Description: Highlights: • Multi-centennial oscillation with 100–200 years periods is evident in proxy data and model simulations during the Holocene. • Multi-centennial oscillation is a global signal and is more significant in the Northern Hemisphere high latitudes. • None of the external forcings is found to be the sole driver of the multi-centennial variability. • It indicates the multi-centennial oscillation may be due to potential internal drivers and essential feedbacks. Abstract: Variability on centennial to multi-centennial timescales is mentioned as a feature in reconstructions of the Holocene climate. As more long transient model simulations with complex climate models become available and efforts have been made to compile large proxy databases, there is now a unique opportunity to study multi-centennial variability with greater detail and a large amount of data than earlier. This paper presents a spectral analysis of transient Holocene simulations from 9 models and 120 proxy records to find the common signals related to oscillation periods and geographic dependencies and discuss the implications for the potential driving mechanisms. Multi-centennial variability is significant in most proxy records, with the dominant oscillation periods around 120–130 years and an average of 240 years. Spectra of model-based global mean temperature (GMT) agree well with proxy evidence with significant multi-centennial variability in all simulations with the dominant oscillation periods around 120–150 years. It indicates a comparatively good agreement between model and proxy data. A lack of latitudinal dependencies in terms of oscillation period is found in both the model and proxy data. However, all model simulations have the highest spectral density distributed over the Northern hemisphere high latitudes, which could indicate a particular variability sensitivity or potential driving mechanisms in this region. Five models also have differentiated forcings simulations with various combinations of forcing agents. Significant multi-centennial variability with oscillation periods between 100 and 200 years is found in all forcing scenarios, including those with only orbital forcing. The different forcings induce some variability in the system. Yet, none appear to be the predominant driver based on the spectral analysis. Solar irradiance has long been hypothesized to be a primary driver of multi-centennial variability. However, all the simulations without this forcing have shown significant multi-centennial variability. The results then indicate that internal mechanisms operate on multi-centennial timescales, and the North Atlantic-Arctic is a region of interest for this aspect.

Description: The defiltration performance of the zeolite ZSM-5/liquid system can be effectively modified by sodium hydroxide (NaOH) additive with various concentrations. The infiltration of NaOH aqueous solutions increases the density of silanol (Si-OH) groups on inner surface of the porous ZSM-5, converting the originally hydrophobic surface to hydrophilic and ceasing the liquid outflow. More importantly, the defiltration performance of the system can be adjusted independently without affecting the working pressure of the system. This unique infiltration associated hydrophobic-hydrophilic transition of nanopore surface leads the ZSM-5 based liquid system to an efficient energy absorption system instead of a super-elastic molecular spring.

Description: IJERPH, Vol. 14, Pages 1474: Effect of CaO on NOx Reduction by Selective Non-Catalytic Reduction under Variable Gas Compositions in a Simulated Cement Precalciner Atmosphere International Journal of Environmental Research and Public Health doi: 10.3390/ijerph14121474 Authors: Ye Sun Weiyi Fan Tianle Zhu Xiaowei Hong High-concentration CaO particles and gas compositions have a significant influence on NOx reduction by selective non-catalytic reduction (SNCR) in cement precalciners. The effect of gas composition on NOx reduction by SNCR with NH3 was studied in a cement precalciner atmosphere with and without CaO at 700–1100 °C. It was found that CaO significantly lowers NOx reduction efficiency between 750 °C and 1000 °C, which is attributed to the catalytic oxidation of NH3 to NO. Although increasing NH3 concentration was advantageous to NOx reduction, the existence of CaO led to the opposite result at 750–900 °C. Adding H2O can suppress the negative effect of CaO on NOx reduction. Decreasing O2 content from 10% to 1% shifts the temperature range in which CaO has a significant effect from 750–1000 °C to 800–1050 °C. CO has a variety of influences on the CaO effect under different experimental conditions. The influences of NH3, H2O, O2, and CO on the effect of CaO can be attributed to the impacts of the gas compositions on gas-phase NH3 conversion, gas-solid catalytic NH3 oxidation, or both processes. A proposed pathway for the effect of gas compositions on NOx reduction in CaO-containing SNCR process was developed that well predicted the CaO-containing SNCR process.