GLORIA

GEOMAR Library Ocean Research Information Access

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
Document type
Keywords
Language
  • 1
    In: Marine chemistry, Amsterdam [u.a.] : Elsevier Science, 1972, 107(2007), 4, Seite 498-515, 0304-4203
    In: volume:107
    In: year:2007
    In: number:4
    In: pages:498-515
    Description / Table of Contents: Two newly developed coring devices, the Multi-Autoclave-Corer and the Dynamic Autoclave Piston Corer were deployed in shallow gas hydrate-bearing sediments in the northern Gulf of Mexico during research cruise SO174 (Oct- Nov 2003). For the first time, they enable the retrieval of near-surface sediment cores under ambient pressure. This enables the determination of in situ methane concentrations and amounts of gas hydrate in sediment depths where bottom water temperature and pressure changes most strongly influence gas/hydrate relationships. At seep sites of GC185 (Bush Hill) and the newly discovered sites at GC415, we determined the volume of low-weight hydrocarbons (C1 through C5) from nine pressurized cores via controlled degassing. The resulting in situ methane concentrations vary by two orders of magnitudes between 0.031 and 0.985 mol kg -1 pore water below the zone of sulfate depletion. This includes dissolved, free, and hydrate-bound CH4. Combined with results from conventional cores, this establishes a variability of methane concentrations in close proximity to seep sites of five orders of magnitude. In total four out of nine pressure cores had CH4 concentrations above equilibrium with gas hydrates. Two of them contain gas hydrate volumes of 15% (GC185) and 18% (GC415) of pore space. The measurements prove that the highest methane concentrations are not necessarily related to the highest advection rates. Brine advection inhibits gas hydrate stability a few centimeters below the sediment surface at the depth of anaerobic oxidation of methane and thus inhibits the storage of enhanced methane volumes. Here, computerized tomography (CT) of the pressure cores detected small amounts of free gas. This finding has major implications for methane distribution, possible consumption, and escape into the bottom water in fluid flow systems related to halokinesis.
    Type of Medium: Online Resource
    Pages: Ill., graph. Darst
    ISSN: 0304-4203
    Language: English
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 2
    In: Global biogeochemical cycles, Hoboken, NJ : Wiley, 1987, 19(2005), 1944-9224
    In: volume:19
    In: year:2005
    In: extent:21
    Type of Medium: Online Resource
    Pages: 21 , graph. Darst
    ISSN: 1944-9224
    Language: English
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 3
    In: Geochemistry, geophysics, geosystems, Hoboken, NJ : Wiley, 2000, 10(2009), 11, 1525-2027
    In: volume:10
    In: year:2009
    In: number:11
    In: extent:21
    Description / Table of Contents: We report on a bathymetric mapping and remotely operated vehicle surveys along the 100600 m region offshore Oregon from 43ʿ50?N to 44°18'N. We interpret our results in light of available geophysical data, published geotectonic models, and analogous observations of fluid venting and carbonate deposition from 44°30'N to 45°00'N. The methane seepage is defined by juxtaposition of a young prism, where methane is generated by bacterial activity and its release is modulated by gas hydrate dynamics, against older sequences that serve as a source of thermogenic hydrocarbons that vent in the shelf. We hypothesize that collision of a buried ridge with the Siletz Terrane results in uplift of gas hydrate bearing sediments in the oncoming plate and that the resulting decrease in pressure leads to gas hydrate dissociation and methane exolution, which, in turn, may facilitate slope failure. Oxidation of the released methane results in precipitation of carbonates that are imaged as high backscatter along a 550 ± 60 m benthic corridor.
