to dDp changes. We go on to estimate dDvc for the mid-Holocene (6-8 ka), the Last Glacial Maximum (LGM; 19-23 ka) and Heinrich Stadial 1 (HS1; 16-18.5 ka). In terms of past hydrological changes, our leaf-wax based estimates of dDp mostly reflect changes in wet season intensity, which is complementary to estimates of wet season length based on leaf-wax d13C.

Description: The past climate evolution of southwestern Africa is poorly understood and interpretations of past hydrological changes are sometimes contradictory. Here we present a record of leaf-wax dD and View the MathML source taken from a marine sediment core at 23°S off the coast of Namibia to reconstruct the hydrology and C3 versus C4 vegetation of southwestern Africa over the last 140 000 years (140 ka). We find lower leaf-wax dD and higher View the MathML source (more C4 grasses), which we interpret to indicate wetter Southern Hemisphere (SH) summer conditions and increased seasonality, during SH insolation maxima relative to minima and during the last glacial period relative to the Holocene and the last interglacial period. Nonetheless, the dominance of C4 grasses throughout the record indicates that the wet season remained brief and that this region has remained semi-arid. Our data suggest that past precipitation increases were derived from the tropics rather than from the winter westerlies. Comparison with a record from the Congo Basin indicates that hydroclimate in southwestern Africa has evolved in antiphase with that of central Africa over the last 140 ka.

Description: The Southern Westerly Winds (SWW) exert a crucial influence over the world ocean and climate. Nevertheless, a comprehensive understanding of the Holocene temporal and spatial evolution of the SWW remains a significant challenge due to the sparsity of high-resolution marine archives and appropriate SWW proxies. Here, we present a north-south transect of high-resolution planktonic foraminiferal oxygen isotope records from the western South Atlantic. Our proxy records reveal Holocene migrations of the Brazil- Malvinas Confluence (BMC), a highly sensitive feature for changes in the position and strength of the northern portion of the SWW. Through the tight coupling of the BMC position to the large-scale wind field, the records allow a quantitative reconstruction of Holocene latitudinal displacements of the SWW across the South Atlantic. Our data reveal a gradual poleward movement of the SWW by about 1-1.5° from the early to the mid-Holocene. Afterwards variability in the SWW is dominated by millennial-scale displacements in the order of 1° in latitude with no recognizable longer-term trend. These findings are confronted with results from a state-of-the-art transient Holocene climate simulation using a comprehensive coupled atmosphere-ocean general circulation model. Proxy-inferred and modeled SWW shifts compare qualitatively, but the model underestimates both orbitally forced multi-millennial and internal millennial SWW variability by almost an order of magnitude. The underestimated natural variability implies a substantial uncertainty in model projections of future SWW shifts.

Description: The temporal succession of changes in Amazonian hydroclimate during Heinrich Stadial 1 (HS1) (ca. 18-14.7 cal ka BP) is currently poorly resolved. Here we present HS1 records based on isotope, inorganic and organic geochemistry from a marine sediment core influenced by the Amazon River discharge. Our records offer a detailed reconstruction of the changes in Amazonian hydroclimate during HS1, integrated over the basin. We reconstructed surface water hydrography using stable oxygen isotopes (d18O) and Mg/Ca-derived paleotemperatures from the planktonic foraminifera Globigerinoides ruber, as well as salinity changes based on stable hydrogen isotope (dD) of palmitic acid. We also analyzed branched and isoprenoid tetraether concentrations, and compared them to existing bulk sediment ln(Fe/Ca) data and vegetation reconstruction based on stable carbon isotopes from n-alkanes, in order to understand the relationship between continental precipitation, vegetation and sediment production. Our results indicate a two-phased HS1 (HS1a and HS1b). During HS1a (18-16.9 cal ka BP), a first sudden increase of sea surface temperatures (SST) in the western equatorial Atlantic correlated with the slowdown of the Atlantic Meridional Overturning Circulation (AMOC) and the associated southern hemisphere warming phase of the bipolar seesaw. This phase was also characterized by an increased delivery of terrestrial material. During HS1b (16.9-14.8 cal ka BP), a decrease in terrestrial input was, however, associated with a marked decline of seawater d18O and palmitic acid dD. Both isotopic proxies independently indicate a drop in sea surface salinity (SSS). A number of records under the influence of the North Brazil Current, in contrast, indicate increases in SST and SSS resulting from a weakened AMOC during HS1. Our records thus suggest that the expected increase in SSS due to the AMOC slowdown was overridden by a two-phased positive precipitation anomaly in Amazonian hydroclimate.

Description: Seafloor methane release can significantly affect the global carbon cycle and climate. Appreciable quantities of methane are stored in continental margin sediments as shallow gas and hydrate deposits, and changes in pressure, temperature and/or bottom-currents can liberate significant amounts of this greenhouse gas. Understanding the spatial and temporal dynamics of marine methane deposits and their relationships to environmental change are critical for assessing past and future carbon cycle and climate change. Here we present foraminiferal stable carbon isotope and sediment mineralogy records suggesting for the first time that seafloor methane release occurred along the southern Brazilian margin during the last glacial period (40–20 cal ka BP). Our results show that shallow gas deposits on the southern Brazilian margin responded to glacial−interglacial paleoceanographic changes releasing methane due to the synergy of sea level lowstand, warmer bottom waters and vigorous bottom currents during the last glacial period. High sea level during the Holocene resulted in an upslope shift of the Brazil Current, cooling the bottom waters and reducing bottom current strength, reducing methane emissions from the southern Brazilian margin.

