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  • 1
    Publication Date: 2023-02-08
    Description: The dynamics of the particulate organic carbon (POC) pool in the ocean are central to the marine carbon cycle. POC is the link between surface primary production, the deep ocean, and sediments. The rate at which POC is degraded in the dark ocean can impact atmospheric CO2 concentration. Therefore, a central focus of marine organic geochemistry studies is to improve our understanding of POC distribution, composition, and cycling. The last few decades have seen improvements in analytical techniques that have greatly expanded what we can measure, both in terms of organic compound structural diversity and isotopic composition, and complementary molecular omics studies. Here we provide a brief overview of the autochthonous, allochthonous, and anthropogenic components comprising POC in the ocean. In addition, we highlight key needs for future research that will enable us to more effectively connect diverse data sources and link the identity and structural diversity of POC to its sources and transformation processes.
    Type: Article , PeerReviewed
    Format: text
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  • 2
    Publication Date: 2024-02-07
    Description: The Last Interglacial (~129,000–116,000 years ago) is the most recent geologic period with a warmer-than-present climate. Proxy-based temperature reconstructions from this interval can help contextualize natural climate variability in our currently warming world, especially if they can define changes on decadal timescales. Here, we established a ~4.800-year-long record of sea surface temperature (SST) variability from the eastern Mediterranean Sea at 1–4-year resolution by applying mass spectrometry imaging of long-chain alkenones to a finely laminated organic-matter-rich sapropel deposited during the Last Interglacial. We observe the highest amplitude of decadal variability in the early stage of sapropel deposition, plausibly due to reduced vertical mixing of the highly stratified water column. With the subsequent reorganization of oceanographic conditions in the later stage of sapropel deposition, when SST forcing resembled the modern situation, we observe that the maximum amplitude of reconstructed decadal variability did not exceed the range of the recent period of warming climate. The more gradual, centennial SST trends reveal that the maximal centennial scale SST increase in our Last Interglacial record is below the projected temperature warming in the twenty-first century.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2020-07-01
    Description: The dynamics of the particulate organic carbon (POC) pool in the ocean are central to the marine carbon cycle. POC is the link between surface primary production, the deep ocean, and sediments. The rate at which POC is degraded in the dark ocean can impact atmospheric CO2 concentration. Therefore, a central focus of marine organic geochemistry studies is to improve our understanding of POC distribution, composition, and cycling. The last few decades have seen improvements in analytical techniques that have greatly expanded what we can measure, both in terms of organic compound structural diversity and isotopic composition, and complementary molecular omics studies. Here we provide a brief overview of the autochthonous, allochthonous, and anthropogenic components comprising POC in the ocean. In addition, we highlight key needs for future research that will enable us to more effectively connect diverse data sources and link the identity and structural diversity of POC to its sources and transformation processes.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 4
    Publication Date: 2021-07-21
    Description: The Upper Pleistocene geoarchives in the south‐eastern Carpathian Basin are represented predominantly by loess–palaeosol records. In 2015, a 10 m sediment core composed of clay‐rich lacustrine sediments was recovered by vibracoring a dry lake basin located between the Vršac Mountains (Serbia) and the Banat Sands in the south‐eastern Carpathian Basin; a location relevant for placing regional archaeological results in a palaeoenvironmental context. Here, we present results from geoelectrical prospection and a lithostratigraphic interpretation of this sequence supported by a detailed granulometric study supplemented by ostracod analysis. An age model based on luminescence dating is discussed against sedimentological proxy data and its implication for palaeoenvironmental change. The cores show a stratigraphy of lighter ochre‐coloured and darker greyish sediment, related to the deposition of clay and silt trapped in an aquatic environment. Geophysical measurements show ~20 m thick lacustrine sediments. The grain‐size distributions including the variability in fine clay are indicative of a lacustrine environment. Fine particles were brought into the depositional environments by aquatic input and settled from suspension; also, direct dust input is constrained by grain‐size results. Riverine input and aeolian dust input interplayed at the locality.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Program IDEI_Proiecte de Cercetare Exploratorie
