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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Water Resources Association 36 (2000), S. 0 
    ISSN: 1752-1688
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Notes: : We measured the base-flow stream chemistry in all the major physiographic provinces of the Chesapeake Bay drainage basin. The spatial variation of stream chemistry was closely related to differences in geology and land cover among the sampled watersheds. Some stream chemistry variables were strongly affected by geological settings in the watersheds while others were more influenced by land cover. The effects of land cover differed among chemical constituents and regions. Concentrations of Ca2+, Mg2+, pH, total alkalinity, and conductivity were mainly functions of carbonate bedrock, especially in the Great Valley. Nitrate-N and total dissolved N were closely related to cropland and increased as the percentage of cropland increased. The rate of increase varied from region to region with the highest in the Piedmont. Na+ and Cl− were mainly affected by the percentage of developed area in a watershed, especially in the Coastal Plain and Piedmont. We observed no significant effects of region or land cover on species of phosphorus because samples were collected under base flow conditions and only dissolved forms were measured. Dissolved silicate (DSi) was not related to any other water chemistry variables. DSi increased as developed area decreased and cropland increased in the Coastal Plain, but these patterns were reversed in the Piedmont. There was no consistent pattern in the spatial variation of land cover effects on the reduced forms of N, dissolved organic P, dissolved organic matter, and K+.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Water Resources Association 35 (1999), S. 0 
    ISSN: 1752-1688
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Notes: : The purpose of this study was to determine the relationships between precipitation at the seasonal and annual scale and water discharge per surface area for seven contiguous first - and second-order tributaries of the Rhode River, a small tidal tributary to Chesapeake Bay, Maryland, USA. The goal was to quantify the effects of a wide range of precipitation, representative of inter-annual variations in weather in this region. The discharges measured included both overland storm flows and groundwater, since the aquifers were perched on a clay aquiclude. Precipitation varied from 824 to 1684 mm/yr and area-weighted Rhode River watershed discharge varied from 130 to 669 mm/yr with an average of 332 mm/yr or 29.1 percent of average precipitation. Average annual dis. charges from three first-order watersheds were significantly lower per surface area and varied from 16.0 to 21.9 percent of precipitation. Winter season precipitation varied from 125 to 541 mm. Area-weighted Rhode River winter discharge varied from 26.3 to 230 mm with an average of 115 mm or 43.9 percent of average precipitation. Spring season precipitation varied from 124 to 510 mm and watershed discharge varied from 40.0 to 321 mm with an average of 138 mm or 46.9 percent of average precipitation. In the summer and fall seasons, watershed discharge averaged 40.6 and 40.9 mm or 13.5 and 14.3 percent of average precipitation, respectively. Except in winter, the proportion of precipitation discharged in the streams increased rapidly with increasing volume of precipitation. Stream order showed a higher correlation with volume of discharge than vegetative cover on the watershed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Water Resources Association 33 (1997), S. 0 
    ISSN: 1752-1688
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Notes: : We measured annual discharges of water, sediments, and nutrients from 10 watersheds with differing proportions of agricultural lands in the Piedmont physiographic province of the Chesapeake Bay drainage. Flow-weighted mean concentrations of total N, nitrate, and dissolved silicate in watershed discharges were correlated with the proportion of cropland in the watershed. In contrast, concentrations of P species did not correlate with cropland. Organic P and C correlated with the concentration of suspended particles, which differed among watersheds. Thus, the ratio of N:P:Si in discharges differed greatly among watersheds, potentially affecting N, P or Si limitation of phytoplankton growth in the receiving waters. Simple regression models of N discharge versus the percentage of cropland suggest that croplands discharge 29–42 kg N ha-1 yr-1 and other lands discharge 1.2–5.8 kg N ha-1 yr-1. We estimated net anthropogenic input of N to croplands and other lands using county level data on agriculture and N deposition from the atmosphere. For most of the study watersheds, N discharge amounted to less than half of the net anthropogenic N.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-072X
