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  • American Geophysical Union  (8)
  • Copernicus Publications on behalf of the European Geosciences Union  (1)
  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 5 (2004): Q01B06, doi:10.1029/2003GC000619.
    Description: We quantitatively analyze the area-age distribution of sedimentary, igneous and metamorphic bedrock based on data from the most recent digital geologic maps of East and Southeast Asia (Coordinating Committee for Coastal and Offshore Geosciences Programmes in East and Southeast Asia (CCOP) and the Geologic Survey of Japan, 1997; 1:2,000,000), published as Digital Geoscience Map G-2 by the Geological Survey of Japan. Sedimentary rocks, volcanic rocks, plutonic rocks, ultramafic rocks and metamorphic rocks cover 73.3%, 8.5%, 8.8%, 0.9%, and 8.6% of the surface area, respectively. The average ages of major lithologic units, weighted according to bedrock area, are as follows: sedimentary rocks (average stratigraphic age of 123 Myr/median age of 26 Myr), volcanic rocks (84 Myr/20 Myr), intrusive rocks (278 Myr/195 Myr), ultramafic rocks (unknown) and metamorphic rocks (1465 Myr/1118 Myr). The variability in lithologic composition and age structure of individual countries reflects the complex tectonic makeup of this region that ranges from Precambrian cratons (e.g., northeast China and North Korea) to Mesozoic-Cenozoic active margins (e.g., Japan, the Philippines, Indonesia and New Guinea). The spatial resolution of the data varies from 44 km2 per polygon (Japan) to 1659 km2 per polygon (Taiwan) and is, on average (490 km2/polygon), similar to our previous analyses of the United States of America and Canada. The temporal and spatial resolution is sufficiently high to perform age-area analyses of individual river basins larger than ∼10,000 km2 and to quantitatively evaluate the relationship between bedrock geology and river chemistry. As many rivers draining tropical, mountainous islands of East and Southeast Asia have a disproportionate effect on the dissolved and particulate load delivered to the world oceans, bedrock geology in such river drainage basins disproportionately affect ocean chemistry.
    Description: Financial support was provided through the U.S. National Science Foundation (NSF-EAR-0125873) to BPE.
    Repository Name: Woods Hole Open Access Server
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 8 (2007): Q06009, doi:10.1029/2006GC001544.
    Description: We quantitatively analyze the area-age distribution of sedimentary, extrusive volcanic, and endogenous (plutonic and/or metamorphic) bedrock on the basis of data from the most recent digital Geological Map of the World at a scale of 1:25,000,000. The spatial resolution of the digital bedrock data averages 13,905 km2 per polygon. Comparison of certain regions of the world, previously analyzed at higher spatial resolution, with the low-resolution world data reveals general consistency in the areal exposure of major rock types as well as a minor systematic bias toward older average bedrock ages in the global data set. Application of the global bedrock data to 19 large-scale drainage regions and three large, internally drained regions reveals considerable regional variability of Earth's bedrock geology that is consistent with the dominant geotectonic setting of the respective drainage region.
    Description: B.P.E. acknowledges financial support from the United States National Science Foundation (NSF-EAR- 0125873) and from the Woods Hole Oceanographic Institution.
    Keywords: Geologic map ; World ; Age ; Bedrock ; Sediment ; Volcanic rock
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 10 (2009): Q06014, doi:10.1029/2008GC002356.
    Description: The Land2Sea database contains data on the sizes of 1519 exorheic river drainage basins (79% of the exorheic land area), annual suspended sediment fluxes (593 rivers, 63% of the exorheic land area), and water discharges (1272 rivers, 76% of the exorheic land area) that have been compiled from a variety of sources. The database extends earlier compilations, such as GEMS/GLORI. The river basins are grouped into 19 large-scale drainage regions to investigate the regional variability in freshwater and sediment fluxes to various ocean basins. The annual suspended sediment flux to the coastal ocean (~18.5 × 109 tons) is dominated by east Asia (6.1 × 109 tons); Arabia, India, and southeast Asia (4.3 × 109 tons); and eastern South America (2.4 × 109 tons). Small topical islands of Oceania support the highest annual sediment fluxes per drainage area (~9650 t km−2 a−1). Annual freshwater discharge to the coastal ocean (~38,857 km3) is dominated by runoff from eastern South America (11,199 km3); east Asia (7114 km3); and Arabia, India, and southeast Asia (4384 km3). The empirical data agree well with results from global models (ART and BQART) that have been trained on a subset of the data compiled here.
    Description: The Woods Hole Oceanographic Institution, the U.S. National Science Foundation (grants EAR-0519387 and OCE-0851015), and the French CNRS (Observatoire Midi- Pyre´ne´es in Toulouse, France) funded this work.
