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  • 1
    In: Applied Sciences, MDPI AG, Vol. 10, No. 22 ( 2020-11-20), p. 8253-
    Kurzfassung: The recovery of noble metals from electrical wires and cables results in waste materials such as polyvinyl chloride (PVC) and polyethylene (PE), that is, waste insulation electrical cables (WIEC), which have been processed by gasification for energy recovery. This study focused on the effect of blending the ratio of WIEC on the gasification feedstock composition and the lower heating value (LHV) of produced syngas, through controlled tests and tests under different loads on the generator. The controlled gasification experiments were carried out at blending ratios between pine biomass and WIEC of 90:10, 80:20, and 70:30 and with pine biomass only (100%). For the loads gasification, the experiments were carried out at a blending ratio of 80:20. The controlled experimental results presented that the highest hydrogen content, approximated 17.7 vol.%, was observed at a blending ratio of 70:30 between pine biomass and WIEC and the highest LHV of syngas was observed at a blending ratio of 90:10, with 5.7 MJ/Nm3. For the load gasification experiments, the results showed that the highest hydrogen content was obtained with a load of 15 kW in the generator, approximately 18.48 vol.% of hydrogen content, and the highest LHV of synthesis gas was observed during the 5 kW test, with 5.22 MJ/Nm3. Overall, the new processing of waste insulation electrical cables using a downdraft gasification reactor demonstrates great promise for high quality syngas production.
    Materialart: Online-Ressource
    ISSN: 2076-3417
    Sprache: Englisch
    Verlag: MDPI AG
    Publikationsdatum: 2020
    ZDB Id: 2704225-X
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    In: Sustainability, MDPI AG, Vol. 12, No. 3 ( 2020-02-01), p. 1036-
    Kurzfassung: The present work studies the possibility of energy recovery by thermal conversion of combustible residual materials, namely tires and rubber-plastic, plastic waste from outdoor luminaires. The waste has great potential for energy recovery (HHV: 38.6 MJ/kg for tires and 31.6 MJ/kg for plastic). Considering the thermal conversion difficulties of these residues, four co-combustion tests with mixtures of tires/plastics + pelletized Miscanthus, and an additional test with 100% Miscanthus were performed. The temperature was increased to the maximum allowed by the equipment, about 500 °C. The water temperature at the boiler outlet and the water flow were controlled (60 °C and 11 L/min). Different mixtures of residues (0–60% tires/plastics) were tested and compared in terms of power and gaseous emissions. Results indicate that energy production increased with the increase of tire residue in the mixture, reaching a maximum of 157 kW for 40% of miscanthus and 60% of tires. However, the automatic feeding difficulties of the boiler also increased, requiring constant operator intervention. As for plastic and rubber waste, fuel consumption generally decreased with increasing percentages of these materials in the blend, with temperatures ranging from 383 °C to 411 °C. Power also decreased by including such wastes (66–100 kW) due to feeding difficulties and cinder-fusing problems related to ash melting. From the study, it can be concluded that co-combustion is a suitable technology for the recovery of waste tires, but operational problems arise with high levels of residues in the mixture. Increasing pollutant emissions and the need for pre-treatments are other limiting factors. In this sense, the thermal gasification process was tested with the same residues and the same percentages of mixtures used in the co-combustion tests. The gasification tests were performed in a downdraft reactor at temperatures above 800 °C. Each test started with 100% acacia chip for reference (like the previous miscanthus), and then with mixtures of 0–60% of tires and blends of plastics and rubbers. Results obtained for the two residues demonstrated the viability of the technology, however, with mixtures higher than 40% it was very difficult to develop a process under stable conditions. The optimum condition for producing a synthesis gas with a substantial heating value occurred with mixtures of 20% of polymeric wastes, which resulted in gases with a calorific value of 3.64 MJ/Nm3 for tires and 3.09 MJ/Nm3 for plastics and rubbers.
