Description: Studies of spatial and temporal changes in modern and past sea-ice occurrence may help to understand the processes controlling the recent decrease in Arctic sea-ice cover. Here, we determined concentrations of IP25, a novel biomarker proxy for sea ice developed in recent years, phytoplankton-derived biomarkers (brassicasterol and dinosterol) and terrigenous biomarkers (campesterol and β-sitosterol) in the surface sediments from the Kara and Laptev seas to estimate modern spatial (seasonal) sea-ice variability and organic-matter sources. C25-HBI dienes and trienes were determined as additional palaeoenvironmental proxies in the study area. Furthermore, a combined phytoplankton-IP25 biomarker approach (PIP25 index) is used to reconstruct the modern sea-ice distribution more quantitatively. The terrigenous biomarkers reach maximum concentrations in the coastal zones and estuaries, reflecting the huge discharge by the major rivers Ob, Yenisei and Lena. Maxima in phytoplankton biomarkers indicating increased primary productivity were found in the seasonally ice-free central part of the Kara and Laptev seas. Neither IP25 nor PIP25, however, shows a clear and simple correlation with satellite sea-ice distribution in our study area due to the complex environmental conditions in our study area and the transportation process of sea-ice diatom in the water column. Differences in the diene/IP25 and triene/IP25 ratios point to different sources of these HBIs and different environmental conditions. The diene/IP25 ratio seems to correlate positively with sea-surface temperature, while negatively with salinity distributions.

Description: Diatom assemblages and organic carbon records from two sediment cores located within an estuarian bay of the inner Kara Sea trace changes in Yenisei River runoff and postglacial depositional environments. Paleosalinity and sea-ice reconstructions are based on modern relationships of local diatom assemblages and summer surface-water salinity. Approximately 15,500 cal yr B.P., rivers and bogs characterized the study area. When sea level reached the 38- to 40-m paleo-isobath approximately 9300 cal yr B.P., the coring site was flooded. From 9300–9100 cal yr B.P., estuarine conditions occurred proximal to the depocenter of fluvially derived material, and salinity was 〈7–8. Paleosalinity increased to 11–13 by 7500 cal yr B.P., following postglacial sea-level rise and the southward shift of the Siberian coast. Sharp decreases in diatom accumulation rates, total sediment, and organic carbon also occurred, suggesting the presence of brackish conditions and greater distance between the coast and study site. Maximum paleosalinity (up to 13) was recorded between 7500 and 6000 cal yr B.P., which was likely caused by the enhanced penetration of Atlantic waters to the Kara Sea. Stepwise decreases to modern salinity levels happened over the last 6000 cal yr.

Description: A review of the data on heavy metals in aerosols over the seas of the Russian Arctic is presented. Results of heavy metal studies in aerosols obtained during 11 research expeditions in summer/autumn period from 1991 to 2000, and at Severnaya Zemlya and Wrangel Island in spring, in 1985–1989 are discussed. Concentrations of most heavy metals in the atmosphere in the marine boundary layer in the Russian Arctic are nearly of the same order as literature data from other Arctic areas. The content of heavy metals in the aerosols over the seas of the Russian Arctic shows an annual variation with maximal concentrations during the winter/spring season. In the summer/autumn period increased concentrations of heavy metals could be explained, in most cases, by natural processes (generation of sea salt aerosols, etc.). In some cases, aerosols from Norilsk and Kola Peninsula were detected. Particular attention was paid to estimation of horizontal and vertical fluxes of atmospheric heavy metals. We estimated annual variations in long-range transport of heavy metals into the Russian Arctic in 1986–1995. In winter and spring, up to 50% of the average air pollutant concentrations in the Russian Arctic are due to the Arctic atmospheric pollution itself. Moreover, the monthly and annual averaged fluxes of six anthropogenic chemical elements (arsenic, nickel, lead, vanadium, zinc and cadmium) onto the surface in the Arctic were estimated, and the values obtained were in reasonable agreement with the literature data available.