    Type of Medium: Online Resource
    Pages: 21 , Ill., graph. Darst
    ISSN: 1525-2027
    Language: English
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 4
    Keywords: Dissertation ; Hochschulschrift ; Weddellmeer ; Methan ; Kreislauf ; Cascade Range ; Kontinentalrand ; Methan ; Kreislauf ; Plattengrenze ; Meeresströmung ; Costa Rica ; Kontinentalrand ; Konvergente Plattengrenze ; Methan ; Kreislauf ; Pazifischer Ozean
    Type of Medium: Online Resource
    Pages: 1 Online-Ressource (193 Seiten = 16 MB) , Illustrationen, Graphen, Karten
    Edition: Online-Ausgabe 2023
    Language: English
    Note: Enth. Zeitschriftenaufsätze
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 5
    Publication Date: 2023-03-03
    Keywords: 140; 157-1; 169; Area/locality; Bush Hill; Campeche Knoll; Center for Marine Environmental Sciences; Chapopote; Comment; Elevation of event; Event label; GC; GeoB10618; Gravity corer; Hydrate; Latitude of event; Longitude of event; M67/2b; MARUM; Meteor (1986); OTEGA II; Sample code/label; SO174/1; SO174/1_47-1; SO174/1_96; SO174/2; SO174/2_140; SO174/2_157-1; SO174/2_169; Sonne; Television-Grab; TVG; X-ray diffraction (XRD)
    Type: Dataset
    Format: text/tab-separated-values, 93 data points
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 6
    Publication Date: 2023-03-03
    Keywords: 140; 157-1; 169; Area/locality; Bush Hill; C1 hydrocarbons; C2 hydrocarbons; C3 hydrocarbons; C5-isomers hydrocarbons; Campeche Knoll; Center for Marine Environmental Sciences; Chapopote; Comment; Elevation of event; Event label; Gas chromatography - Flame Ionization Detection (GC-FID); GC; GeoB10618; Gravity corer; iso-C4 hydrocarbons; Latitude of event; Longitude of event; M67/2b; MARUM; Meteor (1986); n-C4 hydrocarbons; Number; OTEGA II; Sample code/label; SO174/1; SO174/1_47-1; SO174/1_96; SO174/2; SO174/2_140; SO174/2_157-1; SO174/2_169; Sonne; Television-Grab; TVG
    Type: Dataset
    Format: text/tab-separated-values, 123 data points
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 7
    facet.materialart.
    Unknown
    PANGAEA
    In:  Supplement to: Klapp, Stephan A; Bohrmann, Gerhard; Kuhs, Werner F; Murshed, Mangir M; Pape, Thomas; Klein, Helmut; Techmer, Kirsten S; Heeschen, Katja U; Abegg, Friedrich (2010): Microstructures of structure I and II gas hydrates from the Gulf of Mexico. Marine and Petroleum Geology, 27(1), 116-125, https://doi.org/10.1016/j.marpetgeo.2009.03.004
    Publication Date: 2023-03-03
    Description: Gas hydrate samples from various locations in the Gulf of Mexico (GOM) differ considerably in their microstructure. Distinct microstructure characteristics coincide with discrete crystallographic structures, gas compositions and calculated thermodynamic stabilities. The crystallographic structures were established by X-ray diffraction, using both conventional X-ray sources and high-energy synchrotron radiation. The microstructures were examined by cryo-stage Field-Emission Scanning Electron Microscopy (FE-SEM). Good sample preservation was warranted by the low ice fractions shown from quantitative phase analyses. Gas hydrate structure II samples from the Green Canyon in the northern GOM had methane concentrations of 70-80% and up to 30% of C2-C5 of measured hydrocarbons. Hydrocarbons in the crystallographic structure I hydrate from the Chapopote asphalt volcano in the southern GOM was comprised of more than 98% methane. Fairly different microstructures were identified for those different hydrates: Pores measuring 200-400 nm in diameter were present in structure I gas hydrate samples; no such pores but dense crystal surfaces instead were discovered in structure II gas hydrate. The stability of the hydrate samples is discussed regarding gas composition, crystallographic structure and microstructure. Electron microscopic observations showed evidence of gas hydrate and liquid oil co-occurrence on a micrometer scale. That demonstrates that oil has direct contact to gas hydrates when it diffuses through a hydrate matrix.
    Keywords: 140; 157-1; 169; Bush Hill; Campeche Knoll; Center for Marine Environmental Sciences; Chapopote; GC; GeoB10618; Gravity corer; M67/2b; MARUM; Meteor (1986); OTEGA II; SO174/1; SO174/1_47-1; SO174/1_96; SO174/2; SO174/2_140; SO174/2_157-1; SO174/2_169; Sonne; Television-Grab; TVG
    Type: Dataset
    Format: application/zip, 2 datasets
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 8
    facet.materialart.
    Unknown
    PANGAEA
    In:  Supplement to: MacDonald, Ian R; Bohrmann, Gerhard; Escobar, E; Abegg, Friedrich; Blanchon, Paul; Blinova, Valentina N; Brueckmann, Warner; Drews, Manuela; Eisenhauer, Anton; Han, X; Heeschen, Katja U; Meier, Felix; Mortera-Gutierrez, Carlos; Naehr, T; Orcutt, B; Bernard, B; Brroks, J; de Farágo, M (2004): Asphalt volcanism and chemosynthetic life, Campache Knolls, Gulf of Mexico. Science, 304(5673), 999-1002, https://doi.org/10.1126/science.1097154
    Publication Date: 2023-05-12
    Description: In the Campeche Knolls, in the southern Gulf of Mexico, lava-like flows of solidified asphalt cover more than 1 square kilometer of the rim of a dissected salt dome at a depth of 3000 meters below sea level. Chemosynthetic tubeworms and bivalves colonize the sea floor near the asphalt, which chilled and contracted after discharge. The site also includes oil seeps, gas hydrate deposits, locally anoxic sediments, and slabs of authigenic carbonate. Asphalt volcanism creates a habitat for chemosynthetic life that may be widespread at great depth in the Gulf of Mexico.