    Description: Serbian Ministry of Education, Science and Technological Development
    Keywords: 551 ; 554 ; Carpathian Basin ; Late Quaternary ; lacustrine sediment ; geoelectric analyses ; luminescence dating ; grain‐size analysis ; environmental dynamics
    Type: article
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  • 5
    Publication Date: 2021-11-03
    Description: Stable organic carbon and nitrogen isotopes can be used to interpret past vegetation patterns and ecosystem qualities. Here we present these proxies for two loess-palaeosol sequences from the southern Carpathian Basin to reconstruct the palaeoenvironment during the past 350 ka and establish regional commonalities and differences. Until now, isotopic studies on loess sequences from this region were only conducted on deposits from the last glacial cycle. We conducted methodological tests concerning the complete decalcification of the samples prior to stable isotope analyses. Two decalcification methods (fumigation method and wet chemical acidification), different treatment times, and the reproducibility of carbon isotope analyses were tested. Obtained results indicate that the choice of the decalcification method is essential for organic carbon stable isotope analyses of loess-palaeosol sequences because ratios vary by more than 10‰ between the wet chemical and fumigation methods, due to incomplete carbonate removal by the latter. Therefore, we suggest avoiding the fumigation method for studies on loess-palaeosol sequences. In addition, our data show that samples with TOC content 〈0.2% bear increased potential for misinterpretation of their carbon isotope ratios. For our sites, C3-vegetation is predominant and no palaeoenvironmental shifts leading to a change of the dominant photosynthesis pathway can be detected during the Middle to Late Pleistocene. Furthermore, the potential for further stable nitrogen isotope studies is highlighted, since this proxy seems to reflect especially past precipitation patterns and reveals favourable conditions in the southern Carpathian Basin, especially during interstadials.
    Keywords: 551 ; southern Carpathian Basin ; loess-palaeosol sequences ; stable isotope analyses ; Pleistocene ecosystem reconstruction
    Language: English
    Type: map
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  • 6
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Kharbush, J. J., Close, H. G., Van Mooy, B. A. S., Arnosti, C., Smittenberg, R. H., Le Moigne, F. A. C., Mollenhauer, G., Scholz-Boettcher, B., Obreht, I., Koch, B. P., Becker, K. W., Iversen, M. H., & Mohr, W. Particulate organic carbon deconstructed: molecular and chemical composition of particulate organic carbon in the ocean. Frontiers in Marine Science, 7, (2020): 518, doi:10.3389/fmars.2020.00518.
    Description: The dynamics of the particulate organic carbon (POC) pool in the ocean are central to the marine carbon cycle. POC is the link between surface primary production, the deep ocean, and sediments. The rate at which POC is degraded in the dark ocean can impact atmospheric CO2 concentration. Therefore, a central focus of marine organic geochemistry studies is to improve our understanding of POC distribution, composition, and cycling. The last few decades have seen improvements in analytical techniques that have greatly expanded what we can measure, both in terms of organic compound structural diversity and isotopic composition, and complementary molecular omics studies. Here we provide a brief overview of the autochthonous, allochthonous, and anthropogenic components comprising POC in the ocean. In addition, we highlight key needs for future research that will enable us to more effectively connect diverse data sources and link the identity and structural diversity of POC to its sources and transformation processes.
    Description: We thank the Hanse Institute for Advanced Studies (HWK) and the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) project number 422798570, as well as the Geochemical Society, for funding which made the workshop possible. CA was additionally supported by OCE-1736772. BV was additionally supported by NSF OCE-1756254.
