Publication Date:
2022-05-25
Description:
Author Posting. © The Author(s), 2009. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Earth and Planetary Science Letters 288 (2009): 149-1157, doi:10.1016/j.epsl.2009.09.017.
Description:
The silica-undersaturated Nyiragongo volcanics, located in the East African rift, have
globally unique chemical compositions and unusually low viscosities, only higher than
carbonatite lavas, for terrestrial silicate magmas. We report 238U-230Th-226Ra-210Pb series
disequilibria in 13 recent and prehistoric lava samples from Nyiragongo including those
from the 2002 flank eruption and a 2003 lava lake sample. (230Th/238U) ranges from 0.90-
0.97 in the recent lavas and from 0.94-1.09 in the prehistoric lavas. To explain the variable
230Th and 238U excesses in these lavas, we hypothesize that different processes with
opposite effects in terms of fractionating Th/U in the mantle source are involved. These
processes include: 1) low degree partial melting of a phlogopite-bearing mantle source
(consistent with low K/Rb) with residual garnet (consistent with high chondrite-normalized
Dy/Yb), to produce the observed 230Th excesses; and, 2) carbonate metasomatism for the
238U enrichment, consistent with high Zr/Hf in the Nyiragongo lavas.
The Nyiragongo volcanics have higher (230Th/232Th) values than observed in most
mantle-derived rocks, especially ocean-island basalts, suggesting that their mantle-source
was affected by carbonate metasomatism less than 300 ka ago. Several Nyiragongo
samples display significant 226Ra excesses implying rapid magma transport (less than 8 ka)
from the mantle-source to the surface. Modeling the observed (226Ra/230Th) versus Zr/Hf
correlation in the lavas indicates that the 2002, 2003 and a few pre-historic lavas
incorporated 50-60% of a carbonate-metasomatized mantle source while the other prehistoric lavas show 10-22% contribution of this source. This result indicates that the
Nyiragongo lavas were derived from a heterogeneous, non-uniformly carbonated mantle
source. The 2002 lava shows (210Pb/226Ra) equilibrium, whereas the 2003 lava lake sample
shows initial (210Pb/226Ra) 〈 1. The latter observation suggests that Nyiragongo magmas
degas as they rise to the surface over years or decades before eruption. (210Pb/226Ra)
equilibrium in the 2002 lava suggests that the 2002 magma may have stagnated for more
than a decade before eruption. The high CO2 content, high emission rates, extreme fluidity,
along with the inferred short residence time and our inferences of rapid magma transport
and high eruptive frequency suggest that the volcanic hazards of Nyiragongo, both from
lava flows and gas emissions, are higher than previously estimated.
Description:
Lava samples were collected as a part of a field work in Nyiragongo, supported by UN-OCHA grants.
The field team included Paolo Papale, Alba Santo, Dario Tedesco and Orlando Vaselli
with support from the staff of Goma Volcanological Observatory, D. R. Congo. The 2003
lava lake sample was collected by Jacques Durieux. Funding for U-series analyses was
covered by NSF-EAR 063824101 and NSF-EAR 083887800 to KWWS. 210Po analyses
were funded with EAR0738776 to MR. Sample preparation and dissolution was covered
by NSF-EAR 0732679 to ARB. RC acknowledges guest student award from WHOI.
Keywords:
Silica-undersaturated volcanism
;
U-238-Th-230-Ra-226-Pb-210 series disequilibria
;
Magma transport and residence time
;
Carbonate metasomatism
;
Volcanic hazard assessment.
Repository Name:
Woods Hole Open Access Server
Type:
Preprint
Format:
application/pdf
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