Beschreibung: Marine controlled source electromagnetic (CSEM) data have been collected to investigate methane seep sites and associated gas hydrate deposits at Opouawe Bank on the southern tip of the Hikurangi Margin, New Zealand. The bank is located in about 1000 m water depth within the gas hydrate stability field. The seep sites are characterized by active venting and typical methane seep fauna accompanied with patchy carbonate outcrops at the seafloor. Below the seeps, gas migration pathways reach from below the bottom-simulating reflector (at around 380 m sediment depth) toward the seafloor, indicating free gas transport into the shallow hydrate stability field. The CSEM data have been acquired with a seafloor-towed, electric multi-dipole system measuring the inline component of the electric field. CSEM data from three profiles have been analyzed by using 1-D and 2-D inversion techniques. High-resolution 2-D and 3-D multichannel seismic data have been collected in the same area. The electrical resistivity models show several zones of highly anomalous resistivities (〉50 Ωm) which correlate with high amplitude reflections located on top of narrow vertical gas conduits, indicating the coexistence of free gas and gas hydrates within the hydrate stability zone. Away from the seeps the CSEM models show normal background resistivities between ~1 and 2 Ωm. Archie's law has been applied to estimate gas/gas hydrate saturations below the seeps. At intermediate depths between 50 and 200 m below seafloor, saturations are between 40 and 80% and gas hydrate may be the dominating pore filling constituent. At shallow depths from 10 m to the seafloor, free gas dominates as seismic data and gas plumes suggest.

Beschreibung: Since the early discovery of a black-smoker complex in 1978 on the East Pacific Rise at 21°N, speculations and expectations have been driven about the potential and perspectives of mining seafloor massive sulfide (SMS) deposits in the deep-ocean. With a worldwide accelerating industrialization, emerging markets, increased commodity prices and metal demand, and advance¬ments in deep-water mining and extraction technologies, mining of SMS may become economically feasible in the near future (Kowalczyk, 2008). However, we still know little about the resource potential of SMS deposits, and the development of geophysical methods for an assessment of their spatial extent, composition, and inner structure is crucial to derive a proper assessment of their economic value. Novel geophysical mapping techniques and exploration strategies are required to locate extinct and buried clusters of SMS deposits, away from the active vent fields and of larger economic potential, but are difficult to find and sample by conventional methods. In 2015 the International Seabed Authority (ISA) assigned an exploration license for polymetallic sulfide deposits to the German Federal Institute for Geosciences and Natural Resources (BGR) in a specified area comprising 100 patches, each 10 . 10 km in size, distributed along the Central and Southeastern Indian Ridge. The challenge to acquire high resolution near-surface electromagnetic (EM) data in such geologically and morphologically complex mid-ocean ridge environments has been addressed by our recent development of the deep-sea profiler Golden Eye that utilizes a frequency-domain electromagnetic (FDEM) central loop sensor, of 3.3 m diameter (Müller et al., 2016). This system has been used in 2015 and 2017 to map active and relict hydrothermal vent fields in the SMS licensing areas. Aside from technological developments, this paper discusses new data processing routines and methods to unravel the conductivity-depth-distribution, induced polarization and magnetic susceptibility, and joint interpretation with geochem¬istry as key elements to map and evaluate SMS deposits.

Beschreibung: The MARCAN project, launched last January, is working to fill a gap in our knowledge of how freshwater flowing underground shapes and alters the continental margins.

Beschreibung: Several known gas seep sites along the Hikurangi Margin off the east coast of New Zealand were surveyed by marine controlled source electromagnetic (CSEM) experiments. A bottom-towed electric dipole–dipole system was used to reveal the occurrence of gas hydrate and methane related to the seeps. The experiments were part of the international multidisciplinary research program “New Vents” carried out on German R/V Sonne in 2007 (cruise SO191) to study key parameters controlling the release and transformation of methane from marine cold vents and shallow gas hydrate deposits. Two CSEM lines have been surveyed over known seep sites on Opouawe Bank in the Wairarapa region off the SE corner of the North Island. The data have been inverted to sub-seafloor apparent resistivity profiles and one-dimensional layered models. Clearly anomalous resistivities are coincident with the location of two gas seep sites, North Tower and South Tower on Opouawe Bank. A layer of concentrated gas hydrate within the uppermost 100 m below the seafloor is likely to cause the anomalous resistivities, but free gas and thick carbonate crusts may also play a role. Seismic data show evidence of fault related venting which may also indicate the distribution of gas hydrates and/or authigenic carbonate. Geochemical profiles indicate an increase of methane flux and the formation of gas hydrate in the shallow sediment section around the seep sites. Takahe is another seep site in the area where active venting, higher heat flow, shallow gas hydrate recovered from cores, and seismic fault planes, but only moderately elevated resistivities have been observed. The reasons could be a) the gas hydrate concentration is too low, even though methane venting is evident, b) strong temporal or spatial variation of the seep activity, and c) the thermal anomaly indicates rather temperature driven fluid expulsion that hampers the formation of gas hydrate beneath the vent.