Description: Eastern Canadian margin sediments bear testimony to several catastrophic deglacial meltwater discharges from the retreating Laurentide Ice Sheet. The reddish-brown plumite layers deposited on the levees of the Laurentian Fan valleys have been recognized as indications of multiple outburst floods between Heinrich events 2 and 1. Five event layers have been consistently recorded in three new gravity cores retrieved on the SW Grand Banks slope and comply with the previously published Laurentian Fan core MD95-2029. The apparently huge extent of these outburst plumes around the Laurentian Fan as well as their causes and consequences are investigated in this study using physical properties, rock magnetic and grain-size analyses, together with seismoacoustic profiling. We provide the first detailed 14C ages of the outburst event sequence and discuss their recurrence intervals in the context of regional ice retreat. Compared to the hemipelagic interlayers, event layers have overall uniform and systematic changes of rock-magnetic properties. Hematite contents increase over time and proximally while magnetite grain sizes fine upwards and spatially away from the fan. Based on the sediment composition and load, we argue that these plumites were formed by recurrent erosion of glacial mud deposits in the Laurentian Channel by meltwater outbursts. Three alternative glaciological scenarios are evaluated: in each case, the provenance of the transported sediment is not an indicator of the precise source of the meltwater.

Description: The western tropical Atlantic plays an important role in the interhemispheric redistribution of heat during millennial-scale changes in the strength of the Atlantic Meridional Overturning Circulation (AMOC). The proper evaluation of this role depends on a clear understanding of sea surface temperature (SST) variations during AMOC slowdown periods like Heinrich Stadials (HS) in the western tropical Atlantic. However, published SST records from the western tropical Atlantic between ca. 4°S and 7°N show inconsistencies that are apparently related to the employed temperature proxy (i.e., Mg/Ca versus alkenone unsaturation index U37k′). In general, while Mg/Ca values indicate warming during Heinrich Stadials, U37k′ values show cooling. To assess this issue, we sampled core GeoB16224-1 retrieved off French Guiana (i.e., 6°39.38′N) and reconstructed water temperatures at high resolution using Mg/Ca on the foraminifera species Globigerinoides ruber, U37k′, TEX86 and modern analogue technique (MAT) transfer functions using planktonic foraminifera assemblages calibrated for 50 m water depth. Our results show that Mg/Ca and TEX86 values recorded an increase in SST related to AMOC slowdown. Conversely, U37k′ and MAT values registered a decrease in temperatures during HS3 and HS1. Our U37k′ and Mg/Ca results thus confirm the previously reported inconsistency for the period between 48-13 cal ka BP. We suggest that several non-thermal physiological effects probably imparted a negative temperature bias on the U37k′ temperatures during Heinrich Stadials. However, MAT-based temperatures show similar variability with U37k′-based temperatures. Hence, we also suggest that during severe slowdown periods of the AMOC, a steeper meridional temperature gradient together with a southward shift of the Intertropical Convergent Zone produced not only an increase in SST but also a stronger upper water column stratification and a shoaling of the thermocline, decreasing subsurface temperatures. Our new high resolution temperature records allow a better characterization of the thermal response of the upper water column in the tropical western Atlantic to slowdown events of the AMOC, reconciling previously discrepant records.

Description: Biomass burning on the African continent is widespread and interactions with climate, vegetation dynamics and biogeochemical cycling are complex. To obtain a better understanding of these complex relationships, African fire history has been widely studied, although mostly on relatively short time-scales (i.e. yrs to kyrs) and less commonly on long-term scales. Here, we present a 192-kyr, continuous biomass-burning record from sub-Saharan Northwest Africa based on the fire biomarker levoglucosan in a marine sediment core offshore Guinea. Notable features of our record include an increase in levoglucosan accumulation at 80 ka and two peaks at 50-60 ka. The event at 80 ka is likely related to an overall increase in sedimentation rates rather than an increase in biomass burning in the Northwest African savanna region. Our record indicates that glacial/interglacial changes in regional climate and vegetation composition (C3 vs. C4 plants) were not a major influence on biomass burning over the last 192 kyrs. However, we suggest that the burning events at 50-60 ka might be caused by increased occurrence of C3 vegetation and human settlement in this region. At this time, the savanna region became wetter and fuel loads likely increased. Therefore, the region was more hospitable for humans, who likely used fire for hunting activities. Collectively, we hypothesize that on longer (glacial/interglacial) timescales, biomass burning, regional climate and African vegetation are not necessarily coupled, while around 50-60 ka, higher fuel loads and human fire-use may have influenced fire occurrence in sub-Saharan Northwest Africa.

Description: Today the western tropical Atlantic is the most important passage for cross-equatorial transfer of heat in the form of warm surface water flowing from the South into the North Atlantic. Circulation changes north of South America may thus have influenced the global thermohaline circulation system and high northern latitude climate. Here we reconstruct late Quaternary variations of western equatorial Atlantic surface circulation and Amazon lowland climate obtained from a multiproxy sediment record from Ceará Rise. Variations in the illite/smectite ratio suggest drier climatic conditions in the Amazon Basin during glacials relative to interglacials. The 230Thex-normalized fluxes and the 13C/12C record of organic carbon indicate that sea level fluctuations, shelf topography, and changes of the surface circulation pattern controlled variations and amplitude of terrigenous sediment supply to the Ceará Rise. We attribute variations in thermocline depth, reconstructed from vertical planktic foraminiferal oxygen isotope gradients and abundances of the phytoplankton species Florisphaera profunda, to changes in southeast trade wind intensity. Strong trade winds during ice volume maxima are associated with a deep western tropical Atlantic thermocline, strengthening of the North Brazil Current retroflection, and more vigorous eastward flow of surface waters.