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  • Thermodynamics  (2)
  • atmospheric deposition; Binary Object; Crop; fertilizer; File content; manure; nitrogen; Nitrogen Model Inter-Comparison Project; NMIP; pastures; rangeland  (1)
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  • 1
    Publication Date: 2024-06-12
    Description: Excessive anthropogenic nitrogen (N) inputs to the biosphere have disrupted the global nitrogen cycle. To better quantify the spatial and temporal patterns of anthropogenic N enrichments, assess their impacts on the biogeochemical cycles of the planet and other living organisms, and improve nitrogen use efficiency (NUE) for sustainable development, we develop a comprehensive and synthetic dataset for anthropogenic N inputs to the terrestrial biosphere. This Harmonized Anthropogenic N Inputs (HaNi) dataset takes advantage of different data sources in a spatiotemporally consistent way to generate a set of high-resolution gridded N input products from the preindustrial to present (1860-2019). The HaNi dataset includes annual rates of synthetic N fertilizer, manure application/deposition, and atmospheric N deposition in cropland, pasture, and rangeland at 5-arcmin. Specifically, the N inputs are categorized, according to the N forms and the land use, as 1) NH4-N fertilizer applied to cropland, 2) NO3-N fertilizer applied to cropland, 3) NH4-N fertilizer applied to pasture, 4) NO3-N fertilizer applied to pasture, 5) manure N application on cropland, 6) manure N application on pasture, 7) manure N deposition on pasture, 8) manure N deposition on rangeland, 9) NHx-N deposition, and 10) NOy-N deposition. The total anthropogenic N (TN) inputs to global terrestrial ecosystems increased from 29.05 Tg N yr-1 in the 1860s to 267.23 Tg N yr-1 in the 2010s, with the dominant N source changing from atmospheric N deposition (before the 1900s) to manure N (the 1910s-2000s), and to synthetic fertilizer in the 2010s. The proportion of synthetic NH4-N fertilizer increased from 64% in the 1960s to 90% in the 2010s, while synthetic NO3-N fertilizer decreased from 36% in the 1960s to 10% in the 2010s. Hotspots of TN inputs shifted from Europe and North America to East and South Asia during the 1960s-2010s. Such spatial and temporal dynamics captured by the HaNi dataset are expected to facilitate a comprehensive assessment of the coupled human-earth system and address a variety of social welfare issues, such as climate-biosphere feedback, air pollution, water quality, and biodiversity.
    Keywords: atmospheric deposition; Binary Object; Crop; fertilizer; File content; manure; nitrogen; Nitrogen Model Inter-Comparison Project; NMIP; pastures; rangeland
    Type: Dataset
    Format: text/tab-separated-values, 20 data points
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  • 2
    ISSN: 1572-8927
    Keywords: Thermodynamics ; electrolyte mixtures ; activity coefficients ; osmotic coefficients ; Pitzer equations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The parameters for symmetrical mixing of ions of the same sign in the virial-coefficient (Pitzer) system are evaluated from literature data for 25°C in a manner consistent with the higher-order limiting law of Friedman. Twenty-four systems involve cation mixing with a common anion and fourteen involve anion mixing with a common cation. Heat of mixing data were similarly treated in a recent publication; the results give the temperature coefficients of some of these same parameters. The combined results yield the mixing parameters as functions of temperature on a basis both self-consistent and in accord with the limiting law. The results also yield, for a few systems without a common ion, predicted values in good agreement with experimental data.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of solution chemistry 18 (1989), S. 189-199 
    ISSN: 1572-8927
    Keywords: Thermodynamics ; electrolyte solutions ; osmotic coefficients ; liquid-liquid immiscibility ; uranyl sulphate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A comprehensive treatment of the thermodynamic properties of aqueous UO2SO4 to 559 K is presented. This system has the unusual property of liquid-liquid phase separation above its critical temperature of 559 K. The equations for criticality and for phase equilibria in the molality system are developed. The factors leading to this phase separation are discussed as well as the approximations inherent in our equation because of incomplete information.
    Type of Medium: Electronic Resource
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