    Keywords: River ; Database ; Water discharge ; Runoff ; Suspended sediment ; Drainage basin area
    Repository Name: Woods Hole Open Access Server
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  • 4
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    American Geophysical Union
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 8 (2007): Q05014, doi:10.1029/2006GC001505.
    Description: We quantitatively analyze the area-age distribution of sedimentary, igneous, metamorphic, and ultramafic bedrock on the basis of data from the digital geologic map of Brazil, published as a GIS map by the Brazilian Geological Survey. Bedrock units exclusively encompassing sedimentary rocks, igneous rocks, or metamorphic rocks cover 40.4%, 31.5%, and 17.7%, respectively, of the total bedrock area. These numbers have to be considered minimum estimates of the areal abundance of sedimentary, igneous, and metamorphic bedrock because polygons defined by mixed lithologies cover ~8.5–9.5% of the total bedrock area. These mixed units are sedimentary rocks with igneous and/or metamorphic contributions (1.4%), metamorphic rocks with sedimentary contributions (1.2%), metamorphic rocks with igneous contributions (1.5%), igneous rocks with sedimentary and/or metamorphic contributions (4.4%), and ultramafic units with sedimentary, igneous, and/or metamorphic contributions (~1–2%). The average ages of major lithologic units, weighted according to bedrock area, are as follows: sedimentary rocks (average stratigraphic age of 248 ± 5 [1σ] Myr; median stratigraphic age of 87.5 Myr), igneous rocks (1153 ± 13 [1σ] Myr), metamorphic rocks (1678 ± 30 [1σ] Myr), and ultramafic rocks (~1227 ± 25 [1σ] Myr). The average bedrock age of Brazil is 946 ± 7 [1σ] Myr. The range in lithologic composition and age structure of the various bedrock units reflects the complex tectonic makeup of Brazil that ranges from Neogene sedimentary cover in the Amazon Basin to Precambrian cratons (Guyana and Brazilian shields) and Transamazonian greenstone belts. The average spatial resolution of the data is 232 km2 polygon−1 and is sufficient to perform area-age analyses of individual river drainage basins larger than ~5,000 km2.
    Description: B.P.E. acknowledges financial support from the U.S. National Science Foundation (NSF-EAR-0125873) and the Woods Hole Oceanographic Institution.
    Keywords: Geologic map ; Brazil ; Age ; Bedrock ; Sediment
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 11 (2010): Q03016, doi:10.1029/2009GC002869.
    Description: Realistic models of past climate and ocean chemistry depend on reconstructions of the Earth's surface environments in the geologic past. Among the critical parameters is the geologic makeup of continental drainage. Here we show, for the present, that the isotope composition of dissolved strontium in rivers increases linearly with the age of bedrock in drainage basins, with the notable exception of the drainage area of Arabia, India, and Southeast Asia that is affected by unusually radiogenic dissolved Sr from the Himalaya. We also demonstrate that the neodymium isotope compositions of suspended matter in rivers as well as clastic sediments deposited along the ocean margins decrease linearly with the bedrock ages of river drainage basins and large-scale continental drainage regions, as determined from digital geologic maps. These correlations are used to calculate the present-day input of dissolved Sr (4.7 × 1010 mol yr−1, 87Sr/86Sr of ∼0.7111) and particulate Nd isotopes (ɛNd of approximately −7.3 ± 2.2) to the oceans. The fact that the regionally averaged ɛNd of the global detrital input to the global coastal ocean is identical to globally averaged seawater (ɛNd of −7.2 ± 0.5) lends credence to the importance of “boundary exchange” for the Nd isotope composition of water masses. Regional biases in source areas of detrital matter and runoff are reflected by the observation that the average age of global bedrock, weighted according to the riverine suspended sediment flux, is significantly younger (∼336 Myr) than the age of global bedrock weighted according to water discharge (394 Myr), which is younger than the average bedrock age of the nonglaciated, exorheic portions of the continents (453 Myr). The observation that the bedrock age weighted according to Sr flux is younger (339 Myr) than that weighted according to water flux reflects the disproportionate contribution from young sedimentary and volcanic rocks to the dissolved Sr load. Neither the isotope composition of the dissolved nor the particulate continental inputs to the ocean provide unbiased perspectives of the lithologic makeup of the Earth's surface. Temporal changes in bedrock geology as well as the shifting focal points of physical erosion and water discharge will undoubtedly have exerted strong controls on temporal and spatial changes in the isotope chemistry of past global runoff and thus seawater.
    Description: NSF grants EAR‐ 0125873, EAR‐0519387, and OCE‐0851015 to B.P.‐E. and a CNRS‐funded “poste rouge” position for B.P.‐E. at the Observatoire Midi‐Pyrénées in Toulouse supported this work.