    Keywords: 136; Campeche Knoll; Carbon dioxide; Center for Marine Environmental Sciences; Ethane; Isobutane; MARUM; Methane; n-Butane; OTEGA II; Propane; Sample type; see reference(s); SO174/2; SO174/2_136; Sonne; Television-Grab; TVG; δ13C, carbon dioxide, gas hydrate; δ13C, ethane; δ13C, isobutane; δ13C, methane; δ13C, propane
    Type: Dataset
    Format: text/tab-separated-values, 31 data points
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 9
    facet.materialart.
    Unknown
    PANGAEA
    In:  Supplement to: Heeschen, Katja U; Hohnberg, Hans-Jürgen; Haeckel, Matthias; Abegg, Friedrich; Drews, Manuela; Bohrmann, Gerhard (2007): In situ hydrocarbon concentrations from pressurized cores in surface sediments, Northern Gulf of Mexico. Marine Chemistry, 107(4), 498-515, https://doi.org/10.1016/j.marchem.2007.08.008
    Publication Date: 2023-06-27
    Description: Two newly developed coring devices, the Multi-Autoclave-Corer and the Dynamic Autoclave Piston Corer were deployed in shallow gas hydrate-bearing sediments in the northern Gulf of Mexico during research cruise SO174 (Oct-Nov 2003). For the first time, they enable the retrieval of near-surface sediment cores under ambient pressure. This enables the determination of in situ methane concentrations and amounts of gas hydrate in sediment depths where bottom water temperature and pressure changes most strongly influence gas/hydrate relationships. At seep sites of GC185 (Bush Hill) and the newly discovered sites at GC415, we determined the volume of low-weight hydrocarbons (C1 through C5) from nine pressurized cores via controlled degassing. The resulting in situ methane concentrations vary by two orders of magnitudes between 0.031 and 0.985 mol kg**-1 pore water below the zone of sulfate depletion. This includes dissolved, free, and hydrate-bound CH4. Combined with results from conventional cores, this establishes a variability of methane concentrations in close proximity to seep sites of five orders of magnitude. In total four out of nine pressure cores had CH4 concentrations above equilibrium with gas hydrates. Two of them contain gas hydrate volumes of 15% (GC185) and 18% (GC415) of pore space. The measurements prove that the highest methane concentrations are not necessarily related to the highest advection rates. Brine advection inhibits gas hydrate stability a few centimeters below the sediment surface at the depth of anaerobic oxidation of methane and thus inhibits the storage of enhanced methane volumes. Here, computerized tomography (CT) of the pressure cores detected small amounts of free gas. This finding has major implications for methane distribution, possible consumption, and escape into the bottom water in fluid flow systems related to halokinesis.
    Keywords: 152; 153; 158; 166; 170; Bush Hill; Center for Marine Environmental Sciences; DAPC; Dynamic autoclave piston corer; MAC; MARUM; Multi autoclave corer; OTEGA II; SO174/1; SO174/1_118; SO174/1_63; SO174/1_90; SO174/1_97; SO174/2; SO174/2_152; SO174/2_153; SO174/2_158; SO174/2_166; SO174/2_170; Sonne
    Type: Dataset
    Format: application/zip, 5 datasets
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 10
    Publication Date: 2023-07-10
    Keywords: 152; 153; 158; 166; 170; Analysis; Bush Hill; Center for Marine Environmental Sciences; DAPC; Device type; Dynamic autoclave piston corer; Elevation of event; Event label; Latitude of event; Location type; Longitude of event; MAC; MARUM; Multi autoclave corer; OTEGA II; Pressure, water; Sample, optional label/labor no; SO174/1; SO174/1_118; SO174/1_63; SO174/1_90; SO174/1_97; SO174/2; SO174/2_152; SO174/2_153; SO174/2_158; SO174/2_166; SO174/2_170; Sonne
    Type: Dataset
    Format: text/tab-separated-values, 42 data points
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...