    Materialart: Online-Ressource
    ISSN: 2071-1050
    Sprache: Englisch
    Verlag: MDPI AG
    Publikationsdatum: 2020
    ZDB Id: 2518383-7
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    In: C, MDPI AG, Vol. 9, No. 1 ( 2022-12-24), p. 2-
    Kurzfassung: Rural areas can benefit from the development of biorefineries for the valorization of endogenous feedstocks. In this study, a pre-feasibility assessment of an integrated multi-product biorefinery to produce essential oils and biomethane is carried out considering current technical and economic conditions. The proposed concept is based on the steam distillation of forestry biomass for the extraction of essential oils (2900 L/y) followed by biomethane production via syngas methanation using the spent biomass as feedstock (30.4 kg/h). In parallel, the anaerobic treatment of WWTP sludge (5.3 kg/h) is used to produce additional biomethane for mobile applications. The results show that the intended multi-product biorefinery delivers attractive benefits for investors as described by the calculated financial indicators: NPV of EUR 4342.6, IRR of 18.1%, and PB of 6 years. Overall, the pre-feasibility analysis performed in this study demonstrates that the proposed biorefinery concept is promising and warrants further investment consideration via cost and benefit analysis, ultimately promoting the implementation of multi-product biorefineries across Europe.
    Materialart: Online-Ressource
    ISSN: 2311-5629
    Sprache: Englisch
    Verlag: MDPI AG
    Publikationsdatum: 2022
    ZDB Id: 2813973-2
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    In: Applied Sciences, MDPI AG, Vol. 11, No. 7 ( 2021-03-30), p. 3064-
    Kurzfassung: The present study evaluates the digestion of cork boiling wastewater (CBW) through a biochemical methane potential (BMP) test. BMP assays were carried out with a working volume of 600 mL at a constant mesophilic temperature (35 °C). The experiment bottles contained CBW and inoculum (digested sludge from a wastewater treatment plant (WWTP)), with a ratio of inoculum/substrate (Ino/CBW) of 1:1 and 2:1 on the basis of volatile solids (VSs); the codigestion with food waste (FW) had a ratio of 2/0.7:0.3 (Ino/CBW:FW) and the codigestion with cow manure (CM) had a ratio of 2/0.5:0.5 (Ino/CBW:CM). Biogas and methane production was proportional to the inoculum substrate ratio (ISR) used. BMP tests have proved to be valuable for inferring the adequacy of anaerobic digestion to treat wastewater from the cork industry. The results indicate that the biomethane potential of CBWs for Ino/CBW ratios 1:1 and 2:1 is very low compared to other organic substrates. For the codigestion tests, the test with the Ino/CBW:CM ratio of 2/0.7:0.3 showed better biomethane yields, being in the expected values. This demonstrated that it is possible to perform the anaerobic digestion (AD) of CBW using a cosubstrate to increase biogas production and biomethane and to improve the quality of the final digestate.
    Materialart: Online-Ressource
    ISSN: 2076-3417
    Sprache: Englisch
    Verlag: MDPI AG
    Publikationsdatum: 2021
    ZDB Id: 2704225-X
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    In: Environments, MDPI AG, Vol. 10, No. 3 ( 2023-03-07), p. 47-
    Kurzfassung: The construction industry is responsible for a large amount of CO2 emissions and an intensive energy consumption. Cement production is the third largest source of anthropogenic CO2 emissions and is responsible for about 1.8 Gt of CO2 emissions into the atmosphere. The use of waste materials to replace a fraction of cement in the mortar makes it more economically and ecologically friendly. In this work, the main objective was to test incorporations of biochar produced at temperatures of 300, 350, and 400 °C, as a partial replacement for cement in the production of mortar. The materials used for the tests were residual lignocellulosic biomass (WBL) and electrical cable insulation waste (WIEC) mixed in a ratio of 1:1. The biochars produced were crushed and sieved after production to reduce the particles. A sample of biochar was used and tested under these conditions and another sample was washed in water and dried before being incorporated; all tests were carried out with a 5% replacement. Waste recovery tests were also carried out without thermochemical treatment. The specimens were studied for compressive strength and water absorption by immersion. All tests were replicated and were analyzed and compared with a control mixture with no incorporation of biochar in the mixture. It was possible to observe that the tests with the incorporation of biochars at 400 °C showed better results, with only a 24% reduction in resistance to compression.