Beschreibung: Porangahau Ridge, located offshore the Wairarapa on the Hikurangi Margin, is an active ocean-continent collision region in northeastern New Zealand coastal waters. Bottom simulating reflections (BSRs) in seismic data indicate the potential for significant gas hydrate deposits across this part of the margin. Beneath Porangahau Ridge a prominent high-amplitude reflection band has been observed to extend from a deep BSR towards the seafloor. Review of the seismic data suggest that this high-amplitude band is caused by local shoaling of the base of gas hydrate stability due to advective heat flow and it may constitute the location of elevated gas hydrate concentrations. During R/V Tangaroa cruise TAN0607 in 2006 heat flow probing for measurements of vertical fluid migration, sediment coring for methane concentrations, and additional seismic profiles were obtained across the ridge. In a subsequent 2007 expedition, on R/V Sonne cruise SO191, a controlled source electromagnetic (CSEM) experiment was conducted along the same seismic, geochemical, and heat flow transect to reveal the electrical resistivity distribution. CSEM data highlight a remarkable coincidence of anomalously high resistivity along the western, landward flank of the ridge which point to locally higher gas hydrate concentration above the high amplitude reflection band. Measured sediment temperature profiles, also along the western flank, consistently show non-linear and concave geothermal gradients typical of advective heat flow. Geochemical data reveal elevated methane concentrations in surface sediments concomitant with a rapid decline in sulfate concentrations indicating elevated methane flux and oxidation of methane in conjunction with sulfate reduction at the landward ridge base. Together, these data sets suggest that the western rim of Porangahau Ridge is a tectonically driven zone of rising fluids that transport methane and cause an upward inflection of the base of gas hydrate stability and the formation of locally enriched gas hydrate above the reflective zone.

Beschreibung: Highlights • First 2D CSEM study on Black Sea gas hydrates. • Joint Interpretation of marine CSEM, seismic and drilling data. • Stochastic determination of gas hydrate saturation estimates. Marine controlled source electromagnetic (CSEM) data have been analyzed as part of a larger interdisciplinary field study to reveal the distribution and concentration of gas hydrates and free gas in two working areas (WAs) in the offshore Danube fan in the western Black Sea. The areas are located in the Bulgarian sector in about 1500 m water depth (WA1) and in the Romanian sector in about 650 m water depth (WA2). Both areas are characterized by channel levee systems and wide spread occurrences of multiple bottom simulating reflections (BSRs) suggesting the presence of gas hydrates. Electrical resistivity models have been derived from two-dimensional (2D) inversions of inline CSEM data using a seafloor-towed electric dipole-dipole system. Comparing the resistivity models with coincident reflection seismic profiles reveals insight in the sediment stratigraphy of the gas hydrate stability zone (GHSZ). Gas hydrate and free gas saturation estimates have been derived with a stochastic approach of Archie's relationship considering uncertainties in the input parameters available from drilling with the MeBo-200 seafloor rig in WA2. The resistivity models generally reflect the transition of marine to lacustrine conditions expressed by a sharp decay of pore water salinities in the top 30–40 m below seafloor caused by freshwater phases of the Black Sea due to sea level low stands in the past. In WA1, we derived saturation estimates of 10–20% within a 100 m thick layer at around 50 m depth below the channel which compares well with estimates from seismic P-wave velocities. The layer extends below the western levee with even higher saturations of 20–30%, but high gas hydrate saturations are unlikely within the fine grained, clayey sediment section, and the high resistivities may reflect different lithologies of lower permeability and porosity. The resistive layer terminates below the eastern levee where increasing resistivities at depth towards a stack of multiple BSRs indicate gas hydrate and free gas concentrations in the order of 10% to locally 30%. WA2 is characterized by a major slope failure at the landward edge of the gas hydrate stability field next to the channel. Gas hydrate saturation estimates within the slump area are close to zero within the GHSZ which is in agreement with coring results of the nearby MeBo drill sites. Elevated resistivities below the steeply upward bending BSR lead to saturation estimates less than 10% of free gas that may have accumulated.

