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  • American Chemical Society (ACS)  (122.281)
  • Blackwell Science Ltd  (61.712)
Publikationsart
Erscheinungszeitraum
  • 1
    Publikationsdatum: 2020-11-19
    Beschreibung: We report on new stratigraphic, palaeomagnetic and anisotropy of magnetic susceptibility (AMS) results from the Amantea basin, located on-shore along the Tyrrhenian coast of the Calabrian Arc (Italy). The Miocene Amantea Basin formed on the top of a brittlely extended upper plate, separated from a blueschist lower plate by a low-angle top-to-the-west extensional detachment fault. The stratigraphic architecture of the basin is mainly controlled by the geometry of the detachment fault and is organized in several depositional sequences, separated by major unconformities. The first sequence (DS1) directly overlaps the basement units, and is constituted by Serravallian coarse-grained conglomerates and sandstones. The upper boundary of this sequence is a major angular unconformity locally marked by a thick palaeosol (type 1 sequence boundary). The second depositional sequence DS2 (middle Tortonian-early Messinian) is mainly formed by conglomerates, passing upwards to calcarenites, sandstones, claystones and diatomites. Finally, Messinian limestones and evaporites form the third depositional sequence (DS3). Our new biostratigraphic data on the Neogene deposits of the Amantea basin indicate a hiatus of 3 Ma separating sequences DS1 and DS2. The structural architecture of the basin is characterized by faulted homoclines, generally westward dipping, dissected by eastward dipping normal faults. Strike-slip faults are also present along the margins of the intrabasinal structural highs. Several episodes of syn-depositional tectonic activity are marked by well-exposed progressive unconformities, folds and capped normal faults. Three main stages of extensional tectonics affected the area during Neogene-Quaternary times: (1) Serravallian low-angle normal faulting; (2) middle Tortonian high-angle syn-sedimentary normal faulting; (3) Messinian-Quaternary high-angle normal faulting. Extensional tectonics controlled the exhumation of high-P/low-T metamorphic rocks and later the foundering of the Amantea basin, with a constant WNW-ESE stretching direction (present-day coordinates), defined by means of structural analyses and by AMS data. Palaeomagnetic analyses performed mainly on the claystone deposits of DSl show a post-Serravallian clockwise rotation of the Amantea basin. The data presented in this paper constrain better the overall timing, structure and kinematics of the early stages of extensional tectonics of the southern Tyrrhenian Sea. In particular, extensional basins in the southern Tyrrhenian Sea opened during Serravallian and evolved during late Miocene. These data confirm that, at that time, the Amantea basin represented the conjugate extensional margin of the Sardinian border, and that it later drifted south-eastward and rotated clockwise as a part of the Calabria-Peloritani terrane.
    Beschreibung: Published
    Beschreibung: 147-168
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): paleomagnetism ; structural geology ; syn-sedimentary tectonics ; Amantea ; Calabria ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 2
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    Blackwell Science Ltd
    Publikationsdatum: 2017-04-03
    Beschreibung: The method of spherical cap harmonic analysis (SCHA), due to Haines (1985) is appropriate for regional geomagnetic field modelling as it includes the required potential field constraints and, for a given number of model parameters, describes shorter wavelength features than a global spherical harmonic model. If the origin of the coordinate system is moved from the centre of the Earth towards the surface then the Earth's surface is no longer equidistant from the origin. At the Earth's surface the minimum wavelength described by a SCH model in the new coordinate system is smaller at the centre of the region than at the edge. This method of translated origin spherical cap harmonic analysis (TOSCA) has been applied to regional field modelling for Italy. The method is able to take advantage of the dense distribution of data at the centre of region and the model effectively smooths towards the periphery. The performance of the TOSCA model is discussed in relation to a model derived using conventional SCHA.
