ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary Reaction of E-1,4-poly(2-triethylsilyl-1,3-butadiene) (I) with m-chloroperbenzoic acid (MCPBA) yields E-1,4-poly(2,3-epoxy-2-triethylsilyl-1,3-butadiene) (II). Similar reaction of E-1,4-poly[2,3-bis(trimethylsilyl)-1,3-butadiene] (III) with MCPBA gives E-1,4-poly[2,3-epoxy-2,3-bis(trimethylsilyl)-1,3-butadiene] (IV). The product polymers have been characterized by 1H, 13C, and 29Si NMR, IR, GPC, TGA and elemental analysis. 13C and 29Si NMR permit Stereochemical analysis on the microstructures of II and IV.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00261977
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