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  • 1
    Publication Date: 2023-11-18
    Description: Cyclostratigraphy and astrochronology are now at the forefront of geologic timekeeping. While this technique heavily relies on the accuracy of astronomical calculations, solar system chaos limits how far back astronomical calculations can be performed with confidence. High‐resolution paleoclimate records with Milankovitch imprints now allow reversing the traditional cyclostratigraphic approach: Middle Eocene drift sediments from Newfoundland Ridge are well‐suited for this purpose, due to high sedimentation rates and distinct lithological cycles. Per contra, the stratigraphies of Integrated Ocean Drilling Program Sites U1408–U1410 are highly complex with several hiatuses. Here, we built a two‐site composite and constructed a conservative age‐depth model to provide a reliable chronology for this rhythmic, highly resolved (〈1 kyr) sedimentary archive. Astronomical components (g‐terms and precession constant) are extracted from proxy time‐series using two different techniques, producing consistent results. We find astronomical frequencies up to 4% lower than reported in astronomical solution La04. This solution, however, was smoothed over 20‐Myr intervals, and our results therefore provide constraints on g‐term variability on shorter, million‐year timescales. We also report first evidence that the g〈sub〉4〈/sub〉–g〈sub〉3〈/sub〉 “grand eccentricity cycle” may have had a 1.2‐Myr period around 41 Ma, contrary to its 2.4‐Myr periodicity today. Our median precession constant estimate (51.28 ± 0.56″/year) confirms earlier indicators of a relatively low rate of tidal dissipation in the Paleogene. Newfoundland Ridge drift sediments thus enable a reliable reconstruction of astronomical components at the limit of validity of current astronomical calculations, extracted from geologic data, providing a new target for the next generation of astronomical calculations.
    Description: Plain Language Summary: The traditional cyclostratigraphic approach is to align and correlate a geologic depth‐series with an astronomical solution. However, the chaotic nature of the Solar System prevents astronomers from precisely calculating planetary motions beyond 40–50 million years ago. This in turn limits the options for geologists to use the resulting oscillations in Earth's climate system as a metronome for determining geologic time. In this study, we reversed the cyclostratigraphic approach and used the highly rhythmical sedimentary deposits from Newfoundland Ridge (North Atlantic) to back‐calculate planetary motions at ∼41 million years ago. The superior quality of the Newfoundland Ridge geoarchive originates from the combination of relatively high sedimentation rates (∼4 cm/kyr) and the time‐continuous character of our two‐site composite record between 39.5 and 42.8 million years ago. In this work, we had to first overcome considerable challenges in reconstructing the timing of sediment deposition, which we did with highly resolved geochemical measurements from two sites. We then were able to extract information on the Earth's planetary motion and on the Earth‐Moon interactions. These astronomical reconstructions based on geological data can now be used by astronomers to describe the evolution of the solar system further back in time than was previously possible.
    Description: Key Points: A new precession‐based cyclostratigraphy for the middle Eocene intervals of IODP Sites U1408 and U1410. Variability in astronomical fundamental frequencies (g‐terms) on million‐year timescales is larger than previously assumed. Our precession constant estimate for 41 Ma (51.28 ± 0.56″/year) confirms earlier indicators of slower tidal dissipation in the Paleogene.
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: University of California http://dx.doi.org/10.13039/100005595
    Description: Belgian American Educational Foundation http://dx.doi.org/10.13039/100001491
    Description: https://paloz.marum.de/AstroComputation/index.html
    Description: https://paloz.marum.de/confluence/display/ESPUBLIC/NAFF
    Keywords: ddc:551 ; North Atlantic ; Eocene ; cyclostratigraphy ; astrochronology
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2023-07-11
    Description: Acarininid shells were cast in epoxy, ground to midsection and imaged by SEM to identify suitable domains for analysis. Fully quantitative Mg/Ca analyses by a CAMECA SX-51 Electron Probe Microanalyzer (mineral standards, background subtracted, and matrix corrected) were performed using Probe for EPMA© software. An accelerating voltage of 15 kV with 10 nA Faraday current and a tightly focused beam were used, with a counting time of 20s on the peak and 10s on each of the two background positions. These analyses were performed using the “Time Dependent Intensity” feature of the Probe for EPMA software, where Ca and Mg were measured in 4 s increments and counts were plotted against time, with extrapolation to time = 0s as the true count rate. The natural carbonate standards Delight Dolomite, Callender Calcite, and UWC-3 were used for Mg and Ca; Mg-KαX-rays were measured on two spectrometers and aggregated. Carbon was calculated within the matrix correction on an atomic basis as C = (Ca + Mg + Sr). Whenever possible, multiple Mg/Ca measurements were placed in each acarininid shell, and the average value was calculated. Data Quality Information: Only EPMA analytical totals of 98.5 – 100.5 wt.% were considered acceptable
    Keywords: 113-690B; Acarinina soldadoensis; Acarinina soldadoensis, Magnesium/Calcium ratio; Acarininids; Calculated; d18O; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; EPMA; Joides Resolution; Leg113; Mg/Ca; ODP Site 690; PETM; Sample code/label; SIMS; Size fraction; South Atlantic Ocean; Weddell Sea
    Type: Dataset
    Format: text/tab-separated-values, 288 data points
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  • 3
    Publication Date: 2023-07-11
    Description: Sampling and Analyzing Method: Acarininid shells were cast in epoxy, ground to midsection and imaged by SEM to identify suitable, well-preserved domains for analysis. In situ d18O data were acquired in the WiscSIMS Laboratory at the Department of Geoscience, UW-Madison, using a CAMECA IMS-1280 large radius multicollector SIMS. (Kita et al., 2009; Valley and Kita, 2009). Depending on the size of the target, samples were analyzed with a 10 µm or 3 µm primary beam. Four consecutive measurements of UWC-3 calcite standard (d18O = 12.40 per mille Vienna standard mean ocean water; VSMOW; Kozdon et al., 2009) were performed before and after every set of typically 10 sample analyses.
