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  • 1
    Book
    Book
    Chichester [u.a.] : Wiley
    Keywords: Chemistry ; trace analysis ; inorganic compounds ; Spurenanalyse ; Anorganische Verbindungen ; Anorganische Verbindungen ; Spurenanalyse ; Spurenanalyse ; Anorganische Verbindungen
    Type of Medium: Book
    Pages: XII, 182 S. , graph. Darst.
    ISBN: 0471941441
    DDC: 546
    RVK:
    Language: English
    Note: Includes bibliographical references and index
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Veterinary Microbiology 36 (1993), S. 253-259 
    ISSN: 0378-1135
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Medicine
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 313 (1985), S. 565-567 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Samples were collected at Discovery Stations 10704 (North Atlantic Ocean; 3922' N, 12 51' W; 9 April 1983) and 10707 (Eastern Alboran Sea; 37 33' N, 00 47' E; 17-18 April 1983), using rosette-mounted Teflon-coated 2.5-litre Go-Flo bottles, deployed with a conductivity-temperature-depth (CTD) probe ...
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Neuroradiology 42 (2000), S. 81-84 
    ISSN: 1432-1920
    Keywords: Key words Haemorrhage, intracerebral ; Haemosiderin ; Magnetic resonance imaging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract Intracerebral haemorrhage may be visible indefinitely on MRI, due to persistence of haemosiderin in macrophages around the lesion, but it is not clear whether all haemorrhages produce haemosiderin or, if not, what proportion cannot be identified as former haemorrhages on routine MRI. We performed routine MRI (spin-echo T2- and proton-density weighted images) in 116 survivors of moderate to severe head injury, 1–5 years after injury. We reviewed the images blindly and correlated them with CT in the acute stage, to determine how many haemorrhages from the acute stage were identifiable by virtue of haemosiderin deposition on late MRI. Of 106 haemorrhages in 78 patients on CT at the time of injury, 96 (90 %) were visible as haemosiderin on late MRI. Of the old haemorrhages without haemosiderin, seven of ten were in patients where another haemorrhage with haemosiderin was still visible elsewhere in the brain. No patient or haemorrhage features explained the formation or absence of haemosiderin. Thus about 10 % of definite haematomas show no trace of haemosiderin on routine spin-echo MRI. Radiologists should be alerted to supplement routine spin-echo with gradient-echo sequences if there is a reason to suspect, or specifically exclude, prior haemorrhage.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 3 (1974), S. 153-158 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The pulsed beam technique has been used to achieved a high data acuumulation rate in an energy-dispersive analytical system consisting of an electron probe analyser and the Harwell ‘Highspec’ pulse analyser system 3074. The use of fast beam switching ( ∼ 30 ns transient time) and the special timing facilities available in the Harwell equipment reduce the spectrum contamination due to displacement of the probe during switching to a low level and also provide precise measurements of live time, essential for accurate analysis. Analyses performed at spectrum accumulation rate of up to 12 kP.P.S. shows agreement with accepted values to within ± 1% for major constituents. Simple modification of the system permits accumulation rates up to 25 kP.P.S.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Publication Date: 2018-02-05
    Description: Recent work has shown that glaciers are a globally significant source of the micronutrient Fe to the ocean. Polar regions are particularly susceptible to climate change and have been subject to pronounced warming in the past few decades. In response to this warming, the volume of glacial meltwater runoff from Greenland has increased. This meltwater has a relatively high particulate and dissolved Fe content. Seasonal Fe limitation of marine ecosystems has been found in parts of the North Atlantic, so it has been proposed that increasing fluxes of Fe rich meltwater from Greenland to the North Atlantic could alleviate this Fe limitation and thereby increase marine primary production. However, here we use a synthesis of biogeochemical and physical oceanography studies to suggest that the physical circulation around Greenland does not favour direct export of dissolved or particulate Fe from inshore to offshore waters. The Fe budget in surface waters of the North Atlantic may therefore be insensitive to increasing meltwater fluxes from Greenland.
