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  • 1
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 2139-2144 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A polymerizable photoredox system consisting of 4-methacryl oxbenzophenone (MABP) and N,N-dimethlaminoethyl methacrylate (DMAEMA) used for the photopolymerization of acrylonitrile (AN) was studied. It was found that the polymerization rate is proportional to the 0.93th power for the AN concentration, the 0.28th power for the MABP concentration, and the 0.25th power for the DMAEMA concentration. The overall activation energy of the polymerization obtained is 30.43 kJ/mol. The recorded ESR spectrum indicates that the excited-state MABP abstraets hydrogen mainly from the methyl group of the dimethylamino moiety. The comparison of the initiation ability of polymeric MABP or polymeric DMAEMA with their monomeric forms has also been done and the results indicate that in good solvents P (MABP) has a much higher initiation ability than that of monomeric MABP, but monomeric DMAEMA and P (DMAEMA) display almost the same initiation ability. In poor solvent, the initiation ability of P (MABP) is not so obviously higher than that in good solvents. The result of UV analysis of P (AN) initiated by the MABP-DMAEMA system indicates that both MABP and DMAEMA not only initiate the photopolymerization of AN, but also enter into P (AN) polymer chains. © 1994 John Wiley & Sons, Inc.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 23 (1992), S. 93-97 
    ISSN: 0377-0486
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The influence of chloride ions on surface enhanced Raman scattering (SERS) and the time dependence of the SERS intensity of p-aminobenzoic acid (PABA) and pyridine in silver sol were studied. The addition of chloride ions can destroy the equilibrium between the gas-like and the solid-like phase adsorption of PABA on the silver surface and causes a transformation of the molecular adsorption state and a reduction in the SERS intensity. The influence of chloride ions on SERS and the time dependence of SERS intensity in PABA - silver sol and pyridine - silver sol mixtures were studied. It was found that, in the same environment, the SERS' intensity of pyridine increases and that of PABA decreases on addition of KCl. The results show that the chemical effect of chloride ions on SERS of PABA and pyridine in silver sol is overwhelming. The results of light absorption of PABA and pyridine in silver sol are consistent with this conclusion.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 23 (1992), S. 319-323 
    ISSN: 0377-0486
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: Using a new method, the Raman and hyper-Raman tensors for the point groups 8 (C8), 8 (S8), 8/m (C8h), 8mm (C8ν), 822 (D8) and 8/mmm (D8h) have been tabulated.
    Zusätzliches Material: 3 Tab.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    Publikationsdatum: 2013-01-07
    Beschreibung: [1]  We present a three-dimensional (3D) P-wave velocity (Vp) model of the Parkfield region that utilizes existing P-wave arrival time data, including fault zone head waves (FZHW), and data from direct wave secondary arrivals (DWSA). The first-arrival and DWSA travel times are obtained as the global and local minimum travel time paths, respectively. The inclusion of FZHW and DWSA's result in as much as a 5% and 10% increase in the across-fault velocity contrast, respectively, for the Vp model at Parkfield relative to Thurber et al . (2006). Viewed along strike, three pronounced velocity contrast regions are observed: a pair of strong positive velocity contrasts (SW fast), one NW of the 1966 Parkfield earthquake hypocenter and the other SE of the 2004 Parkfield earthquake hypocenter, and a strong negative velocity contrast (NE fast) between the two hypocenters. The negative velocity contrast partially to entirely encompasses peak coseismic slip estimated in several slip models for the 2004 earthquake, suggesting the negative velocity contrast played a part in defining the rupture patch of the 2004 Parkfield earthquake. Following Ampuero and Ben-Zion (2008), the pattern of velocity contrasts is consistent with the observed bilateral rupture propagation for the 2004 Parkfield earthquake. Although the velocity contrasts also suggest bilateral rupture propagation for the 1966 Parkfield earthquake, the fault is creeping to the NW here, i.e., exhibiting velocity-strengthening behavior. Thus it is not surprising that rupture propagated only SE during this event.
    Print ISSN: 0148-0227
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley-Blackwell im Namen von American Geophysical Union (AGU).