    Beschreibung: Published
    Beschreibung: 253-263
    Beschreibung: N/A or not JCR
    Beschreibung: reserved
    Schlagwort(e): ground and satellite data analysis ; regional field modelling ; spherical cap harmonic analysis ; 04. Solid Earth::04.05. Geomagnetism::04.05.03. Global and regional models ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Publikationsdatum: 2017-04-04
    Beschreibung: An analysis of the field scaling power spectrum yields useful information about the source distribution, but it is uncertain whether deterministic, random, fractal or mixed approaches have to be used for the interpretation. To this end, the scaling properties of potential field spectra are analysed for a number of different source models of geological interest. Besides the models of Naidu (purely random sources) and Spector and Grant (gross block statistical ensembles) we consider other types of density and magnetization distributions with spectral exponents in the fractal range, such as a single homogeneous body with a random white source distribution. Spectral slopes in the fractal range are obtained. We also study the effects of important natural sources, such as salt domes and sedimentary basins, representing them with simple Gaussians or combinations of Gaussian signals. The same spectral slopes as for gravity signals generated by 3-D fractal source distributions are found for them. Hence the power law decay of the field is not a characteristic only of fractal source models. If a 3-D fractal source distribution is assumed a priori, a way of verifying the goodness of the model is to examine the whitened field at source level. The probability that the whitened field derives from a random white population is estimated for synthetic and real anomalies by applying the usual statistical tests.
    Beschreibung: Published
    Beschreibung: 311-323
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): fractals ; potential field ; spectral analysis ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    Publikationsdatum: 2017-04-04
    Beschreibung: Eastern Sicily (southern Italy) is characterised by the presence of many natural gas emissions (mofettes, mud volcanoes). These gases are mostly carbon dioxide and methane, with minor amounts of helium, hydrogen, carbon monoxide and hydrocarbons. In this study, the extent and orientation of soil gas anomalies (He and CO2) were investigated on a wide area (approximately 110 km2) located just SW of Mt. Etna. From a structural point of view, this area lays on a typical foredeep–foreland system that marks the boundary between the southern part of the Eurasian plate and the northern part of the African plate in the central Mediterranean. No tectonic structure was revealed in this area by surface geological surveys. Very high soil emissions were found, and their spatial pattern reveals the existence of some active faults all directed about N508E. This direction coincides with that of two major fault systems that cut eastern Sicily and are evident, respectively, NE and SW of the study area. Soil gas data suggest that these fault systems are the expression of a single continuous structural line which is probably responsible for the past and present magma uprise in eastern Sicily. Isotopic values of carbon of CO2 suggest a minor contribution of organic carbon. Moreover, in the highest degassing sites the isotopic values of He found in association with CO2 (He abundance¼11–70 p.p.m.; R/Ra between 6.0 and 6.2) suggest that both gases are mantle derived. The extent of the areas affected by high gas emissions and the amounts of deep CO2 emitted in the investigated area (several hundred tonnes per day) may provide additional supporting evidence of a mantle upwelling taking place beneath this region.
    Beschreibung: Gruppo Nazionale per la Vulcanologia Italy.
    Beschreibung: Published
    Beschreibung: 273–284
    Beschreibung: partially_open
    Schlagwort(e): CO2 ; diffuse degassing ; Sicily ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
    Format: 597 bytes
    Format: 866788 bytes
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    Format: application/pdf
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  • 5
    Publikationsdatum: 2017-04-04
    Beschreibung: This paper documents a phreatomagmatic ¯ank eruption that occurred 18 700 100 a BP, on the lower north-eastern slope of Etna during the Ellittico volcano activity, which produced fall and surge deposits. This type of eruption is connected to a sedimentary basement ridge at Etna. The interaction between the rising magma and the shallow groundwater hosted in the volcanic pile overlying the impermeable sediments resulted in phreatomagmatic instead of strombolian activity. Three eruptive phases are distinguished based on ®eld and analytical data: (i) an explosive phreatomagmatic opening, (ii) a main phase producing coarse lithic-rich fallout and a strombolian deposit, and (iii) the ®nal pulsating surge-forming phase. The discovery of this phreatomagmatic ¯ank eruption, which occurred at lower altitude, raises important issues for previous hazard assessments at Etna.
