Description: This data set contains model values from 4 simulations produced with the isotope-enabled atmosphere GCMs ECHAM5-wiso and ECHAM6-wiso for the period 1979-2018. These simulations been performed at different spatial resolutions (T63 and T127) or with different reanalyses for the nudging (ERA5 and ERA-Interim). A complete description can be found in Cauquoin and Werner (J. Adv. Model. Earth Syst., 2021).

Description: Using new high-resolution 10Be measurements in the NGRIP, EDML and Vostok ice cores, together with previously published data from EDC, we present an improved synchronization between Greenland and Antarctic ice cores during the Laschamp geomagnetic excursion  ∼ 41kyr ago. We estimate the precision of this synchronization to be ±20 years, an order of magnitude better than previous work. We discuss the implications of this new synchronization for making improved estimates of the depth difference between ice and enclosed gas of the same age (Δdepth), difference between age of ice and enclosed gas at the same depth (Δage) in the EDC and EDML ice cores, spectral properties of the 10Be profiles and phasing between Dansgaard–Oeschger-10 (in NGRIP) and AIM-10 (in EDML and EDC).

Description: We present here the first results, for the preindustrial and mid-Holocene climatological periods, of the newly developed isotope-enhanced version of the fully coupled Earth system model MPI-ESM, called hereafter MPI-ESM-wiso. The water stable isotopes H162O, H182O and HDO have been implemented into all components of the coupled model setup. The mid-Holocene provides the opportunity to evaluate the model response to changes in the seasonal and latitudinal distribution of insolation induced by different orbital forcing conditions. The results of our equilibrium simulations allow us to evaluate the performance of the isotopic model in simulating the spatial and temporal variations of water isotopes in the different compartments of the hydrological system for warm climates. For the preindustrial climate, MPI-ESM-wiso reproduces very well the observed spatial distribution of the isotopic content in precipitation linked to the spatial variations in temperature and precipitation rate. We also find a good model–data agreement with the observed distribution of isotopic composition in surface seawater but a bias with the presence of surface seawater that is too 18O-depleted in the Arctic Ocean. All these results are improved compared to the previous model version ECHAM5/MPIOM. The spatial relationships of water isotopic composition with temperature, precipitation rate and salinity are consistent with observational data. For the preindustrial climate, the interannual relationships of water isotopes with temperature and salinity are globally lower than the spatial ones, consistent with previous studies. Simulated results under mid-Holocene conditions are in fair agreement with the isotopic measurements from ice cores and continental speleothems. MPI-ESM-wiso simulates a decrease in the isotopic composition of precipitation from North Africa to the Tibetan Plateau via India due to the enhanced monsoons during the mid-Holocene. Over Greenland, our simulation indicates a higher isotopic composition of precipitation linked to higher summer temperature and a reduction in sea ice, shown by positive isotope–temperature gradient. For the Antarctic continent, the model simulates lower isotopic values over the East Antarctic plateau, linked to the lower temperatures during the mid-Holocene period, while similar or higher isotopic values are modeled over the rest of the continent. While variations of isotopic contents in precipitation over West Antarctica between mid-Holocene and preindustrial periods are partly controlled by changes in temperature, the transport of relatively 18O-rich water vapor near the coast to the western ice core sites could play a role in the final isotopic composition. So, more caution has to be taken about the reconstruction of past temperature variations during warm periods over this area. The coupling of such a model with an ice sheet model or the use of a zoomed grid centered on this region could help to better describe the role of the water vapor transport and sea ice around West Antarctica. The reconstruction of past salinity through isotopic content in sea surface waters can be complicated for regions with strong ocean dynamics, variations in sea ice regimes or significant changes in freshwater budget, giving an extremely variable relationship between the isotopic content and salinity of ocean surface waters over small spatial scales. These complicating factors demonstrate the complexity of interpreting water isotopes as past climate signals of warm periods like the mid-Holocene. A systematic isotope model intercomparison study for further insights on the model dependency of these results would be beneficial.

