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  • 1
    In: Journal of geophysical research. C, Oceans, Hoboken, NJ : Wiley, 1978, 110(2005), 2169-9291
    In: volume:110
    In: year:2005
    In: extent:17
    Materialart: Online-Ressource
    Seiten: 17
    ISSN: 2169-9291
    Sprache: Englisch
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Publikationsdatum: 2014-12-08
    Beschreibung: In this study we first evaluate the small-scale spatial variability of particulate export, using a set of synoptic thorium-234 activity observations sampled within a one-degree radius. These data show significant variability of surface thorium activity on scales of the order of 100 km (∼270–550 dpm m−3). This patchiness of export potentially affects the robustness of point observations and our interpretation of them. Motivated by these observations we subsequently couple an explicit model of thorium-234 dynamics to a coupled physical–biogeochemical basin model capable of resolving these small-scales. The model supports the observations in displaying marked thorium variability on spatial scales of the order of 100 km and smaller, with highest values in the regions of large eddy kinetic energy and large primary productivity. The model is also used to quantify the impact of small-scale variability on export estimates. Our model shows that the primary source of error associated with the presence of small-scale spatial variability is related to the standard assumptions of steady state and non-steady state (〉40% during bloom condition). The non-steady state method can misinterpret variations due to patchiness in thorium activity as temporal changes and lead to errors larger than those introduced by the simpler steady state approach. We show that the non-steady state approach could improve the flux estimates in some cases if the sampling was conducted in a Lagrangian framework. Undersampling the spatial variability results in further bias (〉20%) that can be reduced when the sampling density is increased. Finally, errors due to the dynamical transport of thorium associated with small-scale structures are relatively low (〈20%) except in regions of high eddy kinetic energy.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Publikationsdatum: 2020-07-23
    Beschreibung: Eddy correlation measurements over the ocean give CO2 fluxes an order of magnitude or more larger than expected from mass balance measurements using radiocarbon and radon 222. In particular, Smith and Jones (1985) reported large upward and downward fluxes in a surf zone at supersaturations of 15% and attributed them to the equilibration of bubbles at elevated pressures. They argue that even on the open ocean such bubble injection may create steady state CO2 supersaturations and that inferences of fluxes based on air-sea pCO2 differences and radon exchange velocities must be made with caution. We defend the global average CO2 exchange rate determined by three independent radioisotopic means: prebomb radiocarbon inventories; global surveys of mixed layer radon deficits; and oceanic uptake of bomb-produced radiocarbon. We argue that laboratory and lake data do not lead one to expect fluxes as large as reported from the eddy correlation technique; that the radon method of determining exchange velocities is indeed useful for estimating CO2 fluxes; that supersaturations of CO2 due to bubble injection on the open ocean are negligible; that the hypothesis that Smith and Jones advance cannot account for the fluxes that they report; and that the pCO2 values reported by Smith and Jones are likely to be systematically much too high. The CO2 fluxes for the ocean measured to date by the micrometeorological method can be reconciled with neither the observed concentrations of radioisotopes of radon and carbon in the oceans nor the tracer experiments carried out in lakes and in wind/wave tunnels.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    facet.materialart.
    Unbekannt
    AGU (American Geophysical Union)
    In:  Journal of Geophysical Research: Oceans, 110 . C07S01.
    Publikationsdatum: 2018-04-18
    Beschreibung: Conducted in the northeast Atlantic Ocean (15°20′–21°20′W, 38°N–45°N), the Programme Océan Multidisciplinaire Méso Echelle (POMME) is a research project aimed at a better understanding of the biological production and the carbon budget of the region in relation to the formation mechanisms of the 11°–12°C mode water of the northeast Atlantic. With the help of two research vessels, several tens of floats and drifters, and nine moorings, the field experiment was carried out between autumn 2000 and autumn 2001, with a more intensive phase in the winter and early spring of 2001. The field experiment resolved small (several kilometers) to regional (several hundred kilometers) scales and daily to seasonal variability. A first analysis of the rich data set focused on the large-scale and the mesoscale variability. It shows that the distribution of water mass characteristics and biological activity is strongly influenced by the mesoscales in this supposedly quiet transition zone between the subtropical and subpolar gyres. The seasonal variability, however, presents an imprint of the large-scale structures with a clear north-south gradient in properties and budgets. This region is found on an annual average to be a sink of atmospheric CO2. Smaller scales, associated with fronts and filaments, were clearly observed in many fields (temperature, but also chlorophyll, oxygen, biogenic particles, etc.), with modeling studies suggesting that they play a significant role in subduction, ventilation, and transport of biogeochemical tracers in the POMME region.
    Materialart: Article , PeerReviewed
    Format: text
    Standort Signatur Einschränkungen Verfügbarkeit
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