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  • 1
    Keywords: Hochschulschrift
    Type of Medium: Online Resource
    Pages: 1 Online-Ressource (xiv, 206 Seiten) , Illustrationen, Diagramme, Karten
    DDC: 550
    Language: English
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  • 2
    Keywords: Forschungsbericht ; Stadt ; Klima ; Modell
    Type of Medium: Online Resource
    Pages: 1 Online-Ressource (27 Seiten, 3,74 MB) , Illustrationen, Diagramme
    Language: German
    Note: Förderkennzeichen BMBF 01LP1602P , Verbundnummer 01170829 , Unterschiede zwischen dem gedruckten Dokument und der elektronischen Ressource können nicht ausgeschlossen werden
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  • 3
    Publication Date: 2021-07-21
    Description: The densely farmed U.S. Midwest is a prominent source of nitrous oxide (N2O) but top‐down and bottom‐up N2O emission estimates differ significantly. We quantify Midwest N2O emissions by combining observations from the Atmospheric Carbon and Transport‐America campaign with model simulations to scale the Emissions Database for Global Atmospheric Research (EDGAR). In October 2017, we scaled agricultural EDGAR v4.3.2 and v5.0 emissions by factors of 6.3 and 3.5, respectively, resulting in 0.42 nmol m−2 s−1 Midwest N2O emissions. In June/July 2019, a period when extreme flooding was occurring in the Midwest, agricultural scaling factors were 11.4 (v4.3.2) and 9.9 (v5.0), resulting in 1.06 nmol m−2 s−1 Midwest emissions. Uncertainties are on the order of 50 %. Agricultural emissions estimated with the process‐based model DayCent (Daily version of the CENTURY ecosystem model) were larger than in EDGAR but still substantially smaller than our estimates. The complexity of N2O emissions demands further studies to fully characterize Midwest emissions.
    Description: Plain Language Summary: Nitrous oxide (N2O) is the third most important anthropogenic greenhouse gas contributing to the warming of the planet and the dominant man‐made ozone‐depleting substance in the stratosphere. Its atmospheric concentrations have been rising since industrialization mainly due to an increase in anthropogenic sources, with agriculture being the dominant source. The densely farmed U.S. Midwest plays an important role in the global N2O budget. However, previous studies that have collected observations of N2O indicate that estimates of surface emissions in the Midwest are substantially underestimating the truth. In this study, we combine unique aircraft‐based N2O measurements and model simulations to quantify Midwest emissions in October 2017 and June/July 2019. Agricultural inventory estimates had to be increased by factors up to 20 to match observations, revealing a large underestimation in current inventories. An extreme flooding event in 2019 when the summer observations occurred may be responsible for some of this discrepancy. Estimations of soil N2O emissions calculated with a state‐of‐the‐art biogeochemical model show less underestimation but are still too low compared to the fluxes derived from the aircraft observational data.
    Description: Key Points: Within the ACT‐America project, we gathered a unique airborne in‐situ N2O data set over the U.S. Midwest with enhancements up to 9  ppb. N2O emissions in the U.S. Midwest were on average 0.42 ± 0.28 nmol m−2 s−1 in October 2017 and 1.06 ± 0.57 nmol m−2 s−1 in June to July 2019. Bottom‐up estimates from EDGAR and DayCent underestimate U.S. Midwest N2O emissions by factors up to 20.
    Keywords: agriculture ; climate change ; flux estimate ; Midwest ; nitrous oxide ; top‐down
    Type: article
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  • 4
    Publication Date: 2023-01-31
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 5
    Publication Date: 2023-01-31
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 6
    Publication Date: 2021-03-19
    Description: During the summer monsoon, the western tropical Indian Ocean is predicted to be a hot spot for dimethylsulfide emissions, the major marine sulfur source to the atmosphere, and an important aerosol precursor. Other aerosol relevant fluxes, such as isoprene and sea spray, should also be enhanced, due to the steady strong winds during the monsoon. Marine air masses dominate the area during the summer monsoon, excluding the influence of continentally derived pollutants. During the SO234-2/235 cruise in the western tropical Indian Ocean from July to August 2014, directly measured eddy covariance DMS fluxes confirm that the area is a large source of sulfur to the atmosphere (cruise average 9.1 μmol m−2 d−1). The directly measured fluxes, as well as computed isoprene and sea spray fluxes, were combined with FLEXPART backward and forward trajectories to track the emissions in space and time. The fluxes show a significant positive correlation with aerosol data from the Terra and Suomi-NPP satellites, indicating a local influence of marine emissions on atmospheric aerosol numbers.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 7
    Publication Date: 2021-02-08
