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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 2139-2144 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A polymerizable photoredox system consisting of 4-methacryl oxbenzophenone (MABP) and N,N-dimethlaminoethyl methacrylate (DMAEMA) used for the photopolymerization of acrylonitrile (AN) was studied. It was found that the polymerization rate is proportional to the 0.93th power for the AN concentration, the 0.28th power for the MABP concentration, and the 0.25th power for the DMAEMA concentration. The overall activation energy of the polymerization obtained is 30.43 kJ/mol. The recorded ESR spectrum indicates that the excited-state MABP abstraets hydrogen mainly from the methyl group of the dimethylamino moiety. The comparison of the initiation ability of polymeric MABP or polymeric DMAEMA with their monomeric forms has also been done and the results indicate that in good solvents P (MABP) has a much higher initiation ability than that of monomeric MABP, but monomeric DMAEMA and P (DMAEMA) display almost the same initiation ability. In poor solvent, the initiation ability of P (MABP) is not so obviously higher than that in good solvents. The result of UV analysis of P (AN) initiated by the MABP-DMAEMA system indicates that both MABP and DMAEMA not only initiate the photopolymerization of AN, but also enter into P (AN) polymer chains. © 1994 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 23 (1992), S. 93-97 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of chloride ions on surface enhanced Raman scattering (SERS) and the time dependence of the SERS intensity of p-aminobenzoic acid (PABA) and pyridine in silver sol were studied. The addition of chloride ions can destroy the equilibrium between the gas-like and the solid-like phase adsorption of PABA on the silver surface and causes a transformation of the molecular adsorption state and a reduction in the SERS intensity. The influence of chloride ions on SERS and the time dependence of SERS intensity in PABA - silver sol and pyridine - silver sol mixtures were studied. It was found that, in the same environment, the SERS' intensity of pyridine increases and that of PABA decreases on addition of KCl. The results show that the chemical effect of chloride ions on SERS of PABA and pyridine in silver sol is overwhelming. The results of light absorption of PABA and pyridine in silver sol are consistent with this conclusion.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 23 (1992), S. 319-323 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Using a new method, the Raman and hyper-Raman tensors for the point groups 8 (C8), 8 (S8), 8/m (C8h), 8mm (C8ν), 822 (D8) and 8/mmm (D8h) have been tabulated.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2011-02-10
    Description: Probability behaviors and trends of hydrological extremes, the 7-day high flow (HF7) in this study, of the Poyang Lake basin are thoroughly investigated using eleven probability distribution functions and Mann-Kendall trend test method. Parameters and goodness-of-fit of the probability functions are estimated using the L-moment technique and Kolmogorov-Smirnov statistic D (K-S D). The hydrological data are extracted from 6 major hydrological stations located in the 5 main tributaries of the Poyang Lake basin. The results indicate that: (1) the Wakeby distribution is the good choice for description of the statistical behaviors of HF7 in the study region; (2) changing properties of HF7 are varying from on station to another, implying different fluvial geomorphological features, climate changes and human activities within different tributaries. Generally, the HF7 events are increasing after the construction of water reservoirs except the Wan'an water reservoir. The analysis results demonstrate considerable influences of water reservoirs on high flow changes. Relatively low design standards of the water reservoirs greatly limit the functions of the water reservoirs in terms of flood control. Besides, most water reservoirs were built in the tributaries of the Poyang Lake basin, exerting limited influences on the streamflow extremes; (3) higher frequency of hydrological extremes may cause higher probability of floods, posing increasingly serious challenges for flood control. In this sense, more efforts should be paid to enhance human mitigation to natural hazards such as floods in the Poyang Lake basin. Copyright © 2011 John Wiley & Sons, Ltd.
