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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2009. This is the author's version of the work. It is posted here by permission of Springer for personal use, not for redistribution. The definitive version was published in Contributions to Mineralogy and Petrology 159 (2010): 689-702, doi:10.1007/s00410-009-0448-8.
    Description: The Canary Island primitive basaltic magmas 31 are thought to be derived from a HIMU-type upwelling mantle containing isotopically depleted (NMORB) component and having interacted with an enriched (EM)-type component whose origin is still a subject of debate. We have studied the relationships between Ni, Mn and Ca concentrations in olivine phenocrysts (85.6-90.0 mol.% Fo, 1722-3915 ppm Ni, 1085-1552 ppm Mn, 1222-3002 ppm Ca) from the most primitive subaerial and ODP Leg 157 high-silica (picritic to olivine basaltic) lavas with their bulk rock Sr-Nd-Pb isotope compositions (87Sr/86Sr = 0.70315- 0.70331, 143Nd/144Nd = 0.51288-0.51292, 206Pb/204Pb = 19.55-19.93, 207Pb/204Pb = 15.60- 15.63, 208Pb/204Pb = 39.31-39.69). Our data point toward the presence of both a peridotitic and a pyroxenitic component in the magma source. Using the model [Sobolev et al. (2007) The amount of recycled crust in sources of mantle-derived melts. Science 316: 412-417] in which the reaction of Si-rich melts originated during partial melting of eclogite (a high pressure product of subducted oceanic crust) with ambient peridotitic mantle forms olivine-free reaction pyroxenite, we obtain an endmember composition for peridotite with 87Sr/86Sr = 0.70337, 143Nd/144Nd = 0.51291, 206Pb/204Pb = 19.36, 207Pb/204Pb = 15.61, 208Pb/204Pb = 39.07 (EM-type endmember) and pyroxenite with 87Sr/86Sr = 0.70309, 143Nd/144Nd = 0.51289, 206Pb/204Pb = 20.03, 207Pb/204Pb = 15.62, 208Pb/204Pb = 39.84 (HIMU-type endmember). Mixing of melts from these endmembers in proportions ranging from 70% peridotite and 30% pyroxenite to 28% peridotite and 72% pyroxenite can generate the compositions of the most primitive Gran Canaria shield stage lavas. Combining our results with those from the low silica rocks from the western Canary Islands [Gurenko et al. (2009) Enriched, HIMU-type peridotite and depleted recycled pyroxenite in the Canary plume: a mixed-up mantle. EPSL 277: 514-524], at least four distinct components are required. We propose that they are (1) HIMU-type pyroxenitic component (representing recycled ocean crust of intermediate age) from the plume center, (2) HIMU-type peridotitic component (ancient recycled ocean crust stirred into the ambient mantle) from the plume margin, (3) depleted, MORB-type pyroxenitic component (young recycled oceanic crust) in the upper mantle entrained by the plume, and (4) EM-type peridotitic component from the asthenosphere or lithosphere above the plume center.
    Description: This work was supported by the Wolfgang Paul Award of the Alexander von Humboldt Foundation (to AVS), the Max Planck Society, DFG grants SCHM 250/64, 82-1 and HA3097/2 (to HUS, KH and FH), the Russian Basic Research Foundation (grant 06-05-65234 to AVS) and the Russian Academy of Sciences.
    Keywords: Canary Islands ; Gran Canaria ; ODP Leg 157 ; Olivine ; Mantle plume ; Peridotite ; Pyroxenite ; Radiogenic isotopes ; Ocean crust ; Recycling
    Repository Name: Woods Hole Open Access Server
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  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © Elsevier B.V., 2009. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Earth and Planetary Science Letters 277 (2009): 514-524, doi:10.1016/j.epsl.2008.11.013.