    Description: Oceanic very short-lived substances (VSLSs), such as bromoform (CHBr3), contribute to stratospheric halogen loading and, thus, to ozone depletion. However, the amount, timing, and region of bromine delivery to the stratosphere through one of the main entrance gates, the Indian summer monsoon circulation, are still uncertain. In this study, we created two bromoform emission inventories with monthly resolution for the tropical Indian Ocean and west Pacific based on new in situ bromoform measurements and novel ocean biogeochemistry modeling. The mass transport and atmospheric mixing ratios of bromoform were modeled for the year 2014 with the particle dispersion model FLEXPART driven by ERA-Interim reanalysis. We compare results between two emission scenarios: (1) monthly averaged and (2) annually averaged emissions. Both simulations reproduce the atmospheric distribution of bromoform from ship- and aircraft-based observations in the boundary layer and upper troposphere above the Indian Ocean reasonably well. Using monthly resolved emissions, the main oceanic source regions for the stratosphere include the Arabian Sea and Bay of Bengal in boreal summer and the tropical west Pacific Ocean in boreal winter. The main stratospheric injection in boreal summer occurs over the southern tip of India associated with the high local oceanic sources and strong convection of the summer monsoon. In boreal winter more bromoform is entrained over the west Pacific than over the Indian Ocean. The annually averaged stratospheric injection of bromoform is in the same range whether using monthly averaged or annually averaged emissions in our Lagrangian calculations. However, monthly averaged emissions result in the highest mixing ratios within the Asian monsoon anticyclone in boreal summer and above the central Indian Ocean in boreal winter, while annually averaged emissions display a maximum above the west Indian Ocean in boreal spring. In the Asian summer monsoon anticyclone bromoform atmospheric mixing ratios vary by up to 50% between using monthly averaged and annually averaged oceanic emissions. Our results underline that the seasonal and regional stratospheric bromine injection from the tropical Indian Ocean and west Pacific critically depend on the seasonality and spatial distribution of the VSLS emissions.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 8
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    AGU (American Geophysical Union) | Wiley
    In:  Journal of Geophysical Research: Atmospheres, 123 (10). pp. 5720-5738.
    Publication Date: 2021-02-08
    Description: Halogen- and sulfur-containing compounds are supersaturated in the surface ocean, which results in their emission to the atmosphere. These compounds can be transported to the stratosphere, where they impact ozone, the background aerosol layer, and climate. In this study we calculate the seasonal and interannual variability of transport from the West Indian Ocean (WIO) surface to the stratosphere for 2000-2016 with the Lagrangian transport model FLEXPART using ERA-Interim meteorological fields. We investigate the transport relevant for very short lived substances (VSLS) with tropospheric lifetimes corresponding to dimethylsulfide (1 day), methyl iodide (CH3I, 3.5 days), bromoform (CHBr3, 17 days), and dibromomethane (CH2Br2, 150 days). The stratospheric source gas injection of VSLS tracers from the WIO shows a distinct annual cycle associated with the Asian monsoon. Over the 16-year time series, a slight increase in source gas injection from the WIO to the stratosphere is found for all VSLS tracers and during all seasons. The interannual variability shows a relationship with sea surface temperatures in the WIO as well as the El Niño-Southern Oscillation. During boreal spring of El Niño, enhanced stratospheric injection of VSLS from the tropical WIO is caused by positive sea surface temperature anomalies and enhanced vertical uplift above the WIO. During boreal fall of La Niña, strong injection is related to enhanced atmospheric upward motion over the East Indian Ocean and a prolonged Indian summer monsoon season. Related physical mechanisms and uncertainties are discussed in this study
    Type: Article , PeerReviewed
    Format: text
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  • 9
    Publication Date: 2019-09-23
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 10
    Publication Date: 2019-09-23
    Description: Halogenated organic compounds are naturally produced in the ocean and emitted to the atmosphere. The halogenated very short-lived substances (VSLS), such as bromoform, have atmospheric lifetimes of less than half a year. When VSLS reach the stratosphere, they enhance ozone depletion and thus impact the climate. During boreal summer, the Asian monsoon circulation transfers air masses from the Asian troposphere to the global stratosphere. Still, the extent to which VSLS from the Indian Ocean contribute to the stratospheric halogen burden and their exact origin is unclear. Here we show that the monsoon circulation transports VSLS from the Indian Ocean to the stratosphere. During the research cruises SO234-2 and SO235 in July-August 2014 onboard RV SONNE, we measured oceanic and atmospheric concentrations of bromoform (tropical lifetime at 10 km = 17 days), dibromomethane (150 days) and methyl iodide (3.5 days) in the subtropical and tropical West Indian Ocean and calculated their emission strengths. We use the Langrangian transport model FLEXPART driven by ERA-Interim meteorological fields to investigate the transport of oceanic emissions in the atmosphere. We analyze the direct contribution of observed bromoform emissions to the stratospheric halogen budget with forward trajectories. Furthermore, we investigate the connection between the Asian monsoon anticyclone and the oceanic source regions using backward trajectories. The West Indian Ocean is a strong source region of VSLS to the atmosphere and the monsoon transport is fast enough for bromoform to reach the stratosphere. However, the main source regions for the entrainment of oceanic air masses through the Asian monsoon anticyclone are the West Pacific and Bay of Bengal as well as the Arabian Sea. Our findings indicate that changes in emission or circulation in this area due to climate change can directly affect the stratospheric halogen burden and thus the ozone layer.
    Type: Conference or Workshop Item , NonPeerReviewed
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