    Print ISSN: 0885-6087
    Electronic ISSN: 1099-1085
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Published by Wiley-Blackwell
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  • 5
    Publication Date: 2014-02-15
    Description: A new double Schiff base complex, Cu(PMαFP) 2 en (HPMαFP = 1-phenyl-3-methyl-4-(2-furoyl)-5-pyrazolone, en = ethylenediamine), has been synthesized and characterized by elemental analysis, IR, UV, fluorescence spectra, thermal analysis, X-ray single crystal diffraction and cyclic voltammetry (CV). Its crystal structure is monoclinic with space group Pbca and cell parameters: a = 22.263(3)Å, b = 13.671(2)Å, c = 10.0920(16)Å, Z = 4, S = 1.028, R 1  = 0.0500 and wR 2  = 0.1285. It was found that the Cu 2+ ion is located in the coordination center. The Cu(II) has a slightly distorted plane quadrilateral coordination environment with two oxygen atoms and two nitrogen atoms of double Schiff base ligand in the equatorial plane. The complex has a one-dimensional chain supramolecular structure, which is connected by C H…N bonding interactions. In the electrochemical experiments, the CV curve displays an oxidation peak in the presence of uric acid with Ep = 0.216V in pH = 7.0, showing that the Cu(PMαFP) 2 en/glassy carbon modified electrode has an electrocatalytic activity toward uric acid.
    Print ISSN: 0232-1300
    Electronic ISSN: 1521-4079
    Topics: Geosciences , Physics
    Published by Wiley-Blackwell
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  • 6
    Publication Date: 2014-02-12
    Description: We can apply both fixed and random effects models to multi-regional clinical trial (MRCT) design and data analysis. Thoroughly, understanding the features of these models in an MRCT setting will help assessing their applicability to an MRCT. In this paper, we discuss the interpretations of trial results from these models. We also evaluate the impact of the number of regions and the sample size configuration across the regions on the required total sample size for the overall treatment effect assessment. For quantifying treatment effects of individual regions, the empirical shrinkage estimator and the James–Stein type shrinkage estimator associate with smaller variability compared with the regular sample estimator. We conduct computation and simulation to compare the performance of these estimators when they are applied to assess consistency of treatment effects across regions. We use a multinational trial example to illustrate the application of these methods. Copyright © 2014 John Wiley & Sons, Ltd.
    Print ISSN: 0277-6715
    Electronic ISSN: 1097-0258
    Topics: Mathematics , Medicine
    Published by Wiley-Blackwell
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  • 7
    Publication Date: 2013-11-29
    Description: [1]  Recent advances in computing technologies have renewed interest in the intelligent systems for automatic interpretation of ionograms, images obtained by remote sensing of the ionospheric plasma. The ionogram " autoscaling" techniques based on the template matching method, previously rendered unrealistic for their computing complexity, have now become feasible. This work presents an automatic scaling technique for extracting the main features of the F1 and F2 layers of the ionosphere, such as critical frequency and virtual height, from vertical incidence (VI) ionograms that do not the distinguish O/X polarization of the echoes. The proposed technique uses the Quasi-Parabolic Segments (QPS) to model the electron density profile shapes that are used to synthesize a pool of candidate traces. Moreover, the empirical orthogonal functions (EOF) and image technique are applied to reduce the size of the candidate traces so that the auto-scaling algorithm can run in realistic time. With the template matching algorithm, the technique will provide the initial parameters of the QPS model for the F1 and F2 layers, which are then fine-tuned to obtain the better fitting parameters. In order to evaluate the performance of this technique, a large data set of ionograms recorded in Wuhan at daytime and nighttime in winter, summer, equinoctial months, are analyzed and investigated. The automatic scaling results are compared with manually scaling results. Our results indicate that the proposed technique described in this paper is reliable and efficient and will facilitate the statistical study of temporal and spatial ionospheric characteristics over Wuhan.
