Description: Drilling at Integrated Ocean Drilling Program Site U1381 on the Cocos Ridge offshore Costa Rica recovered 67 primary Miocene (ca. 8 Ma to ca. 16.5 Ma) marine fallout ash layers. Geochemical, volcanological, and geological criteria link these ashes to Plinian eruptions that carried ash to at least 50–450 km from the Galápagos hotspot. These ash layers are the first documentation of highly explosive Miocene Galápagos hotspot volcanism. This volcanism is bimodal with two-thirds of the tephra layers generated by basaltic magmas (glass compositions 〈57 wt% SiO2) and one-third by rhyolitic magmas. The temporal distribution of the tephra layers, inferred from sediment accumulation rates calibrated by 40Ar/39Ar and biostratigraphic ages, reveals a distinct increase in eruption frequency and hence increased volcanic activity of the Galápagos hotspot after 14 Ma which we interpret in the context of dynamic interaction between the Galápagos plume and spreading ridge.

Description: We have applied a combination of fluid inclusion and amphibole thermobarometry to felsic tephras from highly explosive volcanic eruptions along the Central American volcanic arc (CAVA) from Guatemala through Nicaragua in order to constrain pre-eruptive magma ascent and storage conditions. We note that this is the first time a combination of pressure estimates from fluid inclusions and amphibole chemistry have been used to quantify multi-stage magma chamber processes and magma ascent velocities of large eruptions. Our data document a stepwise ascent of magmas through the crust, typically involving at least two levels of stagnation. Amphibole and fluid inclusion thermobarometry both indicate a shallow preeruptive magma storage level at 80 to 200 MPa (3-8 km depth) along the entire arc. The deeper levels of magma storage vary along-arc, with a tendency to greater maximum depths of up to 25 km in Guatemala and El Salvador, compared to maximum depths of 15 km in Nicaragua. We assume that the continental crust of about 45 km thickness in Guatemala, compared to the 30km thickness of the largely oceanic crust of Nicaragua, allowed for deeper positions of the magma chambers. Thus the observed along-arc changes in mid-crustal magma storage depths indicate a dependence between magma chamber formation and the composition and probably density of the local crust. The average composition of the pre-eruptive fluid phase for highly explosive eruptions in Central America amounts to 90% water, 5% CO2 and 5% NaCl equivalents, and show no systematic alongarc variations. The pressures obtained from the earliest fluid inclusions were taken as the pressures of fluid oversaturation and thus for the beginning of degassing. They range between 150 and 400 MPa, and do not show systematic along-arc variations. Such fluid oversaturation pressures correspond to water contents between 4-8 wt% in the felsic melts. Our results show that the depths of fluid saturation are mostly independent of crustal properties. Degassing typically started at pressures 150 to 300 MPa higher that those corresponding to the last stagnation level, providing evidence for the pre-eruptive criticality of the systems.

Description: Large explosive volcanic eruptions inject gases, aerosols, and fine ashes into the stratosphere, potentially influencing climate. Emissions of chlorine (Cl) and bromine (Br) from such large eruptions play an important role for catalytic destruction of ozone in the stratosphere, but hitherto the global effects of simultaneous catastrophic release of volcanic Br and Cl into the stratosphere have not been investigated. The Br release from 14 large explosive eruptions throughout Nicaragua covering an entire subduction zone segment in the past 70 ka was determined with petrologic methods. Melt inclusions in volcanic phenocrysts were analyzed using a new optimized synchrotron–X-ray fluorescence microprobe set-up. Single eruptions produced Br outputs of 4–600 kt, giving an average Br emission of 27 kt per eruption. Using the assumption that 10% of the emitted halogens reach the stratosphere, the average Br and Cl loading to the stratosphere would be 3 ppt and 1500 ppt, respectively, which together would account for 185% of the preindustrial equivalent effective stratospheric Cl loading. We thus conclude that many large tropical volcanic eruptions had and have the potential to substantially deplete ozone on a global scale, eventually forming future ozone holes.

Description: At convergent margins, fluids rise through the forearc in response to consolidation of the upper plate and dewatering of the subducting plate, and produce various cold-seep–related features on the seafloor (mud diapirs, mud mounds). At the Central American forearc, authigenic carbonates precipitated from rising fluids within such structures during active venting while typical mixed-mud sediments were ejected onto the surrounding seafloor where they became intercalated with normal pelagic background sediments, indicating that mud mounds evolved unsteadily through alternating active and inactive phases. Intercalated regional ash layers from Plinian eruptions at the Central American volcanic arc provide time marks that constrain the ages of mud ejection activity. U/Th dating of drill core samples of authigenic carbonate caps of mud mounds yields ages agreeing well with those constrained by ash layers and showing that carbonate caps grow inward rather than outward during active venting. Both dating approaches show that offshore Nicaragua and Costa Rica (1) active and inactive phases can occur simultaneously at neighboring mounds, (2) mounds along the forearc have individual histories of activity, but there are distinct time intervals when nearly all mounds have been active or inactive, (3) lifetimes of mounds reach several hundred thousand years, and (4) highly active periods last 10–50 k.y. with intervening periods of 〉10 k.y. of relative quiescence.

