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Addition of dichlorocarbene to cis-1,4-poly(2-trimethylsilylmethyl-1,3-butadiene)

Fluoride catalyzed elimination of trimethylchlorosilane from cis-1,4-poly(2,3-dichloromethylene-2-trimethylsilylmethyl-1,3-butadiene)

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Summary

Copolymers made up of 1,4-(2,3-dichloromethylene-2-trimethylsilylmethyl-1,3-butadiene) (I) and 1,5-(3-chloro-2-methylene-pent-3-ene) (II) units have been prepared by potassium fluoride elimination of trimethylchlorosilane from cis-1,4-poly(2.3-dichloromethylene-2-trimethylsilylmethyl-1,3-butadiene) (III). III was prepared by the addition of dichlorocarbene to 1,4-poly-(2-trimethylsilylmethyl-1,3-butadiene) (cis/trans = 9/1) (IV). Polymer III was characterized by 1h, 13C and 29Si NMR as well as by elemental analysis. The copolymer was characterized by 1H, 13C and 29Si NMR spectroscopy. The ratio of I and II units in the copolymer were determined by 1H NMR and elemental analysis.

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Authors and Affiliations

  1. K.B. and D.P. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA

    Wan Jiang, Yi-Xiang Ding & William P. Weber

Authors
  1. Wan Jiang
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  2. Yi-Xiang Ding
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  3. William P. Weber
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Jiang, W., Ding, YX. & Weber, W.P. Addition of dichlorocarbene to cis-1,4-poly(2-trimethylsilylmethyl-1,3-butadiene). Polymer Bulletin 21, 541–547 (1989). https://doi.org/10.1007/BF00271980

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  • DOI: https://doi.org/10.1007/BF00271980

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