Description: All types of applications of stable water isotopes, for example, for the reconstruction of paleotemperatures or for climate model validation, rely on a proper understanding of the mechanisms determining the isotopic composition of water vapor and precipitation. In this study, we use the isotope‐enabled limited‐area model COSMOiso to characterize the impacts of continental evapotranspiration, rainout, and subcloud processes on δD of European water vapor and precipitation. To this end, we first confirm a reliable implementation of the most important isotope fractionation processes in COSMOiso by comparing 5 years of modeled δD values with multiplatform δD observations from Europe (remote sensing observations of the δD of water vapor around 2.6 km above ground level, in situ δD measurements in near‐surface water vapor, and δD precipitation data from the Global Network of Isotopes in Precipitation). Based on six 15 year sensitivity simulations, we then quantify the climatological impacts of the different fractionation processes on the δD values. We find δD of European water vapor and precipitation to be most strongly controlled by rainout. Superimposed to this are the effect of subcloud processes, which especially affects δD in precipitation under warm conditions, and the effect of continental evapotranspiration, which exerts an important control over the δD of near‐surface water vapor. In future studies, the validated COSMOiso model can be employed in a similar way for a comprehensive interpretation of European isotope records from climatologically different time periods.

Description: Numerical simulations employing prognostic stable water isotopes can not only facilitate our understanding of hydrological processes and climate change but also allow for a direct comparison between isotope signals obtained from models and various archives. In the current work, we describe the performance and explore the potential of a new version of the Earth system model AWI-ESM (Alfred Wegener Institute Earth System Model), labeled AWI-ESM-2.1-wiso, in which we incorporated three isotope tracers into all relevant components of the water cycle. We present here the results of pre-industrial (PI) and mid-Holocene (MH) simulations. The model reproduces the observed PI isotope compositions in both precipitation and seawater well and captures their major differences from the MH conditions. The simulated relationship between the isotope composition in precipitation (δ18Op) and surface air temperature is very similar between the PI and MH conditions, and it is largely consistent with modern observations despite some regional model biases. The ratio of the MH–PI difference in δ18Op to the MH–PI difference in surface air temperature is comparable to proxy records over Greenland and Antarctica only when summertime air temperature is considered. An amount effect is evident over the North African monsoon domain, where a negative correlation between δ18Op and the amount of precipitation is simulated. As an example of model applications, we studied the onset and withdrawal date of the MH West African summer monsoon (WASM) using daily variables. We find that defining the WASM onset based on precipitation alone may yield erroneous results due to the substantial daily variations in precipitation, which may obscure the distinction between pre-monsoon and monsoon seasons. Combining precipitation and isotope indicators, we suggest in this work a novel method for identifying the commencement of the WASM. Moreover, we do not find an obvious difference between the MH and PI periods in terms of the mean onset of the WASM. However, an advancement in the WASM withdrawal is found in the MH compared to the PI period due to an earlier decline in insolation over the northern location of Intertropical Convergence Zone (ITCZ).

Description: In order to investigate the impact of spatial resolution on the discrepancy between simulated δ18O and observed δ18O in Greenland ice cores, regional climate simulations are performed with the isotope-enabled regional climate model (RCM) COSMO_iso. For this purpose, isotope-enabled general circulation model (GCM) simulations with the ECHAM5-wiso general circulation model (GCM) under present-day conditions and the MPI-ESM-wiso GCM under mid-Holocene conditions are dynamically downscaled with COSMO_iso for the Arctic region. The capability of COSMO_iso to reproduce observed isotopic ratios in Greenland ice cores for these two periods is investigated by comparing the simulation results to measured δ18O ratios from snow pit samples, Global Network of Isotopes in Precipitation (GNIP) stations and ice cores. To our knowledge, this is the first time that a mid-Holocene isotope-enabled RCM simulation is performed for the Arctic region. Under present-day conditions, a dynamical downscaling of ECHAM5-wiso (1.1∘×1.1∘ ) with COSMO_iso to a spatial resolution of 50 km improves the agreement with the measured δ18O ratios for 14 of 19 observational data sets. A further increase in the spatial resolution to 7 km does not yield substantial improvements except for the coastal areas with its complex terrain. For the mid-Holocene, a fully coupled MPI-ESM-wiso time slice simulation is downscaled with COSMO_iso to a spatial resolution of 50 km. In the mid-Holocene, MPI-ESM-wiso already agrees well with observations in Greenland and a downscaling with COSMO_iso does not further improve the model–data agreement. Despite this lack of improvement in model biases, the study shows that in both periods, observed δ18O values at measurement sites constitute isotope ratios which are mainly within the subgrid-scale variability of the global ECHAM5-wiso and MPI-ESM-wiso simulation results. The correct δ18O ratios are consequently not resolved in the GCM simulation results and need to be extracted by a refinement with an RCM. In this context, the RCM simulations provide a spatial δ18O distribution by which the effects of local uncertainties can be taken into account in the comparison between point measurements and model outputs. Thus, an isotope-enabled GCM–RCM model chain with realistically implemented fractionating processes constitutes a useful supplement to reconstruct regional paleo-climate conditions during the mid-Holocene in Greenland. Such model chains might also be applied to reveal the full potential of GCMs in other regions and climate periods, in which large deviations relative to observed isotope ratios are simulated.