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    Publikationsdatum: 2017-06-20
    Beschreibung: The leaf carbon isotope ratio (δ 13 C) is a useful parameter for predicting a plant's water use efficiency, as an indicator for plant classification, and even in the reconstruction of paleoclimatic environments. In this study, we investigated the spatial pattern of leaf δ 13 C values and its relationship with plant functional groups and environmental factors throughout China. The high leaf δ 13 C in the database appeared in central and western China, and the averaged leaf δ 13 C was -27.15‰, with a range from -21.05‰ to -31.5‰. The order of the averaged δ 13 C for plant life forms from most positive to most negative was subshrubs 〉 herbs = shrubs 〉 trees 〉 subtrees. Leaf δ 13 C is also influenced by some environmental factors, such as mean annual precipitation (MAP), relative humidity (RH), mean annual temperature (MAT), solar hours (SH), and altitude, although the overall influences are still relatively weak, in particular the influence of MAT and altitude. And we further found that plant functional types are dominant factors that regulate the magnitude of leaf δ 13 C for an individual site, whereas environmental conditions are key to understanding spatial patterns of leaf δ 13 C when we consider China as a whole. Ultimately, we conducted a multiple regression model of leaf δ 13 C with environmental factors and mapped the spatial distribution of leaf δ 13 C in China by using this model. However, this PLS model overestimated leaf δ 13 C for most life forms, especially for deciduous trees, evergreen shrubs and subtrees, and thus need more improvement in the future.
    Print ISSN: 0148-0227
    Thema: Biologie , Geologie und Paläontologie
    Publiziert von Wiley-Blackwell im Namen von American Geophysical Union (AGU).
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 6
    Publikationsdatum: 2017-06-24
    Beschreibung: Atmospheric water is emerging as an important potable water source. The present work experimentally and theoretically investigates water condensation and collection on flat surfaces with contrasting contact angles and contact angle hysteresis (CAH) to elucidate their roles on water mass collection efficiency. The experimental results indicate that a hydrophilic surface promotes nucleation and individual droplets growth, and a surface with a low CAH tends to let a smaller droplet to slide down, but the overall water mass collection efficiency is independent of both surface contact angle and CAH. The experimental results agree well with our theoretical calculations. During water condensation, a balance has to be struck between single droplet growth and droplet density on a surface so as to maintain a constant water droplet surface coverage ratio, which renders the role of both surface wettability and hysteresis insignificant to the ultimate water mass collection. Moreover, water droplets on the edges of a surface grow much faster than those on the non-edge areas and thus dominate the contribution to the water mass collection by the entire surface, directly pointing out the very important role of edge effect on water condensation and collection. Atmospheric water is an important water source and thus understanding atmospheric water condensation behaviors is critical to further develop effective atmospheric water harvesting materials. This work indicates that the edge effect overplays the surface wettability in condensation water harvesting. The results of this work unequivocally point out the importance of increasing fraction of edge promoting locally favorable aerodynamics.
    Digitale ISSN: 2056-6646
    Thema: Allgemeines , Energietechnik
    Publiziert von Wiley-Blackwell
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 7
    Publikationsdatum: 2017-11-03
    Beschreibung: ABSTRACT This current study intends to investigate the effect of microRNA-128 (miR-128) on cisplatin (DDP) resistance in glioma SHG-44 cells. SHG-44/DDP cells were transfected with miR-128 antisense oligonucleotide (ASO) and assigned into blank, resistance, NC, anti-miR-128, miR-128 mimic, si-JAG1 and anti-miR-128 + si-JAG1 groups. qRT-PCR and western blotting were employed for determining expression of miR-128, JAG1, Bax and Bcl-2. MTT assay, Giemsa staining and flow cytometry were applied to detect DDP resistance, cellular morphology and cell cycle respectively. JAG1 is targeted and negatively regulated by miR-128. In in vitro experiments, compared with the blank group, the rest groups exhibited declined miR-28 and Bax expression, lowered cell inhibition rate and apoptosis rate, but elevated JAG1 and Bcl-2 expression with cells arrested in the S phase. Compared with the resistance group, the anti-miR-128 group showed decreasedBax expression along with a lowered cell inhibition rate and apoptosis rate, but increased JAG1 and Bcl-2 expression with reduced cells arrested in the S phase; while the miR-128 mimic group showed an opposite trend; the si-JAG1 group showed decreased Bcl-2 expression and reduced cells in the S phase. In in vivo experiments, compared with the resistance group, the tumor growth rate, tumor volume and weight as well as JAG1 expression accelerated in the anti-miR-128 group; whereas the miR-128 mimic and si-JAG1 groups exhibited an opposite trend. Our findings demonstrated that miR-128 ASO transfection might down-regulate the expression of miR-128 in SHG-44/DDP and up-regulate the DDP resistance in SHG-44/DDP cells, providing a potential treatment target for glioma. This article is protected by copyright. All rights reserved
    Digitale ISSN: 0091-7419
    Thema: Biologie , Chemie und Pharmazie , Medizin
    Publiziert von Wiley-Blackwell
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 8
    Publikationsdatum: 2017-10-15
    Beschreibung: Purpose To achieve consistent effectiveness in reconstruction of fine image features for cases of varying contrast-to-noise ratio (CNR) to facilitate translating accelerated multicontrast volumetric imaging with isotropic resolution toward clinical utility in peri-infarct characterization. Theory and Methods A low-rank and spatially varying edge-preserving constrained compressed sensing parallel imaging reconstruction method (CP-LASER) is developed to effectively preserve contrast of small-scale structures for highly accelerated multicontrast volumetric imaging in CNR-limited scenarios. CP-LASER synergistically integrates parallel imaging, low-rank and spatially varying edge-preserving sparse modeling to achieve high signal-to-noise-ratio efficiency by leveraging prior knowledge about signal properties including coil sensitivity weighting, spatiotemporally correlated signal relaxation, and spatially varying sparsity. Results In the preclinical study using highly accelerated multicontrast volumetric imaging with an isotropic 1.5-mm resolution, CP-LASER demonstrated robust multicontrast reconstruction of peri-infarct characteristics with excellent correspondence with histopathology. CP-LASER provides better delineation of the peri-infarct border zone with improved sharpness than alternative methods in a clinical demonstration on 1.5T with an isotropic 2.2-mm resolution achieved in a single breath-hold. Conclusion Accelerated multicontrast volumetric imaging with isotropic resolution using CP-LASER has demonstrated the potential to improve peri-infarct characterization in a clinical setting. Magn Reson Med, 2017. © 2017 International Society for Magnetic Resonance in Medicine.