    Description: The Earth’s mantle is chemically and isotopically heterogeneous, and a component of recycled oceanic crust is generally suspected in the convecting mantle [Hofmann and White, 1982. Mantle plumes from ancient oceanic crust. Earth Planet. Sci. Lett. 57, 421-436]. Indeed, the HIMU component (high μ = 238U/204Pb), one of four isotopically distinct end-members in the Earth’s mantle, is generally attributed to relatively old (≥1-2 Ga) recycled oceanic crust in the form of eclogite/pyroxenite, e.g. [Zindler and Hart, 1986. Chemical geodynamics. Ann. Rev. Earth Planet. Sci. 14, 493-571]. Although the presence of the recycled component is generally supported by element and isotopic data, little is known about its physical state at mantle depths. Here we show that the concentrations of Ni, Mn and Ca in olivine from the Canarian shield stage lavas, which can be used to asses the physical nature of the source material (peridotite versus olivine-free pyroxenite) [Sobolev et al., 2007. The amount of recycled crust in sources of mantle-derived melts. Science 316, 412-417], correlate strongly with bulk rock Sr, Nd and Pb isotopic ratios. The most important result following from our data is that the enriched, HIMU-type (having higher 206Pb/204Pb than generally found in the other mantle endmembers) signature of the Canarian hotspot magmas was not caused by a pyroxenite/eclogite constituent of the plume but appears to have been primarily hosted by peridotite. This implies that the old (older than ~1 Ga) ocean crust, which has more evolved radiogenic isotope compositions, was stirred into/reacted with the mantle so that there is not significant eclogite left, whereas younger recycled oceanic crust with depleted MORB isotopic signature (〈1 Ga) can be preserved as eclogite, which when melted can generate reaction pyroxenite.
    Description: This work was supported by Wolfgang Paul Award, Alexander von Humboldt Foundation, to AVS, the Max Planck Society, DFG grants SCHM 250/64 and 82-1, HA3097/2 to HUS, KH and FH, NSF Grant EAR-9105113 to KH, Russian Basic Research Foundation and Russian Academy of Sciences.
    Keywords: Canary Islands ; Mantle plume ; Pyroxenite ; Olivine ; Radiogenic isotopes
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Falloon, T., Hoernle, K., Schaefer, B., Bindeman, I., Hart, S., Garbe-Schonberg, D., & Duncan, R. Petrogenesis of lava from Christmas Island, Northeast Indian Ocean: implications for the nature of recycled components in non-plume intraplate settings. Geosciences, 12(3), (2022): 118, https://doi.org/10.3390/geosciences12030118.
    Description: Lava samples from the Christmas Island Seamount Province (CHRISP) record an extreme range in enriched mantle (EM) type Sr-Nd-Pb-Hf isotope signatures. Here we report osmium isotope data obtained on four samples from the youngest, Pliocene petit-spot phase (Upper Volcanic Series, UVS; ~4.4 Ma), and four samples from the earlier, Eocene (Lower Volcanic Series, LVS; ~40 Ma) shield building phase of Christmas Island. Osmium concentrations are low (5–82 ppt) with initial Os isotopic values (187Os/188Osi) ranging from (0.1230–0.1679). Along with additional new geochemical data (major and trace elements, Sr-Nd-Pb isotopes, olivine δ18O values), we demonstrate the following: (1) The UVS is consistent with melting of shallow Indian mid-ocean ridge basalt (MORB) mantle enriched with both lower continental crust (LCC) and subcontinental lithospheric mantle (SCLM) components; and (2) The LVS is consistent with recycling of SCLM components related to Gondwana break-up. The SCLM component has FOZO or HIMU like characteristics. One of the LVS samples has less radiogenic Os (γOs –3.4) and provides evidence for the presence of ancient SCLM in the source. The geochemistry of the Christmas Island lava series supports the idea that continental breakup causes shallow recycling of lithospheric and lower crustal components into the ambient MORB mantle.
    Description: This research received no external funding.
    Keywords: Osmium isotopes ; Petit-spot volcanism ; Olivine oxygen isotopes ; Intraplate volcanism ; Christmas Island ; Indian Ocean ; CHRISP ; Crust recycling ; Lithosphere recycling ; DUPAL
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Bekaert, D. V., Gazel, E., Turner, S., Behn, M. D., de Moor, J. M., Zahirovic, S., Manea, V. C., Hoernle, K., Fischer, T. P., Hammerstrom, A., Seltzer, A. M., Kulongoski, J. T., Patel, B. S., Schrenk, M. O., Halldórsson, S. A., Nakagawa, M., Ramírez, C. J., Krantz, J. A., Yücel, M., Ballentine, C. J., Giovannelli, D., Lloyd, K. G., Barry, P. H. High (3)He/(4)He in central Panama reveals a distal connection to the Galápagos plume. Proceedings of the National Academy of Sciences of the United States of America, 118(47), (2021): e2110997118, https://doi.org/10.1073/pnas.2110997118.
