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  • 2020-2023  (29)
  • 1955-1959  (165)
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  • 1
    Schlagwort(e): Chemistry. ; Electronic books.
    Materialart: Online-Ressource
    Seiten: 1 online resource (561 pages)
    Ausgabe: 1st ed.
    ISBN: 9783709171660
    Serie: Fortschritte der Chemie Organischer Naturstoffe Progress in the Chemistry of Organic Natural Products Series ; v.12
    Sprache: Englisch
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Buch
    Buch
    London [u.a.] : Oxford Univ. Press
    Materialart: Buch
    Seiten: XI, 244 S , Ill.
    Sprache: Englisch
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Materialart: Buch
    Seiten: Seite 1-58, Blatt Tafel 1 , Illustrationen
    Serie: Philosophical transactions of the Royal Society of London no. 686 = vol. 242 (1960)
    Sprache: Englisch
    Anmerkung: Umschlagtitel
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    Publikationsdatum: 2022-05-16
    Beschreibung: Remote imaging spectroscopy, also known as hyperspectral imaging, uses Radiative Transfer Models (RTMs) to predict the measured radiance spectrum for a specific surface and atmospheric state. Discrepancies between RTM assumptions and physical reality can cause systematic errors in surface property estimates. We present a statistical method to quantify these model errors without invoking ground reference data. Our approach exploits scene invariants — properties of the environment which are stable over space or time — to estimate RTM discrepancies. We describe techniques for discovering these features opportunistically in flight data. We then demonstrate data-driven methods that estimate the aggregate errors due to model discrepancies without having to explicitly identify the underlying physical mechanisms. The resulting distributions can improve posterior uncertainty predictions in operational retrievals.
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    Publikationsdatum: 2022-01-10
    Beschreibung: Changes in electron flux in Earth's outer radiation belt can be modeled using a diffusion‐based framework. Diffusion coefficients D for such models are often constructed from statistical averages of observed inputs. Here, we use stochastic parameterization to investigate the consequences of temporal variability in D. Variability time scales are constrained using Van Allen Probe observations. Results from stochastic parameterization experiments are compared with experiments using D constructed from averaged inputs and an average of observation‐specific D. We find that the evolution and final state of the numerical experiment depends upon the variability time scale of D; experiments with longer variability time scales differ from those with shorter time scales, even when the time‐integrated diffusion is the same. Short variability time scale experiments converge with solutions obtained using an averaged observation‐specific D, and both exhibit greater diffusion than experiments using the averaged‐input D. These experiments reveal the importance of temporal variability in radiation belt diffusion.
    Sprache: Englisch
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 6
    Publikationsdatum: 2022-07-25
    Beschreibung: Future global Visible Shortwave Infrared Imaging Spectrometers, such as the Surface Biology and Geology (SBG) mission, will regularly cover the Earth's entire terrestrial land area. These missions need high fidelity atmospheric correction to produce consistent maps of terrestrial and aquatic ecosystem traits. However, estimation of surface reflectance and atmospheric state is computationally challenging, and the terabyte data volumes of global missions will exceed available processing capacity. This article describes how missions can overcome this bottleneck using the spatial continuity of atmospheric fields. Contemporary imaging spectrometers oversample atmospheric spatial variability, so it is not necessary to invert every pixel. Spatially sparse solutions can train local linear emulators that provide fast, exact inversions in their vicinity. We find that estimating the atmosphere at 200 m scales can outperform traditional atmospheric correction, improving speed by one to two orders of magnitude with no measurable penalty to accuracy. We validate performance with an airborne field campaign, showing reflectance accuracies with RMSE of 1.1% or better compared to ground measurements of diverse targets. These errors are statistically consistent with retrieval uncertainty budgets. Local emulators can close the efficiency gap and make rigorous model inversion algorithms feasible for global missions such as SBG.
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 7
    Publikationsdatum: 2022-03-10
    Beschreibung: Snow and ice melt processes on the Greenland Ice Sheet are a key in Earth’s energy balance and are acutely sensitive to climate change. Melting dynamics are directly related to a decrease in surface albedo, amongst others caused by the accumulation of light-absorbing particles (LAPs). Featuring unique spectral patterns, these accumulations can be mapped and quantified by imaging spectroscopy. We present first results for the retrieval of glacier ice properties from the spaceborne PRISMA imaging spectrometer by applying a recently developed simultaneous inversion of atmospheric and surface state using optimal estimation. The image analyzed in this study was acquired over the South-West margin of the Greenland Ice Sheet in late August 2020. The area is characterized by patterns of both clean and dark ice associated with a high amount of LAPs deposited on the surface. We present retrieval maps and uncertainties for grain size, liquid water, and algae concentration, as well as estimated reflectance spectra for different surface properties. We then show the feasibility of using imaging spectroscopy to interpret multiband sensor data to achieve high accuracy, frequently repeated observations of changing snow and ice conditions. For example, the impurity index calculated from multiband Sentinel-3 OLCI measurements is dependent on dust particles, but we show that algae concentration alone can be predicted from this data with less than 20 % uncertainty. Our study evidence that present and upcoming orbital imaging spectroscopy missions such as PRISMA, EnMAP, CHIME, and the SBG designated observable, can significantly support research of melting ice sheets.