Description: Stable water isotopes in polar ice cores are widely used to reconstruct past temperature variations over several orbital climatic cycles. One way to calibrate the isotope–temperature relationship is to apply the present-day spatial relationship as a surrogate for the temporal one. However, this method leads to large uncertainties because several factors like the sea surface conditions or the origin and transport of water vapor influence the isotope–temperature temporal slope. In this study, we investigate how the sea surface temperature (SST), the sea ice extent, and the strength of the Atlantic Meridional Overturning Circulation (AMOC) affect these temporal slopes in Greenland and Antarctica for Last Glacial Maximum (LGM, ∼ 21 000 years ago) to preindustrial climate change. For that, we use the isotope-enabled atmosphere climate model ECHAM6-wiso, forced with a set of sea surface boundary condition datasets based on reconstructions (e.g., GLOMAP) or MIROC 4m simulation outputs. We found that the isotope–temperature temporal slopes in East Antarctic coastal areas are mainly controlled by the sea ice extent, while the sea surface temperature cooling affects the temporal slope values inland more. On the other hand, ECHAM6-wiso simulates the impact of sea ice extent on the EPICA Dome C (EDC) and Vostok sites through the contribution of water vapor from lower latitudes. Effects of sea surface boundary condition changes on modeled isotope–temperature temporal slopes are variable in West Antarctica. This is partly due to the transport of water vapor from the Southern Ocean to this area that can dampen the influence of local temperature on the changes in the isotopic composition of precipitation and snow. In the Greenland area, the isotope–temperature temporal slopes are influenced by the sea surface temperatures near the coasts of the continent. The greater the LGM cooling off the coast of southeastern Greenland, the greater the transport of water vapor from the North Atlantic, and the larger the temporal slopes. The presence or absence of sea ice very near the coast has a large influence in Baffin Bay and the Greenland Sea and influences the slopes at some inland ice core stations. The extent of the sea ice far south slightly influences the temporal slopes in Greenland through the transport of more depleted water vapor from lower latitudes to this area. The seasonal variations of sea ice distribution, especially its retreat in summer, influence the isotopic composition of the water vapor in this region and the modeled isotope–temperature temporal slopes in the eastern part of Greenland. A stronger LGM AMOC decreases LGM-to-preindustrial isotopic anomalies in precipitation in Greenland, degrading the isotopic model–data agreement. The AMOC strength modifies the temporal slopes over inner Greenland slightly and by a little on the coasts along the Greenland Sea where the changes in surface temperature and sea ice distribution due to the AMOC strength mainly occur.

Description: Atmospheric general circulation models (AGCMs) are known to have a warm and isotopically enriched bias over Antarctica. We test here the hypothesis that these biases are partly consequences of a too diffusive advection. Exploiting the LMDZ-iso model, we show that a less diffusive representation of the advection, especially on the horizontal, is very important to reduce the bias in the isotopic contents of precipitation above this area. The choice of an appropriate representation of the advection is thus essential when using GCMs for paleoclimate applications based on polar water isotopes. Too much diffusive mixing along the poleward transport leads to overestimated isotopic contents in water vapor because dehydration by mixing follows a more enriched path than dehydration by Rayleigh distillation. The near-air surface temperature is also influenced, to a lesser extent, by the diffusive properties of the advection scheme directly via the advection of the air and indirectly via the radiative effects of changes in high cloud fraction and water vapor. A too diffusive horizontal advection increases the temperature and so also contributes to enrich the isotopic contents of water vapor over Antarctica through a reduction of the distillation. The temporal relationship, from Last Glacial Maximum (LGM) to present-day conditions, between the mean annual near-air surface temperature and the water isotopic contents of precipitation for a specific location can also be impacted, with significant consequences on the paleo-temperature reconstruction from observed changes in water isotopes.