    Description: It is well established that mantle plumes are the main conduits for upwelling geochemically enriched material from Earth's deep interior. The fashion and extent to which lateral flow processes at shallow depths may disperse enriched mantle material far (〉1,000 km) from vertical plume conduits, however, remain poorly constrained. Here, we report He and C isotope data from 65 hydrothermal fluids from the southern Central America Margin (CAM) which reveal strikingly high 3He/4He (up to 8.9RA) in low-temperature (≤50 °C) geothermal springs of central Panama that are not associated with active volcanism. Following radiogenic correction, these data imply a mantle source 3He/4He 〉10.3RA (and potentially up to 26RA, similar to Galápagos hotspot lavas) markedly greater than the upper mantle range (8 ± 1RA). Lava geochemistry (Pb isotopes, Nb/U, and Ce/Pb) and geophysical constraints show that high 3He/4He values in central Panama are likely derived from the infiltration of a Galápagos plume–like mantle through a slab window that opened ∼8 Mya. Two potential transport mechanisms can explain the connection between the Galápagos plume and the slab window: 1) sublithospheric transport of Galápagos plume material channeled by lithosphere thinning along the Panama Fracture Zone or 2) active upwelling of Galápagos plume material blown by a “mantle wind” toward the CAM. We present a model of global mantle flow that supports the second mechanism, whereby most of the eastward transport of Galápagos plume material occurs in the shallow asthenosphere. These findings underscore the potential for lateral mantle flow to transport mantle geochemical heterogeneities thousands of kilometers away from plume conduits.
    Description: This work was principally supported by Grant G-2016-7206 from the Alfred P. Sloan Foundation and the Deep Carbon Observatory to P.H.B. We also acknowledge the NSF awards (1144559, 1923915, and 2015789) to P.H.B., which partially supported this work. S.Z. was supported by the Australian Research Council Grant DE210100084 and a University of Sydney Robinson Fellowship. D.G. was partially supported by funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation program Grant Agreement No. 948972—COEVOLVE—ERC-2020-STG. This study was also supported in part by NSF award No. EAR 1826673 to E.G. Folkmar Hauff is acknowledged for contributing to the analysis of the La Providencia samples at GEOMAR.
    Keywords: Helium ; Mantle plume ; Slab window ; Mantle flow ; Geochemistry
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2017-09-12
    Description: The Madeira and Canary island/seamount chains represent two adjacent hotspot tracks in the eastern North Atlantic, which were derived from mixed peridotite–pyroxenite mantle sources. They possess systematically different Sr–Nd–Pb, Os and Hf isotope signatures, implying mixing of DMM-, HIMU- and EM-type components from different mantle lithologies. The lithological nature of these postulated mantle endmembers (e.g., if formed by peridotite, pyroxenite and/or eclogite) is still a subject of debate. We studied the chemical composition of olivine phenocrysts (focusing on their Ni, Mn and Ca concentrations) from the lavas covering the entire volcanic history of the Madeira Archipelago (~0–5 Ma). We demonstrate that Ni × FeO/MgO and Mn/FeO ratios and Ca-concentrations of olivine correlate with Sr, Nd and Pb isotopic compositions of their host lavas. The amounts of peridotite- and pyroxenite-derived melt fractions in the parental Madeira magmas were inferred from olivine compositions and independently confirmed by modeling of two-component sourcemelting using trace elements. Our calculations demonstrate that theamount of recycled crust (=eclogite) in the Madeira magma source varies but does not exceed ~10%. Strong linear relationships between chemical composition of olivine