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  • 1
    Online Resource
    Online Resource
    Berlin, Heidelberg :Springer Berlin / Heidelberg,
    Keywords: Chemical oceanography. ; Electronic books.
    Type of Medium: Online Resource
    Pages: 1 online resource (292 pages)
    Edition: 1st ed.
    ISBN: 9783642321252
    Series Statement: The Handbook of Environmental Chemistry Series ; v.22
    DDC: 551.466
    Language: English
    Note: Intro -- Chemical Structure of Pelagic Redox Interfaces -- Observation and Modeling -- The Handbook of Environmental Chemistry Also Available Electronically -- Aims and Scope -- Series Preface -- Contents -- Introduction: Redox Interfaces in Marine Waters -- 1 Preface -- 2 Occurrence and Hydrophysical Structure -- 3 Global Distribution -- 4 Effects on Chemistry, Biochemistry and Ecosystem Function -- 5 Terminology, Definitions, Boundaries and Thresholds -- 6 The Redox Layers in a Marine Water Column -- 7 Modelling -- 8 Structure of the Monograph -- References -- Biogeochemical Peculiarities of the Vertical Distributions of Nutrients in the Black Sea -- 1 Introduction -- 2 Materials and Methods -- 3 Results and Discussions -- 4 Conclusions -- References -- Anaerobic Microbial Community in the Aerobic Water and at the Oxic/Anoxic Interface in the Black Sea -- 1 Introduction -- 2 Materials and Methods -- 3 Results -- 3.1 Rates of Sulfate Reduction and Methanogenesis in the Water Column of the Black Sea -- 3.2 Detection of SRB and Methanogenic Archaea in Aerobic Surface Waters -- 3.3 Structure of Anaerobic Microbial Communities in the Chemocline of the Black Sea -- 3.4 Identification of SRB from Enrichment Cultures Isolated from Aerobic Water and the Chemocline Zone -- 3.5 Detection of Active Prokaryotic Cells in the Anaerobic Water of the Black Sea -- 4 Discussion -- References -- The Energetic Balance of Microbial Exploitation of Pelagic Redox Gradients -- 1 Introduction -- 2 Microbial Communities Across Pelagic Redox Gradients -- 3 Flux of Electron Acceptors and Donors as Source of Energy -- 4 Observed Carbon Dioxide Fixation and Quantitative Explanation -- References -- Manganese and Iron at the Redox Interfaces in the Black Sea, the Baltic Sea, and the Oslo Fjord -- 1 Introduction -- 2 Methods -- 2.1 Study Site -- 2.2 Sampling. , 2.3 Chemical Measurements -- 2.4 Modeling -- 3 Results -- 3.1 Manganese -- 3.2 Iron -- 4 Discussion -- 5 Modeling -- 6 Conclusions -- References -- Role of Sulfide Oxidation Intermediates in the Redox Balance of the Oxic-Anoxic Interface of the Gotland Deep, Baltic Sea -- 1 Introduction -- 2 Materials and Methods -- 2.1 Sampling -- 2.2 Analytical Techniques -- 2.2.1 Sulfide and Sulfide Oxidation Intermediates -- 2.2.2 Oxygen, Nutrients, and Metals -- 3 Results -- 3.1 Redox Transition Zone -- 3.2 Bottom Layer -- 4 Discussion -- 4.1 Zero-Valent Sulfur-Thiosulfate Distribution Paradox -- 4.2 Nutrients Distribution -- 4.3 Distribution of Metals -- 4.4 Oxic Water Intrusions at and Below RTZ -- 4.5 Origin of the Turbidity Maxima -- 5 Conclusions -- References -- On Interannual Variability of Chemical Characteristics of Redox Layer and Cold Intermediate Layer of the Black Sea -- 1 Introduction -- 2 Materials and Methods -- 3 Results -- 3.1 Characteristic Vertical