    Print ISSN: 0048-6604
    Electronic ISSN: 1944-799X
    Topics: Geosciences , Physics
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  • 8
    Publication Date: 2013-05-22
    Description: The yield of rice ( Oryza sativa L.) has increased substantially with the development of new cultivars, but the role of potassium (K) requirement for the increase in grain yield and the genotypic advance is still unclear. In order to investigate this relationship a database of 1199 on-farm measurements (harvest index 0.4) comprising 〉 400 modern rice cultivars was collected during 2005–2010 across major irrigated lowland rice–production regions of China. This was used to evaluate the relationships among K requirement, grain yield, and genetic improvement. Across all the sites and seasons, mean reciprocal internal efficiency of K (RIE-K, kg K [t grain produced] –1 ) was 19.8 kg K (t grain) –1 and rice yield averaged 8.7 t ha –1 . Considering four levels of grain yield (〈 7.5, 7.5–9, 9–10.5, and 〉 10.5 t ha –1 ), the respective RIEs were 18.7, 19.4, 20.5, and 21.7 kg K (t grain) –1 . The gradual increase in the RIE-K with yield was attributed mainly to the increase in straw and grain K concentration and the decrease in the K harvest index. The RIE-K values for ordinary inbred, ordinary hybrid, and “super rice” were 18.5, 20.1, and 19.9 kg K (t grain) –1 , respectively. Examining the historical development of rice cultivars, the RIE-K decreased from 40.9 (Nanjing1, early tall, inbred) in the 1950s to 19.8 (IR24, semi-dwarf, ordinary inbred) in the 1970s, and then increased to 20.9 (Shanyou63, modern ordinary hybrid) in the 1980s and 20.6 kg K (t grain) –1 (II-you084, “super” rice) in the 2000s. This variation in RIE-K among grain-yield levels and cultivars highlights the importance of information on rice K requirement in calculating K balance and optimal K-fertilizer rate for rice production.
    Print ISSN: 1436-8730
    Electronic ISSN: 1522-2624
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Wiley-Blackwell
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  • 9
    Publication Date: 2014-05-28
    Description: ABSTRACT Xinjiang is the largest arid inland region in China and its agricultural development plays an important role in the socio-economy of China. Drought is one of the major natural hazards in this region and has impacts on agriculture. In this study, spatiotemporal patterns of droughts are analysed based on monthly precipitation datasets from 52 meteorological stations covering the period of 1961–2008 using the Rotated Empirical Orthogonal Functions (REOF) technique and also the Mann–Kendall trend test (MK test). Results of the study indicate that: (1) a wetting tendency is observed in recent years, particularly in northern Xinjiang. Seasonally, the wetting tendency is found mainly in winter. The modes of REOF can be divided by the Tianshan mountain and the principal component (PC) of the northern Xinjiang mode in winter has a significant increasing trend. (2) The area of drought-affected regions is decreasing in northwestern Xinjiang and along the northern side of Tianshan mountain. Seasonally, the area of drought-affected regions is significantly decreasing in winter. (3) The wetting tendency of Xinjiang may alleviate the drought influence. However, uneven spatial patterns of precipitation changes may enhance drought impacts. Besides, drought-related impacts can be greatly alleviated where irrigation conditions are favourable.
    Print ISSN: 0899-8418
    Electronic ISSN: 1097-0088
    Topics: Geosciences , Physics
    Published by Wiley-Blackwell
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  • 10
    Publication Date: 2017-10-15
    Description: Purpose To achieve consistent effectiveness in reconstruction of fine image features for cases of varying contrast-to-noise ratio (CNR) to facilitate translating accelerated multicontrast volumetric imaging with isotropic resolution toward clinical utility in peri-infarct characterization. Theory and Methods A low-rank and spatially varying edge-preserving constrained compressed sensing parallel imaging reconstruction method (CP-LASER) is developed to effectively preserve contrast of small-scale structures for highly accelerated multicontrast volumetric imaging in CNR-limited scenarios. CP-LASER synergistically integrates parallel imaging, low-rank and spatially varying edge-preserving sparse modeling to achieve high signal-to-noise-ratio efficiency by leveraging prior knowledge about signal properties including coil sensitivity weighting, spatiotemporally correlated signal relaxation, and spatially varying sparsity. Results In the preclinical study using highly accelerated multicontrast volumetric imaging with an isotropic 1.5-mm resolution, CP-LASER demonstrated robust multicontrast reconstruction of peri-infarct characteristics with excellent correspondence with histopathology. CP-LASER provides better delineation of the peri-infarct border zone with improved sharpness than alternative methods in a clinical demonstration on 1.5T with an isotropic 2.2-mm resolution achieved in a single breath-hold. Conclusion Accelerated multicontrast volumetric imaging with isotropic resolution using CP-LASER has demonstrated the potential to improve peri-infarct characterization in a clinical setting. Magn Reson Med, 2017. © 2017 International Society for Magnetic Resonance in Medicine.
    Print ISSN: 0740-3194
    Electronic ISSN: 1522-2594
    Topics: Medicine
    Published by Wiley-Blackwell
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