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 8
    Publikationsdatum: 2022-08-05
    Beschreibung: Snow and ice melt processes are a key in Earth's energy-balance and hydrological cycle. Their quantification facilitates predictions of meltwater runoff as well as distribution and availability of fresh water. They control the balance of the Earth's ice sheets and are acutely sensitive to climate change. These processes decrease the surface reflectance with unique spectral patterns due to the accumulation of liquid water and light absorbing particles (LAP), that require imaging spectroscopy to map and measure. Here we present a new method to retrieve snow grain size, liquid water fraction, and LAP mass mixing ratio from airborne and spaceborne imaging spectroscopy acquisitions. This methodology is based on a simultaneous retrieval of atmospheric and surface parameters using optimal estimation (OE), a retrieval technique which leverages prior knowledge and measurement noise in an inversion that also produces uncertainty estimates. We exploit statistical relationships between surface reflectance spectra and snow and ice properties to estimate their most probable quantities given the reflectance. To test this new algorithm we conducted a sensitivity analysis based on simulated top-of-atmosphere radiance spectra using the upcoming EnMAP orbital imaging spectroscopy mission, demonstrating an accurate estimation performance of snow and ice surface properties. A validation experiment using in-situ measurements of glacier algae mass mixing ratio and surface reflectance from the Greenland Ice Sheet gave uncertainties of ±16.4 μg/gice and less than 3%, respectively. Finally, we evaluated the retrieval capacity for all snow and ice properties with an AVIRIS-NG acquisition from the Greenland Ice Sheet demonstrating this approach's potential and suitability for upcoming orbital imaging spectroscopy missions.
    Sprache: Englisch
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 9
    Publikationsdatum: 2022-05-25
    Beschreibung: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Jacox, M. G., Alexander, M. A., Siedlecki, S., Chen, K., Kwon, Y., Brodie, S., Ortiz, I., Tommasi, D., Widlansky, M. J., Barrie, D., Capotondi, A., Cheng, W., Di Lorenzo, E., Edwards, C., Fiechter, J., Fratantoni, P., Hazen, E. L., Hermann, A. J., Kumar, A., Miller, A. J., Pirhalla, D., Buil, M. P., Ray, S., Sheridan, S. C., Subramanian, A., Thompson, P., Thorne, L., Annamalai, H., Aydin, K., Bograd, S. J., Griffis, R. B., Kearney, K., Kim, H., Mariotti, A., Merrifield, M., & Rykaczewski, R. Seasonal-to-interannual prediction of North American coastal marine ecosystems: forecast methods, mechanisms of predictability, and priority developments. Progress in Oceanography, 183, (2020): 102307, doi:10.1016/j.pocean.2020.102307.
    Beschreibung: Marine ecosystem forecasting is an area of active research and rapid development. Promise has been shown for skillful prediction of physical, biogeochemical, and ecological variables on a range of timescales, suggesting potential for forecasts to aid in the management of living marine resources and coastal communities. However, the mechanisms underlying forecast skill in marine ecosystems are often poorly understood, and many forecasts, especially for biological variables, rely on empirical statistical relationships developed from historical observations. Here, we review statistical and dynamical marine ecosystem forecasting methods and highlight examples of their application along U.S. coastlines for seasonal-to-interannual (1–24 month) prediction of properties ranging from coastal sea level to marine top predator distributions. We then describe known mechanisms governing marine ecosystem predictability and how they have been used in forecasts to date. These mechanisms include physical atmospheric and oceanic processes, biogeochemical and ecological responses to physical forcing, and intrinsic characteristics of species themselves. In reviewing the state of the knowledge on forecasting techniques and mechanisms underlying marine ecosystem predictability, we aim to facilitate forecast development and uptake by (i) identifying methods and processes that can be exploited for development of skillful regional forecasts, (ii) informing priorities for forecast development and verification, and (iii) improving understanding of conditional forecast skill (i.e., a priori knowledge of whether a forecast is likely to be skillful). While we focus primarily on coastal marine ecosystems surrounding North America (and the U.S. in particular), we detail forecast methods, physical and biological mechanisms, and priority developments that are globally relevant.
    Beschreibung: This study was supported by the NOAA Climate Program Office’s Modeling, Analysis, Predictions, and Projections (MAPP) program through grants NA17OAR4310108, NA17OAR4310112, NA17OAR4310111, NA17OAR4310110, NA17OAR4310109, NA17OAR4310104, NA17OAR4310106, and NA17OAR4310113. This paper is a product of the NOAA/MAPP Marine Prediction Task Force.
    Schlagwort(e): Prediction ; Predictability ; Forecast ; Ecological forecast ; Mechanism ; Seasonal ; Interannual ; Large marine ecosystem
    Repository-Name: Woods Hole Open Access Server
    Materialart: Article
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 10
    Publikationsdatum: 2022-02-16
    Beschreibung: Muography uses muons naturally produced in the interactions between cosmic rays and atmosphere for imaging and characterization of density differences and time-sequential changes in solid (e.g. rocks) and liquid (e.g. melts±dissolved gases) materials in scales from tens of metres to up to a few kilometres. In addition to being useful in discovering the secrets of the pyramids, ore prospecting and surveillance of nuclear sites, muography successfully images the internal structure of volcanoes. Several field campaigns have demonstrated that muography can image density changes relating to magma ascent and descent, magma flow rate, magma degassing, the shape of the magma body, an empty conduit diameter, hydrothermal activity and major fault lines. In addition, muography is applied for longterm volcano monitoring in a few selected volcanoes around the world. We propose using muography in volcanomonitoring in conjunction with other existing techniques for predicting volcanic hazards. This approach can provide an early indication of a possible future eruption and potentially the first estimate of its scale by producing direct evidence of magma ascent through its conduit in real time. Knowing these issues as early as possible buy critically important time for those responsible for the local alarm and evacuation protocols.
    Beschreibung: Published
    Beschreibung: 20210320
    Beschreibung: 2V. Struttura e sistema di alimentazione dei vulcani
    Beschreibung: JCR Journal
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Einschränkungen Verfügbarkeit
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