    Keywords: Photosynthesis ; Blue-Green Alga ; Phormidium sp. ; Oxidation-Reduction Potential ; Sulfide ; Hot Spring ; Stronatolite ; Anaerobiosis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Photosynthesis in a Phormidium species which forms dense conical-shaped structures in thermal springs is strongly inhibited by aeration but is stimulated by sulfide and other agents (cysteine, thioglycolate, sulfite) which lower the oxidation-reduction potential. The compact structures which this alga forms in nature may restrict oxygen penetration from the environment so that the anaerobic or microaerophilic conditions necessary for photosynthesis can develop. The alga may be defective in a regulatory mechanism that controls the reoxidation of reduced pyridine nucleotides formed during photosynthesis. It is suggested that other mat-forming and benthic blue-green algae may also prefer anaerobic conditions for growth and photosynthesis.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 83 (1995), S. 263-284 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We studied precipitation chemistry at the Rhode River on the western shore of the Chesapeake Bay. We sampled on an event basis, beginning in 1973 for some constituents in bulk precipitation. Beginning in 1981, we also sampled wet precipitation separately from bulk precipitation. In this report, we examine temporal variability of precipitation chemistry at different time scales. Several constituents showed long-term trends. In bulk precipitation, hydronium concentration increased by 27% of its mean concentration per decade, calcium by 67%, ammonium by 28%, and nitrate by 25%, while organic nitrogen decreased by 41%, organic phosphorus by 31%, and organic carbon by 16%. In wet precipitation, ammonium increased by 33% and calcium by 100%, while magnesium decreased by 78% per decade. Concentrations differed greatly among precipitation events, increasing as the volume of precipitation decreased and as the interval since the previous event increased. Most constituents also showed marked seasonal variation. We used a regression model to predict concentrations for each event from month, precipitation volume, and the time since the previous event. We evaluated how much of the interannual variability could be explained by these factors. The event-scale model accounted for almost half of the variability among annual means for ammonium, sodium, and magnesium in bulk precipitation, and for potassium in wet precipitation. This suggests that much of the interannual variability of concentrations may result from interannual variation in the temporal distribution of precipitation.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1573-515X
    Keywords: GIS ; GWLF ; nonpoint source pollution ; nutrient ; watershed modeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract We modeled nutrient export in the ChoptankRiver Basin on the coastal plain of the Chesapeakedrainage, using a modified version of alumped-parameter, hydrochemical model (GWLF).Calibration was performed using long-term (WY1980–WY1990)hydrochemistry data from a gauged site. Thecalibrated model reproduced water yields, TN, and TPexport with cumulative errors of 〈1% over the11-year calibration period and with annual RMS errorsof 10–50%. Model validation was done withindependent measurements at the same gauged site(WY1991 to WY1996) and at another nearby independentlygauged site (WY1991 to WY1995). Local adjustment ofthe groundwater recession coefficient and thedissolved N concentration in agricultural stormflowwas essential for successful application at the secondsite. GWLF appears to be a useful model for estimationof fluxes of water, N and P from ungauged areas withaccuracies of 10–50% at annual time scales.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 49 (2000), S. 217-239 
    ISSN: 1573-515X
    Keywords: ammonium ; beavers ; landscape ; nitrate ; phosphate ; silicate ; total organic-C ; total organic-N ; total organic-P ; total suspended solids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The fluxes and concentrations ofmaterials from two contiguous second-order watershedsin the Coastal Plain of Maryland, U.S.A. were measuredfor six years prior to and six years subsequent to theformation of a 1.25 ha beaver pond near the bottom ofone of the watersheds. The watersheds have a clayaquiclude and were equipped with V-notch weirs andcontinuous volume-integrating water samplers. Thebeaver pond reduced annual discharge of water,total-N, total-P, dissolved silicate, TOC, and TSS by8, 18, 21, 32, 28, and 27%, respectively. Most ofthe total-N reduction was due to increased retentionof nitrate in the winter and