Biogeochemical Structure -- 3.2 Interannual Variability of O2, H2S, NH4 and Mn(II) -- 3.3 Interannual Variability of Carbonate System Parameters -- 4 Discussion -- 5 Conclusions -- References -- Large-Scale Dynamics of Hypoxia in the Baltic Sea -- 1 Introduction -- 2 Data, Tools, and Methods -- 3 Long-Term Large-Scale Oxygen Dynamics -- 4 Redox Alterations of Biogeochemical Cycles -- 5 Conclusions -- References -- Biogeochemical Characteristics in the Elefsis Bay (Aegean Sea, Eastern Mediterranean) in Relation to Anoxia and Climate Change -- 1 Introduction -- 2 Description of the Area -- 3 History of the Area -- 4 Elefsis Bay Characteristics -- 4.1 Field, Laboratory Analysis and Data Assessment -- 4.2 Description of the Ecosystem Dynamics -- 4.2.1 Hydrography -- 4.2.2 Biochemical Characteristics of the Water Column -- DO and Inorganic Nutrients -- Organic Carbon, Nitrogen and Phosphorus. , Chlorophyll and Zooplankton in Elefsis Bay -- Statistical Analysis -- 5 Interannual Variability -- 6 Conclusion -- References -- RedOx Layer Model: A Tool for Analysis of the Water Column Oxic/Anoxic Interface Processes -- 1 Introduction -- 2 Formulation of Model -- 2.1 Biogeochemical Processes Parameterization -- 2.1.1 Autolysis -- 2.1.2 Mineralization of OM -- Mineralization in Oxic Conditions -- Mineralization in Suboxic Conditions -- Sulfate Reduction -- 2.1.3 Ammonification and Phosphatification -- 2.1.4 Nitrification -- 2.1.5 Nitrogen Fixation -- 2.1.6 Anammox -- 2.1.7 Oxidation of Reduced Sulfur Forms with Oxygen -- 2.1.8 S0 Disproportionation -- 2.1.9 Thiodenitrification (Chemolithotrophic Denitrification) -- 2.1.10 Processes of Oxidation and Reduction of Manganese -- Manganese(II) Oxidation with Oxygen -- Manganese(IV) Reduction with Sulfide -- Manganese(III) Oxidation and Reduction -- 2.1.11 Processes of Oxidation and Reduction of Iron -- Iron(II) Oxidation with Oxygen -- Iron(II) Oxidation by Manganese(IV) -- Iron(II) Oxidation by Nitrate -- Iron(III) Reduction by Sulfide -- 2.1.12 Processes of Phosphorus Transformation -- 2.2 Ecosystem Processes Parameterization -- 2.2.1 Phytoplankton (Phy) -- 2.2.2 Zooplankton (Zoo) -- 2.2.3 Aerobic Heterotrophic Bacteria (B_ae_het) -- 2.2.4 Aerobic Autotrophic Bacteria (B_ae_aut) -- 2.2.5 Anaerobic Heterotrophic Bacteria (B_anae _het) -- 2.2.6 Anaerobic Autotrophic Bacteria (B_anae_aut) -- 2.3 Equations for the Biogeochemical Sources RC -- 3 Discussion -- References -- Modelling of the Meromictic Fjord Hunnbunn (Norway) with an Oxygen Depletion Model (OxyDep) -- 1 Introduction -- 2 Materials and Methods -- 2.1 Hunnbunn Hydrophysical and Hydrochemical Structure -- 2.2 GETM Application and Set Up -- 2.3 OxyDep Description -- 2.4 Sinking -- 2.5 Boundary Conditions -- 3 Results and Discussion. , 4 Conclusions -- References -- Numerical Modelling of Biogeochemical Regime Response to Decadal Atmospheric Variability During 1960-2000 in the Black Sea -- 1 Introduction -- 2 Model and Materials -- 2.1 Description of the Model -- 2.2 Analysis of Forcing and Initial Data -- 2.2.1 Forcing Data -- 2.2.2 Initial Conditions -- 2.3 Numerical Experiments -- 2.4 Model Validations -- 3 Interannual Variability of Simulated Biogeochemistry Responses -- 4 Discussion and Conclusions -- References -- Conclusions -- Index.
