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  • ACS (American Chemical Society)  (1)
  • Elsvier  (1)
  • Kiel : GEOMAR Helmholtz-Zentrum für Ozeanforschung Kiel  (1)
  • 2020-2024  (3)
  • 1
    Online Resource
    Online Resource
    MiningImpact 2 - Environmental impacts and risks of deep-sea mining : Abschlussbericht : Vorhabenbezeichnung: Mn-Monstr - Monitoringkonzepte für einen Manganknollenabbau in der Tiefsee : Laufzeit des Vorhabens: 1.8.2018-28.2.2022 (2022)
    Kiel : GEOMAR Helmholtz-Zentrum für Ozeanforschung Kiel
    Details Availability
    Keywords: Forschungsbericht ; Meeresbergbau ; Umweltbelastung
    Type of Medium: Online Resource
    Pages: 1 Online-Ressource (39 Seiten, 1,58 MB) , Illustrationen, Diagramme
    URL: https://edocs.tib.eu/files/e01fb23/1867481707.pdf
    URL: https://doi.org/10.2314/KXP:1867481707
    DOI: 10.2314/KXP:1867481707
    Language: German , English
    Note: Unterschiede zwischen dem gedruckten Dokument und der elektronischen Ressource können nicht ausgeschlossen werden , Förderkennzeichen BMBF 03F0812A , Verbundnummer 01183428 , Sprache der Kurzfassungen: Deutsch, Englisch
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  • 2
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    Production Method under Surveillance: Laboratory Pilot-Scale Simulation of CH 4 –CO 2 Exchange in a Natural Gas Hydrate Reservoir (2021)
    ACS (American Chemical Society)
    Details
    Publication Date: 2024-02-07
    Description: The "guest exchange"of methane (CH4) by carbon dioxide (CO2) in naturally occurring gas hydrates is seen as a possibility to concurrently produce CH4 and sequester CO2. Presently, process evaluation is based on CH4-CO2 exchange yields of small-or medium-scale laboratory experiments, mostly neglecting mass and heat transfer processes. This work investigates process efficiencies in two large-scale experiments (210 L sample volume) using fully water-saturated, natural reservoir conditions and a gas hydrate saturation of 50%. After injecting 50 kg of heated CO2 discontinuously (E1) and continuously (E2) and a subsequent soaking period, the reservoir was depressurized discontinuously. It was monitored using electrical resistivity, temperature and pressure sensors, and fluid flow and gas composition measurements. Phase and component inventories were analyzed based on mass and volume balances. The total CH4 production during CO2 injection was only 5% of the initial CH4 inventory. Prior to CO2 breakthrough, the produced CH4 roughly equaled dissolved CH4 in the produced pore water, which balanced the volume of the injected CO2. After CO2 breakthrough, CH4 ratios in the released CO2 quickly dropped to 2.0-0.5 vol %. The total CO2 retention was the highest just before the CO2 breakthrough and higher in E1 where discontinuous injection improved the distribution of injected CO2 and subsequent mixed hydrate formation. The processes were improved by the succession of CO2 injection by controlled degassing at stability limits below that of the pure CH4 hydrate, particularly in experiment E2. Here, a more heterogeneous distribution of liquid CO2 and larger availability of free water led to smaller initial degassing of liquid CO2. This allowed for quick re-formation of mixed gas hydrates and CH4 ratios of 50% in the produced gases. The experiments demonstrate the importance of fluid migration patterns, heat transport, sample inhomogeneity, and secondary gas hydrate formation in water-saturated sediments.
    Type: Article , PeerReviewed
    Format: text
    Format: text
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    OceanRep: Article in a Scientific Journal - peer-reviewed
  • 3
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    Sediment acidification and temperature increase in an artificial CO2 vent (2021)
    Elsvier
    Details
    Publication Date: 2024-02-07
    Description: Highlights • A mechanistic explanation is provided for the observed CO2 loss in the sediments. • Reactions of CO2 with the sediment lead to significant heating. • The observations were modeled including reactions and losses due to lateral transport. • CO2 leakage will lead to very local effects. Abstract We investigated the effect of an artificial CO2 vent (0.0015−0.037 mol s−1), simulating a leak from a reservoir for carbon capture and storage (CCS), on the sediment geochemistry. CO2 was injected 3 m deep into the seafloor at 120 m depth. With increasing mass flow an increasing number of vents were observed, distributed over an area of approximately 3 m. In situ profiling with microsensors for pH, T, O2 and ORP showed the geochemical effects are localized in a small area around the vents and highly variable. In measurements remote from the vent, the pH reached a value of 7.6 at a depth of 0.06 m. In a CO2 venting channel, pH reduced to below 5. Steep temperature profiles were indicative of a heat source inside the sediment. Elevated total alkalinity and Ca2+ levels showed calcite dissolution. Venting decreased sulfate reduction rates, but not aerobic respiration. A transport-reaction model confirmed that a large fraction of the injected CO2 is transported laterally into the sediment and that the reactions between CO2 and sediment generate enough heat to elevate the temperature significantly. A CO2 leak will have only local consequences for sediment biogeochemistry, and only a small fraction of the escaped CO2 will reach the sediment surface.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Format: text
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    OceanRep: Article in a Scientific Journal - peer-reviewed
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