Beschreibung: Highlights • There is direct and indirect evidence for hydrate occurrence in several areas around Europe. • Hydrate is particularly widespread offshore Norway and Svalbard and in the Black Sea. • Hydrate occurrence often coincides with conventional thermogenic hydrocarbon provinces. • The regional abundance of hydrate in Europe is poorly known. Abstract Large national programs in the United States and several Asian countries have defined and characterised their marine methane hydrate occurrences in some detail, but European hydrate occurrence has received less attention. The European Union-funded project “Marine gas hydrate – an indigenous resource of natural gas for Europe” (MIGRATE) aimed to determine the European potential inventory of exploitable gas hydrate, to assess current technologies for their production, and to evaluate the associated risks. We present a synthesis of results from a MIGRATE working group that focused on the definition and assessment of hydrate in Europe. Our review includes the western and eastern margins of Greenland, the Barents Sea and onshore and offshore Svalbard, the Atlantic margin of Europe, extending south to the northwestern margin of Morocco, the Mediterranean Sea, the Sea of Marmara, and the western and southern margins of the Black Sea. We have not attempted to cover the high Arctic, the Russian, Ukrainian and Georgian sectors of the Black Sea, or overseas territories of European nations. Following a formalised process, we defined a range of indicators of hydrate presence based on geophysical, geochemical and geological data. Our study was framed by the constraint of the hydrate stability field in European seas. Direct hydrate indicators included sampling of hydrate; the presence of bottom simulating reflectors in seismic reflection profiles; gas seepage into the ocean; and chlorinity anomalies in sediment cores. Indirect indicators included geophysical survey evidence for seismic velocity and/or resistivity anomalies, seismic reflectivity anomalies or subsurface gas escape structures; various seabed features associated with gas escape, and the presence of an underlying conventional petroleum system. We used these indicators to develop a database of hydrate occurrence across Europe. We identified a series of regions where there is substantial evidence for hydrate occurrence (some areas offshore Greenland, offshore west Svalbard, the Barents Sea, the mid-Norwegian margin, the Gulf of Cadiz, parts of the eastern Mediterranean, the Sea of Marmara and the Black Sea) and regions where the evidence is more tenuous (other areas offshore Greenland and of the eastern Mediterranean, onshore Svalbard, offshore Ireland and offshore northwest Iberia). We provide an overview of the evidence for hydrate occurrence in each of these regions. We conclude that around Europe, areas with strong evidence for the presence of hydrate commonly coincide with conventional thermogenic hydrocarbon provinces.

Beschreibung: Electromagnetic loop systems rely on the use of non‐conductive materials near the sensor to minimize bias effects superimposed on measured data. For marine sensors, rigidity, compactness, and ease of platform handling are essential. Thus, commonly a compromise between rigid, cost‐effective, and non‐conductive materials (e.g. stainless steel versus fiberglass composites) needs to be found. For systems dedicated to controlled‐source electromagnetic measurements, a spatial separation between critical system components and sensors may be feasible, whereas compact multi‐sensor platforms, remotely operated vehicles, and autonomous unmanned vehicles require the use of electrically conductive components near the sensor. While data analysis and geological interpretations benefit vastly from each added instrument and multidisciplinary approaches, this introduces a systematic and platform immanent bias in the measured electromagnetic data. In this scope we present two comparable case studies targeting loop‐source electromagnetic applications in both time and frequency domain: the MARTEMIS time domain system trades the compact design for a clear separation of 15 m between an upper fiberglass frame, holding most critical titanium system components, and a lower frame with its coil and receivers. In case of the GOLDEN EYE frequency domain profiler, the compact and rigid design is achieved by a circular fiberglass platform, carrying the transmitting and receiving coils, as well as several titanium housings and instruments. In this study, we analyze and quantify the quasi‐static influence of conductive objects on time and frequency domain coil systems by applying an analytically and experimentally verified 3D finite element model. Moreover, we present calibration and optimization procedures to minimize bias inherent in the measured data. The numerical experiments do not only show the significance of the bias on the inversion results, but also the efficiency of a system calibration against the analytically calculated response of a known environment. The remaining bias after calibration is a time/frequency dependent function of seafloor conductivity, which doubles the commonly estimated noise‐floor from 1% to 2%, decreasing the sensitivity and resolution of the devices. By optimizing size and position of critical conductive system components (e.g. titanium housings) and/or modifying the transmitter/receiver geometry, we significantly reduce the effect of this residual bias on the inversion results as demonstrated by 3D‐modelling. These procedures motivate the opportunity to design dedicated, compact, low‐bias platforms and provide a solution for autonomous and remotely steered designs by minimizing their effect on the sensitivity of the controlled‐source electromagnetic sensor.

Beschreibung: First reported in the 1960s, offshore freshened groundwater (OFG) has now been documented in most continental margins around the world. In this review we compile a database documenting OFG occurrences and analyse it to establish the general characteristics and controlling factors. We also assess methods used to map and characterise OFG, identify major knowledge gaps and propose strategies to address them. OFG has a global volume of 1 million km3; it predominantly occurs within 55 km of the coast and down to a water depth of 100 m. OFG is mainly hosted within siliciclastic aquifers on passive margins and recharged by meteoric water during Pleistocene sea‐level lowstands. Key factors influencing OFG distribution are topography‐driven flow, salinisation via haline convection, permeability contrasts, and the continuity/connectivity of permeable and confining strata. Geochemical and stable isotope measurements of pore waters from boreholes have provided insights into OFG emplacement mechanisms, while recent advances in seismic reflection, electromagnetic surveys and mathematical models have improved our understanding of OFG geometry and controls. Key knowledge gaps, such as the extent and function of OFG, and the timing of their emplacement, can be addressed by the application of isotopic age tracers, joint inversion of electromagnetic and seismic reflection data, and development of three‐dimensional hydrological models. We show that such advances, combined with site‐specific modelling, are necessary to assess the potential use of OFG as an unconventional source of water and its role in sub‐seafloor geomicrobiology.