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  • 1
    ISSN: 1572-8854
    Keywords: 8-Coordinate cryptate ; ytterbium(III) ; rare-earth elements
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The first example of an 8-coordinate cryptate of cryptand(2,2,2) [N(CH2CH2OCH2CH2OCH2CH2)3N], Yb3+, and multiple nitrato andN-thiocyanato ligands, H2Yb(NCS)3(NO3)2(2,2,2)·H2O (I), has been synthesized. The crystal and molecular structure ofI have been determined by single-crystal X-ray diffraction. The Yb3+ cation is not located in the cavity of the cryptand(2,2,2), but is connected to it through a water bridge by two hydrogen bonds to form an exclusive cryptate. The two H+ ions are mostly probably bound to the two N atoms of cryptand(2,2,2). The coordinating atoms of the NO 3 − , NCS−, and H2O ligands constitute a trigonododecahedron around the central Yb3+ ion. CryptateI crystallizes in the monoclinic space groupP2l/n withZ=4. The finalR factor for 3659 independent reflections, following correction for Lorentz and polarization effects and havingF 0〉5σ(F 0), is 0.053. Infrared spectroscopic data for1 are consistent with the X-ray crystal structure results.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 39 (2012): L20713, doi:10.1029/2012GL053322.
    Description: Characteristics of the Indian and Australian summer monsoon systems, their seasonality and interactions are examined in a variety of observational datasets and in the Coupled Model Intercomparison Project Phase 3 and 5 (CMIP3 and CMIP5) climate models. In particular, it is examined whether preferred monsoon transitions between the two regions and from one year to another, that form parts of the Tropospheric Biennial Oscillation, can lead to improved predictive skill. An overall improvement in simulation of seasonality for both monsoons is seen in CMIP5 over CMIP3, with most CMIP5 models correctly simulating very low rainfall rates outside of the monsoon season. The predictability resulting from each transition is quantified using a Monte Carlo technique. The transition from strong/weak Indian monsoon to strong/weak Australian monsoon shows ∼15% enhanced predictability in the observations, in estimating whether the following monsoon will be stronger/weaker than the climatology. Most models also successfully simulate this transition. However, enhanced predictability for other transitions is less clear.
    Description: This project was supported by funding from the Australian Research Council (DP110100601) and the Centre of Excellence for Climate System Science. This work was also supported by an award under the Merit Allocation Scheme on the NCI National Facility at the ANU
    Description: 2013-04-26
    Keywords: Australian monsoon ; CMIP models ; Indian monsoon ; Tropospheric biennial oscillation
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Format: text/plain
    Format: application/postscript
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