    Keywords: 113-690B; Acarinina soldadoensis; Acarinina soldadoensis, δ18O; Acarininids; d18O; DEPTH, sediment/rock; DRILL; Drilling/drill rig; EPMA; Joides Resolution; Leg113; Mg/Ca; ODP Site 690; PETM; Sample code/label; SIMS; Size fraction; South Atlantic Ocean; Weddell Sea
    Type: Dataset
    Format: text/tab-separated-values, 204 data points
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  • 4
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    PANGAEA
    In:  Supplement to: Henehan, Michael J; Hull, Pincelli M; Penman, Donald E; Rae, James W B; Schmidt, Daniela N (2016): Biogeochemical significance of pelagic ecosystem function: an end-Cretaceous case study. Philosophical Transactions of the Royal Society B-Biological Sciences, 371(1694), 20150510, https://doi.org/10.1098/rstb.2015.0510
    Publication Date: 2024-01-09
    Description: Pelagic ecosystem function is integral to global biogeochemical cycling, and plays a major role in modulating atmospheric CO2 concentrations (pCO2). Uncertainty as to the effects of human activities on marine ecosystem function hinders projection of future atmospheric pCO2. To this end, events in the geological past can provide informative case studies in the response of ecosystem function to environmental and ecological changes. Around the Cretaceous-Palaeogene (K-Pg) boundary, two such events occurred: Deccan large igneous province (LIP) eruptions and massive bolide impact at the Yucatan Peninsula. Both perturbed the environment, but only the impact coincided with marine mass extinction. As such, we use these events to directly contrast the response of marine biogeochemical cycling to environmental perturbation with and without changes in global species richness. We measure this biogeochemical response using records of deep-sea carbonate preservation. We find that Late Cretaceous Deccan volcanism prompted transient deep-sea carbonate dissolution of a larger magnitude and timescale than predicted by geochemical models. Even so, the effect of volcanism on carbonate preservation was slight compared with bolide impact. Empirical records and geochemical models support a pronounced increase in carbonate saturation state for more than 500 000 years following the mass extinction of pelagic carbonate producers at the K-Pg boundary. These examples highlight the importance of pelagic ecosystems in moderating climate and ocean chemistry.
    Keywords: Ocean Drilling Program; ODP
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 5
    Publication Date: 2024-01-09
    Description: Data from Ocean Drilling Program Site 1263 on Walvis Ridge in SE Atlantic include barite accumulation rates, benthic foraminiferal data, and carbon and oxygen isotopes for Eocene hyperthermals: PETM, ETM2, ETM3. Changes in primary productivity, in export of organic carbon from the surface ocean, and in remineralization deeper in the water column in the so-called “twilight zone” may substantially alter the marine biological carbon pump, thus carbon storage in the oceans. We present different proxy records commonly used for reconstructing paleoproductivity, and re-evaluate their use for understanding dynamic change within and between different constituents of the marine biological pump during transient global warming episodes in the past. Marine pelagic barite records are a proxy for carbon export from the photic and/or mesopelagic zone, and are not positively correlated with benthic foraminiferal proxies for arrival of organic matter to the seafloor over three early Eocene periods of global warming (Ocean Drilling Program Site 1263, SE Atlantic). These two proxies reflect processes in different parts of the water column, thus different components of the biological pump.