    Materialart: Online-Ressource
    ISSN: 2076-3298
    Sprache: Englisch
    Verlag: MDPI AG
    Publikationsdatum: 2023
    ZDB Id: 2777960-9
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 6
    In: Applied Sciences, MDPI AG, Vol. 10, No. 13 ( 2020-07-02), p. 4601-
    Kurzfassung: The recovery of urban waste is a social demand and a measure of the energy-environmental sustainability of cities and regions. In particular, waste of electrical origin, waste of electrical and electronic materials (WEEE) can be recovered with great success. The plastic fraction of these wastes allows their gasification mixed with biomass, and the results allow for producing syngas with a higher energy potential. This work allows for obtaining energy from the recovery of obsolete materials through thermochemical conversion processes of the plastic waste from the disassembly of the luminaires by mixing the said plastic waste in different proportions with the biomass of crop residues (olive). The gasification tests of these mixtures were carried out in a downstream fixed-bed drown daft reactor, at temperatures of approximately 800 °C. The results demonstrate the applied technical and economic feasibility of the technology by thermal gasification, for the production of LHV (Low Heating Value) syngas with highest power energy (more than 5 MJ/m3) produced in mixtures of up to 20% of plastic waste. This study was complemented with the economic-financial analysis. This research can be used as a case study for the energy recovery through gasification processes of plastic waste from luminaires (WEEE), mixed with agricultural biomass that is planned to be carried out on a large scale in the Alentejo (Portugal), as a solution applied in circular economy strategies.
    Materialart: Online-Ressource
    ISSN: 2076-3417
    Sprache: Englisch
    Verlag: MDPI AG
    Publikationsdatum: 2020
    ZDB Id: 2704225-X
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 7
    In: C, MDPI AG, Vol. 9, No. 2 ( 2023-05-09), p. 49-
    Kurzfassung: Waste insulation electrical cables (WIEC) currently do not have an added value, due to their physical–chemical characteristics. Carbonization is known to enhance feedstock properties, particularly fuel and material properties; as such, this article aimed to study the production and activation of biochars using WIEC and lignocellulosic biomass wastes as feedstock. Biochars were produced in a ceramic kiln with an average capacity of 15 kg at different temperatures, namely 300, 350 and 400 °C. After production, the biochars were further submitted to a washing process with water heated to 95 °C ± 5 °C and to an activation process with 2 N KOH. All biochars (after production, washing and activation) were characterized regarding an elemental analysis, thermogravimetric analysis, heating value, chlorine removal, ash content, apparent density and surface area. The main results showed that the increase in carbonization temperature from 300 to 400 °C caused the produced biochars to present a lower amount of oxygen and volatile matter, increased heating value, greater chlorine removal and increased ash content. Furthermore, the activation process increased the surface area of biochars as the production temperature increased. Overall, the carbonization of WIEC mixed with lignocellulosic wastes showed potential in enhancing these waste physical and chemical properties, with prospects to yield added-value products that activates biochar.
    Materialart: Online-Ressource
    ISSN: 2311-5629
    Sprache: Englisch
    Verlag: MDPI AG
    Publikationsdatum: 2023
    ZDB Id: 2813973-2
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 8
    Online-Ressource
    Online-Ressource
    Springer Science and Business Media LLC ; 2020
    In:  Waste and Biomass Valorization Vol. 11, No. 9 ( 2020-09), p. 4639-4647
    In: Waste and Biomass Valorization, Springer Science and Business Media LLC, Vol. 11, No. 9 ( 2020-09), p. 4639-4647
    Materialart: Online-Ressource
    ISSN: 1877-2641 , 1877-265X
    Sprache: Englisch
    Verlag: Springer Science and Business Media LLC
    Publikationsdatum: 2020
    ZDB Id: 2541900-6
    Standort Signatur Einschränkungen Verfügbarkeit
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