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  • 2
    Keywords: Forschungsbericht ; Wasseranalyse
    Type of Medium: Online Resource
    Pages: Online-Ressource
    Series Statement: Meereswissenschaftliche Berichte 68
    Language: English
    Note: Literaturverz. S. 50 - 54
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  • 3
    Keywords: Forschungsbericht ; Ostsee ; Schwarzes Meer ; Meerwasser ; Grenzschicht ; Organischer Stoff ; Abbaureaktion ; Meereschemie ; Sauerstoff ; Oxidation ; Sauerstoffkonzentration ; Reduktion ; Redoxpotenzial ; Pelagial ; Hypoxie ; Mikroorganismus ; Wasseranalyse
    Type of Medium: Book
    Pages: 54 S. , Ill., graph. Darst., Kt.
    Series Statement: Meereswissenschaftliche Berichte 68
    Language: English
    Note: Zsfassung in engl. Sprache. - Literaturverz. S. 50 - 54
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  • 4
    Online Resource
    Online Resource
    Cham : Springer International Publishing | Cham : Imprint: Springer
    Keywords: Environmental chemistry. ; Water. ; Hydrology. ; Physical geography. ; Analytical chemistry. ; Freshwater ecology. ; Marine ecology. ; Aserbaidschan ; Urmiasee ; Seesediment ; Seespiegelschwankung ; Hydrogeochemie ; Biogeochemie ; Provinz West-Aserbaidschan ; Salzsee ; Limnologie ; Hydrochemie ; Trockengebiet
    Description / Table of Contents: Introduction: Lake Urmia – A Hypersaline Waterbody in a Drying Climate -- Seasonal Variation of Evaporation from Hypersaline Basin of the Urmia Lake -- Sediment distribution pattern in Lake Urmia -- The Vanishing of Urmia Lake: A Geolimnological Perspective on the Hydrological Imbalance of the World’s Second Largest Hypersaline Lake -- Modelling Biogeochemical and Physicochemical Regime Changes During the Drying Period of Lake Urmia -- A Review of Tectonics and Seismotectonics of Urmia Lake, NW Iran -- Local Changes in Meteorological Parameters Caused by Desiccation of the Lake Urmia -- Analysis of the Long-Term Trend of Temperature, Precipitation, and Dominant Atmospheric Phenomena in Lake Urmia -- Hydroclimate of the Lake Urmia Catchment Area: A Brief Overview -- Global and Regional Signals in the Water Level Variation in hypersaline Basin of the Lake Urmia -- Comparative Study of the Major Ion Composition in Eurasian Salt Lakes: Lake Urmia, Lake Issyk-Kul, Aral Sea, and Dead Sea -- Hydro-Meteorological Observations in Hypersaline Basin of Lake Urmia -- Lake Urmia Brine Evolution from 2007 to 2019 -- Salt load impact on Lake Urmia basin volume -- How Climate Change and Human Interaction Alter Chemical Regime in Salt Lakes, Case Study: Lake Urmia, Aral Sea, the Dead Sea, and Lake Issyk-Kul -- Modelling Physical and Chemical Processes of the Hypersaline Lake Urmia: Water Level Decline and Restoration by Water Conveyance -- Conclusion.
    Type of Medium: Online Resource
    Pages: 1 Online-Ressource(XII, 330 p. 60 illus., 30 illus. in color.)
    Edition: 1st ed. 2023.
    ISBN: 9783031410536
    Series Statement: The Handbook of Environmental Chemistry 123
    Language: English
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  • 5
    Publication Date: 2024-02-13
    Description: The availability of silicon (Si) in the ocean plays an important role in regulating biogeochemical and ecological processes. The Si budget of the Arctic Ocean appears balanced, with inputs equivalent to outputs, though it is unclear how a changing climate might aggravate this balance. In this study, we focus on Si cycling in Arctic coastal areas and continental shelf sediments to better constrain the Arctic Ocean Si budget. We provide the first estimate of amorphous Si (ASi) loading from erosion of coastal Yedoma deposits (30–90 Gmol yr−1), demonstrating comparable rates to particulate Si loading from rivers (10–90 Gmol yr−1). We found a positive relationship between surface sediment ASi and organic matter content on continental shelves. Combining these values with published Arctic shelf sediment properties and burial rates we estimate 70 Gmol Si yr−1 is buried on Arctic continental shelves, equivalent to 4.5% of all Si inputs to the Arctic Ocean. Sediment dissolved Si fluxes increased with distance from river mouths along cruise transects of shelf regions influenced by major rivers in the Laptev and East Siberian seas. On an annual basis, we estimate that Arctic shelf sediments recycle approximately up to twice as much DSi (680 Gmol Si) as is loaded from rivers (340–500 Gmol Si).