    Keywords: Barite; Benthic Foraminifers; Eocene; hyperthermal; Ocean Drilling Program; ODP; PETM
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 6
    Publication Date: 2024-01-09
    Keywords: 208-1263A; 208-1263B; 208-1263C; 208-1263D; AGE; Age, relative; Barite; Benthic Foraminifers; Depth, composite; Depth, composite revised; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Eocene; Event label; Foraminifera, benthic; hyperthermal; Intercore correlation; Joides Resolution; Leg208; Ocean Drilling Program; ODP; PETM; Sample code/label; Walvis Ridge, Southeast Atlantic Ocean
    Type: Dataset
    Format: text/tab-separated-values, 264 data points
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  • 7
    Publication Date: 2024-01-09
    Keywords: 208-1263A; 208-1263B; 208-1263C; 208-1263D; Accumulation rate, barite; Accumulation rate, mass; AGE; Age, relative; Barite; Benthic Foraminifers; Calculated; Density, dry bulk; Depth, composite; Depth, composite revised; DEPTH, sediment/rock; DRILL; Drilling/drill rig; Dry mass; DSDP/ODP/IODP sample designation; Eocene; Event label; hyperthermal; Intercore correlation; Joides Resolution; Leg208; Linear sedimentation rate; Ocean Drilling Program; ODP; PETM; Reference/source; Sample code/label; Walvis Ridge, Southeast Atlantic Ocean
    Type: Dataset
    Format: text/tab-separated-values, 943 data points
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  • 8
    Publication Date: 2024-01-09
    Keywords: 208-1263A; 208-1263B; 208-1263C; 208-1263D; AGE; Barite; Benthic Foraminifers; Depth, composite revised; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Eocene; Event label; hyperthermal; Intercore correlation; Joides Resolution; Leg208; Nuttallides truempyi, δ13C; Nuttallides truempyi, δ18O; Ocean Drilling Program; ODP; PETM; Reference/source; Sample code/label; Walvis Ridge, Southeast Atlantic Ocean; δ13C, bulk carbonate; δ18O, bulk carbonate
    Type: Dataset
    Format: text/tab-separated-values, 4045 data points
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  • 9
    Publication Date: 2024-01-09
    Keywords: 208-1263A; 208-1263C; Accumulation rate, mass; Accumulation rate, number of benthic foraminifera; AGE; Age, relative; Barite; Benthic Foraminifers; Calculated; Density, dry bulk; Depth, composite; Depth, composite revised; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Eocene; Event label; Foraminifera, benthic; hyperthermal; Intercore correlation; Joides Resolution; Leg208; Linear sedimentation rate; Ocean Drilling Program; ODP; PETM; Reference/source; Sample code/label; Walvis Ridge, Southeast Atlantic Ocean
    Type: Dataset
    Format: text/tab-separated-values, 950 data points
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  • 10
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    PANGAEA
    In:  Supplement to: Carter, Samantha Cassie; Griffith, Elizabeth M; Penman, Donald E (2016): Peak intervals of equatorial Pacific export production during the middle Miocene climate transition. Geology, 44(11), 923-926, https://doi.org/10.1130/G38290.1
    Publication Date: 2023-12-18
    Description: The middle Miocene climate transition (MMCT) is characterized by an abrupt 1‰ increase in benthic foraminiferal oxygen isotopes at ca. 13.8 Ma, marking expansion of the Antarctic Ice Sheet and transition of Earth's climate to a cooler, relatively stable glacial state. Also occurring during this period is a globally recognized positive carbon isotope excursion (16.9-13.5 Ma) in benthic and planktonic foraminifera with shorter carbon isotope maxima (CM) events, linking hypotheses for climate change at the time with the carbon cycle. In order to test whether export production in the eastern equatorial Pacific is related to the largest such event (CM6), coincident with Antarctic Ice Sheet expansion, a high-resolution (〈5 k.y.) record of export production at Integrated Ocean Drilling Program Site U1337 spanning the MMCT (14.02-13.43 Ma) was produced using marine pelagic barite mass accumulation rates. Export production is elevated with an extended period of more than double present-day values. These variations are not orbitally paced and provide evidence for a reorganization of nutrients supplied to the eastern equatorial Pacific in the Miocene and intensification of upwelling. If such changes are representative of the entire region, then this mechanism could sequester enough carbon to have a significant effect on atmospheric pCO2. However, continual delivery of nutrients to the surface waters of the eastern equatorial Pacific is required in order to sustain export production without depleting the surface ocean of limiting nutrients. This might be accomplished by a change in ocean circulation or a combination of other processes requiring further study.
    Keywords: 321-U1337A; 321-U1337C; 321-U1337D; Accumulation rate, barite; Accumulation rate, carbonate; Accumulation rate, mass; AGE; Age, shift; Barium sulfate; Calcium carbonate; Carbon, flux per year; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Event label; Exp321; Integrated Ocean Drilling Program / International Ocean Discovery Program; IODP; Joides Resolution; Latitude of event; Longitude of event; Pacific Equatorial Age Transect II / Juan de Fuca; Sample code/label
    Type: Dataset
    Format: text/tab-separated-values, 1568 data points
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