Description: Sediment depositional patterns along the upper continental slope of the northern South China Sea (SCS) have been studied using two sediment cores (GeoB16601-6, 20°09.07'N, 116°14.38'E, 1012 m water depth and GeoB16602-4, 18°57.12'N, 113°42.64'E, 951 m water depth) recovered during RV SONNE Cruise SO-221'INVERS'. Sediment cores were analyzed for bulk sediment element composition by X-Ray Fluorescence (XRF) core scanning and clay mineral assemblage by X-Ray Diffraction (XRD). The bulk sediment element and the clay mineral compositions of the two cores suggest similar depositional patterns between 50 kyr BP and ~29 kyr BP, and ~14 kyr BP to present, but a clear difference in depositional patterns during the last glacial and deglacial (~29-14 kyr BP) when sea level was below-90 m. Between ~29-14 kyr BP, a higher kaolinite percentage in core GeoB16602-4 in comparison to core GeoB16601-6 is interpreted to reflect a higher contribution of clay supplied by the Pearl River to core site GeoB16602-4. In contrast, core GeoB16601-6 received less Pearl River supplied clayeymaterial during the same period.When the sea levelwas below-90mduring the last glacial lowstand, the detrital fine-grained materials supplied by the Pearl River were mostly transported by coastal currents to the southwest, resulting in a higher contribution of Pearl River discharged material at site GeoB16602-4 than at site GeoB16601-6. We suggest that sea-level induced modifications of the land-ocean distribution together with changes in the palaeo-physiographic conditions, such as the proximity of the palaeo-rivers to the individual core sites might be responsible for the different sediment depositional patterns in the study area. Thus, the overriding control of sea-level induced changes on the sediment depositional environment might mask climate-related changes in sediment depositional pattern in the northern SCS.

Description: The chronology of deglacial meltwater pulses from the Laurentide Ice Sheet is well documented. However, the deglacial history of the North American-Arctic (north-eastern Laurentide and Innuitian) and western Greenland ice sheets draining into the Labrador Sea via Baffin Bay is less well constrained. Here we present new high-resolution, radiocarbon-dated records from the central Baffin Bay spanning ~17 to 10 kyr BP and documenting the full deglacial history of Baffin Bay. Sedimentological and geochemical data confirm the presence of two periods of enhanced detrital carbonate delivery, termed Baffin Bay Detrital Carbonate Events (BBDCs). These events are dated to ~14.2-13.7 kyr BP and ~12.7-11 kyr BP. They are synchronous across Baffin Bay and their mineralogical signature indicates a common source of detrital carbonate from northern Baffin Bay. The first event, BBDC 1, postdates Heinrich Event 1 and the second event, BBDC 0, predates the recently revised timing of Heinrich Event 0. The onset of the BBDC events appears not to be systematically linked to Greenland temperature change as they occur during both interstadial and stadial periods. This indicates that deglaciation of North American-Arctic and western Greenland ice sheets with the associated iceberg and meltwater discharge were decoupled from the dominant North Atlantic climate mode, where iceberg discharge events from the Laurentide Ice Sheet occurred during stadial periods.

Description: Saharan dust has a crucial influence on the earth climate system and its emission, transport and deposition are intimately related to, e.g., wind speed, precipitation, temperature and vegetation cover. The alteration in the physical and chemical properties of Saharan dust due to environmental changes is often used to reconstruct the climate of the past. However, to better interpret possible climate changes the dust source regions need to be known. By analysing the mineralogical composition of transported or deposited dust, potential dust source areas can be inferred. Summer dust transport off northwest Africa occurs in the Saharan air layer (SAL). In continental dust source areas, dust is also transported in the SAL; however, the predominant dust input occurs from nearby dust sources with the low-level trade winds. Hence, the source regions and related mineralogical tracers differ with season and sampling location. To test this, dust collected in traps onshore and in oceanic sediment traps off Mauritania during 2013 to 2015 was analysed. Meteorological data, particle-size distributions, back-trajectory and mineralogical analyses were compared to derive the dust provenance and dispersal. For the onshore dust samples, the source regions varied according to the seasonal changes in trade-wind direction. Gibbsite and dolomite indicated a Western Saharan and local source during summer, while chlorite, serpentine and rutile indicated a source in Mauritania and Mali during winter. In contrast, for the samples that were collected offshore, dust sources varied according to the seasonal change in the dust transporting air layer. In summer, dust was transported in the SAL from Mauritania, Mali and Libya as indicated by ferroglaucophane and zeolite. In winter, dust was transported with the trades from Western Sahara as indicated by, e.g., fluellite.

Description: Sorption of volatile hydrocarbon gases (VHCs) to marine sediments is a recognized phenomenon that has been investigated in the context of petroleum exploration. However, little is known about the biogeochemistry of sorbed methane and higher VHCs in environments that are not influenced by thermogenic processes. This study evaluated two different extraction protocols for sorbed VHCs, used high pressure equipment to investigate the sorption of methane to pure clay mineral phases, and conducted a geochemical and mineralogical survey of sediment samples from different oceanographic settings and geochemical regimes that are not significantly influenced by thermogenic gas. Extraction of sediments under alkaline conditions yielded higher concentrations of sorbed methane than the established protocol for acidic extraction. Application of alkaline extraction in the environmental survey revealed the presence of substantial amounts of sorbed methane in 374 out of 411 samples (91%). Particularly high amounts, up to 2.1 mmol kg**-1 dry sediment, were recovered from methanogenic sediments. Carbon isotopic compositions of sorbed methane suggested substantial contributions from biogenic sources, both in sulfate-depleted and sulfate-reducing sediments. Carbon isotopic relationships between sorbed and dissolved methane indicate a coupling of the two pools. While our sorption experiments and extraction conditions point to an important role for clay minerals as sorbents, mineralogical analyses of marine sediments suggest that variations in mineral composition are not controlling variations in quantities of sorbed methane. We conclude that the distribution of sorbed methane in sediments is strongly influenced by in situ production.