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  • 1
    Keywords: Geochronometry ; Isotope geology ; Petrology ; Geochronometry ; Isotope geology ; Petrology ; Aufsatzsammlung ; Geochronologie ; Isotopengeologie ; Isotopengeochemie ; Gesteinskunde ; Geochemie ; Geochronometrie ; Isotopengeologie
    Type of Medium: Online Resource
    Pages: 1 Online-Ressource (VI, 266 Seiten)
    ISBN: 1862391467
    Series Statement: Geological Society special publication 220
    DDC: 551.701
    RVK:
    Language: English
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  • 2
    Publication Date: 2018-08-10
    Description: Neodymium and hafnium isotopes and elemental concentrations (Sm, Nd, Hf, Zr) have been measured in three water column profiles south of the Antarctic Circumpolar Current in, and to the east of the Ross Sea, in conjunction with five bottom water samples from the Amundsen Sea Embayment. Neodymium and hafnium both appear to be released from sediments in the Embayment. In the case of Nd, this is reflected in radiogenic isotope compositions (εNd up to −5.4) and highly elevated concentrations (up to 41 pmol/kg). Hafnium isotopes, on the other hand, are only very slightly altered relative to the open ocean sites, and boundary release is most prominently indicated by elevated concentrations (〉1 pmol/kg versus ∼0.7 pmol/kg). There is also a local input of both Hf and Nd at the Marie Byrd Seamounts, which leads to Nd isotope compositions as radiogenic as −3.1, and hafnium shifted to less radiogenic compositions in local bottom water. A compilation of the new data with literature data reveals a consistent view of the influence of Antarctica on the Nd isotope composition in Lower Circumpolar Deep Water (LCDW) and Antarctic Bottom Water (AABW). Sector specific Nd addition shifts AABW formed in the Atlantic sector to less radiogenic isotope compositions (average εNd = −9) relative to LCDW (average εNd = −8.4), whereas AABW in the Pacific sector is shifted to more radiogenic values (average εNd = −7). The evolution towards more radiogenic εNd with depth in LCDW in the Pacific sector is likely to reflect admixture of AABW but, in addition, is also controlled by boundary exchange with the slope as observed at the Marie Byrd Seamounts. Hafnium isotopes are relatively homogeneous in the data set, ranging between εHf = +2 and +3.8 for most samples, excluding less radiogenic compositions in deep waters close to the Marie Byrd Seamounts. The Hf isotope composition in the Pacific sector is, however, slightly less radiogenic than in the Atlantic, corresponding to an average of +3 relative to an average of +3.8. This probably reflects unradiogenic Hf inputs from Antarctica to the Pacific sector, which are vertically homogenized by reversible scavenging. The Hf isotope heterogeneity in LCDW between both sectors is likely to indicate a shorter seawater residence time for Hf than for Nd, which is consistent with the dissolved – particulate phase partitioning of both elements
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 3
  • 4
    Publication Date: 2018-08-13
    Description: The GEOTRACES Intermediate Data Product 2017 (IDP2017) is the second publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2016. The IDP2017 includes data from the Atlantic, Pacific, Arctic, Southern and Indian oceans, with about twice the data volume of the previous IDP2014. For the first time, the IDP2017 contains data for a large suite of biogeochemical parameters as well as aerosol and rain data characterising atmospheric trace element and isotope (TEI) sources. The TEI data in the IDP2017 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at crossover stations. The IDP2017 consists of two parts: (1) a compilation of digital data for more than 450 TEIs as well as standard hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing an on-line atlas that includes more than 590 section plots and 130 animated 3D scenes. The digital data are provided in several formats, including ASCII, Excel spreadsheet, netCDF, and Ocean Data View collection. Users can download the full data packages or make their own custom selections with a new on-line data extraction service. In addition to the actual data values, the IDP2017 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering and for statistical analysis. Metadata about data originators, analytical methods and original publications related to the data are linked in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2017 as section plots and rotating 3D scenes. The basin-wide 3D scenes combine data from many cruises and provide quick overviews of large-scale tracer distributions. These 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of tracer plumes near ocean margins or along ridges. The IDP2017 is the result of a truly international effort involving 326 researchers from 25 countries. This publication provides the critical reference for unpublished data, as well as for studies that make use of a large cross-section of data from the IDP2017. This article is part of a special issue entitled: Conway GEOTRACES - edited by Tim M. Conway, Tristan Horner, Yves Plancherel, and Aridane G. González.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 5
    Publication Date: 2018-03-13
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 6
    Publication Date: 2018-08-10