spring and TON in thewinter and summer. Most of the total-P reduction wasthe result of retention of both TPi and TOP in thewinter and summer. Dissolved silicate retentionpeaked in the spring, while TOC and TSS retentionpeaked in the winter. Prior to the formation of thebeaver pond, concentrations of TON, TPi, TOP, TOC, andTSS had highly significant correlations with streamdischarge, especially in the winter, but subsequent tothe pond there was little or no relationship betweenthese concentrations and stream discharge. However,concentrations of nitrate in the spring and ammoniumin the summer were highly correlated with streamdischarge both before and after the formation of thebeaver pond and regressions of discharge versusconcentrations of these nutrients explained more ofthe variation in concentrations after the formation ofthe pond.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 115 (1999), S. 547-575 
    ISSN: 1573-2932
    Keywords: ammonium ; nitrate nitrogen ; organic-N ; watershed ; weather effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We studied discharges of total-N, nitrate, ammonium, and total organic-N from seven contiguous small watersheds on the Atlantic Coastal Plain in Maryland for up to 25 yr. These watersheds have perched aquifers so all groundwater discharges as well as surface runoff were measured at V-notch weirs which included volume-integrating flow-proportional samplers. Interannual variations in annual and seasonal precipitation during this study spanned approximately the range of 160 yr weather records in the region. Annual total-N area yields from the overall watershed varied nine-fold, correlations of all N-parameter discharges with precipitation were highly significant, and power function regressions of precipitation vs N-discharge explained from 36 to 59% of the variance. Nitrogen fluxes from a cropland watershed were much higher and more variable with volume of precipitation, while fluxes from a forested watershed were much lower and were primarily composed of organic-N. Correlations of N-fluxes with precipitation were higher in the winter and spring. Annual and seasonal N-concentrations also often increased significantly with precipitation. Variations in seasonal air temperature sometimes explained significant amounts of variance in N-discharges, especially ammonium. A model composed of regressions was used to construct graphical and tabular summaries.
    Type of Medium: Electronic Resource
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  • 9
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Scientific Reports 8 (2018): 15219, doi:10.1038/s41598-018-33283-4.
    Description: This Article corrects an error in Equation 1
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 10
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Scientific Reports 8 (2018): 9478, doi:10.1038/s41598-018-26948-7.
    Description: Tidal wetlands produce long-term soil organic carbon (C) stocks. Thus for carbon accounting purposes, we need accurate and precise information on the magnitude and spatial distribution of those stocks. We assembled and analyzed an unprecedented soil core dataset, and tested three strategies for mapping carbon stocks: applying the average value from the synthesis to mapped tidal wetlands, applying models fit using empirical data and applied using soil, vegetation and salinity maps, and relying on independently generated soil carbon maps. Soil carbon stocks were far lower on average and varied less spatially and with depth than stocks calculated from available soils maps. Further, variation in carbon density was not well-predicted based on climate, salinity, vegetation, or soil classes. Instead, the assembled dataset showed that carbon density across the conterminous united states (CONUS) was normally distributed, with a predictable range of observations. We identified the simplest strategy, applying mean carbon density (27.0 kg C m−3), as the best performing strategy, and conservatively estimated that the top meter of CONUS tidal wetland soil contains 0.72 petagrams C. This strategy could provide standardization in CONUS tidal carbon accounting until such a time as modeling and mapping advancements can quantitatively improve accuracy and precision.
    Description: Synthesis efforts were funded by NASA Carbon Monitoring System (CMS; NNH14AY67I), USGS LandCarbon and the Smithsonian Institution. J.R.H. was additionally supported by the NSF-funded Coastal Carbon Research Coordination Network while completing this manuscript (DEB-1655622). J.M.S. coring efforts were funded by NSF (EAR-1204079). B.P.H. coring efforts were funded by Earth Observatory (Publication Number 197).
    Repository Name: Woods Hole Open Access Server
    Type: Article
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