    Keywords: Seawater ; River ; Strontium ; Neodymium ; Isotope ; Continental runoff
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 35(4), (2021): e2020GB006895, https://doi.org/10.1029/2020GB006895.
    Description: The Amazon River drains a diverse tropical landscape greater than 6 million km2, culminating in the world's largest export of freshwater and dissolved constituents to the ocean. Here, we present dissolved organic carbon (DOC), organic and inorganic nitrogen (DON, DIN), orthophosphate (PO43−), and major and trace ion concentrations and fluxes from the Amazon River using 26 samples collected over three annual hydrographs. Concentrations and fluxes were predominantly controlled by the annual wet season flood pulse. Average DOC, DON, DIN, and PO43− fluxes (±1 s.d.) were 25.5 (±1.0), 1.14 (±0.05), 0.82 (±0.03), and 0.063 (±0.003) Tg yr−1, respectively. Chromophoric dissolved organic matter absorption (at 350 nm) was strongly correlated with DOC concentrations, resulting in a flux of 74.8 × 106 m−2 yr−1. DOC and DON concentrations positively correlated with discharge while nitrate + nitrite concentrations negatively correlated, suggesting mobilization and dilution responses, respectively. Ammonium, PO43−, and silica concentrations displayed chemostatic responses to discharge. Major and trace ion concentrations displayed clockwise hysteresis (except for chloride, sodium, and rubidium) and exhibited either dilution or chemostatic responses. The sources of weathered cations also displayed seasonality, with the highest proportion of carbonate- and silicate-derived cations occurring during peak and baseflow, respectively. Finally, our seasonally resolved weathering model resulted in an average CO2 consumption yield of (3.55 ± 0.11) × 105 mol CO2 km−2 yr−1. These results represent an updated and temporally refined quantification of dissolved fluxes that highlight the strong seasonality of export from the world's largest river and set a robust baseline against which to gauge future change.
    Description: This work was supported by a grant from the Harbourton Foundation to R. G. M. Spencer and R. M. Holmes. T. W. Drake was supported by ETH Zurich core funding to J. Six. R. G. M. Spencer was additionally supported by NSF OCE-1333157.
    Description: 2021-09-15
    Keywords: Amazon river ; Dissolved organic carbon ; Fluxes ; Weathering ; Geochemistry
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2022-05-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 35(6), (2021): e2021GB006938, https://doi.org/10.1029/2021GB006938.
    Description: As climate-driven El Niño Southern Oscillation (ENSO) events are projected to increase in frequency and severity, much attention has focused on impacts regarding ecosystem productivity and carbon balance in Amazonian rainforests, with comparatively little attention given to carbon dynamics in fluvial ecosystems. In this study, we compared the wet 2012 La Niña period to the following normal hydrologic period in the Amazon River. Elevated water flux during the La Niña period was accompanied by dilution of inorganic ion concentrations. Furthermore, the La Niña period exported 2.77 Tg C yr−1 more dissolved organic carbon (DOC) than the normal period, an increase greater than the annual amount of DOC exported by the Mississippi River. Using ultra-high-resolution mass spectrometry, we detected both intra- and interannual differences in dissolved organic matter (DOM) composition, revealing that DOM exported during the dry season and the normal period was more aliphatic, whereas compounds in the wet season and following the La Niña event were more aromatic, with ramifications for its environmental role. Furthermore, as this study has the highest temporal resolution DOM compositional data for the Amazon River to-date we showed that compounds were highly correlated to a 6-month lag in Pacific temperature and pressure anomalies, suggesting that ENSO events could impact DOM composition exported to the Atlantic Ocean. Therefore, as ENSO events increase in frequency and severity into the future it seems likely that there will be downstream consequences for the fate of Amazon Basin-derived DOM concurrent with lag periods as described here.
    Description: This work was partially supported by National Science Foundation grant OCE-1464396 to Robert G. M. Spencer and funding from the Harbourton Foundation to Robert G. M. Spencer, R. Max Holmes, and Bernhard Peucker-Ehrenbrink.
    Description: 2021-12-11
    Keywords: Amazon river ; carbon cycling ; dissolved organic carbon ; dissolved organic matter ; ENSO ; FT-ICR MS
    Repository Name: Woods Hole Open Access Server
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  • 8
    Publication Date: 2022-05-26
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Biogeosciences 12 (2015): 5597-5618, doi:10.5194/bg-12-5597-2015.