    Beschreibung: University of Catania
    Beschreibung: Published
    Beschreibung: 235-240
    Beschreibung: 3.5. Geologia e storia dei sistemi vulcanici
    Beschreibung: JCR Journal
    Beschreibung: reserved
    Schlagwort(e): Etna ; phreatomagmatic eruption ; hazard assessment ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository-Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Materialart: article
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  • 6
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science & Technology, American Chemical Society (ACS), 57(17), pp. 6799-6807, ISSN: 0013-936X
    Publikationsdatum: 2023-08-16
    Beschreibung: Plastic pollution has become ubiquitous with very high quantities detected even in ecosystems as remote as arctic sea ice and deepsea sediments. Ice algae growing underneath sea ice are released upon melting and can form fast-sinking aggregates. In this pilot study, we sampled and analyzed the ice algaeMelosira arcticaand ambient sea water from three locations in the Fram Strait to assess their microplastic content and potential as a temporary sink and pathway to the deep seafloor. Analysis by μ-Raman and fluorescence microscopy detected microplastics (≥2.2 μm) in all samples at concentrations ranging from 1.3 to 5.7 × 104 microplastics (MP) m−3 in ice algae and from 1.4 to 4.5 × 103 MP m−3 in sea water, indicating magnitude higher concentrations in algae. On average, 94% of the total microplastic particles were identified as 10 μm or smaller in size and comprised 16 polymer types without a clear dominance. The high concentrations of microplastics found in our pilot study suggest thatM. arctica could trap microplastics from melting ice and ambient sea water. The algae appear to be a temporary sink and could act as a key vector to food webs near the sea surface and on the deep seafloor, to which its fast-sinking aggregates could facilitate an important mechanism of transport.
    Repository-Name: EPIC Alfred Wegener Institut
    Materialart: Article , isiRev
    Format: application/pdf
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  • 7
    Publikationsdatum: 2024-04-04
    Beschreibung: Second-generation anticoagulant rodenticides (SGARs) are widely used to control rodent populations, resulting in the serious secondary exposure of predators to these contaminants. In the United Kingdom (UK), professional use and purchase of SGARs were revised in the 2010s. Certain highly toxic SGARs have been authorized since then to be used outdoors around buildings as resistance-breaking chemicals under risk mitigation procedures. However, it is still uncertain whether and how these regulatory changes have influenced the secondary exposure of birds of prey to SGARs. Based on biomonitoring of the UK Common Buzzard (Buteo buteo) collected from 2001 to 2019, we assessed the temporal trend of exposure to SGARs and statistically determined potential turning points. The magnitude of difenacoum decreased over time with a seasonal fluctuation, while the magnitude and prevalence of more toxic brodifacoum, authorized to be used outdoors around buildings after the regulatory changes, increased. The summer of 2016 was statistically identified as a turning point for exposure to brodifacoum and summed SGARs that increased after this point. This time point coincided with the aforementioned regulatory changes. Our findings suggest a possible shift in SGAR use to brodifacoum from difenacoum over the decades, which may pose higher risks of impacts on wildlife.
    Schlagwort(e): apex predator ; conditional inference trees ; effectiveness evaluation ; regulatory changes ; seasonal fluctuation
    Repository-Name: National Museum of Natural History, Netherlands
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
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  • 8
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science & Technology, American Chemical Society (ACS), 58(9), pp. 4302-4313, ISSN: 0013-936X
    Publikationsdatum: 2024-03-28
    Beschreibung: The pollution of the marine environment with plastic debris is expected to increase, where ocean currents and winds cause their accumulation in convergence zones like the North Pacific Subtropical Gyre (NPSG). Surface-floating plastic (〉330 μm) was collected in the North Pacific Ocean between Vancouver (Canada) and Singapore using a neuston catamaran and identified by Fourier-transform infrared spectroscopy (FT-IR). Baseline concentrations of 41,600–102,700 items km–2 were found, dominated by polyethylene and polypropylene. Higher concentrations (factors 4–10) of plastic items occurred not only in the NPSG (452,800 items km–2) but also in a second area, the Papaha̅naumokua̅kea Marine National Monument (PMNM, 285,200 items km–2). This second maximum was neither reported previously nor predicted by the applied ocean current model. Visual observations of floating debris (〉5 cm; 8–2565 items km–2 and 34–4941 items km–2 including smaller “white bits”) yielded similar patterns of baseline pollution (34–3265 items km–2) and elevated concentrations of plastic debris in the NPSG (67–4941 items km–2) and the PMNM (295–3748 items km–2). These findings suggest that ocean currents are not the only factor provoking plastic debris accumulation in the ocean. Visual observations may be useful to increase our knowledge of large-scale (micro)plastic pollution in the global oceans.
