Description: We present geochemical data collected from volcanic ash-bearing sediments on the upper slope of the northern Hikurangi margin during the RV SONNE SO247 expedition in 2016. Gravity coring and seafloor drilling with the MARUM-MeBo200 allowed for collection of sediments down to 105 meters below seafloor (mbsf). Release of dissolved Sr2+with isotopic composition enriched in 86Sr (87Sr/86Sr minimum = 0.708461 at 83.5 mbsf) is indicative of ash alteration. This reaction releases other cations in the 30-70 mbsf depth interval as reflected by maxima in pore-water Ca2+and Ba2+concentrations. In addition, we posit that Fe(III) in volcanogenic glass serves as an electron acceptor for methane oxidation, a reaction that releases Fe2+measured in the pore fluids to a maximum concentration of 184 μM. Several lines of evidence support our proposed coupling of ash alteration with Fe-mediated anaerobic oxidation of methane (Fe-AOM) beneath the sulfate-methane transition (SMT), which lies at ∼7 mbsf at this site. In the ∼30-70 mbsf interval, we observe a concurrent increase in Fe2+and a depletion of CH4with a well-defined decrease in δ13C-CH4values indicative of microbial fractionation of carbon. The negative excursions in δ13C values of both DIC and CH4are similar to that observed by sulfate-driven AOM at low SO2−4concentrations, and can only be explained by the microbially-mediated carbon isotope equilibration between CH4and DIC. Mass balance considerations reveal that the iron cycled through the coupled ash alteration and AOM reactions is consumed as authigenic Fe-bearing minerals. This iron sink term derived from the mass balance is consistent with the amount of iron present as carbonate minerals, as estimated from sequential extraction analyses. Using a numerical modeling approach we estimate the rate of Fe-AOM to be on the order of 0.4μmol cm−2yr−1, which accounts for ∼12% of total CH4removal in the sediments. Although not without uncertainties, the results presented reveal that Fe-AOM in ash-bearing sediments is significantly lower than the sulfate-driven CH4consumption, which at this site is 3.0μmol cm−2yr−1. We highlight that Fe(III) in ash can potentially serve as an electron acceptor for methane oxidation in sulfate-depleted settings. This is relevant to our understanding of C-Fe cycling in the methanic zone that typically underlies the SMT and could be important in supporting the deep biosphere.

Description: The climactic Los Chocoyos (LCY) eruption from Atitlán caldera (Guatemala) is a key chronostratigraphic marker for the Quaternary period given the extensive distribution of its deposits that reached both the Pacific and Atlantic Oceans. Despite LCY tephra being an important marker horizon, a radioisotopic age for this eruption has remained elusive. Using zircon (U–Th)/He geochronology, we present the first radioisotopically determined eruption age for the LCY of 75 ± 2 ka. Additionally, the youngest zircon crystallization 238U–230Th rim ages in their respective samples constrain eruption age maxima for two other tephra units that erupted from Atitlán caldera, W‐Fall (130 +16/−14 ka) and I‐Fall eruptions (56 +8.2/−7.7 ka), which under‐ and overlie LCY tephra, respectively. Moreover, rim and interior zircon dating and glass chemistry suggest that before eruption silicic magma was stored for 〉80 kyr, with magma accumulation peaking within ca. 35 kyr before the LCY eruption during which the system may have developed into a vertically zoned magma chamber. Based on an updated distribution of LCY pyroclastic deposits, a new conservatively estimated volume of ~1220 ± 150 km3 is obtained (volcanic explosivity index VEI 〉 8), which confirms the LCY eruption as the first‐ever recognized supereruption in Central America.

Description: Deutsche Forschungsgemeinschaft SCH 2521/6‐1

Description: The relatively fast and continuous build-up of a volcanic island can lead to an unstable edifice which might be prone to collapse under its own weight. Evidence for major flank-collapse events are found offshore a wide range of volcanic islands, suggesting this phenomenon to be a common process with potentially disastrous consequences as they can generate devastating tsunamis. Fogo Island is situated in the southeastern part of the Cape Verdean Archipelago, about 700 km west of Dakar, NW Africa. During the Monte Amarelo event, approx. 73,000 years ago, its subaerial eastern flank collapsed into the ocean, triggering a mega tsunami with run-up heights of up to 270 m as witnessed by dated tsunami deposits found on the neighboring island of Santiago, ~60 km eastwards from Fogo. Whether the collapse occurred in a single event or multiple phases remains unknown and a volume estimation of the collapse difficult and uncertain as the base of the deposit could not have been captured offshore before. Such information, however, is essential for modeling a more reliable tsunami generation scenario. During the research cruise M155 in June 2019, a set of high-resolution multichannel (MSC) reflection seismic data along with hydroacoustic data was gathered. In most of the MSC profiles, a common reflector is identifiable and regarded as the base of the Monte Amarelo deposit, allowing the reassessment of the volume of failed and remobilized material. In addition, prominent internal reflectors within the chaotic facies defining the Monte Amarelo deposit in the MSC data, strongly suggest the collapse might have happened in multiple phases. Such observation is critical to better assess tsunami modeling associated with volcanic flank collapses.

Description: Volcanic archipelagos are a source of numerous on- and offshore geohazards, including explosive eruptions and potentially tsunamigenic large-scale flank-collapses. Fogo Island in the southern Cape Verdes is one of the most active volcanoes in the world, making it both prone to collapse (as evidenced by the ca. 73 ka Monte Amarelo volcanic flank-collapse), and a source of widely-distributed tephra and volcanic material. The offshore distribution of the Monte Amarelo debris avalanche deposits and the surrounding volcaniclastic apron were previously mapped using only medium-resolution bathymetric data. Here, using recently acquired, higher resolution acoustic data, we revisit Fogo's flank-collapse, and find evidence suggesting that the deposition of hummocky volcanic debris originating from the failed eastern flank most likely triggered the contemporaneous, multi-phase failure of pre-existing seafloor sediments. Additionally, we identify, for the first time, multiple mass-transport deposits in the southern part of the volcaniclastic apron of Fogo and Santiago based on the presence of acoustically chaotic deposits in parametric echo sounder data and volcaniclastic turbiditic sands in recovered cores. These preliminary findings indicate a long and complex history of instability on the southern slopes of Fogo and suggest that Fogo may have experienced multiple flank collapses.