Description: A reconstruction of Holocene sea ice conditions in the Fram Strait provides insight into the palaeoenvironmental and palaeoceanographic development of this climate sensitive area during the past 8500 years BP. Organic geochemical analyses of sediment cores from eastern and western Fram Strait enable the identification of variations in the ice coverage that can be linked to changes in the oceanic (and atmospheric) circulation system. By means of the sea ice proxy IP25, phytoplankton-derived biomarkers and ice rafted detritus (IRD) increasing sea ice occurrences are traced along the western continental margin of Spitsbergen throughout the Holocene, which supports previous palaeoenvironmental reconstructions that document a general cooling. A further significant ice advance during the Neoglacial is accompanied by distinct sea ice fluctuations, which point to short-term perturbations in either the Atlantic Water advection or Arctic Water outflow at this site. At the continental shelf of East Greenland, the general Holocene cooling, however, seems to be less pronounced and sea ice conditions remained rather stable. Here, a major Neoglacial increase in sea ice coverage did not occur before 1000 years BP. Phytoplankton-IP25 indices (“PIP25-Index”) are used for more explicit sea ice estimates and display a Mid Holocene shift from a minor sea ice coverage to stable ice margin conditions in eastern Fram Strait, while the inner East Greenland shelf experienced less severe to marginal sea ice occurrences throughout the entire Holocene. Highlights ► Biomarker and IRD data give insight into Holocene sea ice conditions in Fram Strait. ► We find increasing sea ice coverage off West Spitsbergen throughout the Holocene. ► Oceanic/atmospheric variability caused Neoglacial sea ice fluctuations. ► Ice conditions along East Greenland shelf remain rather stable until 1000 years BP.

Description: In this paper, we summarize data on terrigenous sediment supply in the Kara Sea and its accumulation and spatial and temporal variability during Holocene times. Sedimentological, organic-geochemical, and micropaleontological proxies determined in surface sediments allow to characterize the modern (riverine) terrigenous sediment input. AMS-14C dated sediment cores from the Ob and Yenisei estuaries and the adjacent inner Kara Sea were investigated to determine the terrigenous sediment fluxes and their relationship to paleoenvironmental changes. The variability of sediment fluxes during Holocene times is related to the post-glacial sea-level rise and changes in river discharge and coastal erosion input. Whereas during the late/middle Holocene most of the terrigenous sediments were deposited in the estuaries and the areas directly off the estuaries, huge amounts of sediments accumulated on the Kara Sea shelf farther north during the early Holocene before about 9 Cal. kyr BP. The maximum accumulation at that time is related to the lowered sea level, increased coastal erosion, and increased river discharge. Based on sediment thickness charts, echograph profiles and sediment core data, we estimate an average Holocene (0–11 Cal. kyr BP) annual accumulation of 194×106 t yr−1 of total sediment for the whole Kara Sea. Based on late Holocene (modern) sediment accumulation in the estuaries, probably 12×106 t yr−1 of riverine suspended matter (i.e., about 30% of the input) may escape the marginal filter on a geological time scale and is transported onto the open Kara Sea shelf. The high-resolution magnetic susceptibility record of a Yenisei core suggests a short-term variability in Siberian climate and river discharge on a frequency of 300–700 yr. This variability may reflect natural cyclic climate variations to be seen in context with the interannual and interdecadal environmental changes recorded in the High Northern Latitudes over the last decades, such as the NAO/AO pattern. A major decrease in MS values starting near 2.5 Cal. kyr BP, being more pronounced during the last about 2 Cal. kyr BP, correlates with a cooling trend over Greenland as indicated in the GISP-2 Ice Core, extended sea-ice cover in the North Atlantic, and advances of glaciers in western Norway. Our still preliminary interpretation of the MS variability has to be proven by further MS records from additional cores as well as other high-resolution multi-proxy Arctic climate records.