Description: Volcanic islands export clastic material to their surrounding oceans by explosive eruptions, lava emissions, biogenic production on their shelves, and failure of their slopes, amongst other processes. This raises the question of whether geological events (in particular, eruptions and landslides) can be detected offshore and dated, and whether any relationships (for example, with climate changes) can be revealed using sediment cores. The volcanically active central Azorean islands (Faial, Pico, São Jorge, and Terceira), with their neighboring submarine basins, are potentially good candidates for such an analysis. Here, chronostratigraphies of four gravity cores collected amongst the islands are constructed based on twelve radiocarbon dates and two dates derived by geochemically correlating primary volcaniclastic turbidites with ignimbrites on Faial and Terceira Islands. Age-depth models are built from the hemipelagic intervals to estimate individual turbidite dates. Volumes of turbidites are modeled by multiplying basin areas with bed thickness, allowing for various turbidite thinning rates and directions. The volumes of landslide-generated turbidites are only comparable with the largest volumes of their adjacent upper-slope submarine landslide valleys; therefore, such turbidites in the cores likely derive from these largest landslides. Emplacement intervals between turbidites originating from both landslides and pyroclastic density currents are found to be mostly a few thousand years. Frequencies of landslide-generated turbidites and hemipelagic sedimentation rates were both highest in the past 8 k.y. compared to preceding periods up to 50 k.y. High hemipelagic sedimentation rates are interpreted to be related to sea-level rise, allowing more shelf bioproduction and release of particles by coastal erosion. The coincident increased frequencies of submarine landslides may also be associated with the increased sediment supply from the islands, resulting in a more rapid build-up of unstable sediments on submarine slopes. Notably, the emplacement frequencies of turbidites of pyroclastic density current origins do not suggest the decreased eruption frequency toward the Holocene that has been found elsewhere.

Description: The Lonquimay Volcanic Complex (LVC) in South Central Chile (38.38°S, 71.58°W) is part of the Southern Volcanic Zone of the Andes, which formed in response to the subduction of the Nazca Plate beneath the South American Plate. During the last 10200+-70 years of its magmatic evolution, the LVC produced 23 explosive eruptions documented in the succession of widespread tephra deposits. We investigated this stratigraphic sequence for matrix glass, mineral and bulk rock compositions of the juvenile components. Furthermore, melt inclusions were analyzed for their major element and volatile contents. The tephra succession reflects six mafic replenishments of the LVC magma reservoir followed by progressive magmatic differentiation. Each cycle has been successively tapped by several eruptions. Compositionally zoned tephras were typically deposited early in a cycle, whereas late eruptions discharged more evolved magmas. Intermediate compositions typically contain mixed disequilibrium mineral assemblages. The maximum degree of fractionation reached during a cycle increases with younger ages. Our investigations of melt inclusions, in order to reconstruct the pre-eruptive volatile inventories of the LVC magma chamber, reveal the exsolution of two separate fluid phases. One S-rich fluid phase released from mafic melts in the middle crust and one Cl-rich aqueous phase, released from more ifferentiated melts that resided in the upper part of LVC´s plumbing system. The pre-eruptive saturation state of the LVC melts indicates that felsic eruptions may have been triggered by H2O-supersaturation whereas mafic melts seem to have experienced a complex replenishment history potentially exciting LVC´s mafic eruptions.

Description: The Lonquimay Volcanic Complex (LVC) in the high Southern Andes comprises a stratocone and NEtrending flank-cone alignments. Numerous effusive and explosive volcanic eruptions characterize its post-glacial magmatic activity. Our tephrostratigraphic record, pre-dating the four historically documented eruptions, comprises 22 dated pyroclastic deposits that are used to constrain repose time distribution and eruption probability of the LVC magmatic system. Statistical examination of the stratigraphy-based eruption time series yields probabilities of 20-50% for at least one explosive (VEI"3) eruption within the next 100 years as of 2011. The tephra deposits are subdivided into three petrographic groups: a felsic group (Lonquimay Colored Pumice Tephra, LCPT), an intermediate population (Lonquimay Grey Pumice Tephra, LGPT) and a mafic member (Lonquimay Dark Scoria Tephra, LDST). The distribution of these petrographic groups through the LVC tephrostratigraphy is linked to the observed changes in repose times. LDST deposits as well as deposits compositionally zoned from LCPT to LGPT dominate the lower part of the stratigraphy for which recurrence times are short (RTmean=417±169a). Deposits younger than 6000 b2k (years before 2000 AD) have dominantly LCPT and minor LDST compositions, no longer contain LGPT, and repose times are significantly longer (RTmean=1350±310a). We interpret the change in eruption regime to result from a rearrangement in the magma storage and plumbing system. Thermobarometric calculations based on cpx liquid equilibria and amphibole compositions reveal three distinct magma storage levels: the mafic LDST derive from mid crustal storage (Pmean= 476±95 MPa, Tmean=1073±24°C), felsic LCPT mainly erupted from upper-crustal level (Pmean= 86±49 MPa , Tmean=936±24°C), whereas LGPT samples yield intermediate storage depths (Pmean= 239±100 MPa, Tmean=1013±17°C). Magma contributions from this intermediate reservoir are restricted to 〉6000 b2k when the Lonquimay plumbing system was in a regime of short repose times; disappearance of the intermediate reservoir coincides with the change to longer repose times between eruptions.