and radiogenic isotopes of the host lavas allow us to determine the isotopic composition of peridotite and pyroxenite endmembers of the Madeira hotspot. The peridotite endmember has a highly depleted isotopic composition 87Sr/86Sr = 0.7022–0.7026, 143Nd/144Nd = 0.5132–0.5135, 206Pb/ 204Pb = 17.4–18.6, 207Pb/204Pb = 15.4–15.49, and 208Pb/204Pb = 36.8–38.2, whereas the pyroxenite endmember has an enriched composition 87Sr/86Sr = 0.7031–0.7035, 143Nd/144Nd = 0.5127–0.5130, 206Pb/204Pb = 19.9–21.3, 207Pb/204Pb = 15.59–15.69, and 208Pb/204Pb = 39.6–41.2. Our new data confirm the existence of recycled (pyroxenitic) lithology in the Madeira magma source that was previously interpreted to represent relatively young (b1 Ga) recycled oceanic crust. The isotopically depleted, DMM-like (peridotitic) component sampled by the younger post-erosional stage magmas is thought to reflect the ultramafic portion of the recycled oceanic lithosphere,whereas the HIMU-type pyroxenite of similar age to the peridotite is derived from recycled oceanic crust. Combining our newresultswith the data from the Canary hotspot, we conclude that the b1 Ga recycled crustal component is common to both plume sources. The Canary volcanismalso reflects the presence of older (〉1 Ga) recycled crust and a contribution from African subcontinental lithosphere.
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  • 6
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    Elsevier
    In:  Journal of Volcanology and Geothermal Research, 94 (1-4). pp. 267-282.
    Publication Date: 2017-07-20
    Description: The compositionally zoned San Juan eruption on La Palma emanated from three eruptive centers located along a north–south-trending rift zone in the south of the island. Seismic precursors began weakly in 1936 and became strong in March 1949, with their foci progressing from the north of the rift zone towards its south. This suggests that magma ascended beneath the old Taburiente shield volcano and moved southward along the rift. The eruption began on June 24, 1949, with phreatomagmatic activity at Duraznero crater on the ridgetop (ca. 1880 m above sea level), where five vents erupted tephritic lava along a 400-m-long fissure. On June 8, the Duraznero vents shut down abruptly, and the activity shifted to an off-rift fissure at Llano del Banco, located at ca. 550 m lower elevation and 3 km to the northwest. This eruptive center issued initially tephritic aa and later basanitic pahoehoe lava at high rates, producing a lava flow that entered the sea. Two days after basanite began to erupt at Llano del Banco, Hoyo Negro crater (ca. 1880 m asl), located 700 m north of Duraznero along the rift, opened on July 12 and produced ash and bombs of basanitic to phonotephritic composition in violent phreatomagmatic explosions (White and Schmincke, 1999). Llano del Banco and Hoyo Negro were simultaneously active for 11 days and showed a co-variance of their eruption rates indicating a shallow hydraulic connection. On July 30, after 3 days of quiescence at all vents, Duraznero and Hoyo Negro became active again during a final eruptive phase. Duraznero issued basanitic lava at high rates for 12 h and produced a lava flow that descended towards the east coast. The lava contains ca. 1 vol.% crustal and mantle xenoliths consisting of 40% tholeiitic gabbros from the oceanic crust, 35% alkaline gabbros, and 20% ultramafic cumulates. The occurrence of xenoliths almost exclusively in the final lava is consistent with their origin by wall-rock collapse at depth near the end of the eruption. The volcanic evolution of the 1949 eruption is typical of La Palma eruptions generally. Considerable shallow magma migration prior to and during eruption is manifested by strong seismicity, intense faulting, and the almost unpredictable opening of specific vents which can be spaced three or more km apart.