    Description: Abstract Radiocarbon and uranium-thorium dating results are presented from a genus of calcitic Antarctic cold-water octocorals (family Coralliidae), which were collected from the Marie Byrd Seamounts in the Amundsen Sea (Pacific sector of the Southern Ocean) and which to date have not been investigated geochemically. The geochronological results are set in context with solution and laser ablation-based element/Ca ratios (Li, B, Mg, Mn, Sr, Ba, U, Th). Octocoral radiocarbon ages on living corals are in excellent agreement with modern ambient deep-water �14C, while multiple samples of individual fossil coral specimens yielded reproducible radiocarbon ages. Provided that local radiocarbon reservoir ages can be derived for a given time, fossil Amundsen Sea octocorals should be reliably dateable by means of radiocarbon. In contrast to the encouraging radiocarbon findings, the uranium-series data are more difficult to interpret. The uranium concentration of these calcitic octocorals is an order of magnitude lower than in the aragonitic hexacorals that are conventionally used for geochronological investigations. While modern and Late Holocene octocorals yield initial δ234U in good agreement with modern seawater, our results reveal preferential inward diffusion of dissolved alpha-recoiled 234U and its impact on fossil coral δ234U. Besides alpha-recoil related 234U diffusion, high-resolution sampling of two fossil octocorals further demonstrates that diagenetic uranium mobility has offset apparent coral U-series ages. Combined with the preferential alpha-recoil 234U diffusion, this process has prevented fossil octocorals from preserving a closed system U-series calendar age for longer than a few thousand years. Moreover, several corals investigated contain significant initial thorium, which cannot be adequately corrected for because of an apparently variable initial 232Th/230Th. Our results demonstrate that calcitic cold-water corals are unsuitable for reliable U-series dating. Mg/Ca ratios within single octocoral specimens are internally strikingly homogeneous, and appear promising in terms of their response to ambient temperature. Magnesium/lithium ratios are significantly higher than usually observed in other deep marine calcifiers and for many of our studied corals are remarkably close to seawater compositions. Although this family of octocorals is unsuitable for glacial deep-water �14C reconstructions, our findings highlight some important differences between hexacoral (aragonitic) and octocoral (calcitic) biomineralisation. Calcitic octocorals could still be useful for trace element and some isotopic studies, such as reconstruction of ambient deep water neodymium isotope composition or pH, via boron isotopic measurements.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 7
    Publication Date: 2022-05-25
    Description: © The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Chemical Geology 493 (2018): 210-223, doi:10.1016/j.chemgeo.2018.05.040.
    Description: The GEOTRACES Intermediate Data Product 2017 (IDP2017) is the second publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2016. The IDP2017 includes data from the Atlantic, Pacific, Arctic, Southern and Indian oceans, with about twice the data volume of the previous IDP2014. For the first time, the IDP2017 contains data for a large suite of biogeochemical parameters as well as aerosol and rain data characterising atmospheric trace element and isotope (TEI) sources. The TEI data in the IDP2017 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at crossover stations. The IDP2017 consists of two parts: (1) a compilation of digital data for more than 450 TEIs as well as standard hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing an on-line atlas that includes more than 590 section plots and 130 animated 3D scenes. The digital data are provided in several formats, including ASCII, Excel spreadsheet, netCDF, and Ocean Data View collection. Users can download the full data packages or make their own custom selections with a new on-line data extraction service. In addition to the actual data values, the IDP2017 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering and for statistical analysis. Metadata about data originators, analytical methods and original publications related to the data are linked in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2017 as section plots and rotating 3D scenes. The basin-wide 3D scenes combine data from many cruises and provide quick overviews of large-scale tracer distributions. These 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of tracer plumes near ocean margins or along ridges. The IDP2017 is the result of a truly international effort involving 326 researchers from 25 countries. This publication provides the critical reference for unpublished data, as well as for studies that make use of a large cross-section of data from the IDP2017. This article is part of a special issue entitled: Conway GEOTRACES - edited by Tim M. Conway, Tristan Horner, Yves Plancherel, and Aridane G. González.
    Description: We gratefully acknowledge financial support by the Scientific Committee on Oceanic Research (SCOR) through grants from the U.S. National Science Foundation, including grants OCE-0608600, OCE-0938349, OCE-1243377, and OCE-1546580. Financial support was also provided by the UK Natural Environment Research Council (NERC), the Ministry of Earth Science of India, the Centre National de Recherche Scientifique, l'Université Paul Sabatier de Toulouse, the Observatoire Midi-Pyrénées Toulouse, the Universitat Autònoma de Barcelona, the Kiel Excellence Cluster The Future Ocean, the Swedish Museum of Natural History, The University of Tokyo, The University of British Columbia, The Royal Netherlands Institute for Sea Research, the GEOMAR-Helmholtz Centre for Ocean Research Kiel, and the Alfred Wegener Institute.
    Keywords: GEOTRACES ; Trace elements ; Isotopes ; Electronic atlas ; IDP2017
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 8
    Publication Date: 2022-05-26
    Description: Author Posting. © Association for the Sciences of Limnology and Oceanography, 2012. This article is posted here by permission of Association for the Sciences of Limnology and Oceanography for personal use, not for redistribution. The definitive version was published in Limnology and Oceanography: Methods 10 (2012): 653-665, doi:10.4319/lom.2012.10.653.