Description: The maximum limits of the Eurasian ice sheets during four glaciations have been reconstructed: (1) the Late Saalian (〉140 ka), (2) the Early Weichselian (100–80 ka), (3) the Middle Weichselian (60–50 ka) and (4) the Late Weichselian (25–15 ka). The reconstructed ice limits are based on satellite data and aerial photographs combined with geological field investigations in Russia and Siberia, and with marine seismic- and sediment core data. The Barents-Kara Ice Sheet got progressively smaller during each glaciation, whereas the dimensions of the Scandinavian Ice Sheet increased. During the last Ice Age the Barents-Kara Ice Sheet attained its maximum size as early as 90–80,000 years ago when the ice front reached far onto the continent. A regrowth of the ice sheets occurred during the early Middle Weichselian, culminating about 60–50,000 years ago. During the Late Weichselian the Barents-Kara Ice Sheet did not reach the mainland east of the Kanin Peninsula, with the exception of the NW fringe of Taimyr. A numerical ice-sheet model, forced by global sea level and solar changes, was run through the full Weichselian glacial cycle. The modeling results are roughly compatible with the geological record of ice growth, but the model underpredicts the glaciations in the Eurasian Arctic during the Early and Middle Weichselian. One reason for this is that the climate in the Eurasian Arctic was not as dry then as during the Late Weichselian glacial maximum.

Description: Highlights • Highly variable sea-ice conditions off eastern North Greenland during the Holocene. • The mid to late Holocene is characterized by seasonal to marginal sea-ice conditions. • Seasonal formation of the Northeast-Water (NEW) Polynya during the last 1 ka. Understanding the processes controlling the natural variability of sea ice in the Arctic, one of the most dynamic components of the climate system, can help to constrain the effects of future climate change in this highly sensitive area. For the first time, a high-resolution biomarker study was carried out to reconstruct past sea-ice variability off eastern North Greenland. This area is strongly influenced by cold surface waters and drift ice transported via the East Greenland Current, meltwater pulses from the outlet glaciers of the Northeast Greenland Ice Stream and the build-up of landfast ice. The well-dated Holocene sedimentary section of Core PS93/025 provides insights into variations of the sea-ice conditions (regional and local sea-ice signal), oceanic and atmospheric circulation and the biotic response to these changes. These biomarker records show a reduced to variable sea-ice cover during the early Holocene between 10.2 and 9.3 ka, followed by a steady increase in sea-ice conditions during the mid Holocene. During the last 5–6 ka, sea-ice conditions remained more stable representing a seasonal to marginal sea-ice situation. Based on our biomarker records, stable sea-ice edge conditions, with a fully developed polynya situation occurred since the last 1 ka.

Description: DSDP/ODP drilling in the northern North Atlantic reveals that so far the onset of northern hemisphere cooling deduced from the occurrence of ice-rafted debris (IRD) in deep-sea sediments can be traced back to the middle Miocene. The Greenland ice sheet has probably the longest history on the northern hemisphere. Leg 151 site 909 (Fram Strait) recovered a unique continuous sediment record dating from early/middle Miocene. The composition of the coarse fraction indicates that the oldest IRD pulses are documented around 14 Ma in the Fram Strait (site 909) and around 12.6 Ma on the Vöring Plateau (leg 104, site 642) in the Norwegian–Greenland Sea. Fram Strait site 909 indicates a further stepwise increase of northern hemisphere cooling by serveral IRD pulses during late Miocene (between 10.8 and 8.6 Ma, around 7.2, 6.8 and 6.3 Ma), which ultimately led to a drastic intensification of northern hemisphere glaciation during Plio–Pleistocene. The deep-sea sediment records show that Plio–Pleistocene strengthening of IRD pulses have been observed since approximately 4.0 Ma in the westernmost Norwegian–Greenland Sea and Labrador Sea; by contrast, strengthening of IRD pulses are observed at approximately 3.2–2.7 Ma on the eastern side of the Norwegian–Greenland Sea, including the Barents Sea margin. Sediment composition and physical properties of the drilled, mostly terrigenous sections reveal that orbital parameters have controlled major aspects of shallow and deep-water environments with frequency domains related to 41 ka periods of obliquity dominant in the pre-glacial Miocene, Pliocene and early Quaternary and to 100 ka periods of eccentricity dominant during the past 600,000–700,000 years. The stratigraphy of ice-rafted material reveals a frequently and rapidly changing history of the dynamics of various segments in ice sheets around the Norwegian–Greenland Sea. It is particularly evident from the composition of the ice-rafted material that the Eurasian ice sheets delivered IRD to the eastern part of the Norwegian–Greenland Sea, whereas Greenland source areas are represented in the drill sites of the east Greenland continental margin and in the Labrador Sea. The stratigraphic sequences on the Yermak Plateau suggest that the Svalbard ice sheet may have extended far to the north prior to oxygen isope stage 16 but not since then. Invasions of temperate Atlantic waters during interglacials can be observed as short-lived and rather irregular events. It never reached the area off eastern Greenland except during the Pliocene interval, when tundra floras were able to develop on north-eastern Greenland and planktonic foraminifers suggesting the presence of temperate water masses in the Fram Strait as been documented in the drill sites from the Yermak Plateau.