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 6
    Publication Date: 2021-02-08
    Description: The benthic environment is a crucial component of marine systems in the provision of ecosystem services, sustaining biodiversity and in climate regulation, and therefore important to human society. With the contemporary increase in computational power, model resolution and technological improvements in quality and quantity of benthic data, it is necessary to ensure that benthic systems are appropriately represented in coupled benthic-pelagic biogeochemical and ecological modelling studies. In this paper we focus on five topical challenges related to various aspects of modelling benthic environments: organic matter reactivity, dynamics of benthic-pelagic boundary layer, microphytobenthos, biological transport and small-scale heterogeneity, and impacts of episodic events. We discuss current gaps in their understanding and indicate plausible ways ahead. Further, we propose a three-pronged approach for the advancement of benthic and benthic-pelagic modelling, essential for improved understanding, management and prediction of the marine environment. This includes: (A) development of a traceable and hierarchical framework for benthic-pelagic models, which will facilitate integration among models, reduce risk of bias, and clarify model limitations; (B) extended cross-disciplinary approach to promote effective collaboration between modelling and empirical scientists of various backgrounds and better involvement of stakeholders and end-users; (C) a common vocabulary for terminology used in benthic modelling, to promote model development and integration, and also to enhance mutual understanding.
    Type: Article , PeerReviewed
    Format: text
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  • 7
    Publication Date: 2024-02-07
    Description: Highlights • To study the biogeochemical consequences of a release of CO2 in an anoxic marine environment a FABM family set of models consisting of a transport model, biogeochemical model (including carbonate system processes block) and bubble fate (transport and dissolution) was applied. • The measurements performed during a controlled 2-h long CO2 release experiments show elevated levels of pCO2 and simultaneously decreased values in pH, that was used for the model validation. • The model analysis of consequences of a CO2discharge demonstrates that CO2 bubbles are dissolved shortly after termination of the leak, while changes in pH, pCO2 and TIC can be detected for several days after the leak, but only at a limited distance from the source (〈 10 m in the examples evaluated here). In this paper we investigate the spatial extent and biogeochemical properties of a known CO2 plume using the pelagic transport-biogeochemical model BROM (Bottom RedOx Model). The model consists of a biogeochemical module, a 2-dimensional vertical transport module and gas bubble fate module, parameterizing bubbles rising and dissolution according to existing approaches. A controlled CO2 release experiment was carried out in the Horten Inner Harbor, Norway, in September 2018. This isolated bay is characterized by limited water mixing and anoxia in the bottom layer. CO2 was released at a water depth of 18 m either in a gas phase or dissolved in seawater at leak rates ranging from 0.1 l/min to 15.8 l/min. The chemical response to the release events relative to background variations was measured using chemical sensors mounted on two seabed templates located 4 m and 15 m from the release point, respectively, and compared to the values predicted by the model. The measurements show elevated levels of pCO2 and simultaneously decreased values in pH corresponding to the controlled release experiments. The model's simulations were in good agreement with the baseline observations and the measured changes forced by the experimental leak. The model predicts that after a continuous leak of this magnitude in stagnant conditions of anoxic bottom water, a 2–3 weeks long restoration period occurs, after which the disturbances disappear. This work confirms that the footprint of a potential CO2 leak is localized in the vicinity of the source (tens of meters) where it can be detectable with available chemical sensors.
    Type: Article , PeerReviewed
    Format: text
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