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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © Elsevier B.V., 2007. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Earth and Planetary Science Letters 267 (2008): 341-352, doi:10.1016/j.epsl.2007.11.053.
    Description: Detailed near-bottom investigation of a series of giant, kilometer scale, elongate pockmarks along the edge of the mid-Atlantic continental shelf confirms that methane is actively venting at the site. Dissolved methane concentrations, which were measured with a commercially available methane sensor (METS) designed by Franatech GmbH mounted on an autonomous underwater vehicle (AUV), are as high as 100 nM. These values are well above expected background levels (1-4 nM) for the open ocean. Sediment pore water geochemistry gives further evidence of methane advection through the seafloor. Isotopically light carbon in the dissolved methane samples indicates a primarily biogenic source. The spatial distribution of the near-bottom methane anomalies (concentrations above open ocean background), combined with water column salinity and temperature vertical profiles, indicate that methane-rich water is not present across the entire width of the pockmarks, but is laterally restricted to their edges. We suggest that venting is primarily along the top of the pockmark walls with some advection and dispersion due to local currents. The highest methane concentrations observed with the METS sensor occur at a small, circular pockmark at the southern end of the study area. This observation is compatible with a scenario where the larger, elongate pockmarks evolve through coalescing smaller pockmarks.
    Description: This work was supported by NSF grants OCE- 0242426, OCE-0242804 and OCDE-0242449 and ONR grant N00014-02-1-0691.
    Keywords: Pockmarks ; Seafloor venting ; Methane ; AUV
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 34 (2007): L22603, doi:10.1029/2007GL031344.
    Description: Large quantities of natural gas are emitted from the seafloor into the stratified coastal ocean near Coal Oil Point, Santa Barbara Channel, California. Methane was quantified in the down current surface water at 79 stations in a 280 km2 study area. The methane plume spread over an area of ~70 km2 and emitted on the order of 5 × 104 mol d−1 to the atmosphere. A monthly time series at 14 stations showed variable methane concentrations which were correlated with changing sub-mesoscale surface currents. Air-sea fluxes estimated from the time series indicate that the air-sea flux derived for the 280 km2 area is representative of the daily mean flux from this area. Only 1% of the dissolved methane originating from Coal Oil Point enters the atmosphere within the study area. Most of it appears to be transported below the surface and oxidized by microbial activity.
    Description: The research was supported by the University of California Energy Institute and the National Science Foundation (OCE 0447395).
    Keywords: Air-sea flux ; Shallow marine seep ; Methane
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/postscript
    Format: application/pdf
    Format: text/plain
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2009. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Journal of Environmental Radioactivity 101 (2010): 553-563, doi:10.1016/j.jenvrad.2009.12.004.
    Description: We constructed a survey system of radon/methane/nitrate/salinity to find sites of submarine groundwater discharge (SGD) and groundwater nitrate input. We deployed the system in Waquoit Bay and Boston Harbor, MA where we derived SGD rates using a mass balance of radon with methane serving as a fine resolution qualitative indicator of groundwater. In Waquoit Bay we identified several locations of enhanced groundwater discharge, out of which two (Childs and Quashnet Rivers) were studied in more detail. The Childs River was characterized by high nitrate input via groundwater discharge, while the Quashnet River SGD was notable but not a significant source of nitrate. Our radon survey of Boston Harbor revealed several sites with significant SGD, out of these Inner Harbor and parts of Dorchester Bay and Quincy Bay had groundwater fluxes accompanied by significant water column nitrogen concentrations. The survey system has proven effective in revealing areas of SGD and non-point source pollution.
    Description: R. Camilli acknowledges the National Ocean Partnership Program (NOPP) for supporting the development of the TETHYS mass spectrometer through research grant #OCE-0537173. H. Dulaiova, M. A. Charette and R. Camilli acknowledge funding support from the WHOI Coastal Institute and MIT Sea Grant College Program under NOAA grant number NA06OAR4170019, project number 5710002173. H. Dulaiova was funded by the WHOI Academic Program’s postdoctoral scholarship.
    Keywords: Non-point source pollution ; Submarine groundwater discharge ; Methane ; Radon ; Nitrate ; Waquoit Bay ; Boston Harbor
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
    Format: application/pdf
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