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  • 7
    Publication Date: 2019-09-23
    Description: Crustal assimilation (e.g. Hildreth and Moorbath, 1988) and/or subduction erosion (e.g. Stern, 1991; Kay et al., 2005) are believed to control the geochemical variations along the northern portion of the Chilean Southern Volcanic Zone. In order to evaluate these hypotheses, we present a comprehensive geochemical data set (major and trace elements and O-Sr-Nd-Hf-Pb isotopes) from Holocene primarily olivine-bearing volcanic rocks across the arc between 34.5-38.0°S, including volcanic front centers from Tinguiririca to Callaqui, the rear arc centers of Infernillo Volcanic Field, Laguna del Maule and Copahue, and extending 300 km into the backarc. We also present an equivalent data set for Chile Trench sediments outboard of this profile. The volcanic arc (including volcanic front and rear arc) samples primarily range from basalt to andesite/trachyandesite, whereas the backarc rocks are low-silica alkali basalts and trachybasalts. All samples show some characteristic subduction zone trace element enrichments and depletions, but the backarc samples show the least. Backarc basalts have higher Ce/Pb, Nb/U, Nb/Zr, and Ta/Hf, and lower Ba/Nb and Ba/La, consistent with less of a slab-derived component in the backarc and, consequently, lower degrees of mantle melting. The mantle-like δ18O in olivine and plagioclase phenocrysts (volcanic arc = 4.9-5.6 and backarc = 5.0-5.4 per mil) and lack of correlation between δ18O and indices of differentiation and other isotope ratios, argue against significant crustal assimilation. Volcanic arc and backarc samples almost completely overlap in Sr and Nd isotopic composition. High precision (double-spike) Pb isotope ratios are tightly correlated, precluding significant assimilation of older sialic crust but indicating mixing between a South Atlantic Mid Ocean-Ridge Basalt (MORB) source and a slab component derived from subducted sediments and altered oceanic crust. Hf-Nd isotope ratios define separate linear arrays for the volcanic arc and backarc, neither of which trend toward subducting sediment, possibly reflecting a primarily asthenospheric mantle array for the volcanic arc and involvement of enriched Proterozoic lithospheric mantle in the backarc. We propose a quantitative mixing model between a mixed-source, slab-derived melt and a heterogeneous mantle beneath the volcanic arc. The model is consistent with local geodynamic parameters, assuming water-saturated conditions within the slab.
    Type: Article , PeerReviewed
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  • 8
    Publication Date: 2017-10-11
    Description: Osmium concentrations and isotopic signatures were measured in 28 primarily Holocene basalts (22 of which have been analyzed for Sr–Nd–Pb isotope composition), two carbonatites and two mantle xenoliths from the Canary Islands, Selvagen Grande and Madeira in the eastern North Atlantic. 187Os/188Os ratios in the basalts range from 0.129 to 0.183. The Os isotope systematics indicate that the basalts fall into three petrogenetic groups: (1) a ‘radiogenic’ group with high 187Os/188Os from 0.152 to 0.183; (2) an ‘unradiogenic’ group with low 187Os/188Os from 0.129 to 0.138; (3) an ‘intermediate’ group with 187Os/188Os between 0.139 and 0.151. The Os isotope systematics of the radiogenic group samples are consistent with minor contamination of the basalts by marine sediment. All samples in the unradiogenic group contain mantle xenoliths, and the unradiogenic Os can be explained by bulk assimilation of ≤ 5% mantle peridotite in the form of disaggregated xenoliths. The radiogenic and unradiogenic groups are also characterized by higher 87Sr/86Sr and 208Pb/204Pb but lower 143Nd/144Nd than samples with similar 206Pb/204Pb from the intermediate group, which is interpreted to reflect interaction of plume magmas with the lithospheric mantle. The intermediate group samples are believed to represent the isotopic signature of the mantle plume. The Os isotopic composition of the Canary plume is among the most radiogenic found in ocean island basalts, comparable with the endmember HIMU islands Mangaia and Tubuaii, but at significantly lower 206Pb/204Pb. The radiogenic Os and moderate 206Pb/204Pb signature of the Canary plume is consistent with a plume which contains 25–35% of relatively young (∼1.2 Ga) recycled oceanic crust. Variable degree of mixing of the Canary Island plume source with shallow depleted asthenosphere containing a component of Paleozoic oceanic crust produces the limited range in Os isotopic signatures observed in the Madeira and Canary Island basalts despite a large range in 206Pb/204Pb isotopic composition.
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  • 9
    Publication Date: 2019-01-10
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 10
    Publication Date: 2019-01-11
    Type: Conference or Workshop Item , NonPeerReviewed
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