Description: The microseepage of natural gas from subsurface hydrocarbon reservoirs is a widespread process in petroleum basins. On a global scale, microseepage represents an important natural source of atmospheric methane (CH4). To date, microseepage CH4 flux data have been obtained from ~20 petroleum systems in North America, Europe, and Asia. While the seasonal variations of gas flux due to soil methanotrophic activity are known, the role of geological factors in controlling gas fluxes has been poorly investigated. Here we present new microseepage data from the Dawanqi oil-gas field located within the Tarim Basin (China), a petroleum system characterized by intense faulting and shallow (〈700 m) reservoirs. We measured CH4 fluxes from the ground at 51 sites along three transects by using a closed-chamber connected to a portable gas sensor using off-axis integrated cavity output spectroscopy. Our results indicate that the highest CH4 fluxes occur over faults and/or shallow reservoirs, especially those that were not developed and that have higher fluid pressures. Microseeping CH4 is thermogenic, like that occurring within the Dawanqi reservoirs, as demonstrated by 13C enrichment (δ13C from 46.3‰to 30.7‰) in the chamber. Mean and range microseepage values (17 mg m 2d 1; from 1.4 to 330 mg m 2d 1) are similar to those reported for other petroleum fields with active tectonics. Our results confirm that dry soil over petroleum fields can be a net source of atmospheric CH4 and its flux is primarily controlled by faulting, and reservoir depth and pressure. These factors shall be considered in global bottom-up seepage emission estimates.

Description: Published

Description: 4353–4363

Description: 6A. Geochimica per l'ambiente

Description: JCR Journal

Description: Natural gas microseepage in petroleum-bearing sedimentary basins is an important complement to geophysical methods in oil-gas exploration and a natural source of methane (CH4) for the atmosphere. Microseepage, typically occurring in correspondence with petroleum fields throughout the world, is generally lower in summer, due to temperature-driven methanotrophic consumption, and higher in winter. The global estimates of microseepage methane emission have, however, relatively high uncertainties because of limited amounts of flux data, leading to poor knowledge of the spatial distribution and temporal variability of the gas emission factors. We studied the seasonal variation of microseepage flux to the atmosphere from a petroleum field in China (the Dawanqi oilfield), through methane flux measurements performed in summer 2014, winter 2015, and summer 2019. Winter data refer to frozen soil conditions, with snow cover and ice thickness in the soil exceeding 60 cm. Gas concentration (CH4, CO2, C2+ alkanes) and stable C isotopic composition of CH4 and CO2 in shallow (4 m deep) boreholes confirmed the existence of thermogenic gas seepage. Methane microseepage is higher in summer and lower or nil in winter. This seasonal trend is opposite to what was observed in areas where winter soil is not or poorly frozen. Our data suggest that seasonal microseepage variation may not be univocal worldwide, being strongly dependent on the presence of ice and snow cover in winter. The regional increase of temperature due to climate change, already demonstrated for the Tarim Basin over the last 50 years, could, in the future, reduce winter ice and enhance annual methane emission to the atmosphere.

Description: Published

Description: e2021JD034637

Description: 6A. Geochimica per l'ambiente e geologia medica

Description: JCR Journal

Description: Originating in the equatorial Pacific, the El Niño–Southern Oscillation (ENSO) has highly consequential global impacts, motivating the need to understand its responses to anthropogenic warming. In this Review, we synthesize advances in observed and projected changes of multiple aspects of ENSO, including the processes behind such changes. As in previous syntheses, there is an inter-model consensus of an increase in future ENSO rainfall variability. Now, however, it is apparent that models that best capture key ENSO dynamics also tend to project an increase in future ENSO sea surface temperature variability and, thereby, ENSO magnitude under greenhouse warming, as well as an eastward shift and intensification of ENSO-related atmospheric teleconnections — the Pacific–North American and Pacific–South American patterns. Such projected changes are consistent with palaeoclimate evidence of stronger ENSO variability since the 1950s compared with past centuries. The increase in ENSO variability, though underpinned by increased equatorial Pacific upper-ocean stratification, is strongly influenced by internal variability, raising issues about its quantifiability and detectability. Yet, ongoing coordinated community efforts and computational advances are enabling long-simulation, large-ensemble experiments and high-resolution modelling, offering encouraging prospects for alleviating model biases, incorporating fundamental dynamical processes and reducing uncertainties in projections. Key points Under anthropogenic warming, the majority of climate models project faster background warming in the eastern equatorial Pacific compared with the west. The observed equatorial Pacific surface warming pattern since 1980, though opposite to the projected faster warming in the equatorial eastern Pacific, is within the inter-model range in terms of sea surface temperature (SST) gradients and is subject to influence from internal variability. El Niño–Southern Oscillation (ENSO) rainfall responses in the equatorial Pacific are projected to intensify and shift eastward, leading to an eastward intensification of extratropical teleconnections. ENSO SST variability and extreme ENSO events are projected to increase under greenhouse warming, with a stronger inter-model consensus in CMIP6 compared with CMIP5. However, the time of emergence for ENSO SST variability is later than that for ENSO rainfall variability, opposite to that for mean SST versus mean rainfall. Future ENSO change is likely influenced by past variability, such that quantification of future ENSO in the only realization of the real world is challenging. Although there is no definitive relationship of ENSO variability with the mean zonal SST gradient or seasonal cycle, palaeoclimate records suggest a causal connection between vertical temperature stratification and ENSO strength, and a greater ENSO strength since the 1950s than in past centuries, supporting an emerging increase in ENSO variability under greenhouse warming.

Description: Primary hepatic carcinoma (PHC) is the one of the most common tumors and the common cause of cancer death in the world. Detecting PHC in its early stage by imaging methods may greatly increase survival rates of patients. Ultrasound, computed tomography, magnetic resonance imaging, and positron emission tomography/computed tomography are common imaging methods in the diagnosis of PHC. In this paper, the application of different imaging methods in diagnosing the primary hepatic carcinoma will be discussed.

Description: We propose the optical projection angiography (OPA) based on lateral dynamic scattering light for visualizing a three-dimensional (3D) blood-flow network. In OPA, a pulsed laser source illuminates a live biological sample for eliminating digital camera integration effects. The 2D flow image can be obtained by separating the dynamic and static scattering light signal of each camera pixel in the frequency domain. Flow images at a different angle are combined to reconstruct the 3D volume of the sample to realize OPA. Moreover, as our experiment retains the bright-field optical projection tomography (OPT) setup, the OPA image for the circulatory system and the OPT image for the skeletal structure can simultaneously be reconstructed. The experimental results can potentially be applied in physiological development studies.

Description: El Niño events are characterized by surface warming of the tropical Pacific Ocean and weakening of equatorial trade winds that occur every few years. Such conditions are accompanied by changes in atmospheric and oceanic circulation, affecting global climate, marine and terrestrial ecosystems, fisheries and human activities. The alternation of warm El Niño and cold La Niña conditions, referred to as the El Niño–Southern Oscillation (ENSO), represents the strongest year-to-year fluctuation of the global climate system. Here we provide a synopsis of our current understanding of the spatio-temporal complexity of this important climate mode and its influence on the Earth system.