    Keywords: Marine particles ; Water column ; Phytoplankton ; Marine microbes ; Structural analysis ; Organic matter characterization ; Biomarkers
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 7
    Publication Date: 2024-04-29
    Description: The Last Interglacial (~129,000–116,000 years ago) is the most recent geologic period with a warmer-than-present climate. Proxy-based temperature reconstructions from this interval can help contextualize natural climate variability in our currently warming world, especially if they can define changes on decadal timescales. Here, we established a ~4.800-year-long record of sea surface temperature (SST) variability from the eastern Mediterranean Sea at 1–4-year resolution by applying mass spectrometry imaging of long-chain alkenones to a finely laminated organic-matter-rich sapropel deposited during the Last Interglacial. We observe the highest amplitude of decadal variability in the early stage of sapropel deposition, plausibly due to reduced vertical mixing of the highly stratified water column. With the subsequent reorganization of oceanographic conditions in the later stage of sapropel deposition, when SST forcing resembled the modern situation, we observe that the maximum amplitude of reconstructed decadal variability did not exceed the range of the recent period of warming climate. The more gradual, centennial SST trends reveal that the maximal centennial scale SST increase in our Last Interglacial record is below the projected temperature warming in the twenty-first century.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 8
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    In:  Supplement to: Zeeden, Christian; Hambach, Ulrich; Veres, Daniel; Fitzsimmons, Kathryn E; Obreht, Igor; Bösken, Janina; Lehmkuhl, Frank (2016): Millennial scale climate oscillations recorded in the Lower Danube loess over the last glacial period. Palaeogeography, Palaeoclimatology, Palaeoecology, https://doi.org/10.1016/j.palaeo.2016.12.029
    Publication Date: 2023-05-12
    Description: In this study we provide a correlative age model for last glacial loess at the Rasova-Valea cu Pietre site in the Lower Danube region, based on the correlation of palaeoenvironmental proxies to independently dated palaeoclimate archives, luminescence dating and independent age control provided by the geochemically confirmed presence of the Campanian Ignimbrite (CI) tephra. The CI tephra, originating in the Phlegrean fields of southern Italy, has been dated elsewhere by 40Ar/39Ar to 39?40 ka BP, and is frequently found in the Lower Danube loess. As such, the CI tephra represents a valuable temporal and stratigraphic maker across loess deposits in the region. Our age model facilitates high-resolution correlation of palaeoenvironmental features observed at Rasova to palaeoclimate archives in Greenland and the Black Sea ? Mediterranean area. We observe semi-cyclic behaviour of the frequency dependent magnetic susceptibility throughout the profile, which we ascribe to millennial-scale climate variability also observed elsewhere in the Black Sea region. This is the first study to clearly identify millennial-scale climate variability over the Holocene and last glacial in the Lower Danube loess. Proxy variability in the Holocene indicates continuous aeolian sedimentation through this epoch.
    Keywords: Danube, Romania, Europe; OUTCROP; Outcrop sample; Rasova_section
    Type: Dataset
    Format: application/zip, 2 datasets
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  • 9
    Publication Date: 2023-04-24
    Keywords: Aluminium oxide; Barium; Calcium oxide; Chromium; Copper; DEPTH, sediment/rock; Energy dispersive polarization X-ray fluorescence spectrometer (EDP-XRF); Gallium; Iron oxide, FeO; Lead; Magnesium oxide; Manganese oxide; Nickel; Niobium; Orlovat; OUTCROP; Outcrop sample; Phosphorus pentoxide; Potassium oxide; Rubidium; Serbia; Silicon dioxide; Sodium oxide; Strontium; Thorium; Titanium dioxide; Vanadium; Yttrium; Zinc; Zirconium
    Type: Dataset
    Format: text/tab-separated-values, 2208 data points
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  • 10
    Publication Date: 2023-04-24
    Keywords: Aluminium; Aluminium oxide; Barium/Strontium ratio; Calcium; Calcium oxide; Chloride; Chromium; DEPTH, sediment/rock; Hungary; Iron; Iron oxide, FeO; Magnesium; Magnesium oxide; Manganese; Manganese oxide; Phosphorus; Phosphorus pentoxide; Potassium; Potassium oxide; Ratio; Rubidium/Strontium ratio; Sagvar_S1; Silicon; Silicon dioxide; Sodium; Sodium oxide; SOIL; Soil profile; Sulfur, total; Titanium; Titanium dioxide; Vanadium
    Type: Dataset
    Format: text/tab-separated-values, 868 data points
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