    Print ISSN: 0740-3194
    Digitale ISSN: 1522-2594
    Thema: Medizin
    Publiziert von Wiley-Blackwell
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 9
    Publikationsdatum: 2013-05-22
    Beschreibung: The yield of rice ( Oryza sativa L.) has increased substantially with the development of new cultivars, but the role of potassium (K) requirement for the increase in grain yield and the genotypic advance is still unclear. In order to investigate this relationship a database of 1199 on-farm measurements (harvest index 0.4) comprising 〉 400 modern rice cultivars was collected during 2005–2010 across major irrigated lowland rice–production regions of China. This was used to evaluate the relationships among K requirement, grain yield, and genetic improvement. Across all the sites and seasons, mean reciprocal internal efficiency of K (RIE-K, kg K [t grain produced] –1 ) was 19.8 kg K (t grain) –1 and rice yield averaged 8.7 t ha –1 . Considering four levels of grain yield (〈 7.5, 7.5–9, 9–10.5, and 〉 10.5 t ha –1 ), the respective RIEs were 18.7, 19.4, 20.5, and 21.7 kg K (t grain) –1 . The gradual increase in the RIE-K with yield was attributed mainly to the increase in straw and grain K concentration and the decrease in the K harvest index. The RIE-K values for ordinary inbred, ordinary hybrid, and “super rice” were 18.5, 20.1, and 19.9 kg K (t grain) –1 , respectively. Examining the historical development of rice cultivars, the RIE-K decreased from 40.9 (Nanjing1, early tall, inbred) in the 1950s to 19.8 (IR24, semi-dwarf, ordinary inbred) in the 1970s, and then increased to 20.9 (Shanyou63, modern ordinary hybrid) in the 1980s and 20.6 kg K (t grain) –1 (II-you084, “super” rice) in the 2000s. This variation in RIE-K among grain-yield levels and cultivars highlights the importance of information on rice K requirement in calculating K balance and optimal K-fertilizer rate for rice production.
    Print ISSN: 1436-8730
    Digitale ISSN: 1522-2624
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Publiziert von Wiley-Blackwell
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 10
    Publikationsdatum: 2014-05-28
    Beschreibung: ABSTRACT Xinjiang is the largest arid inland region in China and its agricultural development plays an important role in the socio-economy of China. Drought is one of the major natural hazards in this region and has impacts on agriculture. In this study, spatiotemporal patterns of droughts are analysed based on monthly precipitation datasets from 52 meteorological stations covering the period of 1961–2008 using the Rotated Empirical Orthogonal Functions (REOF) technique and also the Mann–Kendall trend test (MK test). Results of the study indicate that: (1) a wetting tendency is observed in recent years, particularly in northern Xinjiang. Seasonally, the wetting tendency is found mainly in winter. The modes of REOF can be divided by the Tianshan mountain and the principal component (PC) of the northern Xinjiang mode in winter has a significant increasing trend. (2) The area of drought-affected regions is decreasing in northwestern Xinjiang and along the northern side of Tianshan mountain. Seasonally, the area of drought-affected regions is significantly decreasing in winter. (3) The wetting tendency of Xinjiang may alleviate the drought influence. However, uneven spatial patterns of precipitation changes may enhance drought impacts. Besides, drought-related impacts can be greatly alleviated where irrigation conditions are favourable.
    Print ISSN: 0899-8418
    Digitale ISSN: 1097-0088
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley-Blackwell
    Standort Signatur Einschränkungen Verfügbarkeit
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