Description: Three cores recovered off the northwest of Svalbard were studied with respect to glacial/interglacial changes of clay and bulk mineralogy, lithology and organic geochemistry. The cores cover the Late Quaternary Marine Isotope Stages (MIS) 6–1 (ca. 170,000 years) and are located in the vicinity of the Polar Front which separates the warm Atlantic water of the Westspitsbergen Current and the cold Polar Water of the Transpolar Drift. Globally driven changes in the paleoenvironment like the variable advection of warm Atlantic water into the Arctic Ocean can be distinguished from regional events by means of source mineral signatures and organic geochemistry data. In particular, a combination of high organic carbon and low carbonate contents, high C/N-ratios, a particular lithology and a distinct bulk and clay mineral assemblage can be related to Svalbard ice sheet developments between 23,000 and 19,500 14C years. This complex sediment pattern has been traced to the northwest of Spitsbergen as far north as 82°N. Additionally, the same signature has been recognized in detail in upper MIS 5 sediments. The striking similarity of the history of the Svalbard/Barents Sea Ice Sheet during the late and early/middle Weichselian is elaborated. Both sediment horizons are intercalated between biogenic calcite rich core sequences which contain the so-called “High Productivity Zones” or “Nordway Events” related to the increased advection of warm Atlantic water to the Arctic Ocean. This study provides further evidence that the meridional circulation pattern has been present during most of the Weichselian and that the ice cover was often reduced in the northeastern Fram Strait and above the Yermak Plateau. Our findings contradict the widely used reconstructions in modelling of the last glaciation cycle and reveal a much more dynamic system in the Fram Strait and southwestern Eurasian Basin of the Arctic Ocean.

Description: Integrated interpretation of multi-beam bathymetric, sediment-penetrating acoustic (PARASOUND) and seismic data show a multiple slope failure on the northern European continental margin, north of Spitsbergen. The first slide event occurred during MIS 3 around 30 cal. ka BP and was characterised by highly dynamic and rapid evacuation of ca. 1250 km3 of sediment from the lower to the upper part of the continental slope. During this event, headwalls up to 1600 m high were created and ca. 1150 km3 material from hemi-pelagic sediments and from the lower pre-existing trough mouth fan has been entrained and transported into the semi-enclosed Sophia Basin. This megaslide event was followed by a secondary evacuation of material to the Nansen Basin by funnelling of the debris through the channel between Polarstern Seamount and the adjacent continental slope. The main slide debris is overlain by a set of fining-upward sequences as evidence for the associated suspension cloud and following minor failure events. Subsequent adjustment of the eastern headwalls led to failure of rather soft sediments and creation of smaller debris flows that followed the main slide surficial topography. Discharge of the Hinlopen ice stream during the Last Glacial Maximum and the following deglaciation draped the central headwalls and created a fan deposit of glacigenic debris flows.