    Description: Rapid changes in the volume and sources of discharge during the spring freshet lead to pronounced variations in biogeochemical properties in snowmelt-dominated river basins. We used daily sampling during the onset of the freshet in the Fraser River (southwestern Canada) in 2013 to identify rapid changes in the flux and composition of dissolved material, with a focus on dissolved organic matter (DOM). Previous time series sampling (at twice monthly frequency) of dissolved inorganic species in the Fraser River has revealed smooth seasonal transitions in concentrations of major ions and tracers of water and dissolved load sources between freshet and base flow periods. In contrast, daily sampling reveals a significant increase in dissolved organic carbon (DOC) concentration (200 to 550 μmol L−1) occurring over a matter of days, accompanied by a shift in DOM optical properties, indicating a transition towards higher molecular weight, more aromatic DOM composition. Comparable changes in DOM composition, but not concentration, occur at other times of year, underscoring the role of seasonal climatology in DOM cycling. A smaller data set of total and dissolved Hg concentrations also showed variability during the spring freshet period, although dissolved Hg dynamics appear to be driven by factors beyond DOM as characterized here. The time series records of DOC and particulate organic carbon (POC) concentrations indicate that the Fraser River exports 0.25–0.35 % of its annual basin net primary productivity. The snowmelt-dominated hydrology, forested land cover, and minimal reservoir impoundment of the Fraser River may influence the DOC yield of the basin, which is high relative to the nearby Columbia River and of similar magnitude to that of the Yukon River to the north. Anticipated warming and decreased snowfall due to climate changes in the region may cause an overall decrease in DOM flux from the Fraser River to the coastal ocean in coming decades
    Description: This work was partially supported by a WHOI Ocean Ventures Fund award to BMV and NSF grants EAR-1226818 to BPE, OCE-0851015 to TIE, BPE, and VG, and OCE-0851101 to RGMS, and support to BPE from Jane and James Orr.
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  • 9
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 125(1), (2020): e2019JG005414, doi:10.1029/2019JG005414.
    Description: A survey of 25 coastal‐draining rivers across the Canadian Arctic Archipelago (CAA) shows that these systems are distinct from the largest Arctic rivers that drain watersheds extending far south of the Arctic circle. Observations collected from 2014 to 2016 illustrate the influences of seasonal hydrology, bedrock geology, and landscape physiography on each river's inorganic geochemical characteristics. Summertime data show the impact of coincident gradients in lake cover and surficial geology on river geochemical signatures. In the north and central CAA, drainage basins are generally smaller, underlain by sedimentary bedrock, and their hydrology is driven by seasonal precipitation pulses that undergo little modification before they enter the coastal ocean. In the southern CAA, a high density of lakes stores water longer within the terrestrial system, permitting more modification of water isotope and geochemical characteristics. Annual time‐series observations from two CAA rivers reveal that their concentration‐discharge relationships differ compared with those of the largest Arctic rivers, suggesting that future projections of dissolved ion fluxes from CAA rivers to the Arctic Ocean may not be reliably made based on compositions of the largest Arctic rivers alone, and that rivers draining the CAA region will likely follow different trajectories of change under a warming climate. Understanding how these small, coastal‐draining river systems will respond to climate change is essential to fully evaluate the impact of changing freshwater inputs to the Arctic marine system.
    Description: This work was only possible through a network of enthusiastic and devoted collaborators. Partners included Polar Knowledge Canada and the Canadian High Arctic Research Station, the Arctic Research Foundation, the Kugluktuk Angoniatit Association, and the Canadian Arctic GEOTRACES Program. We acknowledge support from the Department of Fisheries and Oceans Canada, the Woods Hole Oceanographic Institution Coastal Ocean Institute, The G. Unger Vetlesen Foundation, Jane and James Orr, and the Woods Hole Research Center. Many thanks go to Austin Maniyogena, Angulalik Pedersen, Adrian Schimnowski, JS Moore, Les Harris, Oksana Schimnowski, as well as Barbara Adjun, Amanda Dumond, and Johnny Nivingalok, and the captains and crew of the research vessels CCGS Amundsen and R/V Martin Bergmann, all of whom supported our research and helped with sample collection. Special thanks also go to Valier Galy, Zhaohui “Aleck” Wang, Marty Davelaar, Michiyo Yamamoto‐Kawai, Hugh McLean, Mike Dempsey, Baba Pedersen, Maureen Soon, Katherine Hoering, Sean Sylva, Ekaterina Bulygina, and Anya Suslova for their invaluable contributions during field program planning, preparations, and laboratory analyses. Robert Max Holmes is thanked for many fruitful discussions. We also thank several anonymous reviewers for their helpful comments on the paper's content and structure. All of the data presented in this paper can be found at https://doi.org/10.1594/PANGAEA.908497.
    Keywords: Arctic Rivers ; Geochemistry ; Major ion chemistry ; Stable isotopes ; Northern hydrology
    Repository Name: Woods Hole Open Access Server
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