    Type: Article , PeerReviewed
    Format: text
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  • 7
    Publication Date: 2020-05-04
    Description: Over much of the world's surface oceans, nitrate and phosphate concentrations are below the limit of detection (LOD) of conventional techniques of analysis. However, these nutrients play a controlling role in primary productivity and carbon sequestration in these waters. In recent years, techniques have been developed to address this challenge, and methods are now available for the shipboard analysis of nanomolar (nM) nitrate and phosphate concentrations with a high sample throughput. This article provides an overview of the methods for nM nitrate and phosphate analysis in seawater. We outline in detail a system comprising liquid waveguide capillary cells connected to a conventional segmented-flow autoanalyser and using miniaturised spectrophotometers. This approach is suitable for routine field measurements of nitrate and phosphate and achieves LODs of 0.8 nM phosphate and 1.5 nM nitrate. © 2008 Elsevier Ltd. All rights reserved.
    Type: Article , PeerReviewed
    Format: text
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  • 8
    Publication Date: 2014-01-27
    Description: This paper reports on investigations into interferences with the measurements of nanomolar nitrate. +. nitrite and soluble reactive phosphate (SRP) in oceanic surface seawater using a segmented continuous flow autoanalyser (SCFA) interfaced with a liquid-waveguide capillary flow-cell (LWCC). The interferences of silicate and arsenate with the analysis of SRP, the effect of sample filtration on the measurement of nanomolar nitrate. +. nitrite and SRP concentrations, and the stability of samples during storage are described.The investigation into the effect of arsenate (concentrations up to 100nM) on phosphate analysis (concentrations up to 50nM) indicated that the arsenate interference scaled linearly with phosphate concentrations, resulting in an overestimation of SRP concentrations of 4.6±1.4 for an assumed arsenate concentration of 20nM. The effect of added Si(OH)4 was to increase SRP signals by up to 36±19nM (at 100μM Si(OH)4). However, at silicate concentrations below 1.5μM, which are typically observed in oligotrophic surface ocean waters, the effect of silicate on the phosphate analysis was much smaller (≤0.78±0.15nM change in SRP). Since arsenate and silicate interferences vary between analytical approaches used for nanomolar SRP analysis, it is important that the interferences are systematically assessed in any newly developed analytical system.Filtration of surface seawater samples resulted in a decrease in concentration of 1.7-2.7. nM (±0.5. nM) SRP, and a small decrease in nitrate concentrations which was within the precision of the method (±0.6. nM). A stability study indicated that storage of very low concentration nutrient samples in the dark at 4°C for less than 24. h resulted in no statistically significant changes in nutrient concentrations. Freezing unfiltered surface seawater samples from an oligotrophic ocean region resulted in a small but significant increase in the SRP concentration from 12.0 ± 1.3 nM (n=3) to 14.7 ± 0.6. nM (n=3) (Student's t-test; p=0.021). The corresponding change in nitrate concentration was not significant (Student's t-test; p>0.05). © 2010 Elsevier B.V.
    Type: Article , PeerReviewed
    Format: text
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  • 9
    Publication Date: 2014-01-28
    Description: We have conducted a study of hydrothermal plumes overlying the Mid-Atlantic Ridge near 5° S to investigate whether there is a significant export flux of dissolved Fe from hydrothermal venting to the oceans. Our study combined measurements of plume-height Fe concentrations from a series of 6 CTD stations together with studies of dissolved Fe speciation in a subset of those samples. At 2.5 km down plume from the nearest known vent site dissolved Fe concentrations were ∼ 20 nM. This is much higher than would be predicted from a combination of plume dilution and dissolved Fe(II) oxidation rates, but consistent with stabilisation due to the presence of organic Fe complexes and Fe colloids. Using Competitive Ligand Exchange-Cathodic Stripping Voltammetry (CLE-CSV), stabilised dissolved Fe complexes were detected within the dissolved Fe fraction on the edges of one non-buoyant hydrothermal plume with observed ligand concentrations high enough to account for stabilisation of ∼ 4 of the total Fe emitted from the 5° S vent sites. If these results were representative of all hydrothermal systems, submarine venting could provide 12-22 of the global deep-ocean dissolved Fe budget. © 2008 Elsevier B.V. All rights reserved.
    Type: Article , PeerReviewed
    Format: text
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  • 10
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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