    Description: We report data on the isotopic composition of cadmium, copper, iron, lead, zinc, and molybdenum at the GEOTRACES IC1 BATS Atlantic intercalibration station. In general, the between lab and within-lab precisions are adequate to resolve global gradients and vertical gradients at this station for Cd, Fe, Pb, and Zn. Cd and Zn isotopes show clear variations in the upper water column and more subtle variations in the deep water; these variations are attributable, in part, to progressive mass fractionation of isotopes by Rayleigh distillation from biogenic uptake and/or adsorption. Fe isotope variability is attributed to heavier crustal dust and hydrothermal sources and light Fe from reducing sediments. Pb isotope variability results from temporal changes in anthropogenic source isotopic compositions and the relative contributions of U.S. and European Pb sources. Cu and Mo isotope variability is more subtle and close to analytical precision. Although the present situation is adequate for proceeding with GEOTRACES, it should be possible to improve the within-lab and between-lab precisions for some of these properties.
    Description: The National Science Foundation sponsored the cruise and many of the shipboard participants; in particular E.B. was funded to participate on the cruise by NSF Grant OCE-0751409 and his preparation of this paper was partially supported by grants from the Kuwait Foundation for the Advancement of Science (KFAS) and the Singapore-MIT Alliance for Research and Technology (SMART).
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 9
    Publication Date: 2023-03-03
    Keywords: Alboran Sea; Date/Time of event; DEPTH, sediment/rock; Elevation of event; Event label; ICP-MS, Thermo Finnigan, Element 2; Latitude of event; Location of event; Longitude of event; Manganese/Calcium ratio; Mediterranean Sea, Western Basin; MUC; MultiCorer; Neodymium/Calcium ratio; POS334; POS334_74-6; POS334_75-7; POS334_78-7; POS334_79-7; POS334_80-7; POS334_81-6; Poseidon; Sample comment; Tirreno Sea
    Type: Dataset
    Format: text/tab-separated-values, 48 data points
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  • 10
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    In:  Supplement to: Gutjahr, Marcus; Vance, Derek; Hoffmann, Dirk L; Hillenbrand, Claus-Dieter; Foster, Gavin L; Rae, James W B; Kuhn, Gerhard (2013): Structural limitations in deriving accurate U-series ages from calcitic cold-water corals contrast with robust coral radiocarbon and Mg/Ca systematics. Chemical Geology, 355, 69-87, https://doi.org/10.1016/j.chemgeo.2013.07.002
    Publication Date: 2023-05-12
    Description: Radiocarbon and uranium-thorium dating results are presented from a genus of calcitic Antarctic cold-water octocorals (family Coralliidae), which were collected from the Marie Byrd Seamounts in the Amundsen Sea (Pacific sector of the Southern Ocean) and which to date have not been investigated geochemically. The geochronological results are set in context with solution and laser ablation-based element/Ca ratios (Li, B, Mg, Mn, Sr, Ba, U, Th). Octocoral radiocarbon ages on living corals are in excellent agreement with modern ambient deep-water D14C, while multiple samples of individual fossil coral specimens yielded reproducible radiocarbon ages. Provided that local radiocarbon reservoir ages can be derived for a given time, fossil Amundsen Sea octocorals should be reliably dateable by means of radiocarbon. In contrast to the encouraging radiocarbon findings, the uranium-series data are more difficult to interpret. The uranium concentration of these calcitic octocorals is an order of magnitude lower than in the aragonitic hexacorals that are conventionally used for geochronological investigations. While modern and Late Holocene octocorals yield initial d234U in good agreement with modern seawater, our results reveal preferential inward diffusion of dissolved alpha-recoiled 234U and its impact on fossil coral d234U. Besides alpha-recoil related 234U diffusion, high-resolution sampling of two fossil octocorals further demonstrates that diagenetic uranium mobility has offset apparent coral U-series ages. Combined with the preferential alpha-recoil 234U diffusion, this process has prevented fossil octocorals from preserving a closed system U-series calendar age for longer than a few thousand years. Moreover, several corals investigated contain significant initial thorium, which cannot be adequately corrected for because of an apparently variable initial 232Th/230Th. Our results demonstrate that calcitic cold-water corals are unsuitable for reliable U-series dating. Mg/Ca ratios within single octocoral specimens are internally strikingly homogeneous, and appear promising in terms of their response to ambient temperature. Magnesium/lithium ratios are significantly higher than usually observed in other deep marine calcifiers and for many of our studied corals are remarkably close to seawater compositions. Although this family of octocorals is unsuitable for glacial deep-water D14C reconstructions, our findings highlight some important differences between hexacoral (aragonitic) and octocoral (calcitic) biomineralisation. Calcitic octocorals could still be useful for trace element and some isotopic studies, such as reconstruction of ambient deep water neodymium isotope composition or pH, via boron isotopic measurements.
    Keywords: AWI_Paleo; Paleoenvironmental Reconstructions from Marine Sediments @ AWI
    Type: Dataset
    Format: application/zip, 3 datasets
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