    Repository-Name: EPIC Alfred Wegener Institut
    Materialart: Article , peerRev
    Format: application/pdf
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  • 9
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    Unbekannt
    American Chemical Society (ACS)
    In:  EPIC3Environmental Science and Technology, American Chemical Society (ACS), 58(10), pp. 4637-4647, ISSN: 0013-936X
    Publikationsdatum: 2024-04-08
    Beschreibung: Marine dissolved organic matter (DOM) is an important component of the global carbon cycle, yet its intricate composition and the sea salt matrix pose major challenges for chemical analysis. We introduce a direct injection, reversed-phase liquid chromatography ultrahigh resolution mass spectrometry approach to analyze marine DOM without the need for solid-phase extraction. Effective separation of salt and DOM is achieved with a large chromatographic column and an extended isocratic aqueous step. Postcolumn dilution of the sample flow with buffer-free solvents and implementing a counter gradient reduced salt buildup in the ion source and resulted in excellent repeatability. With this method, over 5,500 unique molecular formulas were detected from just 5.5 nmol carbon in 100 μL of filtered Arctic Ocean seawater. We observed a highly linear detector response for variable sample carbon concentrations and a high robustness against the salt matrix. Compared to solid-phase extracted DOM, our direct injection method demonstrated superior sensitivity for heteroatom-containing DOM. The direct analysis of seawater offers fast and simple sample preparation and avoids fractionation introduced by extraction. The method facilitates studies in environments, where only minimal sample volume is available e.g. in marine sediment pore water, ice cores, or permafrost soil solution. The small volume requirement also supports higher spatial (e.g., in soils) or temporal sample resolution (e.g., in culture experiments). Chromatographic separation adds further chemical information to molecular formulas, enhancing our understanding of marine biogeochemistry, chemodiversity, and ecological processes.
    Repository-Name: EPIC Alfred Wegener Institut
    Materialart: Article , isiRev
    Format: application/pdf
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  • 10
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    American Chemical Society (ACS)
    In:  EPIC3Environmental Science and Technology, American Chemical Society (ACS), ISSN: 0013-936X
    Publikationsdatum: 2024-04-08
    Beschreibung: Marine permeable sediments are important sites for organic matter turnover in the coastal ocean. However, little is known about their role in trapping dissolved organic matter (DOM). Here, we examined DOM abundance and molecular compositions (9804 formulas identified) in subtidal permeable sediments along a near- to offshore gradient in the German North Sea. With the salinity increasing from 30.1 to 34.6 PSU, the DOM composition in bottom water shifts from relatively higher abundances of aromatic compounds to more highly unsaturated compounds. In the bulk sediment, DOM leached by ultrapure water (UPW) from the solid phase is 54 ± 20 times more abundant than DOM in porewater, with higher H/C ratios and a more terrigenous signature. With 0.5 M HCl, the amount of leached DOM (enriched in aromatic and oxygen-rich compounds) is doubled compared to UPW, mainly due to the dissolution of poorly crystalline Fe phases (e.g., ferrihydrite and Fe monosulfides). This suggests that poorly crystalline Fe phases promote DOM retention in permeable sediments, preferentially terrigenous, and aromatic fractions. Given the intense filtration of seawater through the permeable sediments, we posit that Fe can serve as an important intermediate storage for terrigenous organic matter and potentially accelerate organic matter burial in the coastal ocean.
    Repository-Name: EPIC Alfred Wegener Institut
    Materialart: Article , isiRev
    Format: application/pdf
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